公开(公告)号：US20060079537A1

公开(公告)日：2006-04-13

申请号：US10531898

申请日：2003-11-14

申请人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A61K31/519 ,  C07D487/04

CPC分类号： C07D487/04 ,  A01N43/90

摘要： 2-Substituted triazolopyrimidines of the formula I, in which the substituents are as defined below: L are halogen, cyano, nitro, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, —C(═O)-A or S(═O)pA′; A and A′ are as defined in the description; p is 0, 1 or 2; m is 0, 1, 2, 3, 4 or 5; X is cyano, alkyl, haloalkyl, alkoxy or haloalkoxy; R1,R2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, alkadienyl, haloalkenyl, cycloalkenyl, alkynyl, haloalkynyl or cycloalkynyl, phenyl, naphthyl or a five- to ten-membered saturated, partially unsaturated or aromatic heterocycle which contains one to four heteroatoms from the group consisting of O, N and S, R1 and R2 together with the nitrogen atom to which they are attached may also form a five- or six-membered ring which may be interrupted by an atom from the group consisting of O, N and S, where R1 and/or R2 may be substituted as defined in the description; and R3 is cyano, hydroxyl, alkoxy, alkenyloxy, haloalkoxy, haloalkenyloxy, NR1R2 or S(O)nR31, where n and R31 are as defined in the description; Processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi are described.

摘要翻译： 氰基，硝基，烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基，烯氧基，炔氧基，卤代烷氧基，-C（ - O） - 取代的取代基如下： -A或S（-O） A'; A和A'如说明书所定义; p为0,1或2; m为0,1,2,3,4或5; X是氰基，烷基，卤代烷基，烷氧基或卤代烷氧基; R 1，R 2是氢，烷基，卤代烷基，环烷基，卤代环烷基，烯基，链二烯基，卤代烯基，环烯基，炔基，卤代炔基或环炔基，苯基，萘基或五 - 至十元饱和的，部分不饱和的或芳族杂环，其含有一至四个由O，N和S组成的组的杂原子，R 1和R 2连同 它们所连接的氮原子也可以形成可被来自O，N和S的原子间隔的五元或六元环，其中R 1和/或 R 2可以如说明书中定义的取代; 和R 3是氰基，羟基，烷氧基，烯氧基，卤代烷氧基，卤代烯氧基，NR 1 R 2或S（O）n 其中n和R 31如在说明书中所定义的; 描述了制备这些化合物的方法和中间体，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途。

公开(公告)号：US20050272749A1

公开(公告)日：2005-12-08

申请号：US10531981

申请日：2003-11-04

申请人： Jordi Tormo Blasco ,  Carsten Bletner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Tormo Blasco ,  Carsten Bletner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： C07D487/04 ,  A61K31/519

CPC分类号： C07D487/04

摘要： 5-Alkyl-7-aminotriazolopyrimidines of the formula I, where: R1, R2 are hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, cycloalkyl, phenyl, naphthyl; 5- or 6-membered saturated, unsaturated or aromatic heterocyclyl which contains one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; or R1 and R2 together with the bridging nitrogen atom can form a 5- or 6-membered ring which contains one to four nitrogen atoms or one to three nitrogen atoms and one sulfur or oxygen atom; R3 is cycloalkyl or bicycloalkyl; where R1, R2 and R3 may be substituted as outlined in the description; X is alkyl or haloalkyl; and their salts; processes and intermediates for their preparation, compositions comprising them and their use for controlling phytopathogenic harmful fungi are described.

摘要翻译： 式I的5-烷基-7-氨基三唑并嘧啶，其中：R 1，R 2是氢，烷基，烯基，炔基，卤代烷基，环烷基，苯基，萘基; 含有1-4个氮原子或一至三个氮原子和一个硫或氧原子的5-或6-元饱和，不饱和或芳族杂环基; 或R 1和R 2与桥连氮原子一起可以形成含有1-4个氮原子或一至三个氮原子的5-或6-元环，并且 一个硫或氧原子; R 3是环烷基或双环烷基; 其中R 1，R 2和R 3可以如说明书中概述的那样被取代; X是烷基或卤代烷基; 和它们的盐; 描述了其制备方法和中间体，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途。

