Method of printing sheet-form substrates by the inkjet printing process

    公开(公告)号:US07144451B2

    公开(公告)日:2006-12-05

    申请号:US10399878

    申请日:2001-12-12

    IPC分类号: C09D11/02 B41J2/01

    CPC分类号: C09D11/328

    摘要: The invention relates to a method of printing sheet-form substrates by the inkjet printing process, which method comprises printing those materials with an aqueous ink comprising a) at least one dye of formula wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1–C4alkyl, R3 and R4 are each independently of the other unsubstituted or substituted C1–C4alkyl, R5 and R6 are each independently of the other C1–C4alkyl, C1–C4alkoxy, halogen, hydroxy, carboxy, C2–C4alkanoylamino or sulfo, X is halogen, hyrodroxy, C1–C4alkoxy that is unsubstituted or substituted in the alkyl moiety, phenoxy that is unsubstituted or substituted in the phenyl ring, C1–C4alkylthio that is unsubstituted or substituted in the alkyl moiety, phenylthio that is unsubstituted or substituted in the phenyl ring, amino, N-mono-, or N, N-di-C1–C6alkylamino that is unsubstituted or substituted in the alkyl moiety and uninterrupted or interrupted in the alkyl moiety by oxygen, C5–C7cycloaklylamino that is unsubstituted or substituted in the cycloalkyl ring, phenyl- or naphthyl-amino that is unsubstituted or substituted in the aryl moiety, N—C1–C4alkyl-N-phenyl- or N—C1–C4alkyl-N-naphthyl-amino that is unsubstituted or substituted in the aryl moiety, benzylamino that is unsubstituted or substituted in the phenyl moiety, morpholino or piperidin-1-yl, and n and m are each independently of the other the number 0, 1, 2 or 3; and b) a solubilizer or a humectant.

    Optical recording materials having high storage density
    53.
    发明申请
    Optical recording materials having high storage density 审中-公开
    具有高存储密度的光记录材料

    公开(公告)号:US20060159882A1

    公开(公告)日:2006-07-20

    申请号:US10546077

    申请日:2004-02-23

    IPC分类号: B32B3/02

    摘要: The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer based on compounds of formula (I) wherein G1 and G2 are each independently of the other, A1 and A2 are each independently of the other N(R12), O, S or Se and A3 is C(C1-C5alkyI)2, C(C4-C5 alkylene), N(R12), O, S, Se, N═C(R13) or unsubstituted or R14-substituted CH═CH; M1 is a transition metal of groups (IX) to (XIII), preferably Co, Cu, Ni, Pd or Zn, especially Co, Cu or Ni; Q1 and Q2 are each independently of the other C(R15), N or P, . . . For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density. Also claimed are new compounds of formula (I), with the exception of the compounds disclosed in J. Org. Chem. 67/16, 5753-5772 [2002].

    摘要翻译: 本发明涉及一种光记录介质,其包括基于基底,反射层和基于式(I)的化合物的记录层,其中G 1和G 2各自独立地 的另一个,A 1和A 2各自独立地为另一个N(R 12),O,S或Se和A < C(C 1-4)烷基是C(C 1 -C 5烷基)2,C(C 1-4) N(R 12),O,S,Se,NC(R 13)或未取代的或者R“ 取代CH-CH; M 1是(IX)至(XIII)基团的过渡金属,优选Co,Cu,Ni,Pd或Zn,特别是Co,Cu或Ni; Q 1和Q 2各自独立于另一个C(R 15),N或P。 。 。 关于进一步取代基的详细定义,参见说明书。 记录和回放特别是在350至500nm的波长下进行,例如使用蓝色激光。 录制和播放质量非常好,可以保持较高的存储密度。 还要求的是式(I)的新化合物,除了J.Org公开的化合物外。 Chem。 67 / 16,5753-5772 [2002]。

    Dye mixtures, 1:2 cobalt complex formazan dyes and their use
    55.
    发明授权
    Dye mixtures, 1:2 cobalt complex formazan dyes and their use 失效
    染料混合物,1:2钴络合物甲an染料及其用途

    公开(公告)号:US06551364B2

    公开(公告)日:2003-04-22

    申请号:US09790782

    申请日:2001-02-22

    IPC分类号: D06P110

    摘要: Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.

