摘要:
This disclosure relates to the processes for producing polycarbonates from specific crude bisphenols. The bisphenols are characterized in that immediately after their preparation they are subjected to (i) separation, of excess phenols and low-boiling substances, by means of an evaporator, and (ii) removal of monophenols by desorption.The invention also relates to high-molecular weight aromatic polycarbonates made of crude bisphenols and their use in a variety of applications.
摘要:
This development is concerned with aromatic thermoplastic polycarbonates with special chain terminators which give the polymers enhanced hydrolysis resistance and impact toughness. These chain terminators are alkyl substituted monohydroxy phenyls in which each phenyl is substituted by one alkyl group having 8 or 9 carbon atoms and about 47 to 89% of its hydrogen atoms trisubstituted on carbon atoms with up to about 20% of the substituents in the ortho position and the balance at the para position. This development is also concerned with a process for synthesizing such polymers by using such chain terminators as reactants in generically known synthesis methods for polycarbonates.
摘要:
Resins having a softening point of from 50.degree. to 130.degree. C., an OH-number of from 250 to 400 and an iodine number of from 90 to 160, obtainable by reacting an alkyl phenol-formaldehyde novolak or an alkyl phenol mixture-formaldehyde novolak under acid-catalysed conditions with a polunuclear phenol or polynuclear phenol mixture and formaldehyde and/or an aliphatic aldehyde or aliphatic aldehyde mixture, the ratio by weight of the alkyl phenol or alkyl phenol mixture to the polynuclear phenol or polynyclear phenol mixture being from 2.2:1 to 1:10.
摘要:
Thermoplastic aromatic polyesters comprising cocondensed bisphenol residues generally have a refractive index n.sub.d of from 1.60 to 1.66, an Abbe coefficient v.sub.d of from 27 to 21 and a color triplet of about 5.1, 0.1, O and are excellent starting materials for the production of optical components, particularly high quality lenses for still and cine cameras.
摘要:
High-molecular weight polycarbonate elastomers are produced by reacting polymer segments having an average molecular weight (Mn) of more than 600 and carboxyl groups with diphenols and phosgene according to the two-phase boundary polycondensation process at a pH value between about 9 and about 14 and a temperature between about 0.degree. C. and 80.degree. C. and, thereafter, either heat-treating the resulting reaction products at temperatures between about 40.degree. C. and about 100.degree. C. or gelling the resulting reaction products in solution in organic solvents.
摘要:
Boron-containing resins suitable for reinforcing rubber are obtained by reacting diphenylol alkane novolaks with boron compounds and unsaturated fatty acids or fatty acid esters.
摘要:
The present invention relates to a process of producing .alpha., .alpha., .alpha., .alpha.', .alpha.', .alpha.'-hexakisaryl-1,3- and -1,4-dimethyl benzenes by reacting .alpha., .alpha., .alpha.', .alpha.'-tetrakisaryl-1,3 or -1,4-bis-(chloromethyl)- or -bis-(hydroxymethyl)- benzenes with 2 to 30 times the molar quantity (based on the tetrakis benzene) of phenol or a substituted phenol.
摘要:
Disclosed are oligomeric phosphonates, and in particular, hyperbranched oligophosphonates, that include oligophosphonates, random or block co-oligo(phosphonate ester)s and co-oligo(phosphonate carbonate)s produced using a condensation process terminated with hydroxyl, epoxy, vinyl, vinyl ester, isopropenyl, isocyanate groups, and the like. These materials can be used as a reactive additive to other polymers, oligomers or monomer mixtures to impart flame resistance without diminishing melt processability which is important in the fabrication of polymers for many applications.
摘要:
Disclosed are oligomeric phosphonates including oligophosphonates, random or block co-oligo(phosphonate ester)s and co-oligo(phosphonate carbonate)s produced using a condensation process terminated with hydroxyl, epoxy, vinyl, vinyl ester, isopropenyl, isocyanate groups, and the like. These materials can be used as a reactive additive to other polymers, oligomers or monomer mixtures to impart flame resistance without diminishing melt processability which is important in the fabrication of polymers for many applications.
摘要:
A method for preparing substantially pure optionally substituted diaryl alkylphosphonates from an optionally substituted triarylphosphite and an optionally substituted trialkylphosphite or an optionally substituted alkanol under special reaction conditions is described.