公开(公告)号：US06562833B1

公开(公告)日：2003-05-13

申请号：US09701859

申请日：2000-12-05

申请人： Bernd Müller ,  Hubert Sauter ,  Herbert Bayer ,  Oliver Cullmann ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Arne Ptock ,  Norbert Götz ,  Thomas Grote ,  Michael Rack ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  John-Bryan Speakman

发明人： Bernd Müller ,  Hubert Sauter ,  Herbert Bayer ,  Oliver Cullmann ,  Markus Gewehr ,  Wassilios Grammenos ,  Andreas Gypser ,  Arne Ptock ,  Norbert Götz ,  Thomas Grote ,  Michael Rack ,  Eberhard Ammermann ,  Gisela Lorenz ,  Siegfried Strathmann ,  John-Bryan Speakman

IPC分类号： C07D23942

CPC分类号： C07D239/42 ,  A01N43/54

摘要： 2-(N-phenylamino)pyrimidines of the formula I, where: R1, R3 independently of one another are cyano, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or are C3-C8-cycloalkyl or a group C(═NORx)Ry R2 is halogen, C1-C8-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, where the radicals alkyl, alkenyl and alkynyl may be substituted by cyano, halogen, C1-C4-alkoxy or C1-C4-alkoxycarbonyl, or R1 and R2 together with the two linking carbon atoms form a fused-on partially unsaturated 4- to 8-membered ring which may be up to trisubstituted by identical or different substituents selected from the group consisting of C1-C4-alkyl, halogen and C1-C4-alkoxy-carbonyl, which may contain a carbonyl group and/or, in addition to the multiple bond of the pyrimidine ring, a double bond and/or which may be interrupted by O, S or N—(C1-C4-alkyl); the substituents R4 to R8, Rx, Ry, Ra and Rb are as defined in the description; are used as fungicides.

摘要翻译： 式I的2-（N-苯基氨基）嘧啶，其中：R 1，R 3彼此独立地是氰基，C 1 -C 8 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，其中基团烷基，烯基和 炔基可以被氰基，卤素，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基羰基取代，或者是C 3 -C 8 - 环烷基或C（= NOR x）R 1 R 2是卤素，C 1 -C 8烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基，其中基团烷基，烯基和炔基可以被氰基，卤素，C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷氧基羰基取代，或者R 1和R 2与两个连接碳原子一起形成稠合 - 部分不饱和的4-至8-元环，其可以由可以含有羰基的C 1 -C 4 - 烷基，卤素和C 1 -C 4 - 烷氧基 - 羰基的相同或不同取代基取代三取代， /或除了嘧啶环的多重键之外，可以被O，S或N-（C 1 -C 4 - 烷基）中断的双键和/或被中间的取代基取代基R4至R8，Rx，Ry，Ra 和Rb如t所定义 他的描述;被用作杀真菌剂。

公开(公告)号：US06482984B2

公开(公告)日：2002-11-19

申请号：US09760710

申请日：2001-01-17

申请人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Markus Gewehr ,  Jordi Tormo i Blasco ,  Arne Ptock ,  Bernd Müller ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz

发明人： Wassilios Grammenos ,  Hubert Sauter ,  Andreas Gypser ,  Markus Gewehr ,  Jordi Tormo i Blasco ,  Arne Ptock ,  Bernd Müller ,  Oliver Cullmann ,  Thomas Grote ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz

IPC分类号： C07C23305

CPC分类号： C07C251/48 ,  A01N37/50

摘要： Iminooxy-substituted benzyl phenyl ethers of the formula I in which the substituents and the index are as defined below: Y is H, CH3, F or Cl; Q is C(═CHOCH3)—COOCH3, C(═CHCH3)—COOCH3, C(═NOCH3)—COOCH3, C(═NOCH3)—CONHCH3 or N(—OCH3)—COOCH3; X is hydrogen, halogen, alkyl, alkoxy or CF3; m is 1 or 2, where the radicals X may be different if m=2; R1 is alkyl and R2 is hydrogen or alkyl; or R1 and R2 together are cyclopropyl, cyclopentyl or cyclohexyl; R3 is alkyl or CF3; and R4 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl or haloalkynyl; processes and intermediates for their preparation, compositions comprising them, and their use, are described.

