公开(公告)号：US20090202938A1

公开(公告)日：2009-08-13

申请号：US12028063

申请日：2008-02-08

Applicant: Celin Savariar-Hauck ,  Marco Scala ,  Mirko Hartleb

Inventor： Celin Savariar-Hauck ,  Marco Scala ,  Mirko Hartleb

IPC: G03F7/004 ,  G03F7/12

CPC classification number: B41C1/1016 ,  B41C1/1066 ,  B41C2201/02 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41C2210/266

Abstract: A computer-to-press multi-layer, positive-working imageable element has improved surface abrasion resistance from a micro-roughening of the outermost surface. This improvement is provided by spraying a solution consisting essentially of one or more dissolved organic resins in a solvent onto the outermost imageable layer of the imageable element. The one or more organic resins are soluble or dispersible in an aqueous alkaline solution and are present in the sprayed solution in an amount of at least 3 weight %. The sprayed solution is applied to deposit at least 10 mg/m2 and no more than 100 mg/m2 of the one or more dissolved organic resins onto the outermost imageable layer in the form of dots in a random pattern. The sprayed dots are then dried. The imageable elements can be imaged and developed to provide lithographic printing plates.

Abstract translation: 计算机到压机多层正性可成像元件从最外表面的微粗糙化改善了表面耐磨性。 通过将基本上由一种或多种溶解的有机树脂组成的溶液溶解在可成像元件的最外部可成像层上来提供这种改进。 一种或多种有机树脂可溶于或分散在碱性水溶液中，并且以至少3重量％的量存在于喷雾溶液中。 施加喷雾溶液以随机图案以点的形式将至少10mg / m 2且不超过100mg / m 2的一种或多种溶解的有机树脂沉积到最外可成像层上。 然后将喷雾的点干燥。 可成像和显影成像元件以提供平版印刷版。

公开(公告)号：US20090155722A1

公开(公告)日：2009-06-18

申请号：US12300801

申请日：2007-05-22

Applicant: Hieronymus Andriessen ,  Steven Lezy ,  Hubertus Van Aert ,  Joan Vermeersch

Inventor： Hieronymus Andriessen ,  Steven Lezy ,  Hubertus Van Aert ,  Joan Vermeersch

IPC: G03F7/20 ,  B41M5/00

CPC classification number: B41C1/1025 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  Y10S430/145

Abstract: A method for making a lithographic printing plate includes the steps of (i) providing a negative-working, heat-sensitive lithographic printing plate precursor including a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye, wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm, and the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.70 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fractionation, and the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60%; (ii) exposing the precursor to infrared light; and (iii) developing the exposed precursor in an alkaline aqueous solution.

Abstract translation: 制备平版印刷版的方法包括以下步骤：（i）提供负型热敏平版印刷版原版，其包含具有亲水性表面的载体，或提供有亲水层和设置在其上的涂层， 包括包含疏水性热塑性聚合物颗粒，粘合剂和红外吸收染料的图像记录层的涂层，其中所述疏水性热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40 nm，并且不考虑任选的抗衡离子的IR染料的量通过流体动力学分级测定的每摩尔热塑性聚合物颗粒的总表面的每摩尔浓度大于0.70mg，并且疏水性热塑性聚合物颗粒的量 相对于成像层的成分的总重量为至少60％; （ii）将前体暴露于红外光; 和（iii）在碱性水溶液中显影暴露的前体。

公开(公告)号：US20090148793A1

公开(公告)日：2009-06-11

申请号：US12239035

申请日：2008-09-26

Applicant: Keiichi ADACHI ,  Shigekatsu FUJII ,  Yoshinori TAGUCHI ,  Takashi SATO

Inventor： Keiichi ADACHI ,  Shigekatsu FUJII ,  Yoshinori TAGUCHI ,  Takashi SATO

IPC: G03F7/26 ,  G03F7/00

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/10 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41N3/08 ,  G03F7/322

