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    Process for reducing coke formation in heavy feed catalytic cracking
    62.
    发明授权
    Process for reducing coke formation in heavy feed catalytic cracking 失效
    重质进料催化裂化中焦炭形成减少的方法

    公开(公告)号：US4409093A

    公开(公告)日：1983-10-11

    申请号：US285737

    申请日：1981-07-22

    Applicant: Roby Bearden, Jr. ,  Gordon Stuntz

    Inventor： Roby Bearden, Jr. ,  Gordon Stuntz

    IPC: C10G11/02 ,  C10G11/18 ,  C10G47/34 ,  C10G9/16

    CPC classification number: C10G11/02 ,  C10G11/18

    Abstract: A method for decreasing the amount of coke produced during the cracking of hydrocarbon feedstock to lower molecular weight products in a reaction zone is disclosed, where the feedstock contains at least two metal contaminants selected from the class consisting of nickel, vanadium and iron, and where these contaminants become deposited on the catalyst. The method comprises passing catalyst from the reaction zone through a regeneration zone operated under net reducing conditions and through a reduction zone maintained at an elevated temperature for a time sufficient to at least partially passivate the catalyst.

    Abstract translation: 公开了一种在反应区中将烃原料裂解成较低分子量产物时产生的焦炭量减少的方法，其中原料含有选自镍，钒和铁的至少两种金属污染物，其中 这些污染物沉积在催化剂上。 该方法包括使来自反应区的催化剂通过在净还原条件下运行的再生区，并通过保持在升高温度下的还原区足以使催化剂至少部分钝化的时间。

    High surface area catalysts
    64.
    发明授权
    High surface area catalysts 失效
    高表面积催化剂

    公开(公告)号：US4244839A

    公开(公告)日：1981-01-13

    申请号：US955526

    申请日：1978-10-30

    Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

    Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

    IPC: B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  B01J31/12 ,  B01J23/28 ,  B01J23/88 ,  B01J27/04

    CPC classification number: B01J37/086 ,  B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  Y10S208/951

    Abstract: High surface area metal-containing catalysts are prepared by dispersing a thermally decomposable metal compound in a hydrocarbon oil having a Conradson carbon content of up to about 50 weight percent, the thermally decomposable metal compound being added in an amount sufficient to obtain a specified ratio of atoms of Conradson carbon of the oil chargestock to atoms of metal constituent of the thermally decomposable compound, heating the compound in the presence of a gas comprising either hydrogen or hydrogen sulfide or hydrogen and hydrogen sulfide to form a solid high surface area catalyst within the oil, and recovering the resulting high surface area catalyst. The metal constituent of the thermally decomposable metal compound may be a metal of Groups II, III, IV, V, VIB, VIIB, VIII or mixtures thereof. The high surface area solids are suitable as catalysts, catalyst supports or catalyst components for use in hydrocarbon treating processes and in chemical processes.

    Abstract translation: 通过将可热分解的金属化合物分散在具有高达约50重量％的康拉逊碳含量的烃油中制备高表面积含金属的催化剂，所述可热分解的金属化合物的添加量足以获得规定的比例 将油料的康拉德森碳的原子与可热分解的化合物的金属成分的原子一起加热，在包含氢或硫化氢或氢气和硫化氢的气体存在下加热化合物，以在油中形成固体高表面积催化剂 ，并回收得到的高表面积催化剂。 可热分解的金属化合物的金属组分可以是II，III，IV，V，VIB，VIIB，VIII族的金属或其混合物。 高表面积固体适合用作催化剂，催化剂载体或用于烃处理方法和化学方法的催化剂组分。

    Combined disulfurization and conversion with alkali metals
    67.
    发明授权
    Combined disulfurization and conversion with alkali metals 失效
    与碱金属组合脱硫和转化

    公开(公告)号：US4076613A

    公开(公告)日：1978-02-28

    申请号：US571903

    申请日：1975-04-28

    Applicant: Roby Bearden, Jr.

    Inventor： Roby Bearden, Jr.

