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公开(公告)号：US4877581A
公开(公告)日：1989-10-31
申请号：US239257
申请日：1988-09-01
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
摘要： A paraffin conversion process for hydroisomerizing a nitrogen and wax-containing hydrocarbon feedstock comprising contacting the feedstock with a catalyst including a ZSM-11 zeolite characterized by an alpha value from about 10 to 50, in combination with a Group VIII metal hydrogenation-dehydrogenation component of platinum or palladium at a temperature of about 400.degree. F. to about 850.degree. F. and at a pressure of from about 200 to about 2000 psig.
摘要翻译： 一种用于使含氮和含蜡的烃原料加氢异构化的链烷烃转化方法，包括使原料与包含Z值为约10至50的α值的ZSM-11沸石的催化剂结合，与第VIII族金属加氢脱氢组分 铂或钯，温度为约400°F至约850°F，压力为约200至约2000psig。
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公开(公告)号：US4479804A
公开(公告)日：1984-10-30
申请号：US301356
申请日：1981-09-11
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
摘要： A fixed-sulfur, solid fuel product is obtained by an improved coking process wherein petroleum fractions are coked in the presence of added alkaline earth metal oxides. The fixed-sulfur, solid fuel product comprises coke and from about 3 to 30 weight percent, preferably from about 5 to 15 weight percent, "ash" (calculated as calcium oxide) derived from the alkaline earth additive. The quantity alkaline earth metal oxide or precursor thereof added to the coking zone is dependent on the sulfur content of the product coke and on the desired ash content of the solid fuel product. The coking zone may comprise delayed, fluid bed, or moving bed cokers.
摘要翻译： 通过改进的焦化方法获得固定硫固体燃料产物，其中石油馏分在加入的碱土金属氧化物的存在下被焦化。 固体硫固体燃料产品包括焦炭和约3至30重量％，优选约5至15重量％的衍生自碱土金属添加剂的“灰分”（以氧化钙计算）。 添加到焦化区中的碱土金属氧化物或其前体的量取决于产物焦炭的硫含量和固体燃料产品的所需灰分含量。 焦化区可以包括延迟的流化床或移动床焦炭。
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公开(公告)号：US4305809A
公开(公告)日：1981-12-15
申请号：US127667
申请日：1980-03-06
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
IPC分类号： C10B55/00 , C10L9/10 , C10G9/32 , C10G19/073
摘要： A fixed-sulfur, solid fuel product is obtained by an improved coking process wherein petroleum fractions are coked in the presence of added alkaline earth metal oxides. The fixed-sulfur, solid fuel product comprises coke and from about 3 to 30 weight percent, preferably from about 5 to 15 weight percent, "ash" (calculated as calcium oxide) derived from the alkaline earth additive. The quantity alkaline earth metal oxide or precursor thereof added to the coking zone is dependent on the sulfur content of the product coke and on the desired ash content of the solid fuel product. The coking zone may comprise delayed, fluid bed, or moving bed cokers.
摘要翻译： 通过改进的焦化方法获得固定硫固体燃料产物，其中石油馏分在加入的碱土金属氧化物的存在下被焦化。 固体硫固体燃料产品包括焦炭和约3至30重量％，优选约5至15重量％的衍生自碱土金属添加剂的“灰分”（以氧化钙计算）。 添加到焦化区中的碱土金属氧化物或其前体的量取决于产物焦炭的硫含量和固体燃料产品的所需灰分含量。 焦化区可以包括延迟的流化床或移动床焦炭。
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公开(公告)号：US4808296A
公开(公告)日：1989-02-28
申请号：US18112
申请日：1987-02-24
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
CPC分类号： C10G45/64
摘要： The present invention is a catalyst composition and method for dewaxing a wax-containing hydrocarbon feedstock which includes a zeolite characterized by a silica-to-alumina ratio from about 12 to about 200, a Constraint Index of from about 1 to about 12, and an alpha value of not more than about 50, in combination with a Group VIII metal hydrogenation-dehydrogenation component.
摘要翻译： 本发明是一种用于脱蜡含蜡烃原料的催化剂组合物和方法，其包括以二氧化硅与氧化铝的比为约12至约200，约束指数为约1至约12的沸石和 α值不超过约50，与VIII族金属氢化脱氢组分组合。
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公开(公告)号：US4790928A
公开(公告)日：1988-12-13
申请号：US153395
申请日：1988-02-08
CPC分类号： B01J29/40 , C07C1/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/40
摘要： The acidity of a zeolite catalyst is reduced by calcination in an essentially water-free atmosphere at temperatures above 700.degree. C., preferably from 725.degree. to 800.degree. C., to reduce the alpha value to less than about 10 percent of its original value. The low acidity catalysts produced in this way may be used for conversions requiring low acidity, shape selective catalysis, including dewaxing. The calcined, low acidity catalysts exhibit improved dewaxing activity.
