Fast-writable and precision-writable high-capacity optical storage media
    2.
    发明授权
    Fast-writable and precision-writable high-capacity optical storage media 失效
    快速写入和精确写入的大容量光存储介质

    公开(公告)号:US06849315B2

    公开(公告)日:2005-02-01

    申请号:US10483130

    申请日:2002-07-04

    摘要: The invention relates to an optical recording medium, comprising a substrate and a recording layer, wherein the recording layer comprises a compound of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are each independently of the others hydrogen, G1 or C1-C24alkyl, C2-C24alkenyl, C2-C24alkynyl, C3-C24cycloalkyl, C3-C24cycloalkenyl, C7-C24aralkyl, C6-C24aryl, C4-C12heteroaryl or C1-C12heterocycloalkyl, each unsubstituted or substituted by one or more identical or different substituents G1, wherein R1 and R2, R1 and R13, R2 and R3, R3 and R4, R4 and R5, R5 and R6, R6 and R7, R7 and R8, R8 and R9, R9 and R10, R10 and R11, R11 and R12 and/or R12 and R13 can independently of one another be bonded to one another in pairs separately or, when they contain substitutable sites, via a direct bond or via a —CH2—, —O—, —S—, —NH— or —NC1-C24alkyl-bridge in such a manner that, together with the atoms and bonds indicated in formula (I), five- or six-membered, saturated, unsaturated or aromatic, unsubstituted or G1-substituted rings are formed, G1 is any desired substituent,? xm- is an inorganic, organic organometallic anion, Yn+ is a proton or a metal, ammonium or phosphonium cation, and m and n are each independently of the other a number from 1 to 5, and p and q are each independently of the other O or a number from 0.2 to 6, the ratio of p and q to one another, depending upon m and n and, as applicable, the number of charged G1, being such that in formula (I) there is no excess positive or negative charge. Generally the optical recording medium according to the invention additionally comprises a reflecting layer. The recording media according to the invention exhibit high sensitivity and good playback characteristics, especially at high recording and playback speeds. The light stability is also excellent.

    摘要翻译: 本发明涉及一种光记录介质,包括基片和记录层,其中记录层包括式(I)化合物,其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R10 ,R11,R12和R13各自独立地为氢,G1或C1-C24烷基,C2-C24链烯基,C2-C24炔基,C3-C24环烷基,C3-C24环烯基,C7-C24芳烷基,C6-C24芳基,C4-C12杂芳基或C1- C 1 -C 6杂环烷基,每个未取代或被一个或多个相同或不同的取代基G1取代,其中R1和R2,R1和R13,R2和R3,R3和R4,R4和R5,R5和R6,R6和R7,R7和R8,R8 并且R 9,R 9和R 10,R 10和R 11,R 11和R 12和/或R 12和R 13可以彼此独立地彼此相互键合,或者当它们含有可取代的位置时,经由直接键或通过-CH 2 - ,-O - , - S - , - NH-或-NCl-C24烷基 - 桥,其与式(I)中所示的原子和键一起为五或六元饱和, 形成不饱和或芳族,未取代或者G1取代的环,G1是a

    Azo dyes, processes for their preparation and their use
    3.
    发明授权
    Azo dyes, processes for their preparation and their use 失效
    偶氮染料,其制备方法及其用途

    公开(公告)号:US5650497A

    公开(公告)日:1997-07-22

    申请号:US679841

    申请日:1996-07-15

    摘要: Azo dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen,R.sub.6 is hydrogen or C.sub.1 -C.sub.4 Alkyl,X is --C.sub.1 -C.sub.4 alkylene-O--C.sub.1 -C.sub.4 alkyl andY is hydrogen; unsubstituted or hydroxy- or C.sub.1 -C.sub.4 alkoxy-substituted C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.4 -alkonoyl or C.sub.1 -C.sub.4 alkoxycarbonyl; a radical of the formula --CH.sub.2 --CH.dbd.CH.sub.2 ;C.sub.1 -C.sub.4 alkylsulfonyl; or unsubstituted or C.sub.1 -C.sub.4 alkyl-, C.sub.1 -C.sub.4 alkoxy- or halogen-substituted phenylsulfonyl, produce dyeings with good fastness properties on fibre materials containing nitrogen or containing hydroxyl groups.

