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公开(公告)号：US4604261A
公开(公告)日：1986-08-05
申请号：US626519
申请日：1984-06-29
申请人： Nai Y. Chen , Thomas F. Degnan
发明人： Nai Y. Chen , Thomas F. Degnan
CPC分类号： B01J8/0438 , B01J8/0415 , B01J8/0469 , B01J8/048 , C10G45/58 , C10G49/002
摘要： A hydroprocessing trickle reactor construction which will facilitate the catalytic dewaxing of liquid petroleum or lube feedstocks in a highly efficient and economical manner, particularly through the use of reactors employing stationary bed of a defined, shape-selective crystalline aluminosilicate zeolite catalyst, preferably ZSM-5. Pursuant to one embodiment of the hydroprocessing reactor, the latter is essentially constituted of a trickle bed reactor wherein a plurality of vertically tiered and staggered trays support the beds of catalyst material, such as the crystalline zeolite, and through which the liquid petroleum feedstock trickles downwardly from the upper end of the reactor, while hydrogen is concurrently injected into the catalyst on each of the trays. This causes the hydrogen to percolate through the catalyst bed and to contact and efficiently strip the downwardly trickling stream of liquid petroleum feedstock of low boiling conversion products or waxy components, such as naphtha. Pursuant to a second embodiment of the hydroprocessing catalystic reactor construction, inclined supporting stationary beds of catalyst are vertically tiered with the liquid petroleum stock trickling down through the reactor so as to enter the upper portion of the bed contained in each tray, flowing along the inclined tray surface thereof forming a liquid seal along the bottom surface of each tray and forcing hydrogen introduced into each tray to flow upwardly through the catalyst bed and react with the liquid petroleum feedstock. The liquid is directed to trickle downwardly to a lower catalyst bed through the interposition of suitable baffles, whereas hydrogen gas inclusive of low boiling, volatile conversion products stripped from the liquid petroleum in the catalyst beds flows upwardly through passages beneath the baffles into a central vertical conduit in the reactor, from when they are conducted by being entrained in an upwardly-flowing carrier gas out of the upper end of the reactor.
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52.发明授权Hydrotreating/isomerization process to produce low pour point distillate fuels and lubricating oil stocks 失效加氢处理/异构化工艺生产低倾点馏出燃料和润滑油库存
公开(公告)号：US4518485A
公开(公告)日：1985-05-21
申请号：US557696
申请日：1983-12-02
摘要： A process for dewaxing a hydrocarbon feedstock with a relatively high pour point and containing paraffins selected from the group of normal paraffins and slightly branched paraffins and sulfur and nitrogen compounds which comprises subjecting said oil to hydrotreating in a hydrotreating zone operated at hydrotreating conditions sufficient to remove at least a portion of said sulfur and nitrogen compounds and subjecting said hydrotreated oil to catalytic dewaxing by contacting said oil with a catalyst comprising zeolite beta having a silica/alumina ratio of at least 30:1 and a hydrogenation/dehydrogenation component under isomerization conditions.
摘要翻译： 一种使具有较高倾点的烃原料脱蜡并含有选自正构烷烃和轻支化链烷烃和硫和氮化合物的链烷烃的方法，其包括使所述油在加氢处理区中加氢处理，所述加氢处理区在加氢处理条件下操作，所述加氢处理条件足以除去 所述硫和氮化合物的至少一部分，并使所述加氢处理的油通过使所述油与二氧化硅/氧化铝比为至少30:1的沸石β和在异构化条件下的氢化/脱氢组分接触的催化剂进行催化脱蜡。
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公开(公告)号：US4501926A
公开(公告)日：1985-02-26
申请号：US533017
申请日：1983-09-16
摘要： Hydrocarbon feedstocks such as distillate fuel oils and gas oils are dewaxed by isomerizing the waxy components over a zeolite beta catalyst. The process may be carried out in the presence or absence of added hydrogen. Preferred catalysts have a zeolite silica:alumina ratio over 100:1.
