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    Fast-writable and precision-writable high-capacity optical storage media
    1.
    发明授权
    Fast-writable and precision-writable high-capacity optical storage media 失效
    快速写入和精确写入的大容量光存储介质

    公开(公告)号：US06849315B2

    公开(公告)日：2005-02-01

    申请号：US10483130

    申请日：2002-07-04

    申请人： Urs Lehmann ,  Peter Aeschlimann ,  Peter Sutter ,  Beat Schmidhalter ,  Jean-Luc Budry ,  Heinz Spahni

    发明人： Urs Lehmann ,  Peter Aeschlimann ,  Peter Sutter ,  Beat Schmidhalter ,  Jean-Luc Budry ,  Heinz Spahni

    IPC分类号： B41M5/26 ,  C09B11/00 ,  C09B11/02 ,  C09B11/20 ,  C09B11/28 ,  C09B45/14 ,  C09B45/20 ,  C09B55/00 ,  C09B69/02 ,  G11B7/004 ,  G11B7/24 ,  G11B7/244 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/249 ,  G11B7/253 ,  G11B7/254 ,  G11B7/2542 ,  G11B7/258 ,  G11B7/259 ,  G11B7/26 ,  B32B3/02

    CPC分类号： G11B7/244 ,  C09B11/28 ,  G11B7/2467 ,  G11B7/249 ,  G11B7/253 ,  G11B7/2542 ,  G11B7/259 ,  Y10T428/21

    摘要： The invention relates to an optical recording medium, comprising a substrate and a recording layer, wherein the recording layer comprises a compound of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are each independently of the others hydrogen, G1 or C1-C24alkyl, C2-C24alkenyl, C2-C24alkynyl, C3-C24cycloalkyl, C3-C24cycloalkenyl, C7-C24aralkyl, C6-C24aryl, C4-C12heteroaryl or C1-C12heterocycloalkyl, each unsubstituted or substituted by one or more identical or different substituents G1, wherein R1 and R2, R1 and R13, R2 and R3, R3 and R4, R4 and R5, R5 and R6, R6 and R7, R7 and R8, R8 and R9, R9 and R10, R10 and R11, R11 and R12 and/or R12 and R13 can independently of one another be bonded to one another in pairs separately or, when they contain substitutable sites, via a direct bond or via a —CH2—, —O—, —S—, —NH— or —NC1-C24alkyl-bridge in such a manner that, together with the atoms and bonds indicated in formula (I), five- or six-membered, saturated, unsaturated or aromatic, unsubstituted or G1-substituted rings are formed, G1 is any desired substituent,? xm- is an inorganic, organic organometallic anion, Yn+ is a proton or a metal, ammonium or phosphonium cation, and m and n are each independently of the other a number from 1 to 5, and p and q are each independently of the other O or a number from 0.2 to 6, the ratio of p and q to one another, depending upon m and n and, as applicable, the number of charged G1, being such that in formula (I) there is no excess positive or negative charge. Generally the optical recording medium according to the invention additionally comprises a reflecting layer. The recording media according to the invention exhibit high sensitivity and good playback characteristics, especially at high recording and playback speeds. The light stability is also excellent.

    摘要翻译： 本发明涉及一种光记录介质，包括基片和记录层，其中记录层包括式（I）化合物，其中R1，R2，R3，R4，R5，R6，R7，R8，R9，R10 ，R11，R12和R13各自独立地为氢，G1或C1-C24烷基，C2-C24链烯基，C2-C24炔基，C3-C24环烷基，C3-C24环烯基，C7-C24芳烷基，C6-C24芳基，C4-C12杂芳基或C1- C 1 -C 6杂环烷基，每个未取代或被一个或多个相同或不同的取代基G1取代，其中R1和R2，R1和R13，R2和R3，R3和R4，R4和R5，R5和R6，R6和R7，R7和R8，R8 并且R 9，R 9和R 10，R 10和R 11，R 11和R 12和/或R 12和R 13可以彼此独立地彼此相互键合，或者当它们含有可取代的位置时，经由直接键或通过-CH 2 - ，-O - ， - S - ， - NH-或-NCl-C24烷基 - 桥，其与式（I）中所示的原子和键一起为五或六元饱和， 形成不饱和或芳族，未取代或者G1取代的环，G1是a

