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公开(公告)号：US06630271B1
公开(公告)日：2003-10-07
申请号：US09496186
申请日：2000-02-02
IPC分类号： H01M618
CPC分类号： H01M10/0565 , C08F214/22 , C08F2438/01 , H01M4/13 , H01M6/181 , H01M10/052 , H01M2300/0025
摘要： Use of vinylidenfluoride (VDF) copolymers for preparing electrolyte polymers, wherein the VDF copolymers have the following polymeric structure (I): (CH2—CF2)m—(CXY—C(ORf)Z)n—(CF2—CF(CF3))p) wherein: Rf is a perfluoroalkyl group having from 1 to 3 carbon atoms; X, Y, and Z equal to or different from each other are selected from F, Cl or H; m,n and p are integers, n or p can be 0 but not simultaneously; said VDF copolymers being obtainable by emulsion polymerization at 75-120° C., preferably 95°-120° C., in the presence of organic initiators.
摘要翻译： 使用偏氟乙烯（VDF）共聚物制备电解质聚合物，其中VDF共聚物具有以下聚合物结构（I）：其中：Rf是具有1至3个碳原子的全氟烷基; X，Y和Z等于或不同 彼此之间选自F，Cl或H; m，n和p是整数，n或p可以是0而不是同时;所述VDF共聚物可以通过在有机引发剂的存在下在75-120℃，优选95℃-120℃的乳液聚合获得。
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公开(公告)号：US5883177A
公开(公告)日：1999-03-16
申请号：US845145
申请日：1997-04-21
IPC分类号： C08F16/38 , C08F214/18 , C08F214/24 , C08F214/26 , C08F214/28 , C08F216/14 , C09D127/18 , C09D145/00 , C08K5/02
CPC分类号： C09D145/00 , C09D127/18
摘要： Use of amorphous perfluoropolymers based on homopolymers of the TTD dioxole or its amorphous copolymers to prepare solutions in fluoro-containing solvents, to obtain solutions for coatings, wherein TTD has the formula: ##STR1## wherein R.sub.F is a perfluoroalkylic radical with 1-5 carbon atoms, linear or branched when possible; X.sub.1 and X.sub.2 equal to or different from each other being F or CF.sub.3 ; the TTD amount ranges from 40 to 100% by moles.
摘要翻译： 使用基于TTD二氧杂环戊烯或其无定形共聚物的均聚物的无定形全氟聚合物在含氟溶剂中制备溶液，以获得涂料溶液，其中TTD具有下式：其中RF是具有1-5个碳的全氟烷基 原子，可以是直链或支链的; X 1和X 2彼此相同或不同，是F或CF 3; TTD量为40-100摩尔％。
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53.发明授权
公开(公告)号：US5639838A
公开(公告)日：1997-06-17
申请号：US538180
申请日：1995-08-23
IPC分类号： C08F16/14 , C08F214/26 , C08F216/14 , C09K3/10 , C08F16/24
CPC分类号： C08F214/262
摘要： Fluoroelastomers comprising, by mole:(a) from 33 to 75% of tetrafluoroethylene (TFE);(b) from 15 to 45% of a perfluorovinylether (PVE);(c) from 10 to 22% of vinylidene fluoride (VDF).They are endowed with high resistance to polar solvents and to bases, excellent compression set also at high temperatures, low Tg and good processability.They result particularly suitable for the manufacture of sealing elements (O-rings) for plants intended to the production of methylterbutylether (MTBE).
