摘要:
A composition comprises a polymer having a first pendant group selected from at least one perfluorinated ether group or perfluoroalkanesulfonamido group, a second pendant group comprising an ammonium group, wherein the second pendant group is free of silicon, and a third pendant group comprising an ammonium group and a reactive silicon-containing group. The polymer and composition are useful for protecting a substrate, for example, to render the substrate oil repellent, water repellent, or both, or to provide stain repellency to the substrate.
摘要:
Fluorinated polymers having first divalent units represented by formula, and a plurality of groups of formula —CH2—CH2—O—. Compositions containing the fluorinated polymer and solvent, and methods of treating hydrocarbon-bearing formations using these compositions are disclosed. A method of making a composition containing the fluorinated polymer is also disclosed.
摘要:
Compositions comprising cationic compounds having fluorinated ether groups and hydrolyzable silane groups are provided, the compounds having the formula: (I)
摘要:
An easy-to-clean article with a stainless steel surface treated with a mixture of a fluorinated composition and a first compound. The fluorinated composition comprises a polyfluoropolyether group and a hydrolysable silane group. The first compound comprises an amino group, an epoxy group, or a mercapto group and a hydrolysable silane group. A method of treating a stainless steel surface with the mixture is also disclosed.
摘要:
The invention relates to grout powder for admixture with water to produce grout. The grout powder comprises cement powder and is characterized in that the grout powder has been mixed with a fluorochemical compound. The present invention further relates to a method of preparing grout powder for admixture with water to produce grout, comprising mixing grout powder comprising cement powder with a fluorochemical compound. Still further, the invention relates to an alternative method for making the grout powder, which method comprises treating at least one of the components of the grout powder with a fluorochemical compound.
摘要:
Fluorinated surfactants having a weight average molecular weight in a range from 1200 to 10000 grams per mole, wherein the fluorinated surfactant comprises at least one component represented by formula or a salt thereof, wherein: R is H, —CH3, or —CH2CO2H; and m is an integer having a value from 0 to 11. Z is a divalent segment consisting of copolymerized units of perfluoroalkanesulfonamidoalkyl (meth)acrylate and at least one of (meth)acrylic acid, β-carboxyethyl (meth)acrylic acid, or itaconic acid. The molar ratio of perfluoroalkanesulfonamidoalkyl to carboxylic acid groups in the fluorinated surfactant has a value from 0.5 to 3. Methods of making the fluorinated surfactants are also disclosed.
摘要翻译:重均分子量为1200〜10000克/摩尔的氟化表面活性剂,其中氟化表面活性剂包含至少一种由式或其盐表示的组分,其中:R为H,-CH 3或-CH 2 CO 2 H; m为0〜11的整数。Z为由(甲基)丙烯酸全氟烷基磺酰氨基烷基酯和(甲基)丙烯酸,(甲基)丙烯酸羧基乙酯,(甲基)丙烯酸等至少一种共聚单元构成的二价链段 衣康酸。 氟化表面活性剂中全氟烷基磺酰胺基烷基与羧酸基团的摩尔比为0.5-3。还公开了制备氟化表面活性剂的方法。
摘要:
The present invention provides a curable composition for use in retarding the formation of biofilms. The curable composition comprises a polymer derived from ethylenically unsaturated units having pendent long-chain aliphatic groups; ethylenically unsaturated units having pendent poly(oxyalkylene) groups; and ethylenically unsaturated units having pendent substrate-reactive groups; and a crosslinking agent.
摘要:
Perfluoro lower alkanesulfonamide-derived silanes which in an organic solvent are useful in treating siliceous substrates are described. The compositions may optionally contain an additional non-fluorinated compound in a mixture or condensation product. Methods for preparing perfluoro lower alkanesulfonamide-derived silanes are also described.
摘要:
Fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain or soil repellent. The composition comprises a dispersion or a solution of a fluorinated compound which comprises the reaction product of the following combination of reactants: (i) a fluorinated polyether according to the formula: Rf—Q—Tk (I) wherein Rf represents a monovalent perfluorinated polyether group having a molecular weight of at least 750 g/mol, Q represents a chemical bond or a divalent or trivalent organic linking group, T represents a functional group capable of reacting with an isocyanate and k is 1 or 2; (ii) an isocyanate component selected from a polyisocyanate compound that has at least 3 isocyanate groups or a mixture of polyisocyanate compounds wherein the average number of isocyanate groups per molecule is more than 2; and (iii) optionally one or more co-reactants capable of reacting with an isocyanate group.
摘要:
The present invention provides the use of a fluorinated polyether composition as a surfactant, said fluorinated polyether composition comprising a mixture of fluorinated polyethers of the formula: (Rf)n—Xw—Z (I) wherein n is 1 or 2, w is 0 or 1, X is a divalent or trivalent organic linking group, Z is a polar group selected from the group consisting of an acid group or a salt thereof, an ammonium group, an amine-oxide group and an amphoteric group, and Rf represents a perfluorinated polyether group of the formula: CF3CF2CF2—O—[CF(CF3)CF2O]k—CF(CF3)— wherein k is at least 1; said mixture of fluorinated polyethers having a weight average molecular weight between 750 g/mol and 5000 g/mol and the amount of perfluorinated polyether groups in said mixture where k is 2 or less, is not more than 10% by weight of the total amount of perfluorinated polyether groups in said mixture.