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公开(公告)号：US5840810A
公开(公告)日：1998-11-24
申请号：US659457
申请日：1996-06-06
IPC分类号： C08L23/26 , C08F8/00 , C08F8/42 , C08F210/10
CPC分类号： C08F8/42 , C08F8/00 , C08F2800/10 , C08F2810/30 , C08F2810/50
摘要： There is provided a method of introducing functionality into a copolymer of an isoolefin and an alkylstyrene at the alkylbenzyl carbon atom comprising the steps of: forming a solution of said copolymer in a hydrocarbon solvent; adding to said polymer solution an alkali metal Na, K, Rb, Cs alkoxide and an alkyl lithium compound to form a superbase with the polymer solution; and adding an electrophile to the metalated polymer solution; also provided are the metalated copolymers and the functionalized derivatives therefrom.
摘要翻译： 提供了在烷基苄基碳原子上将官能度引入异烯烃和烷基苯乙烯的共聚物的方法，包括以下步骤：在烃溶剂中形成所述共聚物的溶液; 向所述聚合物溶液中加入碱金属Na，K，Rb，Cs醇盐和烷基锂化合物以与所述聚合物溶液形成超级碱基; 并向金属化聚合物溶液中加入亲电试剂; 还提供了金属化共聚物及其官能化衍生物。
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公开(公告)号：US5548029A
公开(公告)日：1996-08-20
申请号：US404803
申请日：1995-03-15
CPC分类号： C08L23/22 , C08F8/00 , C08F8/20 , C08G81/021 , C08L23/02 , Y02P20/582
摘要： Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
摘要翻译： 作为其中R和R'可以是氢，烷基和伯和仲烷基卤化物的式“IMAGE”表示的异烯烃/对烷基苯乙烯共聚物的接枝共聚物，“a”为约14至约70,000，“b “为0至约70,000，”c“为0至约70,000，”d“为约1至约70,000，X为卤素，Nu为由聚合物亲核试剂提供的亲核残基。
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63.发明授权Graft copolymers of para-alkylstyrene/isoolefin copolymers as blend compatibilizers 失效对位烷基苯乙烯/异烯烃共聚物作为共混相容剂的接枝共聚物
公开(公告)号：US5548023A
公开(公告)日：1996-08-20
申请号：US402792
申请日：1995-03-13
CPC分类号： C08L23/22 , C08F8/00 , C08F8/20 , C08G81/021 , C08L23/02 , Y02P20/582
摘要： A method of compatibilizing a blend of at least a hydrocarbon polymer with at least one other polymer which is incompatible with the hydrocarbon polymer, said method comprising adding to the polymer blend a compatibilizer which is an isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
摘要翻译： 一种使至少一种烃聚合物与至少一种与烃聚合物不相容的其它聚合物的共混物相容的方法，所述方法包括向聚合物共混物中加入作为由式I表示的异烯烃/对烷基苯乙烯共聚物的增容剂 ，并且伯和仲烷基卤化物“a”的范围为约14至约70,000，“b”为0至约70,000，“c”为0至约70,000，“d”为约1至约70,000 ，X是卤素，Nu是由聚合物亲核试剂提供的亲核残基。
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公开(公告)号：US5182333A
公开(公告)日：1993-01-26
申请号：US791764
申请日：1991-11-12
CPC分类号： C08L23/22 , C08F10/10 , C08L23/283 , Y10S525/918
摘要： A substantially gel free C.sub.4 to C.sub.7 isoolefin homopolymer rubber, butyl copolymer rubber, halogenated butyl rubber (e.g., chlorinated or brominated), or mixtures thereof, comprising a molecular weight distribution such that the ratio of the moments of said molecular weight distribution, Mz/Mw, is equal to or exceeds 2.0, and that portion of said molecular weight distribution which is equal to and greater than 4 times the peak molecular weight, Mp, comprises greater than 8 percent of the total polymer species, and Mp is greater than about 250,000 and wherein said polymer species of molecular weight less than Mp are substantially branch free. Various means are disclosed for effecting the molecular weight distribution including blending of homopolymers and/or copolymers of appropriate molecular weight and molecular weight distribution and direct polymerization using a functional reagent to introduce branching. The rubber compositions are particularly useful in applications in which butyl or halogenated butyl rubber is used and where it is desired to obtain high green strength in combination with an increased rate of stress relaxation. Such polymers are particularly well suited for use in tire innerliner compositions.
摘要翻译： 基本上不含凝胶的C4至C7异烯烃均聚物橡胶，丁基共聚物橡胶，卤化丁基橡胶（例如，氯化或溴化）或其混合物，其包含分子量分布，使得所述分子量分布的时间比Mz / Mw等于或超过2.0，等于和大于峰分子量Mp的4倍的分子量分布的那部分包含大于总聚合物种类的8％，并且M p大于约 250,000，并且其中分子量小于Mp的所述聚合物种类基本上无分支。 公开了用于实现分子量分布的各种方法，包括使用适当的分子量和分子量分布的均聚物和/或共聚物的共混，并使用官能试剂引入支化的直接聚合。 橡胶组合物在使用丁基或卤代丁基橡胶的应用中特别有用，并且其中期望获得高的绿色强度并且结合增加的应力松弛速率。 这种聚合物特别适用于轮胎内衬组合物。
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公开(公告)号：US5071913A
公开(公告)日：1991-12-10
申请号：US131938
申请日：1987-12-11
CPC分类号： B60C1/0008 , C08F10/10 , C08F210/12 , C08L23/22 , C08L23/283 , Y10S525/918
摘要： A substantially gel free C.sub.4 to C.sub.7 isoolefin homopolymer rubber, butyl copolymer rubber, halogenated butyl rubber (e.g., chlorinated or brominated), or mixtures thereof, comprising a molecular weight distribution such that the ratio of the moments of said molecular weight distribution, Mz/Mw, is equal to or exceeds 2.0, and that portion of said molecular weight distribution which is equal to and greater than 4 times the peak molecular weight, Mp, comprises greater than 8 percent of the total polymer species, and Mp is greater than about 250,000 and wherein said polymer species of molecular weight less than Mp are substantially branch free. Various means are disclosed for effecting the molecular weight distribution including blending of homopolymers and/or copolymers of appropriate molecular weight and molecular weight distribution and direct polymerization using a functional reagent to introduce branching. The rubber compositions are particularly useful in applications in which butyl or halogenated butyl rubber is used and where it is desired to obtain high green strength in combination with an increased rate of stress relaxation. Such polymers are particularly well suited for use in tire innerliner compositions.