    Optical recording materials having high storage density
    2.
    发明申请
    Optical recording materials having high storage density 审中-公开
    具有高存储密度的光记录材料

    公开(公告)号：US20060159882A1

    公开(公告)日：2006-07-20

    申请号：US10546077

    申请日：2004-02-23

    申请人： Urs Lehmann ,  Peter Sutter ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Urs Lehmann ,  Peter Sutter ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： B32B3/02

    CPC分类号： G11B7/246 ,  C07D413/12 ,  C07D417/12 ,  G11B7/2472 ,  G11B7/2475 ,  G11B7/2478 ,  G11B7/2492 ,  G11B7/2495 ,  G11B7/2531 ,  G11B7/2533 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/2575 ,  G11B2007/25706 ,  G11B2007/2571 ,  G11B2007/25713 ,  G11B2007/25715 ,  G11B2007/25716

    摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer based on compounds of formula (I) wherein G1 and G2 are each independently of the other, A1 and A2 are each independently of the other N(R12), O, S or Se and A3 is C(C1-C5alkyI)2, C(C4-C5 alkylene), N(R12), O, S, Se, N═C(R13) or unsubstituted or R14-substituted CH═CH; M1 is a transition metal of groups (IX) to (XIII), preferably Co, Cu, Ni, Pd or Zn, especially Co, Cu or Ni; Q1 and Q2 are each independently of the other C(R15), N or P, . . . For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density. Also claimed are new compounds of formula (I), with the exception of the compounds disclosed in J. Org. Chem. 67/16, 5753-5772 [2002].

    摘要翻译： 本发明涉及一种光记录介质，其包括基于基底，反射层和基于式（I）的化合物的记录层，其中G 1和G 2各自独立地 的另一个，A 1和A 2各自独立地为另一个N（R 12），O，S或Se和A < C（C 1-4）烷基是C（C 1 -C 5烷基）2，C（C 1-4） N（R 12），O，S，Se，NC（R 13）或未取代的或者R“ 取代CH-CH; M 1是（IX）至（XIII）基团的过渡金属，优选Co，Cu，Ni，Pd或Zn，特别是Co，Cu或Ni; Q 1和Q 2各自独立于另一个C（R 15），N或P。 。 。 关于进一步取代基的详细定义，参见说明书。 记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。 录制和播放质量非常好，可以保持较高的存储密度。 还要求的是式（I）的新化合物，除了J.Org公开的化合物外。 Chem。 67 / 16,5753-5772 [2002]。

    Metal complexes
    4.
    发明申请
    Metal complexes 审中-公开
    金属配合物

    公开(公告)号：US20060276651A1

    公开(公告)日：2006-12-07

    申请号：US10553776

    申请日：2004-05-05

    申请人： Urs Lehmann ,  Colin Morton ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Urs Lehmann ,  Colin Morton ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： C07F15/06 ,  C07F15/04 ,  C07F15/02 ,  C07F1/08

    CPC分类号： G11B7/2478 ,  C09B57/10 ,  C09B67/0033 ,  C09B69/04 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/2472 ,  G11B7/249 ,  G11B7/2492 ,  G11B7/2495 ,  G11B7/2498 ,  G11B7/2531 ,  G11B2007/24612

    摘要： The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are, as defined in the description. Use of the metal complexes formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.