摘要翻译： 诸如馏出燃料油和瓦斯油之类的烃原料通过在沸石β催化剂上使蜡状组分异构化来脱蜡。 该方法可以在存在或不加入氢气的情况下进行。 优选的催化剂具有100:1以上的沸石二氧化硅：氧化铝比。
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公开(公告)号：US4479804A
公开(公告)日：1984-10-30
申请号：US301356
申请日：1981-09-11
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
摘要： A fixed-sulfur, solid fuel product is obtained by an improved coking process wherein petroleum fractions are coked in the presence of added alkaline earth metal oxides. The fixed-sulfur, solid fuel product comprises coke and from about 3 to 30 weight percent, preferably from about 5 to 15 weight percent, "ash" (calculated as calcium oxide) derived from the alkaline earth additive. The quantity alkaline earth metal oxide or precursor thereof added to the coking zone is dependent on the sulfur content of the product coke and on the desired ash content of the solid fuel product. The coking zone may comprise delayed, fluid bed, or moving bed cokers.
摘要翻译： 通过改进的焦化方法获得固定硫固体燃料产物，其中石油馏分在加入的碱土金属氧化物的存在下被焦化。 固体硫固体燃料产品包括焦炭和约3至30重量％，优选约5至15重量％的衍生自碱土金属添加剂的“灰分”（以氧化钙计算）。 添加到焦化区中的碱土金属氧化物或其前体的量取决于产物焦炭的硫含量和固体燃料产品的所需灰分含量。 焦化区可以包括延迟的流化床或移动床焦炭。
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公开(公告)号：US4411770A
公开(公告)日：1983-10-25
申请号：US369330
申请日：1982-04-16
申请人： Nai Y. Chen , Eric J. Scott , David S. Shihabi
发明人： Nai Y. Chen , Eric J. Scott , David S. Shihabi
CPC分类号： C10G47/16
摘要： This invention provides an improved process for hydroconversion of a heavy hydrocarbon oil having a CCR content of 8-30 weight percent, which process involves contacting the heavy oil in a hydrovisbreaking zone containing a low acidity zeolite catalyst and recovering and fractionating the visbroken effluent to provide distillate products and a 1000.degree. F.+ fraction which has a Kinematic Viscosity between about 30,000-60,000 centistokes at 100.degree. F.
摘要翻译： 本发明提供了一种用于加氢转化具有8-30重量％的CCR含量的重质烃的改进方法，该方法包括使重油与含有低酸度沸石催化剂的加氢脱硫区接触并回收和分馏分解出的流出物以提供 蒸馏产物和1000°F +级分，其在100°F下的运动粘度在约30,000-60,000厘沲之间。
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公开(公告)号：US4363717A
公开(公告)日：1982-12-14
申请号：US225284
申请日：1981-01-15
申请人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
发明人： Bruce P. Pelrine , Nai Y. Chen , Tsoung Y. Yan
CPC分类号： C10G21/003 , B01D11/0407 , C10G11/08 , C10G47/08
摘要： This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products.The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.
摘要翻译： 本发明提供了一种将重质烃油升级为机动车燃料产品的方法。 在超临界条件下将重质烃油与金属卤化物催化剂和溶剂组分混合以形成（1）含有精炼烃裂化物的致密气体溶剂相，其基本上不含金属卤化物催化剂含量; 和（2）残留沥青相。
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公开(公告)号：US4305809A
公开(公告)日：1981-12-15
申请号：US127667
申请日：1980-03-06
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
IPC分类号： C10B55/00 , C10L9/10 , C10G9/32 , C10G19/073
摘要： A fixed-sulfur, solid fuel product is obtained by an improved coking process wherein petroleum fractions are coked in the presence of added alkaline earth metal oxides. The fixed-sulfur, solid fuel product comprises coke and from about 3 to 30 weight percent, preferably from about 5 to 15 weight percent, "ash" (calculated as calcium oxide) derived from the alkaline earth additive. The quantity alkaline earth metal oxide or precursor thereof added to the coking zone is dependent on the sulfur content of the product coke and on the desired ash content of the solid fuel product. The coking zone may comprise delayed, fluid bed, or moving bed cokers.