Abstract: A processing method of a lithographic printing plate precursor includes: exposing imagewise a lithographic printing plate precursor comprising a support on a surface of which at least one of: a hydrophilizing treatment; and an undercoat layer has been provided and an image-recording layer, to cure an exposed area of the image-recording layer; and undergoing developing processing with an aqueous solution having pH of from 2 to 10, wherein the aqueous solution comprises an amphoteric surfactant and an anionic surfactant selected from an anionic surfactant having an aliphatic chain and a total number of carbon atoms included in the aliphatic chain of 6 or more and an anionic surfactant having an aromatic ring and a total number of carbon atoms of 12 or more, and a content of the anionic surfactant is from 0.1 to 3.3% by weight of the aqueous solution.

Abstract translation: 平版印刷版原版的加工方法包括：使表面上具有以下至少一种的支撑体的平版印刷版原版成像曝光：亲水化处理; 并提供底涂层和图像记录层，以固化图像记录层的曝光区域; 并用pH为2〜10的水溶液进行显影处理，其中所述水溶液包含两性表面活性剂和阴离子表面活性剂，所述阴离子表面活性剂选自阴离子表面活性剂，所述阴离子表面活性剂选自具有脂族链的脂族链和包含在脂族链中的脂族链总数 6以上的阴离子表面活性剂和具有芳香环，总碳原子数为12以上的阴离子表面活性剂，阴离子表面活性剂的含量为水溶液的0.1〜3.3重量％。

公开(公告)号：US20090111051A1

公开(公告)日：2009-04-30

申请号：US11877841

申请日：2007-10-24

Applicant: Ting Tao ,  Eric E. Clark

Inventor： Ting Tao ,  Eric E. Clark

IPC: G03C1/00 ,  G03F7/26

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/266 ,  B41M5/368

Abstract: A negative-working imageable composition and element includes an initiator composition, an infrared radiation absorbing compound, a polymeric binder, and a stabilizing composition. The imaged element can be developed on-press and exhibits improved shelf-life under high humidity conditions. The stabilizing composition comprising at least one compound represented by Structure (ST-I) and at least one compound represented by Structure (ST-II): wherein m is 1 or 2, n is 1 to 50, R is hydrogen when m is 1, R1 through R3 are independently hydrogen or methyl, and L is an aliphatic, carbocyclic, heterocyclic, heteroatom divalent linking group, or a combination thereof.

Abstract translation: 负性可成像组合物和元素包括引发剂组合物，红外辐射吸收化合物，聚合物粘合剂和稳定化组合物。 成像元件可以在印刷机上显影，并且在高湿度条件下显示改善的保存期限。 所述稳定化组合物包含至少一种由结构（ST-1）表示的化合物和至少一种由结构（ST-II）表示的化合物：其中m为1或2，n为1至50，当m为1时，R为氢 R 1至R 3独立地为氢或甲基，L为脂族，碳环，杂环，杂原子二价连接基团或其组合。

公开(公告)号：US07491487B2

公开(公告)日：2009-02-17

申请号：US11071441

申请日：2005-03-04

Applicant: Atsushi Sugasaki

Inventor： Atsushi Sugasaki

IPC: G03F7/00

CPC classification number: G03F7/035 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/266 ,  G03F7/0388 ,  Y10S430/107 ,  Y10S430/145

Abstract: A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R1 and R2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.

Abstract translation: 一种可聚合组合物，其包含：通过使用由下式（I）表示的化合物作为原料之一合成的聚氨酯树脂; 光聚合或热聚合引发剂; 和具有烯键式不饱和键的可加成聚合化合物：其中X表示三价或更高价的原子; R1和R2各自独立地表示单键或任选具有取代基的亚烷基，条件是R 1和R 2不同时表示单键; A表示直链连接基团; n为1〜5的整数。

公开(公告)号：US20080318155A1

公开(公告)日：2008-12-25

申请号：US12144238

申请日：2008-06-23

Applicant: Shota SUZUKI ,  Yu Iwai ,  Junji Kawaguchi

Inventor： Shota SUZUKI ,  Yu Iwai ,  Junji Kawaguchi

IPC: G03F7/20

CPC classification number: B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24

Abstract: A lithographic printing plate precursor includes: an aluminum support; an intermediate layer; and an image-recording layer, in this order, wherein at least one of the intermediate layer and the image-recording layer contains a compound having an amino group and a functional group capable of interacting with the aluminum support in a molecule.