    IPC: C10G65/12 ,  C10G13/06 ,  B01J27/04

    CPC classification number: C10G65/12

    Abstract: Improved processes for the combined desulfurization and hydroconversion of various sulfur-containing pertroleum oils, and particularly various residua feedstocks, are disclosed. These feedstocks are thus contacted with alkali metals, such as sodium, in the molten state, in a conversion zone maintained at specified conditions such that the feedstocks are both desulfurized and subjected to significant hydroconversion, particularly demonstrated by significant reductions in the 1,050.degree. F+ fraction of these feedstocks, as well as significantly decreased Conradson carbon and increased API gravity. In addition, the deep demetallization and moderate denitrogenation of these feedstocks is also achieved. These important results are obtained by maintaining the conversion zone at temperatures of above 750.degree. F, and in the presence of sufficient added hydrogen to produce a hydrogen pressure in the conversion zone of between about 1500 and 3000 psig.

    Abstract translation: 公开了用于各种含硫石油油，特别是各种残留原料的联合脱硫和加氢转化的改进方法。 因此，这些原料在熔融状态下与碱性金属（例如钠）在保持在特定条件下的转化区中接触，使得原料都脱硫并进行显着的加氢转化，特别是通过显着降低1,050°F +馏分 的这些原料，以及Conradson碳显着降低和API重力增加。 此外，还实现了这些原料的深度脱金属和中等脱氮。 这些重要的结果是通过将转化区保持在高于750°F的温度下，并且在有足够的氢气存在下，在转化区中产生约1500-3000psig的氢气压力而获得的。

    Hydroconversion of heavy hydrocarbons
    69.
    发明授权
    Hydroconversion of heavy hydrocarbons 失效
    重油烃的氢化

    公开(公告)号：US4066530A

    公开(公告)日：1978-01-03

    申请号：US745394

    申请日：1976-11-26

    Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

    Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

    IPC: B01J37/00 ,  C10G45/16 ,  C10G13/06 ,  B01J27/04

    CPC classification number: B01J37/00 ,  C10G45/16

    Abstract: A catalytic hydroconversion process is effected by reacting with hydrogen a heavy hydrocarbonaceous oil containing a catalyst comprising an iron component and a catalytically active other metal component prepared by dissolving an oil soluble metal compound in the oil and converting the metal compound in the oil to the corresponding catalytically active metal component. Preferred oil soluble compounds are molybdenum compounds.

    Abstract translation: 烃油的催化加氢转化方法是通过将油溶性金属化合物溶解在油中，将化合物转化成油中的固体非胶态催化剂并使含有催化剂的油与氢反应。 优选的化合物是钼化合物。

    Combined desulfurization and hydroconversion with alkali metal hydroxides
    70.
    发明授权
    Combined desulfurization and hydroconversion with alkali metal hydroxides 失效
    与碱金属氢氧化物联合脱硫和加氢转化

    公开(公告)号：US4003823A

    公开(公告)日：1977-01-18

    申请号：US571912

    申请日：1975-04-28

    Applicant: William C. Baird, Jr. ,  Roby Bearden, Jr.

    Inventor： William C. Baird, Jr. ,  Roby Bearden, Jr.

    IPC: C10G19/00 ,  C10G19/08 ,  C10G47/22 ,  C10G13/06 ,  B01J27/04

    CPC classification number: C10G19/00 ,  C10G19/08 ,  C10G47/22

    Abstract: Processes for the simultaneous desulfurization and hydroconversion of heavy carbonaceous feeds, including various sulfur-containing heavy petroleum oils, are disclosed. These feeds are contacted with alkali metal hydroxides in a conversion zone, in the presence of added hydrogen, and at elevated temperatures, whereby the feeds are substantially desulfurized, while at the same time significant upgrading of these feedstocks is obtained as demonstrated by decreased Conradson carbon, increased API gravity, and the conversion of a substantial portion of the 1,050.degree. F+ portion of the feedstream. In addition, methods for the regeneration of alkali metal hydroxides from the alkali metal salts produced in the conversion zone are disclosed.

    Abstract translation: 公开了重质碳质饲料（包括各种含硫重质石油）同时脱硫和加氢转化的方法。 这些进料在转化区，在加入的氢气存在下，在升高的温度下与碱金属氢氧化物接触，从而使进料基本上脱硫，同时，这些原料的显着升级得到，如Conradson碳 ，API重力增加，以及进料流的1,050°F +部分的大部分转化。 此外，公开了在转化区中产生的碱金属盐再生碱金属氢氧化物的方法。

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