公开(公告)号：US06837381B2

公开(公告)日：2005-01-04

申请号：US10002549

申请日：2001-11-02

申请人： Masahiko Hirose

发明人： Masahiko Hirose

IPC分类号： B01D69/12 ,  B01D71/38 ,  B01D71/56 ,  B01D71/60

CPC分类号： B01D71/38 ,  B01D69/125 ,  B01D71/56 ,  B01D71/60

摘要： The present invention provides a composite reverse osmosis membrane as a polyamide membrane including a side chain amino group such as a residue of a polyvinyl alcohol-based amine compound represented by Formula 1. Such a membrane can remove organic impurities under a low pressure, providing an economical method for removal of impurities. An aqueous solution including a polyvinyl alcohol-based amine compound having a side chain amino group represented by Formula 1 is applied on a polysulfone-based ultrafiltration membrane as a microporous support. Next, trimesic acid chloride solution is applied causing interfacial polycondensation, which generates a reverse osmosis membrane. When this composite reverse osmosis membrane is evaluated by using a pH 6.5 aqueous solution including 500 mg/l of sodium chloride at an operation pressure of 5 kg/cm2 and at a temperature of 25° C., the permeable flux is at least 1.5 m3/m2·d, and the salt rejection is 80% or less. wherein 0

摘要翻译： 本发明提供作为聚酰胺膜的复合反渗透膜，其包含侧链氨基，例如由式1表示的聚乙烯醇类胺化合物的残基。这种膜可以在低压下除去有机杂质，提供 经济的去除杂质的方法。 将作为微孔载体的聚砜系超滤膜涂布在具有由式1表示的侧链氨基的聚乙烯醇系胺化合物的水溶液中。 接下来，施加均苯三酰氯溶液引起界面缩聚，产生反渗透膜。 当通过在5kg / cm 2的操作压力和25℃的温度下使用包含500mg / l氯化钠的pH 6.5水溶液评价该复合反渗透膜时，渗透通量为 至少1.5m 3 / m 2 .d，并且盐排斥率为80％以下。在0

公开(公告)号：US06805796B2

公开(公告)日：2004-10-19

申请号：US09782339

申请日：2001-02-13

申请人： Masahiko Hirose ,  Atsushi Hiro ,  Mark Wilf

发明人： Masahiko Hirose ,  Atsushi Hiro ,  Mark Wilf

IPC分类号： B01D6310

CPC分类号： B01D61/022 ,  C02F1/441

摘要： A water treatment apparatus according to the present invention includes a plurality of composite reverse osmosis membrane modules arranged in multi-stages, each of the modules including a porous support and a polyamide skin layer formed on the porous support. In this apparatus, the module at the final stage is supplied with some of permeated water obtained from at least one module preceding the module at the final-stage, and a rest of the permeated water is discharged from or recovered in the apparatus along with permeated water obtained from the final-stage module.

摘要翻译： 根据本发明的水处理装置包括多级布置的多个复合反渗透膜模块，每个模块包括多孔载体和形成在多孔载体上的聚酰胺表层。 在该装置中，最终阶段的模块被供给在最后阶段从模块之前的至少一个模块获得的一些渗透水，并且其余的渗透水与渗透的装置一起从设备中排出或回收 从最后一级模块获得的水。

公开(公告)号：US5989426A

公开(公告)日：1999-11-23

申请号：US677322

申请日：1996-07-02

申请人： Masahiko Hirose ,  Hiroki Ito ,  Kazuo Tanaka

发明人： Masahiko Hirose ,  Hiroki Ito ,  Kazuo Tanaka

IPC分类号： B01D61/02 ,  B01D67/00 ,  B01D69/00 ,  B01D69/12 ,  B01D29/00 ,  B01D63/00 ,  B01D61/00

CPC分类号： B01D67/0088 ,  B01D61/022 ,  B01D69/00 ,  B01D69/12 ,  B01D69/125

摘要： A composite reverse osmosis membrane has a polyamide type skin layer whose specific surface area ranges from 3 to 1000. The composite reverse osmosis membrane of this invention is superior in the salt rejection property and water permeability. The composite reverse osmosis membrane comprises a negatively-charged crosslinked polyamide type skin layer obtained by reacting a compound having polyfunctional amino groups and a polyfunctional acid halide compound having polyfunctional acid halide groups, and a microporous support to support the skin layer. The specific surface area of the skin layer is at least 3. A first stage of reverse osmosis treatment is carried out in a membrane module using this composite reverse osmosis membrane. The skin layer can be coated with a layer of an organic polymer having positively-charged groups e.g. polyethyleneimine in order to be used as another membrane module. The organic polymer of this case is crosslinked, for example, by glutaraldehyde. The layer which is crosslink-coated on its surface area is a composite reverse osmosis membrane excellent in desalination of mineral salt in a low-concentration region and removal of cationic organic materials.