    摘要翻译: 其中R 1,R 2,R 3,R 4和R 5彼此独立地是氢,C 1 -C 4烷基,C 1 -C 4烷氧基或卤素,R 6是氢或C 1 -C 4烷基, C1-C4亚烷基-O-C1-C4烷基,Y是氢; 未取代的或羟基或C 1 -C 4烷氧基取代的C 1 -C 8烷基,C 2 -C 4 - 烷酰基或C 1 -C 4烷氧基羰基; 式-CH 2 -CH = CH 2的基团; C 1 -C 4烷基磺酰基; 或未取代的或C 1 -C 4烷基 - ,C 1 -C 4烷氧基或卤素取代的苯基磺酰基,在含氮或含羟基的纤维材料上产生具有良好牢度性能的染色。

    Process for producing 2,3,5-trichloropyridine
    4.
    发明授权
    Process for producing 2,3,5-trichloropyridine 失效
    制备2,3,5-三氯吡啶的方法

    公开(公告)号:US4258194A

    公开(公告)日:1981-03-24

    申请号:US74216

    申请日:1979-09-10

    CPC分类号: C07D213/61 C07F9/4075

    摘要: A novel process for producing 2,3,5-trichloropyridine is described. In this process, 2,3,4,5-tetrachloropyridine is reacted, in an alkanephosphonic acid dialkyl ester (dialkyl alkane phosphonate) having 1 to 4 carbon atoms in each of the alkyl groups or in a phosphoric acid trialkyl ester (trialkyl phosphate) having 1 to 4 carbon atoms in each of the alkyl groups as the solvent, at 60.degree. to 120.degree. C., in the presence of 1.4 to 2.8 mols, per mol of 2,3,4,5-tetrachloropyridine, of an ammonium salt of an inorganic or organic acid, with 1.2 to 1.6 gram atoms of zinc per mol of 2,3,4,5-tetrachloropyridine, the 2,3,4,5-tetrachloropyridine being selectively dechlorinated in the 4-position.2,3,5-Trichloropyridine is a valuable intermediate for producing herbicidally effective .alpha.-[4-(3',5'-dichloropyrid-2-yloxy)-phenoxy-]-alkanecarboxylic acids and derivatives thereof.There are also described novel ammonium salts of methanephosphonic acid monomethyl ester, in the presence of which salts the selective dechlorination of 2,3,4,5-tetrachloropyridine in the 4-position is advantageously performed.

    摘要翻译: 描述了一种制备2,3,5-三氯吡啶的新方法。 在该方法中,2,3,4,5-四氯吡啶在各烷基中的烷基膦酸二烷基酯(具有1至4个碳原子的二烷基烷烃膦酸酯)或磷酸三烷基酯(磷酸三烷基酯)中反应, 在每个烷基中作为溶剂具有1至4个碳原子,在60至120℃下,在1.4至2.8摩尔存在下,每摩尔2,3,4,5-四氯吡啶,铵 无机或有机酸的盐,每摩尔2,3,4,5-四氯吡啶为1.2-1.6克原子锌,2,3,4,5-四氯吡啶在4位选择性脱氯。 2,3,5-三氯吡啶是产生除草有效的α-[4-(3',5'-二氯吡啶-2-基氧基) - 苯氧基] - 烷羧酸及其衍生物的有价值的中间体。 还描述了甲基膦酸单甲酯的新型铵盐,在其存在下,有利地进行4位的2,3,4,5-四氯吡啶的选择性脱氯。

    Optical recording materials having high storage density
    5.
    发明申请
    Optical recording materials having high storage density 审中-公开
    具有高存储密度的光记录材料

    公开(公告)号:US20060159882A1

    公开(公告)日:2006-07-20

    申请号:US10546077

    申请日:2004-02-23

    IPC分类号: B32B3/02

    摘要: The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer based on compounds of formula (I) wherein G1 and G2 are each independently of the other, A1 and A2 are each independently of the other N(R12), O, S or Se and A3 is C(C1-C5alkyI)2, C(C4-C5 alkylene), N(R12), O, S, Se, N═C(R13) or unsubstituted or R14-substituted CH═CH; M1 is a transition metal of groups (IX) to (XIII), preferably Co, Cu, Ni, Pd or Zn, especially Co, Cu or Ni; Q1 and Q2 are each independently of the other C(R15), N or P, . . . For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density. Also claimed are new compounds of formula (I), with the exception of the compounds disclosed in J. Org. Chem. 67/16, 5753-5772 [2002].