摘要翻译： 取代基和指数如下定义的式Iin的亚氨氧基取代的苄基苯基醚：Y是H，CH 3，F或Cl; Q是C（= CHOCH 3）-COOCH 3，C（= CHCH 3）-COOCH 3，C （= NOCH 3）-COOCH 3，C（= NOCH 3）-CONHCH 3或N（-OCH 3）-COOCH 3; X是氢，卤素，烷基，烷氧基或CF 3; m是1或2，其中基团X可以不同，如果m = 2; R 1是烷基，R 2是氢或烷基; 或者R 1和R 2一起是环丙基，环戊基或环己基; R 3是烷基或CF 3; 和R 4是烷基，烯基，炔基，卤代烷基，卤代烯基或卤代炔基;其制备方法和中间体，包含它们的组合物及其用途。

公开(公告)号：US20120316062A1

公开(公告)日：2012-12-13

申请号：US13513323

申请日：2010-12-06

申请人： Markus Gewehr

发明人： Markus Gewehr

IPC分类号： A01N47/34 ,  A01N43/68 ,  A01N43/56 ,  A01N43/40 ,  A01N47/12 ,  A01N43/54 ,  A01N43/88 ,  A01P7/04 ,  A01P3/00 ,  A01C1/06 ,  A01N43/16

CPC分类号： A01N37/28 ,  A01N43/68 ,  A01N47/24 ,  A01N47/34 ,  A01N2300/00

摘要： The present invention relates to synergistic mixtures comprising, as active components, one insecticidal compound I selected from the group of insect growth regulators comprising chitin synthesis inhibitors, moulting disruptors and ecdysone receptor agonists; and one fungicidal compound II selected from the group of strobilurine fungicides in synergistic effective amounts.

摘要翻译： 本发明涉及包含作为活性组分的一种杀虫化合物I的协同混合物，所述杀虫化合物I选自包含甲壳素合成抑制剂，蜕皮破坏剂和蜕皮激素受体激动剂的昆虫生长调节剂组; 和一种杀菌化合物II，其选自组合有效量的嗜球果伞菌素杀真菌剂。

公开(公告)号：US20100041557A1

公开(公告)日：2010-02-18

申请号：US12530666

申请日：2008-03-14

申请人： Eike Hupe ,  Markus Gewehr ,  Peter Erk ,  Heidi Emilia Saxell ,  Ulrich Griesser ,  Michaela Tischler

发明人： Eike Hupe ,  Markus Gewehr ,  Peter Erk ,  Heidi Emilia Saxell ,  Ulrich Griesser ,  Michaela Tischler

IPC分类号： A01N35/00 ,  C07C317/14 ,  A01P13/00

CPC分类号： C07C317/24 ,  A01N41/10

摘要： The present invention relates to two crystalline forms of 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoro-ethoxymethyl)benzoyl]cyclohexan-1,3-dione, which is also known under the common name tembotrione. The invention also relates to a process for the production of these crystalline forms and formulations for plant protection which contain one of these crystalline forms of tembotrione.

摘要翻译： 本发明涉及2- [2-氯-4-甲基磺酰基-3-（2,2,2-三氟 - 乙氧基甲基）苯甲酰基]环己烷-1,3-二酮的两种结晶形式，其也是常见的 名字tembotrione 本发明还涉及一种用于生产这些结晶形式的方法和用于植物保护的制剂，其含有这些晶体形式的一种。

公开(公告)号：US20090233795A1

公开(公告)日：2009-09-17

申请号：US11922728

申请日：2006-06-30

申请人： Jochen Dietz ,  Markus Gewehr ,  Siegfried Strathmann ,  Reinhard Stierl ,  Frank Werner ,  Maria Scherer

发明人： Jochen Dietz ,  Markus Gewehr ,  Siegfried Strathmann ,  Reinhard Stierl ,  Frank Werner ,  Maria Scherer

IPC分类号： A01N25/26 ,  A01N43/88 ,  A01N43/84 ,  A01N43/90 ,  A01N43/653 ,  A01N43/50 ,  A01N43/56 ,  A01P3/00

CPC分类号： A01N43/56 ,  A01N43/90 ,  A01N43/653 ,  A01N47/24 ,  A01N37/38 ,  A01N35/04 ,  A01N47/38 ,  A01N47/14 ,  A01N2300/00