    摘要翻译： 本发明涉及式I的金属络合物，包含金属络合物的组合物，包含金属络合物或组合物的记录介质以及组合物在制备光学记录介质中的用途：其中取代基如 描述。 使用金属络合物配方（I）与氧杂菁染料组合令人惊讶地导致氧固醇染料在固体状态下聚集的相对较弱的趋势，使得吸收曲线在固体状态下仍然有利地是狭窄的事件，结果 其中具有高反射率的记录介质以及在所需光谱范围内的高灵敏度和良好的回放特性是可用的。

    High-performance optical storage media
    7.
    发明申请
    High-performance optical storage media 审中-公开
    高性能光存储介质

    公开(公告)号：US20050238840A1

    公开(公告)日：2005-10-27

    申请号：US10514923

    申请日：2003-04-15

    申请人： Urs Lehmann ,  Peter Aeschlimann ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Colin Morton

    发明人： Urs Lehmann ,  Peter Aeschlimann ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Colin Morton

    IPC分类号： B41M5/26 ,  C09B11/24 ,  C09B11/28 ,  C09B45/14 ,  C09B45/20 ,  C09B56/00 ,  C09B69/02 ,  G11B7/244 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/247 ,  G11B7/249 ,  G11B7/2492 ,  G11B7/2495 ,  G11B7/253 ,  G11B7/2534 ,  G11B7/258 ,  G11B7/259 ,  G11B7/26 ,  G11B7/24

    CPC分类号： C09B56/00 ,  C09B11/24 ,  G11B7/246 ,  G11B7/2467 ,  G11B7/247 ,  G11B7/248 ,  G11B7/249 ,  G11B7/2492 ,  G11B7/2495 ,  G11B7/2534 ,  G11B7/259

    摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula: (Formula I), (Formula II) or (Formula III); wherein R, to R, may be hydrogen or a variety of substituents, but R1 and R9 are not simultaneously hydrogen; Ym-— is an inorganic, organic or organometallic anion, or a mixture thereof; Zn+ is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye of compounds of formula (I), (II) or (III) to grooved substrates by spin-coating.

    摘要翻译： 本发明涉及一种包括基底，反射层和记录层的光学记录介质，其中记录层包含式（I）化合物，（式II）或（式III）化合物。 其中R 1至R 3可以是氢或各种取代基，但R 1和R 9不同时为氢; 是无机，有机或有机金属阴离子或其混合物; Z + N +是质子或金属，铵或鏻阳离子或其混合物; m，n和o各自独立地为1〜3的整数; 并且p和q各自为0至4的数，根据相关子结构的电荷，o，p和q彼此的比例使得在式（1）中不存在过量的正电荷或负电荷 I），（II）或（III）。 还要求保护的是高氯酸呫吨酯在制备具有有机金属阴离子的式（I），（II）或（III）的化合物中的用途，以及在施用式（I）化合物的染料层时使用乳酸盐， ，（II）或（III））通过旋涂进行开槽基板。

    Writable high-capacity optical storage media containing metal complexes
    8.
    发明申请
    Writable high-capacity optical storage media containing metal complexes 审中-公开
    包含金属络合物的可写入大容量光存储介质

    公开(公告)号：US20050008974A1

    公开(公告)日：2005-01-13

    申请号：US10495678

    申请日：2002-11-07

    申请人： Colin Morton ,  Taher Yousaf ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Heinz Spahni

    发明人： Colin Morton ,  Taher Yousaf ,  Jean-Luc Budry ,  Beat Schmidhalter ,  Heinz Spahni

    IPC分类号： B41M5/26 ,  C07D487/22 ,  C07F15/02 ,  G11B7/004 ,  G11B7/24 ,  G11B7/244 ,  G11B7/248 ,  G11B7/253 ,  G11B7/26 ,  C09B47/04

    CPC分类号： C07D487/22 ,  G11B7/248

    摘要： The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.

    摘要翻译： 本发明涉及一种包括基材和记录层的光学记录介质，其中记录层包含式（I）的配合物，或其中Q 2是式（II）的配体或其互变异构体，和 R1，R2，R3，R4，R5，R6，R7和R8各自独立地为H，卤素，氰基，COOR9，CONHR9，CONR9R10，R9，OR9，SR9，NHR9或NR9R10，其中R9和R10各自 独立于其它C 6 -C 10芳基，C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基，C 3 -C 24环烯基，C 2 -C 24烯基，C 3 -C 24环烯基，C 2 -C 24炔基，C 1 -C 12杂环烷基，未取代或取代的C 1 -C 12杂环烯基， R 1和R 2，R 3和R 4，R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合，M m是具有5个碳原子的过渡金属阳离子 或6个电子，L1是具有子结构NC，PC或As-C，L2的配体，独立于L1，是另一个配体c 保持至少一个杂原子N，P，As，O，S，Se或Te，L3 - 是CN - ，SCN - ，NCS - ，OCN - ，NCO - ， - N3-，L1-O - ，L1-S-，L