摘要翻译： 含有摩尔的氟弹性体：（a）33-75％的四氟乙烯（TFE）; （b）15至45％的全氟乙烯基醚（PVE）; （c）10至22％的偏二氟乙烯（VDF）。 它们具有对极性溶剂和碱的高耐性，在高温下也具有优异的压缩永久变形，低Tg和良好的加工性。 它们特别适用于制造用于生产甲基丁基醚（MTBE）的植物的密封元件（O型圈）。
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54.发明授权Vinylidene fluoride based fluoroelastomeric copolymers modified with perfluoroalkylvinylether 失效用全氟烷基乙烯醚改性的偏二氟乙烯基氟弹性体共聚物
公开(公告)号：US5260393A
公开(公告)日：1993-11-09
申请号：US15266
申请日：1993-02-08
IPC分类号： C08F214/22 , C08F16/24
CPC分类号： C08F214/222
摘要： Fluoroelastic copolymers, suitable for the manufacture of O-rings, comprising by weight:48-65% of VDF units21-36% of HFP units3-9% of PAVE units0-17% of TFE units
摘要翻译： 适用于制造O型圈的氟弹性共聚物，其重量百分比：48-65％VDF单元21-36％HFP单元3-9％PAVE单元0-17％TFE单元
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55.发明授权Fluoroelastomers endowed with improved processability and process for preparing them 失效氟弹性体具有改进的加工性和制备它们的方法
公开(公告)号：US5219964A
公开(公告)日：1993-06-15
申请号：US925845
申请日：1992-08-07
IPC分类号： C08F4/08 , C08F214/22 , C08F214/26
CPC分类号： C08F214/22 , C08F214/26
摘要： Fluoroelastomers characterized by the presence of iodine or bromine atoms at the end of the polymeric chain in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, and by a bromine content in the chain ranging from 0.05 to 2% by weight referred to the total weight of the monomeric units.Said fluoroelastomers exhibit improved characteristics of processability, particularly as regards the utilization in injection molding processes and the detaching from the molds, as well as of stability to heat.A process for preparing fluoroelastomers containing iodine or bromine atoms at the ends of the polymeric chain, in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, which process comprises polymerizing mixes of fluorinated monomers (VDF, TFE, HFP, FVE) in bulk, in suspension, in aqueous emulsion, or in solution of organic solvents by means of radical starters, in the presence of compounds capable of providing I.sup.- or Br.sup.- ions in the polymerization medium and conditions.
摘要翻译： 其特征在于聚合物链末端存在碘或溴原子，其量为每个聚合物链等于或低于1个碘或溴原子，并且链中的溴含量为0.05-2重量％ 指单体单元的总重量。 所述含氟弹性体表现出改进的加工性能，特别是关于注射成型工艺的利用和从模具的分离以及对热的稳定性。 在聚合物链的末端制备含有碘或溴原子的含氟弹性体的方法，其量等于或低于每个聚合物链1个碘或溴原子，该方法包括将氟化单体（VDF，TFE，HFP， FVE）在悬浮液中，在水性乳液中，或在有机溶剂的溶液中，通过自由基引发剂在能够在聚合介质和条件下提供I-或Br离子的化合物存在下进行。
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公开(公告)号：US08461448B2
公开(公告)日：2013-06-11
申请号：US12594525
申请日：2008-04-04
申请人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
发明人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
IPC分类号： H01L31/042
CPC分类号： H02S50/15 , B32B27/322 , H01L31/048 , H01L31/0481 , Y02E10/50
摘要： The present invention pertains to a solar cell module comprising at least one photovoltaic element encapsulated between a front layer on its light receiving surface side and a back layer, said front layer comprising at least one layer comprising a tetrafluoroethylene (TFE) polymer [polymer (F)], said polymer (F) comprising: recurring units derived from TFE; and from 15 to 25% wt of recurring units derived from at least one perfluoromonomer [monomer (CM)] chosen among: (i) perfluoroalkylvinylethers complying with formula CF2═CFORf1, in which Rf1 is a C1-C6 perfluoroalkyl, e.g. —CF3, —C2F5, —C3F7; and/or (ii) perfluoro-oxyalkylvinylethers complying with formula CF2═CFOX0, in which X0 is a C1-C12 perfluorooxyalkyl having one or more ether groups, like perfluoro-2-propoxy-propyl; and (iii) mixtures thereof. Still objects of the invention are a process for the manufacture of the solar cell module as above defined and its use for producing current to external sources, e.g. for powering a fixed-wing aircraft.
摘要翻译： 本发明涉及太阳能电池模块，其包括封装在其光接收表面侧的前层和背层之间的至少一个光伏元件，所述前层包括至少一层包含四氟乙烯（TFE）聚合物[聚合物（F ）]，所述聚合物（F）包含：衍生自TFE的重复单元; 和15至25重量％的衍生自至少一种全氟单体[单体（CM）]的重复单元，其选自：（i）符合式CF2 = CFORf1的全氟烷基乙烯基醚，其中Rf1为C1-C6全氟烷基，例如 -CF 3，-C 2 F 5，-C 3 F 7; 和/或（ii）符合式CF 2 = CFOX 0的全氟烷氧基乙烯基醚，其中X 0是具有一个或多个醚基的C 1 -C 12全氟氧烷基，如全氟-2-丙氧基丙基; 和（iii）它们的混合物。 本发明的另一目的是制造如上所述的太阳能电池组件的方法及其用于产生电流至外部源的用途，例如， 为固定翼飞机提供动力。
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公开(公告)号：US20090264596A1
公开(公告)日：2009-10-22
申请号：US12492396
申请日：2009-06-26
CPC分类号： C08L27/12 , C08L27/18 , C08L29/10 , C08L2205/02 , C08L2666/04
摘要： Fluoropolymers comprising a fluoroelastomer matrix incorporating therein particles of a semicrystalline fluoropolymer formed of tetrafluoroethylene (TFE) homopolymers or copolymers, wherein the average particle sizes of the semicrystalline fluoropolymer latex range from 10 to 100 nm.