    摘要翻译: 本发明涉及一种光记录介质,其包括基于基底,反射层和基于式(I)的化合物的记录层,其中G 1和G 2各自独立地 的另一个,A 1和A 2各自独立地为另一个N(R 12),O,S或Se和A < C(C 1-4)烷基是C(C 1 -C 5烷基)2,C(C 1-4) N(R 12),O,S,Se,NC(R 13)或未取代的或者R“ 取代CH-CH; M 1是(IX)至(XIII)基团的过渡金属,优选Co,Cu,Ni,Pd或Zn,特别是Co,Cu或Ni; Q 1和Q 2各自独立于另一个C(R 15),N或P。 。 。 关于进一步取代基的详细定义,参见说明书。 记录和回放特别是在350至500nm的波长下进行,例如使用蓝色激光。 录制和播放质量非常好,可以保持较高的存储密度。 还要求的是式(I)的新化合物,除了J.Org公开的化合物外。 Chem。 67 / 16,5753-5772 [2002]。

    Anthraquinone dyes, preparation thereof and use thereof
    6.
    发明授权
    Anthraquinone dyes, preparation thereof and use thereof 失效
    蒽醌染料,其制备及其用途

    公开(公告)号:US06964689B2

    公开(公告)日:2005-11-15

    申请号:US10451173

    申请日:2001-12-13

    摘要: The present invention relates to anthraquinone dyes of the formula (I) where R1 is hydrogen, R2 is hydrogen or CO—C2C6alkyl moiety may be substituted by carboxyl, or is (II) wherein R6 is hydrogen, C1-C4alkyl, hydroxyl, carboxyl or halogen, R7 is hygrogen, C1-C4alkyl or halogen and R8 is hydrogen or C2-C3alkyl or when R4 is halogen R8 ? may be methyl or halogen R3 is hydrogen or halogen, R4 is hydrogen or halogen and n is (0), (1) or (2), with the proviso that R3, R4, R6, R7 and R8 are not all hydrogen at one and the same time, processes for their preparation and their use for dyeing or printing hydrophobic fiber materials or for preparing colored plastics or polymeric color particles.

    摘要翻译: 本发明涉及式(I)的蒽醌染料,其中R 1是氢,R 2是氢或CO-C 2 C C 6烷基部分可以被羧基取代,或者是(II)其中R 6是氢,C 1 -C 4烷基部分, 羟基,羧基或卤素,R 7是氢,C 1 -C 4烷基或卤素,R 1,R 2,R 3, 8是氢或C 2 -C 3烷基,或当R 4是卤素时,R i im id =“CUSTOM-CHARACTER “=”3.13mm“wi =”1.78mm“file =”US06964689-20051115-P00900.TIF“alt =”custom character“img-content =”character“img-format =”tif“/> 8? 可以是甲基或卤素R 3是氢或卤素,R 4是氢或卤素,n是(0),(1)或(2),条件是 R 3,R 4,R 6,R 7和R 8, 同时不是所有的氢,它们的制备方法及其用于染色或印刷疏水纤维材料或用于制备着色塑料或聚合物着色颗粒的用途。

    Dyeing or printing of manufactured natural polymer and synthetic hydrophobic fiber materials
    8.
    发明授权
    Dyeing or printing of manufactured natural polymer and synthetic hydrophobic fiber materials 有权
    制造天然聚合物和合成疏水纤维材料的染色或印花

    公开(公告)号:US06893472B2

    公开(公告)日:2005-05-17

    申请号:US10451170

    申请日:2001-12-13

    摘要: The present invention relates to a process for dyeing or printing manufactured natural polymer or synthetic hydrophobic fiber materials, characterized in that it comprises using dyes of the formula (I), where R1 is hydrogen, hydroxyl or a radical —NHCO—R6, where R6 is C1-C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R2 is hydrogen, hydroxyl or a radical W—R7, where W is —NHCO— or —S— and R7 is C1C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R3 is hydrogen, R4 is hydrogen or hydroxyl, R5 is hydrogen, halogen, methoxy, phenoxy or phenylthio, or R3 and R4 combine to form the radical of the formula (II), where the rings A and B may independently bear further substituents, to the use of these dyes for trichromatic dyeing of manufactured natural polymer or synthetic hydrophobic fiber materials and mass dyeing of plastics materials and to producing solid on-tone combinations of plastics material and manufactured natural polymer or synthetic fiber material.

