Explosion taming surfactants for the production of perfluoropolymers
    55.
    发明授权
    Explosion taming surfactants for the production of perfluoropolymers 有权
    用于生产全氟聚合物的爆炸性游离表面活性剂

    公开(公告)号:US08119750B2

    公开(公告)日:2012-02-21

    申请号:US11457236

    申请日:2006-07-13

    IPC分类号: C08F16/24

    CPC分类号: C08F14/26 C08F2/22

    摘要: A process comprising polymerizing tetrafluoroethylene in an aqueous emulsion in the presence of a non-telogenic surfactant having an anionic portion with the general formula (I): Rf—O-L-CO2—  (I) wherein Rf is selected from a partially fluorinated alkyl group, a perfluorinated alkyl group, a partially fluorinated alkyl group interrupted by one or more oxygen atoms, and a perfluorinated alkyl group interrupted by one or more oxygen atoms, wherein Rf has from 1 to 10 carbon atoms; and L is an alkylene group having the general formula (CX2)n wherein each X is independently selected from Rf, fluorine, and hydrogen and n is selected from 1 to 5, with the proviso that the surfactant contains at least one unit selected from a —CH2— unit and a —CHF— unit. Also provided are aqueous dispersions comprising these surfactants and methods of coating substrates with the aqueous dispersions.

    摘要翻译: 在具有通式(I)的阴离子部分的非脱落表面活性剂存在下,在水乳液中聚合四氟乙烯的方法:Rf-OL-CO 2 - (I)其中Rf选自部分氟化的烷基, 全氟化烷基,被一个或多个氧原子间隔的部分氟化烷基和被一个或多个氧原子间隔的全氟化烷基,其中Rf具有1至10个碳原子; 并且L是具有通式(CX2)n的亚烷基,其中每个X独立地选自Rf,氟和氢,n选自1至5,条件是表面活性剂含有至少一个选自 -CH2-单元和-CHF-单元。 还提供了包含这些表面活性剂的水分散体和用水分散体涂覆底物的方法。

    Dental Composition Containing a Surfactant and an F-Containing Compound, Process of Production and Use Thereof
    59.
    发明申请
    Dental Composition Containing a Surfactant and an F-Containing Compound, Process of Production and Use Thereof 有权
    含有表面活性剂和含F化合物的牙科用组合物,其制造及使用方法

    公开(公告)号:US20100292362A1

    公开(公告)日:2010-11-18

    申请号:US12747927

    申请日:2008-12-17

    IPC分类号: A61K6/10

    摘要: The invention relates to a curable dental composition comprising a) a curable organopolysiloxane polymer, b) a crosslinker compound capable of crosslinking said organopolysiloxane polymer, c) a catalyst capable of catalyzing a crosslinking reaction of component (A) and component (B), d) a surfactant, e) a F-containing compound, wherein the F-containing compound has the following formula: (G1-L1-O)s-Rfa-O-L2-G2 wherein: G1 and G2 each independently represents a non-ionic endgroup that is free of polyoxyalkylene groups or contains polyoxyalkylene such that the total amount thereof in the F-containing compound is not more than 10% by weight based on the molecular weight of the F-containing compound; L1 and L2 each independently represents an aliphatic hydrocarbon group or a partially or fully fluorinated aliphatic hydrocarbon group; Rfa represents a mono-valent or divalent partially or fully fluorinated aliphatic group or a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms; with the proviso that at least one of the following conditions is fulfilled: (i) at least one of the moieties L1-G1 and L2-G2 is partially or fully fluorinated or (ii) Rf is a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms. The invention also relates to a kit of parts and a method of producing a dental composition as well as the use of the dental composition for the preparation of or as impression material or for the preparation of crowns and bridges.

    摘要翻译: 本发明涉及一种可固化牙科用组合物,其包含a)可固化的有机基聚硅氧烷聚合物,b)能够交联所述有机聚硅氧烷聚合物的交联剂化合物,c)能够催化组分(A)和组分(B)的交联反应的催化剂,d )表面活性剂,e)含F化合物,其中所述含F化合物具有下式:(G1-L1-O)s-Rfa-O-L2-G2其中:G1和G2各自独立地表示非 - 不含聚氧化烯基团或含有聚氧化烯的离子性端基,使得其含氟化合物的总量相对于含F化合物的分子量为10重量%以下; L1和L2各自独立地表示脂族烃基或部分或完全氟化的脂族烃基; Rfa表示被一个或多个氧原子间隔的一价或二价部分或完全氟化的脂族基团或部分或全部氟化脂族基团; 条件是满足以下条件中的至少一个:(i)部分L1-G1和L2-G2中的至少一个部分或完全氟化,或(ii)Rf是部分或完全氟化的脂族基团,被 一个或多个氧原子。 本发明还涉及一种用于制备牙科用组合物的试剂盒和牙科用组合物的制备方法,或用作制备印模材料或用于制备牙冠和牙桥的牙科用组合物。