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    Ethylene polymerization catalyst
    53.
    发明授权
    Ethylene polymerization catalyst 失效
    乙烯聚合催化剂

    公开(公告)号：US4810761A

    公开(公告)日：1989-03-07

    申请号：US32359

    申请日：1987-03-31

    申请人： Mary T. Zoeckler ,  Frederick J. Karol

    发明人： Mary T. Zoeckler ,  Frederick J. Karol

    IPC分类号： C08F4/60 ,  C08F4/64 ,  C08F4/68 ,  C08F10/02

    CPC分类号： C08F10/02

    摘要： A vanadium catalyst composition comprising:(i) the reaction product of a vanadium trihalide wherein the halogen is chlorine, bromine, or iodine, or mixtures thereof, and an electron donor, which is a liquid, organic Lewis base in which the vanadium trihalide is soluble;(ii) a silica support onto which component (i) is impregnated;(iii) a salt admixed with the silica support, the cation of said salt being selected from the group consisting of Groups I and II of the Periodic Chart of the Atoms;(v) a halocarbon promoter; and(v) a hydrocarbyl aluminum cocatalyst.

    Use of alkylaluminum compounds and hydroxyl-containing compounds to initiate polymerization of ethylene with chromium oxide catalysts
    54.
    发明授权
    Use of alkylaluminum compounds and hydroxyl-containing compounds to initiate polymerization of ethylene with chromium oxide catalysts 失效
    使用烷基铝化合物和含羟基的化合物引发乙烯与氧化铬催化剂的聚合

    公开(公告)号：US4564660A

    公开(公告)日：1986-01-14

    申请号：US509602

    申请日：1983-06-30

    申请人： Gary H. Williams ,  Frederick J. Karol

    发明人： Gary H. Williams ,  Frederick J. Karol

    IPC分类号： C08F4/62 ,  C08F2/34 ,  C08F4/60 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/02 ,  Y10S526/901 ,  Y10S526/912

    摘要： A method for smoothly and reliably initiating polymerization of ethylene with a supported chromium oxide catalyst, with smaller amounts of catalyst and in substantially shorter periods of time then heretofore required, by adding an alkylaluminum compound and a hydroxyl-containing compound to the reactor of a polymerization reaction system prior to the commencement of polymerization and subjecting said alkylaluminum compound and hydroxyl-containing compound to suitable conditions of temperature and pressure for a time sufficient for said alkylaluminum compound to react completely with the moisture present in said reactor and said hydroxyl-containing compound.

    摘要翻译： 通过在聚合反应器中加入烷基铝化合物和含羟基的化合物，平滑可靠地引发乙烯与负载的氧化铬催化剂的聚合，其用量较少的催化剂和在短的时间段内需要， 反应体系在聚合开始之前并且使所述烷基铝化合物和含羟基化合物在合适的温度和压力条件下持续足够的时间使所述烷基铝化合物与存在于所述反应器和所述含羟基化合物中的水分完全反应。

    Polymerization of ethylene with supported .pi. allyl chromium complexes
    55.
    发明授权
    Polymerization of ethylene with supported .pi. allyl chromium complexes 失效
    乙烯与负载的pi烯丙基铬络合物的聚合

    公开(公告)号：US4540758A

    公开(公告)日：1985-09-10

    申请号：US613233

    申请日：1975-09-15

    申请人： Robert N. Johnson ,  Frederick J. Karol

    发明人： Robert N. Johnson ,  Frederick J. Karol

    IPC分类号： C08F10/02 ,  C08F4/02

    CPC分类号： C08F10/02

    摘要： A process for the polymerization or copolymerization of an olefinically unsaturated monomer which comprises contacting the monomer with a chromium metal catalyst composition which is the product obtained by adsorbing a chromium metal complex which contains allyl hydrocarbon radicals with an inert inorganic oxide support which has --OH groups on its surface and which is free from adsorbed water, said monomer being an olefinically unsaturated monomer other than a polar vinyl monomer.

    摘要翻译： 一种烯属不饱和单体的聚合或共聚方法，其包括使单体与铬金属催化剂组合物接触，所述铬金属催化剂组合物是通过用具有-OH基团的惰性无机氧化物载体吸附含有烯丙基烃基的铬金属络合物获得的产物 在其表面上不含吸附水，所述单体是极性乙烯基单体以外的烯属不饱和单体。

    Catalyst composition for copolymerizing ethylene
    57.
    发明授权
    Catalyst composition for copolymerizing ethylene 失效
    乙烯共聚用催化剂组合物

    公开(公告)号：US4354009A

    公开(公告)日：1982-10-12

    申请号：US288336

    申请日：1981-07-30

    申请人： George L. Goeke ,  Burkhard E. Wagner ,  Frederick J. Karol

    发明人： George L. Goeke ,  Burkhard E. Wagner ,  Frederick J. Karol

    IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F210/16 ,  C08F10/02

    CPC分类号： C08F210/16 ,  Y10S526/901

    摘要： The copolymerization of ethylene with other alpha olefins in a low pressure gas phase reaction is improved with the use of a catalyst composition prepared by forming a precursor composition from a magnesium compound, titanium compound and electron donor compound; diluting said precursor composition with an inert carrier material; treating said diluted precursor composition with a hydrocarbyl aluminum dihalide compound; and activating the precursor composition treated in this manner with an organo aluminum compound.