    摘要翻译: 本发明涉及一种用于染色或印刷制备的天然聚合物或合成疏水纤维材料的方法,其特征在于它包括使用式(I)的染料,其中R 1是氢,羟基或 基团-NHCO-R 6,其中R 6是C 1 -C 6烷基或未取代的C 1 -C 6烷基, C 1 -C 4烷基 - 或卤素取代的苯基,R 2是氢,羟基或基团R 7, ,其中W是-NHCO-或-S-,R 7是C 1 -C 6烷基或未取代的或C 1 -C 6烷基, 烷基 - 或卤素取代的苯基,R 3是氢,R 4是氢或羟基,R SUB > 5 是氢,卤素,甲氧基,苯氧基或苯硫基,或R 3和R 4结合形成式(II)的基团,其中 环A和B可以独立地承担进一步的取代基,这些染料用于制造的三色染色 天然聚合物或合成疏水纤维材料和塑料材料的大量染色,以及生产塑料材料和制造的天然聚合物或合成纤维材料的固体色调组合。

    Azo dyes
    9.
    发明授权
    Azo dyes 失效
    偶氮染料

    公开(公告)号:US5710258A

    公开(公告)日:1998-01-20

    申请号:US595435

    申请日:1996-02-05

    CPC分类号: C09B62/473 C07C309/76

    摘要: The invention relates to compounds of formula ##STR1## The compounds of formula (1) are suitable as dye for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials and give dyeings of prints having good allround fastness properties.

    摘要翻译: 本发明涉及式KNN(1)的化合物。式(1)的化合物适用于染色或印刷含羟基或含氮纤维材料的染料,并给出具有良好耐牢度性能的印花的染色。

    Disazo dyes containing two carbonylamino groups processes for their
preparation and their use
    10.
    发明授权
    Disazo dyes containing two carbonylamino groups processes for their preparation and their use 失效
    含有两个羰基氨基的双偶氮染料用于其制备和使用

    公开(公告)号:US5691459A

    公开(公告)日:1997-11-25

    申请号:US679785

    申请日:1996-07-15

    摘要: Azo dyes of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are unsubstituted or hydroxy-, C.sub.1 -C4-alkoxy- or halogen-substituted C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy; unsubstituted or C.sub.1 -C4-alkyl-, C.sub.1 -C4-alkoxy- or halogen-substituted phenyl or phenoxy; or a radical of the formula --N(R.sub.3)R.sub.4, in which R.sub.3 und R.sub.4 independently of one another are hydrogen, C.sub.1 -C.sub.4 -alkyl, or C.sub.2 -C.sub.4 -alkanoyl which is unsubstituted or further substituted in the alkyl part by hydroxyl or C.sub.1 -C.sub.4 -alkoxy, with the proviso that R.sub.1 and R.sub.2 are not simultaneously methyl, produce dyeings with good fastnesses on fibre materials containing nitrogen or containing hydroxyl groups.

    摘要翻译: 其中R 1和R 2彼此独立地是未取代的或羟基,C 1 -C 4 - 烷氧基或卤素取代的C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基的式(Ⅺ)的偶氮染料; 未取代的或C 1 -C 4 - 烷基 - ,C 1 -C 4 - 烷氧基 - 或卤素取代的苯基或苯氧基; 或式-N(R3)R4的基团,其中R3和R4彼此独立地是氢,C1-C4-烷基或C2-C4-烷酰基,其在烷基部分被羟基取代或进一步取代,或 C1-C4-烷氧基,条件是R1和R2不同时为甲基,在含有氮或含羟基的纤维材料上产生具有良好牢度的染色。