摘要翻译： 复合反渗透膜具有比表面积为3〜1000的聚酰胺型表皮层。本发明的复合反渗透膜的耐盐析性和透水性优异。 复合反渗透膜包括通过使具有多官能氨基的化合物和具有多官能酰卤基团的多官能酰卤化合物和微孔载体反应获得的带负电荷的交联聚酰胺型表皮层，以支撑皮肤层。 表皮层的比表面积为至少3.在使用该复合反渗透膜的膜组件中进行第一阶段的反渗透处理。 表皮层可以涂覆有一层具有带正电荷的基团的有机聚合物，例如， 聚乙烯亚胺以便用作另一个膜组件。 这种情况下的有机聚合物例如用戊二醛交联。 在其表面积上交联涂层是在低浓度区域脱盐矿物盐和去除阳离子有机物质的复合反渗透膜。

公开(公告)号：US5336409A

公开(公告)日：1994-08-09

申请号：US7763

申请日：1993-01-22

申请人： Hisao Hachisuka ,  Katsuhide Kojima ,  Yutaka Nakazono ,  Mitsuru Shimizu ,  Masahiko Hirose ,  Yasuo Kihara ,  Masatoshi Maeda ,  Hisashi Ikebata ,  Kenji Matsumoto

发明人： Hisao Hachisuka ,  Katsuhide Kojima ,  Yutaka Nakazono ,  Mitsuru Shimizu ,  Masahiko Hirose ,  Yasuo Kihara ,  Masatoshi Maeda ,  Hisashi Ikebata ,  Kenji Matsumoto

IPC分类号： B01D69/12 ,  B01D71/56 ,  C07C61/29 ,  C08G69/26

CPC分类号： C07C61/29 ,  B01D69/125 ,  B01D71/56 ,  C08G69/26

摘要： A composite reverse osmosis membrane comprising a thin membrane and a microporous supporting membrane supporting it, wherein said thin membrane mainly comprises a crosslinked polyamide comprising; (a) an amine component containing at least one member selected from the group consisting of substantially monomeric amine compounds each having at least two primary and/or secondary amino groups, and (b) an acid halide component containing at least one member selected from the group consisting of substantially monomeric cyclic acid halide compounds each having at least two acid halide groups and comprising at least two rings.

摘要翻译： 一种复合反渗透膜，包括薄膜和支撑其的微孔支撑膜，其中所述薄膜主要包含交联聚酰胺，其包含： （a）含有至少一种选自基本上单体的胺化合物的胺成分，所述基本上单体胺化合物各自具有至少两个伯和/或仲氨基，和（b）含有至少一种选自 由基本上单体的环状酰卤化合物组成，每个化合物具有至少两个酰卤基并且包含至少两个环。

公开(公告)号：US4634635A

公开(公告)日：1987-01-06

申请号：US655223

申请日：1984-09-27

申请人： Yasuhisa Shiraishi ,  Takashi Fujita ,  Yoshiharu Ochi ,  Masahiko Hirose ,  Katsutarou Ichihara ,  Takashi Ishigami

发明人： Yasuhisa Shiraishi ,  Takashi Fujita ,  Yoshiharu Ochi ,  Masahiko Hirose ,  Katsutarou Ichihara ,  Takashi Ishigami

IPC分类号： B44C1/04 ,  B44C1/00 ,  B44F1/08 ,  C23C16/32 ,  G02C5/00 ,  G04B37/22 ,  B32B13/04

CPC分类号： B44F1/08 ,  C23C16/325 ,  G04B37/221

摘要： An ornament coated with silicon carbide having black luster which has been formed by chemical vapor deposition aided by D.C. glow discharge using hydrogen, a silicon compound and a hydrocarbon.The black ornament according to the present invention is very suitable for a case of a watch, a frame of eyeglasses and so on.

摘要翻译： 通过化学气相沉积形成的具有黑色光泽的碳化硅的装饰物，其通过使用氢，硅化合物和烃的直流辉光放电辅助形成。 根据本发明的黑色装饰品非常适用于手表，眼镜架等的情况。

公开(公告)号：US4339326A

公开(公告)日：1982-07-13

申请号：US208404

申请日：1980-11-19

申请人： Masahiko Hirose ,  Tsuyoshi Yasui ,  Masahiko Yotuyanagi

发明人： Masahiko Hirose ,  Tsuyoshi Yasui ,  Masahiko Yotuyanagi

IPC分类号： B01J19/08 ,  C23C8/36 ,  C23C16/50 ,  H05H1/46 ,  C23C15/00 ,  C23F1/00

CPC分类号： C23C16/50 ,  C23C8/36 ,  H05H1/46

摘要： There is provided an apparatus for processing a surface of an object to be processed by utilizing microwave plasma within a plasma-producing chamber, which comprises a microwave power-generating means; a wave guide for transmitting microwaves generated from said microwave power-generating means; a closed vessel constituting the plasma-producing chamber separated from said wave guide by a separating means; an antenna for transmitting microwaves, one end thereof protruding into the wave guide and another end thereof protruding into the closed vessel and a supporting means, for holding or supporting the electroconductive object to be processed, provided within the closed vessel and so attached to the antenna that the antenna and the electroconductive object may be electrically connected to each other.

摘要翻译： 提供了一种用于通过在等离子体产生室内利用微波等离子体来处理被处理物体的表面的装置，其包括微波发生装置; 用于发送从所述微波发电装置产生的微波的波导; 构成等离子体产生室的封闭容器通过分离装置与所述波导分离; 用于传输微波的天线，其一端突出到波导管中，另一端突出到密闭容器中，支撑装置用于保持或支撑待加工的导电物体，设置在密封容器内并附着在天线上 天线和导电物体可以彼此电连接。