    摘要翻译： 通过使用通过由镁化合物，钛化合物和电子给体化合物形成前体组合物制备的催化剂组合物，改善了在低压气相反应中乙烯与其它α烯烃的共聚合; 用惰性载体材料稀释所述前体组合物; 用二烃基二卤化铝化合物处理所述稀释的前体组合物; 并且用有机铝化合物活化以这种方式处理的前体组合物。

    Process for the preparation of high density ethylene polymers in fluid bed reactor
    58.
    发明授权
    Process for the preparation of high density ethylene polymers in fluid bed reactor 失效
    在流化床反应器中制备高密度乙烯聚合物的方法

    公开(公告)号：US4303771A

    公开(公告)日：1981-12-01

    申请号：US12712

    申请日：1979-02-16

    申请人： Burkhard E. Wagner ,  George L. Goeke ,  Frederick J. Karol

    发明人： Burkhard E. Wagner ,  George L. Goeke ,  Frederick J. Karol

    IPC分类号： C08F2/34 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/52

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F210/16

    摘要： A catalytic process for preparing ethylene polymers having a density of .gtoreq.0.94 to .ltoreq.0.97 and a melt flow ratio of about .gtoreq.22 to .ltoreq.32 in a low pressure gas phase process at a productivity of .gtoreq.50,000 pounds of polymer per pound of Ti with a catalyst formed from selected organoaluminum compounds and a precursor composition of the formulaMg.sub.m Ti.sub.1 (OR).sub.n X.sub.p (ED).sub.qwherein ED is a selected electron donor compoundm is .gtoreq.0.5 to .ltoreq.56n is 0, 1 or 2p is .gtoreq.2 to .ltoreq.116q is >1.5 m+2R is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, andX is selected from the group consisting ofCl, Br, I or mixtures thereof,which catalyst is in particulate form and impregnated in a porous inert carrier material.

    摘要翻译： 在低压气相方法中，制备密度> 0.94至0.97的乙烯聚合物和熔体流动比约> / = 22至 每磅钛的50,000磅聚合物与由选择的有机铝化合物形成的催化剂和式MgmTi1（OR）nXp（ED）q的前体组合物，其中ED为选定的电子给体化合物m为≥0.5至 56 n为0,1或2 p为> / = 2至 1.5 m + 2 R为C1至C14脂族或芳族烃基，或COR'，其中R'为C1至C14脂族 或芳族烃基，X选自Cl，Br，I或其混合物，该催化剂为颗粒形式并浸渍在多孔惰性载体材料中。

    Process for preparing olefin oxide polymerization catalysts by aging the catalysts
    59.
    发明授权
    Process for preparing olefin oxide polymerization catalysts by aging the catalysts 失效
    通过老化催化剂制备烯烃氧化物聚合催化剂的方法

    公开(公告)号：US4193892A

    公开(公告)日：1980-03-18

    申请号：US928974

    申请日：1978-07-28

    申请人： George L. Goeke ,  Frederick J. Karol

    发明人： George L. Goeke ,  Frederick J. Karol

    IPC分类号： C08G65/26 ,  C08G59/68 ,  C08G65/00

    CPC分类号： C08G65/2651 ,  C08G65/269

    摘要： In a process for the preparation of an olefin oxide polymerization catalyst comprising:(i) admixing calcium, ammonia, an alkylene oxide modifier, and an organic nitrile modifier, the alkylene oxide consisting of carbon, hydrogen, and oxirane oxygen atoms and the organic nitrile consisting of carbon, nitrogen, and hydrogen atoms, at least one hydrogen atom being acidic, to form a slurry of modified calcium hexammine in ammonia; and(ii) evaporating ammonia to provide a solid residue,the improvement comprising:aging the solid residue at a temperature in the range of about 150.degree. C. to about 225.degree. C.

    摘要翻译： 在制备烯烃氧化物聚合催化剂的方法中，包括：（i）混合钙，氨，烯化氧改性剂和有机腈改性剂，由碳，氢和环氧乙烷氧原子组成的烯化氧和有机腈 由碳，氮和氢原子组成，至少一个氢原子是酸性的，以在氨中形成改性的六羟基胺的浆料; 和（ii）蒸发氨以提供固体残留物，其改进包括：将固体残余物在约150℃至约225℃的温度下老化。