    High-capacity storage media
    10.
    发明授权
    High-capacity storage media 失效
    大容量存储介质

    公开(公告)号：US5851621A

    公开(公告)日：1998-12-22

    申请号：US842292

    申请日：1997-04-23

    申请人： Heinz Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    发明人： Heinz Wolleb ,  Beat Schmidhalter ,  Jean-Luc Budry

    IPC分类号： B41M5/26 ,  C07D311/82 ,  C07D491/16 ,  C09B11/28 ,  G11B7/244 ,  G11B7/246 ,  G11B7/249 ,  G11B7/253 ,  G11B7/2534 ,  G11B7/258 ,  B32B3/00

    CPC分类号： G11B7/246 ,  C09B11/28 ,  G11B7/249 ,  G11B7/253 ,  G11B7/258 ,  G11B7/2534 ,  Y10S428/913 ,  Y10S430/146 ,  Y10T428/21 ,  Y10T428/31678

    摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, which recording layer consists essentially of a dye of the formula (I), ##STR1## in which R.sub.1 and R.sub.6 are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, aralkyl or aryl, R.sub.6 and R.sub.7 are unsubstituted or substituted alkyl, alkenyl, alkynyl, aralky or aryl, R.sub.3, R.sub.4, R.sub.8 and R.sub.9 are hydrogen, halogen, OR.sub.17, SR.sub.17, NR.sub.18 R.sub.19, NO.sub.2, alkyl, alkenyl or Alkynyl, R.sub.5 and R.sub.10 are hydrogen, halogen, OR.sub.17, SR.sub.17, NO.sub.2, NR.sub.18 R.sub.19 or unsubstituted or substituted alkyl, alkenyl, alkynyl or aralkyl, and R.sub.11 is hydrogen, (CH.sub.2).sub.1-10 COO.sup.-, (CH.sub.2).sub.1-10 COOR.sub.24, alkyl, alkenyl, alkynyl or unsubstituted or substituted aralkyl or aryl; Y is the anion of an inorganic, organic or organometallic acid, Z is a metal cation, ammonium cation or phosphonium cation, m, n and o are from 1 to 3, and p and q are from 0 to 4; and the stoichiometry of o, p and q is such as not to result in any excess positive or negative charge in the formula (I). The substituents can, if desired, be connected to one another in such a way, via a direct bond or via a bridge --O-- or --NR.sub.12 --, as to form additional five- or six-membered rings. The novel recording media are of high sensitivity and have good reproduction characteristics.

    摘要翻译： 本发明涉及一种光记录介质，其包括基板，反射层和记录层，该记录层基本上由式（I）的染料，其中R 1和R 6为氢或未取代的 或取代的烷基，烯基，炔基，芳烷基或芳基，R6和R7是未取代的或取代的烷基，烯基，炔基，芳基或芳基，R3，R4，R8和R9分别是氢，卤素，OR17，SR17，NR18R19， ，烯基或炔基，R 5和R 10是氢，卤素，OR 17，SR 17，NO 2，NR 18 R 19或未取代或取代的烷基，烯基，炔基或芳烷基，R 11是氢，（CH 2）1-10 COO-，（CH 2） 烷基，烯基，炔基或未取代或取代的芳烷基或芳基; Y是无机，有机或有机金属酸的阴离子，Z是金属阳离子，铵阳离子或鏻阳离子，m，n和o为1至3，p和q为0至4; 并且o，p和q的化学计量比如在式（I）中不会导致任何过量的正电荷或负电荷。 如果需要，取代基可以以这样的方式通过直接键或通过桥-O-或-NR 12 - 彼此连接，形成另外的五元或六元环。 该新颖的记录介质具有高灵敏度和良好的再生特性。