摘要： Fungicidal mixtures comprising, as active components, 1) at least one 3-mono disubstituted N-biphenylpyrazolecarboxamide of the formula I in which X=oxygen or sulfur; R1=cyano, nitro, halogen, C1-C6-alkyl, C1-C6-haloalkyl, methoxy, difluoromethoxy, trifluoromethoxy, methylthio, difluoromethylthio or trifluoromethylthio; R2=halogen, C1-C4-alkyl or C1-C4-haloalkyl; R3=hydrogen or halogen; and 2) at least one active compound II selected from active compound groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II, the use of the compound(s) I with active compounds II for preparing such mixtures and also compositions and seed comprising these mixtures.

摘要翻译： 作为活性组分的杀真菌混合物，1）至少一种其中X =氧或硫的式I的3-单二取代的N-联苯基吡唑甲酰胺; R1 =氰基，硝基，卤素，C1-C6-烷基，C1-C6-卤代烷基，甲氧基，二氟甲氧基，三氟甲氧基，甲硫基，二氟甲硫基或三氟甲硫基; R2 =卤素，C1-C4-烷基或C1-C4卤代烷基; R3 =氢或卤素; 和2）选自活性化合物基团A）至F）的至少一种活性化合物II：A）唑类; B）嗜球果伞素 C）甲酰胺; D）杂环化合物; E）氨基甲酸酯; F）其他杀菌剂; 协同有效量的方法，使用至少一种化合物I和至少一种活性化合物II的混合物控制有害真菌的方法，化合物I与活性化合物II用于制备此类混合物的用途，以及组合物和种子，包括 这些混合物。

公开(公告)号：US20090123561A1

公开(公告)日：2009-05-14

申请号：US11988660

申请日：2006-07-13

申请人： Markus Gewehr ,  Reinhard Stierl ,  Jochen Dietz ,  Bernd Muller ,  Maria Scherer ,  Siegfriend Strathmann ,  Frank Werner ,  Michael Vonend

发明人： Markus Gewehr ,  Reinhard Stierl ,  Jochen Dietz ,  Bernd Muller ,  Maria Scherer ,  Siegfriend Strathmann ,  Frank Werner ,  Michael Vonend

IPC分类号： A01N43/90 ,  A01N59/26 ,  A01P3/00

CPC分类号： A01N43/56 ,  A01N47/14 ,  A01N37/34 ,  A01N43/653 ,  A01N37/50 ,  A01N47/24 ,  A01N43/54 ,  A01N35/04 ,  A01N47/38 ,  A01N37/38 ,  A01N2300/00

摘要： Fungicidal mixtures, comprising as active components 1) 1-methylpyrazol-4-ylcarboxanilides I in which X=oxygen or sulfur, R1=halogen, C1-C4-alkyl or C1-C4-haloalkyl, R2═H or halogen and R3=nitro, cyano, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy or C1-C4-alkylthio and 2) at least one active compound II, selected from the active compound groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II and the use of the compound(s) I with active compounds II for preparing such mixtures, and also compositions and seed comprising such mixtures.

摘要翻译： 包含作为活性组分的杀真菌混合物1）1-甲基吡唑-4-基甲酰苯胺I，其中X =氧或硫，R1 =卤素，C1-C4-烷基或C1-C4卤代烷基，R2-H或卤素，R3 =硝基 氰基，卤素，C 1 -C 4 - 烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基或C 1 -C 4 - 烷硫基，和2）至少一种活性化合物II， A）至F）：A）唑类; B）嗜球果伞素 C）甲酰胺; D）杂环化合物; E）氨基甲酸酯; F）其他杀菌剂; 协同有效量的方法，使用至少一种化合物I和至少一种活性化合物II的混合物来控制有害真菌，以及使用化合物I与活性化合物II制备这种混合物，以及组合物和种子 包括这样的混合物。

公开(公告)号：US20090042724A1

公开(公告)日：2009-02-12

申请号：US11921772

申请日：2006-06-28

申请人： Jochen Dietz ,  Markus Gewehr ,  Siegfried Strathmann ,  Reinhard Stierl ,  Frank Werner ,  Maria Scherer

