公开(公告)号：US5268475A

公开(公告)日：1993-12-07

申请号：US784198

申请日：1991-10-28

申请人： Urs Lauk

发明人： Urs Lauk

IPC分类号： C07D498/04 ,  C07D519/00 ,  C09B19/00 ,  C09B19/02 ,  C09B62/04 ,  C09B67/22 ,  D06P3/10 ,  D06P3/66 ,  D06P3/82

CPC分类号： C07D498/04 ,  C07D519/00 ,  C09B19/02 ,  C09B62/043

摘要： The compounds of formula (1) are suitable for use as direct dyes for dyeing and printing a wide range of materials, especially cellulosic fibers, to give dyeings and prints of good all-round fastness properties: ##STR1## wherein R and R.sub.1 are each independently of the other hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl,X is a direct bond, --O--, --S-- or --N(R.sub.4)--, wherein R.sub.4 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl, X.sub.1 is --O--, --S-- or --N(R.sub.4)--, wherein R.sub.4 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aryl or aralkyl,Y and Y.sub.1 are each independently of the other C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, sulfo, carboxy, carbamoyl, N-mono- or N,N-di-C.sub.1 -C.sub.4 alkylcarbamoyl, N-phenyl- or N,N-diphenylcarbamoyl, sulfamoyl, N-mono- or N,N-di-C.sub.1 -C.sub.4 alkylsulfamoyl or N-phenyl- or N,N-diphenylsulfamoyl, Z and Z.sub.1 are each independently of the other hydroxy or unsubstituted or substituted alkyl, aryl or aralkyl,R.sub.2 and R.sub.3 are each independently of the other hydrogen, halogen, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, unsubstituted or substituted phenyl, benzyl, benzoylamino or phenoxy, sulfo, carboxy, carbamoyl, phenylcarbamoyl or C.sub.2 -C.sub.5 alkanoylamino,A is an unsubstituted or substituted alkylene, cycloalkylene, arylene or aralkylene radical,B is a bivalent organic linking group, andm, n, p and q are each independently of one another 0 or 1.

摘要翻译： 式（1）的化合物适合用作染色和印刷各种材料，特别是纤维素纤维的直接染料，以提供良好的全面坚牢性质的染色和印花：（1） 其中R和R 1各自独立地为另一个氢或未取代或取代的烷基，环烷基，芳基或芳烷基，X是直接键，-O-，-S-或-N（R4） - ，其中R4是氢或未取代的 或取代的烷基，环烷基，芳基或芳烷基，X 1为-O-，-S-或-N（R 4） - ，其中R 4为氢或未取代或取代的烷基，环烷基，芳基或芳烷基，Y和Y 1各自独立地为 其它C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，磺基，羧基，氨基甲酰基，N-单或N，N-二-C 1 -C 4烷基氨基甲酰基，N-苯基 - 或N，N-二苯基氨基甲酰基，氨磺酰基， 或N，N-二-C 1 -C 4烷基氨磺酰基或N-苯基 - 或N，N-二苯基氨磺酰基，Z和Z 1各自独立地为另一个羟基或未取代或取代的烷基，芳基或芳烷基，R 2和R 3 氰基，C 1 -C 4烷基，C 1 -C 4烷氧基，未取代或取代的苯基，苄基，苯甲酰氨基或苯氧基，磺基，羧基，氨基甲酰基，苯基氨基甲酰基或C 2 -C 5烷酰基氨基，A是未取代或取代的亚烷基 ，亚环烷基，亚芳基或亚芳基，B是二价有机连接基团，m，n，p和q彼此独立地为0或1。

公开(公告)号：US5149789A

公开(公告)日：1992-09-22

申请号：US490710

申请日：1990-03-08

申请人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

发明人： Joerg L. Jessen ,  Klaus Pandl ,  Hermann Loeffler ,  Bernd Siegel ,  Manfred Patsch

