公开(公告)号：US07226695B2

公开(公告)日：2007-06-05

申请号：US10479486

申请日：2002-06-11

申请人： Masataka Takeuchi ,  Hiroshi Yasuda ,  Junko Mizuguchi

发明人： Masataka Takeuchi ,  Hiroshi Yasuda ,  Junko Mizuguchi

IPC分类号： H01M4/02

CPC分类号： H01M4/137 ,  C08G61/122 ,  C08G73/0694 ,  H01G11/56 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M4/625 ,  H01M10/36 ,  H01M2300/0011 ,  H01M2300/0065 ,  H01M2300/0082 ,  Y02E60/13

摘要： The present invention relates to a method for producing a polymer/conductive carbon composite electrode comprising dehydration condensation polymerization of a tetramine derivative and a tetracarbonyl compound in the presence of an electrically conductive carbon material. The synthetized polymer comprises quinoxaline structural units such as polyphenyl quinoxaline (PPQ) and serves as an active material having proton conductivity. The composite material for electrode obtained by the method has a large capacity of inserting/releasing a proton and excellent in durability. An electrode comprising the composite material and a secondary battery comprising the electrode is excellent in safety and reliability high-speed current characteristics, has a longer life and a larger gravimetric energy density (Wh/kg).

摘要翻译： 本发明涉及一种聚合物/导电性碳复合电极的制造方法，其特征在于，在导电性碳材料的存在下，包括四胺衍生物和四羰基化合物的脱水缩聚。 合成的聚合物包括喹喔啉结构单元如聚苯基喹喔啉（PPQ），并且用作具有质子传导性的活性材料。 通过该方法获得的电极用复合材料具有大的插入/释放质子的能力，并且耐久性优异。 包含复合材料的电极和包含电极的二次电池具有优异的安全性和可靠性的高速电流特性，具有更长的寿命和更大的重量能量密度（Wh / kg）。

公开(公告)号：US06720109B1

公开(公告)日：2004-04-13

申请号：US09684633

申请日：2000-10-10

申请人： Masataka Takeuchi ,  Junko Mizuguchi

发明人： Masataka Takeuchi ,  Junko Mizuguchi

IPC分类号： H01M460

CPC分类号： H01M4/608 ,  C08G61/122 ,  C08G73/0694 ,  H01M4/60

摘要： The present invention provides a proton migration type secondary battery using as an electrode active material a polymer having a quinoxaline structure exhibiting a large proton insertion-release capacity, the secondary battery being excellent in its safety, reliability and rapid current properties, and having a long life and a high weight energy density (kWh/kg), compared with the conventional aqueous solution type double layer capacitor and a lead acid battery using sulfuric acid. Also, the present invention provides a proton migration type secondary battery excellent in productivity and further in safety and reliability by using a solid electrolyte and/or a gel electrolyte obtained by curing a mixture of a polymerizable compound excellent in its polymerizability and a proton conductive electrolyte. Further, the present inventors provide a proton migration type secondary battery having a further long life and excellent in reliability by adding a non-electrically conductive powder to the electrolyte.

摘要翻译： 本发明提供一种质子迁移型二次电池，其使用具有显示出大的质子插入释放能力的喹喔啉结构的聚合物作为电极活性物质，二次电池的安全性，可靠性和电流特性优异，且具有长的 寿命和高重量能量密度（kWh / kg），与常规水溶液型双层电容器和使用硫酸的铅酸电池相比，本发明提供了一种质量优良的质子迁移型二次电池， 通过使通过固化聚合性优异的聚合性化合物与质子传导电解质的混合物而获得的固体电解质和/或凝胶电解质的安全性和可靠性。此外，本发明人提供了具有更长寿命的质子迁移型二次电池 并且通过向第三种添加非导电性粉末而具有优异的可靠性 电解液。

公开(公告)号：US06306509B2

公开(公告)日：2001-10-23

申请号：US08946850

申请日：1997-10-08

申请人： Masataka Takeuchi ,  Shuichi Naijo ,  Takashi Ohkubo ,  Junji Yotsuyanagi ,  Motoyuki Hirata

发明人： Masataka Takeuchi ,  Shuichi Naijo ,  Takashi Ohkubo ,  Junji Yotsuyanagi ,  Motoyuki Hirata

IPC分类号： B32B2700

CPC分类号： B32B37/24 ,  B32B7/02 ,  G01N27/4073 ,  G02F1/1525 ,  H01G9/155 ,  H01G11/56 ,  H01M6/181 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1053 ,  H01M8/1067 ,  H01M8/109 ,  H01M8/1093 ,  H01M2300/0082 ,  Y02E60/13 ,  Y10T428/24901 ,  Y10T428/30 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31598 ,  Y10T428/31605 ,  Y10T428/31681 ,  Y10T428/31728 ,  Y10T428/31765 ,  Y10T428/31794

摘要： A laminate comprising an ion conductive material having excellent ion conductivity at room temperature or at lower temperatures, a small water content, sufficiently high mechanical strength and storage stability to allow for handling the ion conductive material in practice, and a form which is easily integrated into an electrochemical element or electrochemical devices. Also disclosed is a production method thereof, and a method of producing a battery, a capacitor or an electrochemical element or apparatus using the laminate. The laminate comprises an intermediate layer of an ion conductive material having on the upper and lower portions thereof outer layers having an ion conductivity lower than that of the intermediate layer. Furthermore, at least one of the outer layers is a layer comprising a non electron-conductive material.