    摘要翻译: X为取代或未取代的C 1 -C 8烷基,苯基,萘基,呋喃基或噻吩基,R 1和R 2彼此独立地为甲基的甲an化合物的至少一种1:2钴络合物染料的染料混合物为氢或取代或 未取代的C 1 -C 8烷基,苯基或萘基,m为1至4的数,并且环I,II,III和IV可以与至少一种如权利要求1所定义的式(2)的蒽醌染料一起进一步取代, 或与至少一种含有由所定义的式(3),(4),(5)和(6)的化合物组成的组的两种相同或不同的偶氮化合物的1:2铬或1:2钴配合物染料一起使用。 在权利要求1中;和新颖的1:2钴络合物甲an染料。染料混合物特别适用于染色或印刷天然和合成的聚酰胺纤维材料,获得具有良好牢度的染色或印花。

    Dye mixtures, 1:2 cobalt complex formazan dyes and their use
    56.
    发明授权
    Dye mixtures, 1:2 cobalt complex formazan dyes and their use 失效
    染料混合物,1:2钴络合物甲an染料及其用途

    公开(公告)号:US06428582B1

    公开(公告)日:2002-08-06

    申请号:US08592898

    申请日:1996-01-29

    IPC分类号: C09B5000

    摘要: Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.

    摘要翻译: X为取代或未取代的C 1 -C 8烷基,苯基,萘基,呋喃基或噻吩基,R 1和R 2彼此独立地为甲基的甲an化合物的至少一种1:2钴络合物染料的染料混合物为氢或取代或未取代的 C 1 -C 8烷基,苯基或萘基,m是1至4的数,并且环I,II,III和IV可以与至少一种如权利要求1所定义的式(2)的蒽醌染料一起进一步取代,或 以及来自包含式(3),(4),(5)和(6)的化合物的两种相同或不同的偶氮化合物的至少一种1:2铬或1:2钴络合物染料,如 权利要求1;和新颖的1:2钴络合物甲an染料。染料混合物特别适用于染色或印刷天然和合成聚酰胺纤维材料,获得具有良好牢度的染色或印花。

    Addition products of acryloylamino-substituted dyes, and the preparation and use thereof
    57.
    发明授权
    Addition products of acryloylamino-substituted dyes, and the preparation and use thereof 失效
    丙烯酰氨基取代染料的添加产物及其制备和应用

    公开(公告)号:US06281339B1

    公开(公告)日:2001-08-28

    申请号:US09660846

    申请日:2000-09-13

    IPC分类号: C09B62465

    摘要: Monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine dyes comprising at least one structural unit of formula (1) wherein Z is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24-alkylamino, unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino, each unsubstituted or substituted in the aryl moiety; morpholino; piperazin-1-yl or piperidin-1-yl, and X is hydrogen, hydroxy, chlorine or bromine, or X has the meanings given for Z, yield dyeings or prints having good fastness to light and high color brilliance.

    摘要翻译: 包含至少一个式(1)结构单元的单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲az或二恶嗪染料,其中Z是在烷基部分未被取代或取代的C1-C24烷氧基,或在烷基部分中不间断或中断氧 ; 在苯环中未取代或取代的苯氧基; 在烷基部分未取代或取代的C 1 -C 4烷硫基; 在苯环中未取代或取代的苯硫基; 氨基; 在烷基部分未取代或取代的N-单或N,N-二-C 1 -C 24 - 烷基氨基,或在烷基部分中不间断或间断地被氧或由-NR 1 - ,其中R 1是氢或C1- C4烷基; C10-C20萜氨基; 在环烷基环中未取代或取代的C 5 -C 7环烷基氨基; 苯基或萘基 - 氨基或N-C 1 -C 4烷基-N-苯基 - 或N-C 1 -C 4烷基-N-萘基 - 氨基,其各自未被取代或在芳基部分取代; 吗啉代 哌嗪-1-基或哌啶-1-基,X是氢,羟基,氯或溴,或X具有给定的含义,产率染色或具有良好的耐光牢度和高色泽的印花。

    Process for dichromatic or trichromatic dyeing or printing
    58.
    发明授权
    Process for dichromatic or trichromatic dyeing or printing 失效
    双色或三色染色或印刷方法

    公开(公告)号:US5779740A

    公开(公告)日:1998-07-14

    申请号:US752299

    申请日:1996-11-19

    摘要: Process for dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre material, which comprises using at least one blue-dyeing fibre-reactive anthraquinone dye of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.12 alkyl, X.sub.1 is halogen, B.sub.1 is an organic bridge member and V.sub.1 is an aliphatic or aromatic amine containing a fibre-reactive group, together with at least one fibre-reactive sulfo group containing yellow- or orange-dyeing dye or together with at least one fibre-reactive sulfo group containing red-dyeing dye. Level dyeings with good fastness properties are obtained.

    摘要翻译: 用于二色或三色染色或印刷天然或合成聚酰胺纤维材料的方法,其包括使用至少一种式(1)的蓝染色纤维反应性蒽醌染料,其中R 1和R 2彼此独立地是氢 或取代或未取代的C 1 -C 12烷基,X 1为卤素,B 1为有机桥基,V 1为含有纤维反应性基团的脂族或芳族胺,以及至少一种含有黄色或橙色染色的纤维反应性磺基 染料或与至少一种含有染色染料的纤维反应性磺基组合。 获得具有良好牢度特性的水平染色。