公开(公告)号：US09076973B2

公开(公告)日：2015-07-07

申请号：US13968551

申请日：2013-08-16

Applicant: Universal Display Corporation

Inventor： Chuanjun Xia ,  Bert Alleyne ,  Raymond C. Kwong ,  James Fiordeliso ,  Michael S. Weaver ,  Nasrin Ansari ,  Alan DeAngelis ,  Dinesh Rayabarapu ,  Vadim Adamovich

IPC: H01L35/24 ,  H01L51/00 ,  C07F15/00 ,  C09K11/06 ,  H05B33/14 ,  H01L51/50

CPC classification number: H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1059 ,  C09K2211/1066 ,  C09K2211/1074 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0054 ,  H01L51/006 ,  H01L51/0074 ,  H01L51/0081 ,  H01L51/5016 ,  H05B33/14

Abstract: Novel organic compounds containing a twisted aryl group are provided. In particular, the compounds provided contain a 2-phenylpyridine ligand having a twisted aryl group on the pyridine portion of the ligand. The compounds may be used in organic light emitting devices, particularly as emitting dopants. Devices comprising the compounds containing twisted aryl may demonstrate improved color, efficiency, stability and manufacturing. Additionally, methods are provided for making homoleptic Ir (III) compounds which may contain a twisted aryl.

Abstract translation: 提供含有扭曲芳基的新型有机化合物。 特别地，所提供的化合物含有在配体的吡啶部分上具有扭曲的芳基的2-苯基吡啶配体。 这些化合物可以用于有机发光器件，特别是用作发射掺杂剂。 包含含有扭曲芳基的化合物的装置可以显示改进的颜色，效率，稳定性和制造。 另外，提供了用于制备可含有扭曲芳基的同质Ir（III）化合物的方法。

公开(公告)号：US20250133952A1

公开(公告)日：2025-04-24

申请号：US18978831

申请日：2024-12-12

Applicant: UNIVERSAL DISPLAY CORPORATION

Inventor： Pierre-Luc T. Boudreault ,  Alexey Dyatkin ,  David Zenan Li ,  Scott Joseph ,  Chuanjun Xia ,  Hitoshi Yamamoto ,  Michael S. Weaver ,  Bert Alleyne ,  James Fiordeliso

IPC: H10K85/30 ,  C07F15/00 ,  C09K11/06 ,  H10K50/11 ,  H10K50/15 ,  H10K50/16 ,  H10K50/17 ,  H10K50/18 ,  H10K50/81 ,  H10K50/82 ,  H10K101/10

Abstract: A compound having an ancillary ligand L1 having the formula: Formula I is disclosed. The ligand L1 is coordinated to a metal M having an atomic number greater than 40, and two adjacent substituents are optionally joined to form into a ring. Such compound is suitable for use as emitters in organic light emitting devices.

公开(公告)号：US12274157B2

公开(公告)日：2025-04-08

申请号：US18497730

申请日：2023-10-30

Applicant: Universal Display Corporation

Inventor： Eric A. Margulies ,  Zhiqiang Ji ,  Jui-Yi Tsai ,  Chun Lin ,  Alexey Borisovich Dyatkin ,  Mingjuan Su ,  Bin Ma ,  Michael S. Weaver ,  Julia J. Brown ,  Lichang Zeng ,  Walter Yeager ,  Alan Deangelis ,  Chuanjun Xia

IPC: C07F13/00 ,  C07F15/00 ,  C09K11/06 ,  H10K85/30 ,  H10K50/11 ,  H10K50/81 ,  H10K50/82 ,  H10K101/10

Abstract: A compound is disclosed that has a metal coordination complex structure having at least two ligands coordinated to the metal; wherein the compound has a first substituent R1 at one of the ligands' periphery; wherein a first distance is defined as the distance between the metal and one of the atoms in R1 where that atom is the farthest away from the metal among the atoms in R1; wherein the first distance is also longer than any other atom-to-metal distance between the metal and any other atoms in the compound; and wherein when a sphere having a radius r is defined whose center is at the metal and the radius r is the smallest radius that will allow the sphere to enclose all atoms in the compound that are not part of R1, the first distance is longer than the radius r by at least 2.9 Å.