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66.发明授权Thermoplastic elastomer composition having viscosity-enhanced and vulcanized elastomer dispersions 有权具有粘度增强和硫化弹性体分散体的热塑性弹性体组合物公开(公告)号：US07538158B2
公开(公告)日：2009-05-26
申请号：US10548059
申请日：2003-03-06
CPC分类号： C08L23/283 , C08L77/00 , C08L2666/20
摘要： A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.
摘要翻译： 一种具有改进的机械性能和抗疲劳性的热塑性弹性体组合物，其包含（A）卤代异丁烯弹性体，（B）聚酰胺和（C）选自叔胺和仲二胺的胺组分，其中弹性体作为结构域分散在连续 聚酰胺的相。
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公开(公告)号：US07338688B2
公开(公告)日：2008-03-04
申请号：US10476548
申请日：2002-04-08
申请人： Hsien-Chang Wang , Wai Keung Wong
发明人： Hsien-Chang Wang , Wai Keung Wong
IPC分类号： B05D3/02
CPC分类号： C09D123/22 , B32B1/08 , B32B15/18 , B32B25/04 , B32B25/18 , C08F8/42 , C09D123/28 , Y10T428/1393
摘要： Protective liners or coatings for metal conduits, pipes and tanks subjected to corrosive liquids are disclosed. The liners comprise a composition containing a silylated copolymer of, for example, isobutylene and para-methylstyrene, which are curable by contact with moisture.
摘要翻译： 公开了用于经受腐蚀性液体的金属管道，管道和罐的保护衬垫或涂层。 衬垫包括含有例如异丁烯和对甲基苯乙烯的甲硅烷基化共聚物的组合物，其可通过与水分接触而固化。
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公开(公告)号：US06545101B2
公开(公告)日：2003-04-08
申请号：US09777398
申请日：2001-02-06
IPC分类号： C08F1000
CPC分类号： C08G83/003 , C08F8/26 , C08F8/46 , C08F2810/30 , C08F2810/40 , C08G81/00 , C08G81/02 , C08G81/024 , C08G83/001 , C08F110/10
摘要： Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succinimide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
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69.发明授权Solid nucleophilic reagent for conversion of benzylic halogen functionality on polymers to other functionalities 失效用于将苄基卤官能团转化为聚合物的固体亲核试剂到其它官能团公开(公告)号：US06372858B1
公开(公告)日：2002-04-16
申请号：US09687685
申请日：2000-10-13
IPC分类号： C08F800
CPC分类号： C08F8/22 , Y02P20/582 , C08F210/10 , C08F8/26
摘要： A solid nucleophilic reagent for the conversion of benzylic halogen functionality on polymers to other functionalities, and methods of making and using the same.
摘要翻译： 用于将苄基卤官能团转化为聚合物的固体亲核试剂到其它官能团，以及制备和使用它们的方法。
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70.发明授权Isobutylene based elastomer blends having improved strength elasticity, and reduced permeability 有权异丁烯基弹性体共混物具有改善的强度弹性和降低的渗透性公开(公告)号：US06326433B1
公开(公告)日：2001-12-04
申请号：US09569363
申请日：2000-05-11
申请人： Hsien-Chang Wang , Ilan Duvdevani , Sudhin Datta , Connie R. Qian
发明人： Hsien-Chang Wang , Ilan Duvdevani , Sudhin Datta , Connie R. Qian
IPC分类号： C08L2310
CPC分类号： C08F210/10 , B60C1/0008 , C08F8/20 , C08L23/0815 , C08L23/14 , C08L23/142 , C08L23/16 , C08L23/18 , C08L23/22 , C08L23/283 , C08L2314/06 , C08L2666/04 , C08F212/00 , C08F210/06
摘要： The improved green strength, green elongation, and green relaxation properties of isobutylene based elastomers at elevated temperatures along with improved aging and barrier properties are achieved by blending semi-compatible, semi-crystalline polymers with the isobutylene elastomers. The improved properties are maintained in subsequent rubber compounds containing said blends and are particularly useful in tire and pharmaceutical container applications.
摘要翻译： 通过将半相容的半结晶聚合物与异丁烯弹性体共混，可以提高异丁烯基弹性体在高温下改善的生坯强度，绿色伸长率和绿色松弛性能，同时改善老化和阻隔性能。 在随后的包含所述共混物的橡胶化合物中维持改进的性能，并且在轮胎和药物容器应用中特别有用。
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