摘要翻译： 一种层压体，其包含在室温或较低温度下具有优异的离子传导性的离子导电材料，水分含量低，机械强度足够高和储存稳定性，以便于在实践中处理离子导电材料，以及易于结合到 电化学元件或电化学装置。 还公开了其制造方法，以及使用该层压体的电池，电容器或电化学元件或装置的制造方法。 层压体包括离子传导材料的中间层，其中上部和下部具有比中间层低的离子传导性的外层。 此外，外层中的至少一层是包含非电子传导材料的层。

公开(公告)号：US5665490A

公开(公告)日：1997-09-09

申请号：US478760

申请日：1995-06-07

申请人： Masataka Takeuchi ,  Koji Tokita ,  Miyuki Ueda ,  Jun Noguchi ,  Hideo Yashima ,  Eri Tamura ,  Kazuhiko Ooga

发明人： Masataka Takeuchi ,  Koji Tokita ,  Miyuki Ueda ,  Jun Noguchi ,  Hideo Yashima ,  Eri Tamura ,  Kazuhiko Ooga

IPC分类号： C08F290/06 ,  C08F290/14 ,  C08G18/28 ,  C08G18/48 ,  C08G18/81 ,  C08G65/329 ,  C08G65/332 ,  C08G65/333 ,  H01B1/12 ,  H01G9/02 ,  H01G9/025 ,  H01G9/038 ,  H01M4/62 ,  H01M6/18 ,  H01M6/40 ,  H01M10/052 ,  H01M10/0565

CPC分类号： H01G9/038 ,  C08F290/062 ,  C08F290/142 ,  C08G18/283 ,  C08G18/2835 ,  C08G18/4833 ,  C08G18/4837 ,  C08G18/4883 ,  C08G18/8116 ,  C08G65/329 ,  C08G65/3322 ,  C08G65/33348 ,  H01B1/122 ,  H01G11/56 ,  H01G9/025 ,  H01M10/052 ,  H01M10/0565 ,  H01M4/621 ,  H01M4/622 ,  H01M6/181 ,  H01M6/40 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022 ,  Y10S977/948 ,  Y10T29/417 ,  Y10T29/49108

摘要： A solid polymer electrolyte comprising a composite of (a) a polymeric component which comprises (i) a polymer obtained from at least one compound represented by general formula (IA), (IIA) and/or (IIIA) as described in the specification; or (ii) a polymer obtained from at least one compound having alcoholic hydroxyl groups wherein at least one hydrogen atom of said alcoholic hydroxyl groups is replaced by a unit represented by general formula (X) or (XI) as described in the specification, and (b) at least one electrolyte salt, which has a high ionic conductivity and can be made into a thin film. The present invention is also directed to an electrode comprising the solid polymer electrolyte and an electroactive substance or polarizable material; as well as a process for manufacturing the same. In addition, the present invention is directed to a primary and secondary battery having the solid polymer electrolyte, as well as a process for manufacturing the same. The battery of the present invention has a high battery, has good cyclability. Finally, the present invention is directed to a solid-state electric double layer capacitor comprising the solid polymer electrolyte, as well as a process for manufacturing the same. The electric double layer capacitor has a high output voltage and a large take-out current.

摘要翻译： 包含（a）聚合物组分的复合材料的固体聚合物电解质，其包含（i）由至少一种由通式（IA）表示的化合物，（IIA）和/或（IIIA）表示的化合物获得的聚合物，如说明书中所述; 或者（ii）由至少一种具有醇羟基的化合物获得的聚合物，其中所述醇羟基的至少一个氢原子被如本说明书所述的由通式（X）或（XI）表示的单元代替，和 （b）至少一种电解质盐，其具有高的离子导电性并可制成薄膜。 本发明还涉及包含固体聚合物电解质和电活性物质或可极化材料的电极; 以及其制造方法。 此外，本发明涉及具有固体聚合物电解质的一次电池和二次电池及其制造方法。 本发明的电池具有高电池，具有良好的循环性。 最后，本发明涉及一种包含固体聚合物电解质的固态双电层电容器及其制造方法。 双电层电容器具有高输出电压和大的取出电流。