公开(公告)号：US12127470B2

公开(公告)日：2024-10-22

申请号：US17946129

申请日：2022-09-16

Applicant: Universal Display Corporation

Inventor： Chuanjun Xia ,  Bert Alleyne ,  Raymond C. Kwong ,  James Fiordeliso ,  Michael S. Weaver ,  Nasrin Ansari ,  Alan Deangelis ,  Dinesh Rayabarapu ,  Vadim Adamovich

IPC: C07F15/00 ,  C09K11/06 ,  H01L51/50 ,  H05B33/14 ,  H10K85/30 ,  H10K50/11 ,  H10K85/60 ,  H10K101/10

CPC classification number: H10K85/342 ,  C07F15/0033 ,  C09K11/06 ,  H05B33/14 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1059 ,  C09K2211/1066 ,  C09K2211/1074 ,  C09K2211/1092 ,  C09K2211/185 ,  H10K50/11 ,  H10K85/324 ,  H10K85/622 ,  H10K85/633 ,  H10K85/6576 ,  H10K2101/10

Abstract: A compound of:




is disclosed. In Formula III, ring B and ring C are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; A-B represents a bonded pair of carbocyclic or heterocyclic rings coordinated to a metal M via a nitrogen atom in ring A and an sp2 hybridized atom in ring B; A-C represents a bonded pair of carbocyclic or heterocyclic rings; M is a metal having an atomic number greater than 40; L′ is a monoanionic bidentate ligand; m is the oxidation state of the metal M; and n is at least 1.

公开(公告)号：US20240306409A1

公开(公告)日：2024-09-12

申请号：US18650802

申请日：2024-04-30

Applicant: UNIVERSAL DISPLAY CORPORATION

Inventor： Chun LIN ,  Tyler Fleetham ,  Michael S. Weaver

IPC: H10K50/11 ,  H10K101/00 ,  H10K101/10

CPC classification number: H10K50/11 ,  H10K2101/10 ,  H10K2101/27

Abstract: Provided is an OLED that includes in its emissive region a first compound, a second compound, and a third compound, where the first compound is capable of functioning as a phosphorescent emitter in an OLED at room temperature, the second compound meets at least one of the following conditions:



(1) the second compound is capable of functioning as a TADF emitter in an OLED at room temperature; and
(2) the second compound is capable of forming an exciplex with the first compound in an OLED at room temperature, and the third compound is a fluorescent compound that functions as an emitter in the OLED of the present disclosure at room temperature.

公开(公告)号：US20240057374A1

公开(公告)日：2024-02-15

申请号：US18381684

申请日：2023-10-19

Applicant: Universal Display Corporation

Inventor： Nicholas J. Thompson ,  Marc A. Baldo ,  Michael S. Weaver ,  Vinod M. Menon

IPC: H10K50/85 ,  H10K50/13 ,  H10K50/805 ,  H10K50/828

CPC classification number: H10K50/85 ,  H10K50/131 ,  H10K50/805 ,  H10K50/828 ,  H10K50/822

Abstract: An OLED is disclosed that includes an enhancement layer having optically active metamaterials, or hyperbolic metamaterials, which transfer radiative energy from the organic emissive material to a non-radiative mode, wherein the enhancement layer is disposed over the organic emissive layer opposite from the first electrode, and is positioned no more than a threshold distance away from the organic emissive layer, wherein the organic emissive material has a total non-radiative decay rate constant and a total radiative decay rate constant due to the presence of the enhancement layer, and the threshold distance is where the total non-radiative decay rate constant is equal to the total radiative decay rate constant; and an outcoupling layer disposed over the enhancement layer, wherein the outcoupling layer scatters radiative energy from the enhancement layer to free space.