IPC分类号： C09B50/00 ,  C09B62/04 ,  C09B62/08 ,  D06P3/10 ,  D06P3/66

CPC分类号： C09B62/043

摘要： Reactive dyes of the formula ##STR1## where 1 is 0 or 1,n is 0 or 1,E is nitrogen or C--Cl,A is the radical of an azo dye attached to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group,B--if E is nitrogen--is the radical of an azo dye or of a formazan dye which in either case is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group or else--if n is 0--is fluorine, chlorine or unsubstituted or substituted amino, or --if E is C--C1--is fluorine, chlorine or methyl,X.sup.1 and X.sup.2 are independently of the other fluorine or chlorine,X.sup.3 is fluorine or chlorine or else--if E is C--Cl--methylsulfonyl andZ.sup.1 and Z.sup.2 are independently of the other a radical of the formula ##STR2## where L.sup.3 and L.sup.4 are independently of the other hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,with the proviso that l and n are not simultaneously 0 and that, if E is C--Cl or if n is 0 and Z.sup.1 is the radical of the formula ##STR3## where L.sup.3 and L.sup.4 are each as defined above, A may also be the radical of a formazan dye which is bonded to the triazine ring via an imino or C.sub.1 -C.sub.4 -alkylimino group, are useful for dyeing or printing hydroxyl- or nitrogen-containing substrates.

摘要翻译： 式1的反应性染料，其中1为0或1，n为0或1，E为氮或C-Cl，A为通过亚氨基或C 1 -C 4烷基连接到三嗪环上的偶氮染料的基团， 烷基亚氨基，B-如果E是氮 - 是偶氮染料或甲an染料的基团，其在任一情况下通过亚氨基或C 1 -C 4 - 烷基亚氨基键合到三嗪环，否则 - 如果n是0- 是氟，氯或未取代或取代的氨基，或 - 如果E是C-C1 - 是氟，氯或甲基，则X1和X2独立于其他氟或氯，X3是氟或氯，或者 - 如果E是C -Cl-甲基磺酰基，Z 1和Z 2独立地为下式的基团：其中L 3和L 4独立于另一个氢或未取代或取代的C 1 -C 4 - 烷基，其中 条件是l和n不同时为0，并且如果E是C-Cl或如果n是0，并且Z1是式“IMAGE”的基团，其中L3和L4各自如上所定义，A也可以是t 通过亚氨基或C 1 -C 4烷基亚胺基与三嗪环结合的甲an染料的基团可用于染色或印刷含羟基或含氮基底。

公开(公告)号：US5041540A

公开(公告)日：1991-08-20

申请号：US431383

申请日：1989-11-03

申请人： Klaus Pandl ,  Manfred Patsch

发明人： Klaus Pandl ,  Manfred Patsch

IPC分类号： C09B62/038 ,  C09B62/04 ,  D06P1/38

CPC分类号： C09B62/043

摘要： Novel copper formazan reactive dyes which contain one or two chromophoric radicals derived from a copper formazan of the formula ##STR1## where R.sup.1 is hydrogen, hydroxysulfonyl, C.sub.1 -C.sub.4 -alkoxy or chlorine, R.sup.2 is hydrogen or hydroxysulfonyl and one of the two radicals R.sup.3 and R.sup.4 is hydrogen and the other is hydroxysulfonyl or, if at least one of the two radicals R.sup.1 and R.sup.2 is hydroxysulfonyl, R.sup.3 and R.sup.4 can each at the same time also be hydrogen, and two or three halotriazine radicals as reactive system, and salts thereof, are useful for dyeing or printing hydroxyl- or nitrogen-containing organic substrates.

摘要翻译： 新型铜甲脒活性染料，其含有一个或两个衍生自式为“IMAGE”的铜甲two的发色团，其中R1是氢，羟基磺酰基，C1-C4-烷氧基或氯，R2是氢或羟基磺酰基，两个基团之一R3 并且R4是氢，另一个是羟基磺酰基，或者如果两个基团R 1和R 2中的至少一个是羟基磺酰基，则R3和R4各自同时也可以是氢，两个或三个卤代三嗪基作为反应体系， 可用于染色或印刷含羟基或含氮有机基材。

公开(公告)号：US4737190A

公开(公告)日：1988-04-12

申请号：US790181

申请日：1985-10-22

申请人： Masaru Shimada ,  Toshiyuki Kawanishi ,  Kakuji Murakami ,  Tamotsu Aruga ,  Hiroyuki Uemura

发明人： Masaru Shimada ,  Toshiyuki Kawanishi ,  Kakuji Murakami ,  Tamotsu Aruga ,  Hiroyuki Uemura

IPC分类号： C08J3/02 ,  C08L83/04 ,  C09B33/12 ,  C09B43/16 ,  C09B62/04 ,  C09D5/00 ,  C09D11/00 ,  C09D183/04 ,  C09D11/02

CPC分类号： C09D11/328 ,  C09B43/16 ,  C09B62/043

摘要： An aqueous ink composition for ink-jet recording comprising an aqueous solution of a water-soluble dye of formula (I) and a humectant dissolved in water: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen, an alkyl group, an alkoxy group, halogen, a carboxyl group or a sulfonic acid group; R.sup.3 and R.sup.4 each represent a hydroxyl group, halogen, an alkoxy group, an unsubstituted or substituted amino group; X represents --O--, --CH.sub.2 --, --C.sub.2 H.sub.4 --, --CH.dbd.CH--, --S--, --SO.sub.2 -- or --; Ar.sup.1 and Ar.sup.2 each represent an unsubstituted or substituted phenyl group, an unsubstituted or substituted naphthyl group; M represents hydrogen ion, an alkali metal cation, amine cation or an ammonium ion; and n is an integer of 1, 2 or 3.