Abstract translation: 平版印刷版原版包括：铝载体; 中间层 和图像记录层，其中中间层和图像记录层中的至少一个含有具有氨基的化合物和能够在分子中与铝载体相互作用的官能团。

公开(公告)号：US20080311525A1

公开(公告)日：2008-12-18

申请号：US12093473

申请日：2006-11-17

Applicant: Willi-Kurt Gries ,  Marc Van Damme

Inventor： Willi-Kurt Gries ,  Marc Van Damme

IPC: G03F7/20

CPC classification number: G03F7/092 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/08 ,  B41C2210/10 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/32

Abstract: A method of making a lithographic printing plate includes the steps of: a) providing a lithographic printing plate precursor including (i) a support having a hydrophilic surface or which is provided with a hydrophilic layer, (ii) a coating on the support including a photopolymerizable layer, and, optionally, an intermediate layer between the photopolymerizable layer and the support, wherein the photopolymerizable layer includes a polymerizable compound and a polymerization initiator, b) image-wise exposing the coating in a plate setter, c) optionally, heating the precursor in a pre-heating unit, d) developing the precursor off-press in a gumming unit by treating the coating of the precursor with a gum solution, thereby removing the non-exposed areas of the photopolymerizable layer from the support, wherein the photopolymerizable layer further includes a polymer containing an acid group and a basic nitrogen-containing compound capable of neutralizing the acid group, or wherein the photopolymerizable layer further includes a polymer containing an acid group which is neutralized by a basic nitrogen-containing compound.

Abstract translation: 制备平版印刷版的方法包括以下步骤：a）提供平版印刷版前体，其包括（i）具有亲水性表面的或具有亲水层的载体，（ii）载体上的涂层，包括 光聚合层和可选择地在可光聚合层和载体之间的中间层，其中可光聚合层包括可聚合化合物和聚合引发剂，b）成像曝光在印版机中的涂层，c）任选地加热 预处理单元中的前体，d）通过用胶溶液处理前体的涂层，在上胶单元中显影前体脱模，从而从支持体除去可光聚合层的未曝光区域，其中可光聚合 层还包括含有酸基的聚合物和能够中和酸基的碱性含氮化合物，或其中的照片 可聚合层还包括含有由碱性含氮化合物中和的酸基的聚合物。

公开(公告)号：US20080311509A1

公开(公告)日：2008-12-18

申请号：US12064466

申请日：2006-08-18

Applicant: Alexander Williamson ,  Marc Van Damme ,  Wojciech Jaunky ,  Hubertus Van Aert

Inventor： Alexander Williamson ,  Marc Van Damme ,  Wojciech Jaunky ,  Hubertus Van Aert

IPC: G03F7/00 ,  G03F7/20

CPC classification number: G03F7/033 ,  B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  G03F7/031

Abstract: A photopolymer printing plate precursor includes a photosensitive coating on a support, wherein the photosensitive coating includes a composition that is photopolymerizable upon absorption of light, and the composition includes at least one binder, a polymerizable compound, a sensitizer, and a photoinitiator. The binder is a copolymer that has a Tg of less than 70° C., and wherein 1 mol-% to 50 mol-% of the monomeric units of the copolymer are substituted by at least one acidic group, has a very high sensitivity and resistance of the exposed image portions against alkaline developers, when exposed with a laser, even if no pre-heat step is performed.