发明人： Jochen Dietz ,  Markus Gewehr ,  Siegfried Strathmann ,  Reinhard Stierl ,  Frank Werner ,  Maria Scherer

IPC分类号： A01C1/06 ,  A01N43/84 ,  A01N43/50 ,  A01N43/653

CPC分类号： A01N43/56 ,  A01N2300/00

摘要： The present invention relates to fungicidal mixtures comprising, as active components,1) at least one 2,4-disubstituted N-biphenylpyrazolecarboxamide of the formula I in which X=oxygen or sulfur; R1 and R2=independently of one another cyano, nitro, halogen, C1-C6-alkyl, C1-C6-haloalkyl, methoxy, difluoromethoxy or trifluoromethoxy; R3=halogen, C1-C4-alkyl or C1-C4-haloalkyl; R4=hydrogen or halogen; and 2) at least one active compound II selected from groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using mixtures of at least one compound I and at least one active compound II, the use of the compounds I with active compounds II for preparing such mixtures and also compositions and seed comprising these mixtures.

摘要翻译： 本发明涉及杀真菌混合物，其包含作为活性组分的1）至少一种其中X =氧或硫的式I的2,4-二取代N-联苯基吡唑甲酰胺; R 1和R 2彼此独立地是氰基，硝基，卤素，C 1 -C 6 - 烷基，C 1 -C 6卤代烷基，甲氧基，二氟甲氧基或三氟甲氧基; R3 =卤素，C1-C4-烷基或C1-C4卤代烷基; R4 =氢或卤素; 和2）选自A）至F）的至少一种活性化合物II：A）唑类; B）嗜球果伞素 C）甲酰胺; D）杂环化合物; E）氨基甲酸酯; F）其他杀菌剂; 协同有效量的方法，使用至少一种化合物I和至少一种活性化合物II的混合物来控制有害真菌，使用化合物I与活性化合物II制备这种混合物，以及组合物和种子包含这些混合物。

公开(公告)号：US20090036305A1

公开(公告)日：2009-02-05

申请号：US11919588

申请日：2006-05-10

申请人： Markus Gewehr ,  Jochen Dietz ,  Thomas Grote ,  Wassilios Gremmenos ,  Udo Hunger ,  Bernd Muller ,  Frank Schieweck ,  Anja Schwogler ,  Jan Klaas Lohmann ,  Joachim Rheinheimer ,  Jens Renner ,  Peter Schafer

发明人： Markus Gewehr ,  Jochen Dietz ,  Thomas Grote ,  Wassilios Gremmenos ,  Udo Hunger ,  Bernd Muller ,  Frank Schieweck ,  Anja Schwogler ,  Jan Klaas Lohmann ,  Joachim Rheinheimer ,  Jens Renner ,  Peter Schafer

IPC分类号： A01N43/56 ,  C07D231/14 ,  A01P3/00

CPC分类号： A01N43/56 ,  C07D231/14

摘要： The present invention relates to pyrazolecarboxamides of the formula I in which the variables are as defined below: X is trifluoromethyl; R1 is F, Cl, Br, C1-C4-alkyl or C1-C4-haloalkyl; R2 is hydrogen, halogen or C1-C4-alkyl; R3 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-alkynyl or C3-C6-cycloalkyl; W is O or S; with the proviso that, if R3 is hydrogen and W is oxygen, a) R1 and R2 are not simultaneously methyl and F, respectively; b) R1 and R2 are not simultaneously trifluoromethyl and hydrogen or fluorine, respectively. to processes for preparing these compounds, to seeds and compositions comprising them and to methods for controlling harmful fungi.

摘要翻译： 本发明涉及式I的吡唑酰胺，其中变量如下所定义：X是三氟甲基; R1是F，Cl，Br，C1-C4-烷基或C1-C4卤代烷基; R2是氢，卤素或C1-C4-烷基; R 3是氢，C 1 -C 4 - 烷基，C 1 -C 4卤代烷基，C 2 -C 4 - 烯基，C 2 -C 4 - 炔基或C 3 -C 6 - 环烷基; W为O或S; 条件是，如果R3是氢并且W是氧，则a）R1和R2分别不同时为甲基和F; b）R1和R2分别不同时为三氟甲基和氢或氟。 制备这些化合物的方法，包括它们的种子和组合物以及用于控制有害真菌的方法。