摘要翻译： 一种用于喷墨记录的水性油墨组合物，其包含式（I）的水溶性染料的水溶液和溶于水的湿润剂：其中R 1和R 2各自表示氢，烷基 ，烷氧基，卤素，羧基或磺酸基; R 3和R 4各自表示羟基，卤素，烷氧基，未取代或取代的氨基; X表示-O-，-CH 2 - ， - C 2 H 4 - ， - CH = CH - ， - S - ， - SO 2 - 或 - Ar1和Ar2各自表示未取代或取代的苯基，未取代或取代的萘基; M表示氢离子，碱金属阳离子，胺阳离子或铵离子; n为1,2或3的整数。

公开(公告)号：US4453945A

公开(公告)日：1984-06-12

申请号：US486520

申请日：1983-04-19

申请人： Masakatsu Miyamoto ,  Yoshiharu Suzuki ,  Masayoshi Ojima ,  Yutaka Iizuka ,  Ryuzo Orita ,  Tadashi Matsuo

发明人： Masakatsu Miyamoto ,  Yoshiharu Suzuki ,  Masayoshi Ojima ,  Yutaka Iizuka ,  Ryuzo Orita ,  Tadashi Matsuo

IPC分类号： C09B62/04 ,  D06P1/38 ,  D06P3/66 ,  D06P3/82 ,  C09B62/00

CPC分类号： D06P3/66 ,  C09B62/04 ,  C09B62/043 ,  D06P3/8219 ,  D06P3/8252 ,  D06P3/8266 ,  Y10S8/918

摘要： The present invention relates to a process for dyeing cellulose fibers or its union fibers which is effected according to an exhaustion dyeing method using a reactive dye containing at least one s-triazinyl group having a group of the formula: ##STR1## wherein M represents a hydrogen or an alkali metal, in an aqueous dyeing bath having a pH in the range of 4 to 10 and a dyeing temperature in the range of 110.degree. C. to below 140.degree. C.

摘要翻译： 本发明涉及一种染色纤维素纤维或其联合纤维的方法，该方法是使用含有至少一种具有下式基团的s-三嗪基的活性染料根据耗尽染色方法进行的：其中M表示 氢或碱金属，在pH为4〜10，染色温度为110〜140℃的水性染色浴中。

公开(公告)号：US4283331A

公开(公告)日：1981-08-11

申请号：US005058

申请日：1979-01-22

申请人： Karl Seitz ,  Dieter Mausezahl

发明人： Karl Seitz ,  Dieter Mausezahl

IPC分类号： C09B29/42 ,  C09B31/153 ,  C09B43/12 ,  C09B45/02 ,  C09B62/006 ,  C09B62/04 ,  C09B29/22 ,  C09B29/36 ,  C09B31/14

CPC分类号： C09B45/025 ,  C09B29/3626 ,  C09B31/153 ,  C09B62/0067 ,  C09B62/043

摘要： Azo dyes of the formula ##STR1## in which D is the sulfo group-containing radical of an aromatic or heterocyclic diazo component, which can be further substituted and itself can contain an azo bridge, R.sub.1 and R.sub.2 independently of one another are each a hydrogen atom or a substituted or unsubstituted alkyl or aryl radical and X is a substituted or unsubstituted alkyl or alkenyl radical, and their heavy metal complexes, it being possible for the azo dyes of the formula (1) and their heavy metal complexes to contain reactive radicals.