公开(公告)号：US11697661B2

公开(公告)日：2023-07-11

申请号：US17030803

申请日：2020-09-24

Applicant: Universal Display Corporation

Inventor： Lichang Zeng ,  Zhiqiang Ji ,  Eric A. Margulies ,  Paul M. Lahti ,  Michael S. Weaver

IPC: H01L51/50 ,  C07F15/00 ,  C09K11/06 ,  H10K50/12 ,  H10K50/15 ,  H10K50/18 ,  H10K50/81 ,  H10K50/82 ,  H10K50/17 ,  H10K85/30 ,  H10K50/11 ,  H10K101/10

CPC classification number: C07F15/0033 ,  C09K11/06 ,  H10K50/12 ,  H10K50/15 ,  H10K50/171 ,  H10K50/18 ,  H10K50/81 ,  H10K50/82 ,  H10K85/342 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/185 ,  H10K50/11 ,  H10K2101/10

Abstract: A compound having the formula Ir(LA)n(LB)3−n, having the structure




Formula I, is disclosed. In Formula I, each of Z1, Z2, Z3, and Z4 is CR2; X is O, S, or Se; n is an integer from 1 to 3; R1, R2, R3, R4, and R5 each independently represent mono- to a maximum possible number of substitutions, or no substitution; R1, R2, R3, R4, and R5 are each independently selected from a variety of substituents; any two substitutions in R1, R2, R3, R4, and R5 are optionally joined to form a ring; at least one pair of substitutions in R1, R2, R3, R4, and R5 are joined together to form a bridge structure comprising a backbone structure that forms a fused first ring, which can be further substituted; and the backbone structure is saturated. Organic light emitting devices and consumer products containing the compounds are also disclosed.

公开(公告)号：US20210313545A1

公开(公告)日：2021-10-07

申请号：US17354038

申请日：2021-06-22

Applicant: Universal Display Corporation

Inventor： Nicholas J. Thompson ,  Marc A. Baldo ,  Michael S. Weaver ,  Vinod M. Menon

IPC: H01L51/52 ,  H01L51/50

Abstract: An OLED is disclosed that includes an enhancement layer having optically active metamaterials, or hyperbolic metamaterials, which transfer radiative energy from the organic emissive material to a non-radiative mode, wherein the enhancement layer is disposed over the organic emissive layer opposite from the first electrode, and is positioned no more than a threshold distance away from the organic emissive layer, wherein the organic emissive material has a total non-radiative decay rate constant and a total radiative decay rate constant due to the presence of the enhancement layer, and the threshold distance is where the total non-radiative decay rate constant is equal to the total radiative decay rate constant; and an outcoupling layer disposed over the enhancement layer, wherein the outcoupling layer scatters radiative energy from the enhancement layer to free space.

公开(公告)号：US20210217971A1

公开(公告)日：2021-07-15

申请号：US17210087

申请日：2021-03-23

Applicant: UNIVERSAL DISPLAY CORPORATION

Inventor： PIERRE-LUC T. BOUDREAULT ,  Alexey Dyatkin ,  David Zenan Li ,  Scott Joseph ,  Chuanjun Xia ,  Hitoshi Yamamoto ,  Michael S. Weaver ,  Bert Alleyne ,  James Fiordeliso

IPC: H01L51/00 ,  C09K11/06 ,  C07F15/00 ,  H01L51/50

Abstract: A compound having an ancillary ligand L1 having the formula: Formula I is disclosed. The ligand L1 is coordinated to a metal M having an atomic number greater than 40, and two adjacent substituents are optionally joined to form into a ring. Such compound is suitable for use as emitters in organic light emitting devices.

公开(公告)号：US11056540B2

公开(公告)日：2021-07-06

申请号：US16814763

申请日：2020-03-10

Applicant: Universal Display Corporation

Inventor： Nicholas J. Thompson ,  Michael S. Weaver ,  Michael Fusella

IPC: H01L27/32 ,  H01L51/50 ,  H01L51/52

Abstract: Device structures are provided that include one or more plasmonic OLEDs and zero or more non-plasmonic OLEDs. Each plasmonic OLED includes an enhancement layer that includes a plasmonic material which exhibits surface plasmon resonance that non-radiatively couples to an organic emissive material and transfers excited state energy from the emissive material to a non-radiative mode of surface plasmon polaritons in the plasmonic OLED.