摘要翻译： 通过改进的焦化方法获得固定硫固体燃料产物，其中石油馏分在加入的碱土金属氧化物的存在下被焦化。 固体硫固体燃料产品包括焦炭和约3至30重量％，优选约5至15重量％的衍生自碱土金属添加剂的“灰分”（以氧化钙计算）。 添加到焦化区中的碱土金属氧化物或其前体的量取决于产物焦炭的硫含量和固体燃料产品的所需灰分含量。 焦化区可以包括延迟的流化床或移动床焦炭。
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公开(公告)号：US4263129A
公开(公告)日：1981-04-21
申请号：US071979
申请日：1979-09-04
申请人： Nai Y. Chen , David S. Shihabi
发明人： Nai Y. Chen , David S. Shihabi
CPC分类号： B01J29/405 , B01J29/40 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/42 , Y10S208/02
摘要： Conversion of hydrocarbons is conducted over low acidity zeolites such as the sodium form of zeolite ZSM-5 to yield products like those produced by hydrocracking but with substantially decreased proportion of light hydrocarbons having one to four carbon atoms. (Sulfiding of sodium zeolites activates such sodium zeolites for the present purpose.) The hydrocarbon conversion is conducted with mixed-phase charge (Trickle mode) under hydrogen pressure or with liquid-phase charge in a liquid-full reactor.
摘要翻译： 碳氢化合物的转化是通过低沸点沸石如沸石ZSM-5的沸石进行的，以产生类似于通过加氢裂化产生的产物，但具有1-4个碳原子的轻质烃的比例实质上降低。 （为了本目的，钠沸石的硫化活化这种钠沸石。）在氢气压力下或在液体充满反应器中用液相电荷在混合相电荷（涓流模式）下进行烃转化。
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公开(公告)号：US4213847A
公开(公告)日：1980-07-22
申请号：US39468
申请日：1979-05-16
申请人： Nai Y. Chen , Ikai Wang
发明人： Nai Y. Chen , Ikai Wang
CPC分类号： B01J8/0453 , B01J2208/00274 , B01J2208/00283 , C10G2400/10 , Y10S203/06
摘要： Heavy petroliferous stocks such as vacuum and atmospheric resids, tar sand oils, shale oils, liquids from conversion of coal and the like are concurrently distilled and hydroprocessed for removal of sulfur, nitrogen and metals and are hydrocracked or otherwise hydroprocessed in a packed distillation column under hydrogen pressure wherein the packing is constituted, at least to a substantial extent in both stripping and rectifying sections by catalyst suited to the desired conversions. In a specific application to catalytic hydrodewaxing of lubricating oil stocks, improvement of Viscosity Index (VI) of dewaxed product results.
摘要翻译： 同时蒸馏并加氢处理重金属含量如真空和常压渣油，焦油砂油，页岩油，转化煤等液体，并进行加氢处理以除去硫，氮和金属，并加氢裂化或以其他方式加氢处理在填料蒸馏塔中 通过适合所需转化率的催化剂，至少大大地在汽提和精馏段中构成填料的氢气压力。 在具体应用于润滑油原料的催化加氢脱蜡时，脱蜡产物的粘度指数（VI）得到改善。
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公开(公告)号：US4211635A
公开(公告)日：1980-07-08
申请号：US32080
申请日：1979-04-23
申请人： Nai Y. Chen
发明人： Nai Y. Chen
CPC分类号： C10G45/64 , C10G2400/10
摘要： Distillate petroliferous stocks such as neutral lubricating stocks and distillate fuels are hydroprocessed for dewaxing and/or removal of sulfur, nitrogen and metals under hydrogen pressure in a downflow reactor packed with a catalyst suited to the desired conversions in which lighter portions of the charge are introduced to respectively lower levels of the catalyst bed, whereby product withdrawn from the bottom of the reactor is reconstituted distillate of which lighter portions have received milder treatment. In a specific application to catalytic hydrodewaxing of lubricating oil stocks, improvement of Viscosity Index (VI) of dewaxed product results.
摘要翻译： 在装有催化剂的下流式反应器中，加氢处理含有中性润滑油和馏出燃料的蒸馏石油，用于在氢气压力下脱蜡和/或除去硫，氮和金属，其中所述催化剂填充有适合于引入较轻部分电荷的所需转化率的催化剂 以分别降低催化剂床的含量，由此从反应器底部排出的产物是其较轻部分已经受到较轻处理的重组馏出物。 在具体应用于润滑油原料的催化加氢脱蜡时，脱蜡产物的粘度指数（VI）得到改善。
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