摘要翻译： 式（1）的偶氮染料其中D是芳族或杂环重氮组分的含磺基团的基团，其可以被进一步取代，并且其本身可以包含彼此独立的偶氮桥，R 1和R 2是 各自为氢原子或取代或未取代的烷基或芳基，X为取代或未取代的烷基或烯基，以及它们的重金属络合物，式（1）的偶氮染料及其重金属配合物可能 含有反应性基团。

公开(公告)号：US4082739A

公开(公告)日：1978-04-04

申请号：US427896

申请日：1973-12-26

申请人： Karl Seitz

发明人： Karl Seitz

IPC分类号： C09B62/04 ,  C09B62/06 ,  C09B62/08 ,  D06P1/382 ,  D06P3/66

CPC分类号： C09B62/043

摘要： A dyestuff of the formula ##STR1## wherein F.sub.1 represents a dyestuff radical, particularly an azo dyestuff radical, R.sub.1 and R.sub.2 represent hydrogen, lower alkyl, or aryl, X.sub.1 and X.sub.2 each represent halogen, and X.sub.3 represents halogen, amino, lower alkyl amino, di-lower alkyl amino, lower alkoxy, phenoxy, lower alkylthio, or a group of the formula --N(R.sub.3)--F.sub.2 in which R.sub.3 represents hydrogen, lower alkyl, or aryl and F.sub.2 represents a dyestuff radical, particularly an azo dyestuff radical.

公开(公告)号：US4038267A

公开(公告)日：1977-07-26

申请号：US471986

申请日：1974-05-21

申请人： Yoshihisa Sueda ,  Suketsugu Koumura ,  Kazuyoshi Hirabayashi ,  Hirohito Kenmochi ,  Hisashige Terao ,  Yoshio Mori

发明人： Yoshihisa Sueda ,  Suketsugu Koumura ,  Kazuyoshi Hirabayashi ,  Hirohito Kenmochi ,  Hisashige Terao ,  Yoshio Mori

IPC分类号： C09B62/04 ,  C09B43/16 ,  C09B33/00 ,  C09B35/00

CPC分类号： C09B62/04 ,  C09B62/043

摘要： A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 - C.sub.4 alkyl, or C.sub.1 - C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## (wherein Q" is a dye residue, R.sub.1 " is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 " is halogen, Q, Q' and Q" may independently be the same or different and X, Y and Z are not hydrogen at the same time).

摘要翻译： 适用于染色纤维素纤维材料的染料，具有下式，其中R和R'各自为氢，C1-C4烷基或C1-C4羟基烷基，m为1至6的整数，n 和n'各自为2〜4的整数，当m为2以上时，n可以相同或不同，2〜4之间的整数，X为氢或式“IMAGE”（其中Q为 染料残基，R1为氢或C1-C4烷基，R2为卤素）; Y是氢或式（IMAGE）的基团（其中Q'是染料残基，当m为2或更大时，Q可以相同或不同，R1'是氢或C1-C4烷基，R2' 是卤素）; Z是氢或式（IMAGE）的基团（其中Q“是染料残基，R1”是氢或C1-C4烷基，R2“是卤素，Q，Q'和Q”可以独立地 相同或不同，X，Y和Z不同时为氢）。

公开(公告)号：US3983115A

公开(公告)日：1976-09-28

申请号：US536131

申请日：1974-12-24

申请人： Karl Seitz ,  Rainer Begrich ,  Henri Riat ,  Fritz Oesterlein

发明人： Karl Seitz ,  Rainer Begrich ,  Henri Riat ,  Fritz Oesterlein

IPC分类号： C07D251/44 ,  C08K5/00 ,  C08K5/3477 ,  C08L89/00 ,  C09B62/04 ,  G03C1/30

CPC分类号： G03C1/30 ,  C07D251/44 ,  C09B62/043

摘要： Bis-dihalogeno-s-triazinyl-ureas of the formula ##EQU1## wherein each of X.sub.1 and X.sub.2 is halogen.

摘要翻译： 式（Ⅱ）的二 - 二卤代-s-三嗪基 - 脲其中X 1和X 2各自为卤素，其中R 1，R 2，R 2，R 3，R 3， 。

公开(公告)号：US3664995A

公开(公告)日：1972-05-23

申请号：US3664995D

申请日：1969-12-22

申请人： ICI LTD

发明人： ANDREW HERBERT FRANCIS ,  JACKSON NEVILLE

IPC分类号： C09B62/022 ,  C09B62/04 ,  C09B62/08

CPC分类号： C09B62/043

摘要： Dyestuffs of the formula: IN WHICH D1 and D2 are azo, anthraquinone or nitro dye radicals, R1-R6 are H or lower alkyl groups, A1 and A2 are radicals of the benzene or naphthalene series and T1 is a chloro-s-triazine radical, are reactive dyestuffs for cellulose having good fastness to light and washing. They are especially notable for the high proportion which reacts with the fiber when applied from saline dyebaths.