摘要翻译： 沸石催化剂的酸度通过在高于700℃，优选725℃至800℃的温度下在基本无水的气氛中煅烧而降低，以将α值降低到其原始值的约10％ 。 以这种方式生产的低酸性催化剂可用于需要低酸度，形状选择性催化（包括脱蜡）的转化。 煅烧的低酸度催化剂表现出改善的脱蜡活性。
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公开(公告)号：US4358290A
公开(公告)日：1982-11-09
申请号：US163599
申请日：1980-06-27
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
CPC分类号： C10L9/10
摘要： An improved solid fuel obtained by blending fluid coke with 2 to 20 wt. % of a heavy petroleum liquid.
摘要翻译： 通过将流体焦炭与2〜20重量份混合而获得的改进的固体燃料。 ％重质石油液体。
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公开(公告)号：US4302324A
公开(公告)日：1981-11-24
申请号：US163835
申请日：1980-06-27
申请人： Nai Y. Chen , Dennis E. Walsh
发明人： Nai Y. Chen , Dennis E. Walsh
CPC分类号： C10B55/02
摘要： A delayed coking process in which part of the coke produced is heated by partial burning and mixed with preheated coker feedstock to raise the temperature of the coking mass present in the coking drums. The rapid heat transfer thus obtained brings about some immediate flashing of volatiles and makes possible higher than usual temperatures in the coking drums. The results are a reduction of residence time in the drums and an increase in the yield of volatile products. Hot coke in excess of that required to heat the feed may be gasified. Thus, resultant net coke yields are lower than the conventional delayed coking process.
摘要翻译： 延迟焦化方法，其中产生的焦炭的一部分通过部分燃烧加热并与预热的焦化器原料混合，以提高存在于焦化鼓中的焦化物质的温度。 如此获得的快速热传递导致挥发物的一些即时闪蒸，并且使得可能比焦化鼓中的通常温度高。 结果是减少了在鼓中的停留时间和挥发性产物的产率的增加。 超过加热进料所需热焦炭可能气化。 因此，得到的净焦炭产量低于常规的延迟焦化方法。
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公开(公告)号：US4247384A
公开(公告)日：1981-01-27
申请号：US20601
申请日：1979-03-15
CPC分类号： C10G1/083
摘要： Improved method for solubilizing solid carbonaceous materials, e.g., wood and/or coal in an aromatic petroleum or coal-derived solvent in the presence of alkali and hydrogen transfer agent at elevated temperatures. The liquid products can be used as fuels or further processed into desirable products.
摘要翻译： 在碱和氢转移剂存在下，在升高的温度下，在芳香族石油或来自煤的溶剂中溶解固体碳质材料（例如木材和/或煤）的改进方法。 液体产品可用作燃料或进一步加工成所需产品。
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公开(公告)号：US09337505B2
公开(公告)日：2016-05-10
申请号：US14007667
申请日：2012-03-31
CPC分类号： H01M8/0618 , C01B3/382 , C01B2203/0244 , C01B2203/042 , C01B2203/0485 , C01B2203/065 , C01B2203/1023 , C01B2203/1247 , C01B2203/1614 , C10G27/04 , C10G2300/1022 , C10G2300/1051 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4006 , C10G2300/70 , C10G2300/80 , C10G2300/805 , C10G2300/807 , C10G2400/04 , C10G2400/08
摘要： A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.
摘要翻译： 将包含大于50ppmw硫的液体燃料重整为小于400ppmw的硫的方法，该方法包括将含有一种或多种浓度从大于50ppmw至小于400ppmw硫的一种或多种有机硫化合物的液体烃燃料与 氧化剂和蒸汽或水，所述接触发生在催化剂床中，所述催化剂床包含沉积在超短通道长度金属基底上的重整催化剂，使得该方法在高于950℃的峰值催化剂温度下进行，以便 以产生包含氢和一氧化碳的重整产物混合物。
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公开(公告)号：US20140017583A1
公开(公告)日：2014-01-16
申请号：US14007667
申请日：2012-03-31
IPC分类号： H01M8/06
CPC分类号： H01M8/0618 , C01B3/382 , C01B2203/0244 , C01B2203/042 , C01B2203/0485 , C01B2203/065 , C01B2203/1023 , C01B2203/1247 , C01B2203/1614 , C10G27/04 , C10G2300/1022 , C10G2300/1051 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4006 , C10G2300/70 , C10G2300/80 , C10G2300/805 , C10G2300/807 , C10G2400/04 , C10G2400/08
摘要： A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.
摘要翻译： 将包含大于50ppmw硫的液体燃料重整为小于400ppmw的硫的方法，该方法包括将含有一种或多种浓度从大于50ppmw至小于400ppmw硫的一种或多种有机硫化合物的液体烃燃料与 氧化剂和蒸汽或水，所述接触发生在催化剂床中，所述催化剂床包含沉积在超短通道长度金属基底上的重整催化剂，使得该方法在高于950℃的峰值催化剂温度下进行，以便 以产生包含氢和一氧化碳的重整产物混合物。
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