Abstract translation: 光聚合物印版前体包括载体上的感光涂层，其中感光涂层包括在吸收光时可光聚合的组合物，并且该组合物包括至少一种粘合剂，可聚合化合物，敏化剂和光引发剂。 粘合剂是Tg低于70℃的共聚物，其中1摩尔％至50摩尔％的共聚物的单体单元被至少一个酸性基团取代，具有非常高的灵敏度和 即使没有进行预热步骤，曝光图像部分对碱性显影剂的电阻，当用激光曝光时。

公开(公告)号：US20080286685A1

公开(公告)日：2008-11-20

申请号：US12119123

申请日：2008-05-12

Applicant: Norio AOSHIMA

Inventor： Norio AOSHIMA

IPC: G03F7/20

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22

Abstract: The invention provides a planographic printing plate precursor having at least: a support; and an image recording layer that is provided on the support, the image recording layer comprising: an infrared ray absorbing agent (A); a polymerization initiator (B); a polymerizable compound (C); and a compound (D) represented by the following Formula (I). In Formula (I), at least one of R1 to R3 represents —(CH2CH2O)n—R4, while the remainder of R1 to R3 respectively independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or R5—COOH; R4 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; n represents an integer of 1 to 20; and R5 represents an alkylene group having 1 to 6 carbon atoms. The invention further provides a printing method using the planographic printing plate precursor and performing on-press development.

Abstract translation: 本发明提供一种至少具有：支持体的平版印刷版前体， 以及设置在所述支撑体上的图像记录层，所述图像记录层包括：红外线吸收剂（A）; 聚合引发剂（B）; 可聚合化合物（C）; 和由下式（I）表示的化合物（D）。 在式（I）中，R 1至R 3中的至少一个表示 - （CH 2 CH 2 CH 2） 其中R 1〜R 3的其余部分分别独立地表示氢原子，R 1，R 2，R 3， ，具有1至4个碳原子的烷基或R 5 -COOH; R 4表示氢原子或具有1至4个碳原子的烷基; n表示1〜20的整数， R 5表示碳原子数1〜6的亚烷基。 本发明还提供一种使用平版印刷版原版的印刷方法，并进行印刷机的显影。

公开(公告)号：US07435532B2

公开(公告)日：2008-10-14

申请号：US11316833

申请日：2005-12-27

Applicant: Akio Oda ,  Norio Aoshima

Inventor： Akio Oda ,  Norio Aoshima

IPC: G03C1/76 ,  G03F7/028 ,  G03F7/032 ,  G03F7/20 ,  G03F7/30

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  Y10S430/145

Abstract: A lithographic printing plate precursor having a good press life with a practical energy amount, which can be on-press developed without passing through a development processing step after recording an image by a laser of emitting an infrared ray, is provided, which is a lithographic printing plate precursor capable of performing a development and printing by loading on a printing press after imagewise exposure and supplying an oily ink and an aqueous component, the lithographic printing plate precursor comprising a support and an image recording layer, wherein the image recording layer comprises (A) a polymerization initiator, (B) a polymerizable monomer, (C) a binder polymer, and (D) a crosslinked resin particle having a reactive group or (F) a microcapsule containing a polymerizable monomer in the capsule wall, and the image recording layer is imagewise polymerization-curable upon irradiation of actinic ray.

Abstract translation: 提供具有实用能量量的良好压机寿命的平版印刷版原版，其可以在通过发射红外线的激光记录图像之后不经过显影处理步骤而被加压显影，其是平版印刷 能够通过在成像曝光后在印刷机上进行显影和印刷并供应油性油墨和水性成分的印版前体，所述平版印刷版原版包含载体和图像记录层，其中所述图像记录层包含（ A）聚合引发剂，（B）可聚合单体，（C）粘合剂聚合物和（D）具有反应性基团的交联树脂颗粒或（F）在胶囊壁中含有可聚合单体的微胶囊和图像 记录层在光化射线照射时是成像聚合可固化的。