摘要翻译： 含有含氟弹性体基体的含氟聚合物包含由四氟乙烯（TFE）均聚物或共聚物形成的半结晶含氟聚合物的颗粒，其中半结晶含氟聚合物胶乳的平均粒径为10-100nm。
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公开(公告)号：US07393906B2
公开(公告)日：2008-07-01
申请号：US11640862
申请日：2006-12-19
IPC分类号： C08F16/24
CPC分类号： C08F216/1416 , C08F34/02
摘要： Amorphous perfluorinated homopolymers and copolymers of perfluorodioxoles of formula (IA): wherein R′F is equal to RF or ORF wherein RF is a linear or branched perfluoroalkyl radical having 1-5 carbon atoms; X1 and X2, equal to or different from each other, are F, CF3; said polymers having a dioxole content≧95% by moles, having the following property combination: Tg, measured according to the ASTM 3418 (DSC) method, from 180° C. to 195° C.; intrinsic viscosity, measured at the temperature of 30° C. in perfluoroheptane (Galden® D80) according to the ASTM D 2857-87 method, from 13 cc/g to 100 cc/g.
摘要翻译： 无规全氟化均聚物和式（IA）的全氟二氧杂环戊烯的共聚物：其中R'F等于R或F或其中R F是具有1-5个碳原子的直链或支链全氟烷基; X 1，X 2和X 2彼此相同或不同，为F，CF 3 3， 所述聚合物具有≥95摩尔％的二氧杂环戊烯含量，具有以下性能组合：根据ASTM 3418（DSC）方法测量的Tg为180℃至195℃; 根据ASTM D 2857-87方法在全氟庚烷（D D D D80）中在30℃的温度下测量的特性粘度为13cc / g至100cc / g。
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公开(公告)号：US07199199B2
公开(公告)日：2007-04-03
申请号：US10823771
申请日：2004-04-14
IPC分类号： C08F16/24
CPC分类号： C08F216/1416 , C08F34/02
摘要： Amorphous perfluorinated homopolymers and copolymers of perfluorodioxoles of formula (IA): wherein R′F is equal to RF or ORF wherein RF is a linear or branched perfluoroalkyl radical having 1–5 carbon atoms; X1 and X2, equal to or different from each other, are F, CF3; said polymers having a dioxole content ≧95% by moles, having the following property combination: Tg, measured according to the ASTM 3418 (DSC) method, from 180° C. to 195° C.; intrinsic viscosity, measured at the temperature of 30° C. in perfluoroheptane (Galden® D80) according to the ASTM D2857-87 method, from 13 cc/g to 100 cc/g.
摘要翻译： 无规全氟化均聚物和式（IA）的全氟二恶烷的共聚物：
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公开(公告)号：US20050245691A1
公开(公告)日：2005-11-03
申请号：US11114098
申请日：2005-04-26
CPC分类号： C08K5/0025 , C08K3/01 , C08K3/24 , C08L27/16
摘要： Ionically curable fluoroelastomers based on vinylidenfluoride (VDF) comprising: a) 100 parts by weight of fluoroelastomer based on vinylidenfluoride (VDF) substantially polar end groups free; b) from 0.1 to 0.35 phr of accelerating agent; c) from 1 to 15 phr of curing agent; d) from 2 to 20 phr of one or more inorganic acid acceptors, preferably bivalent metal oxides; e) from 0 to 3 phr, preferably from 0 to 1.5 phr of one or more basic compounds preferably hydroxides of bivalent metals or of weak acid metal salts; f) from 0 to 80 phr of reinforcing fillers;. g) from 0 to 3 phr of coadjuvants of processability.
摘要翻译： 基于乙烯基氟化物（VDF）的可离子固化的含氟弹性体，包括：a）100重量份基于无极性基团的乙烯基氟化物（VDF）的含氟弹性体; b）0.1至0.35phr的促进剂; c）1〜15phr固化剂; d）2至20phr的一种或多种无机酸受体，优选二价金属氧化物; e）0-3phr，优选0-1.5phr一种或多种碱性化合物，优选二价金属或弱酸性金属盐的氢氧化物; f）0至80phr的增强填料。 g）0-3phr可加工性的佐剂。
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