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公开(公告)号：US09192916B2
公开(公告)日：2015-11-24
申请号：US12563591
申请日：2009-09-21
申请人： Mark G. Riley , Bryan K. Glover
发明人： Mark G. Riley , Bryan K. Glover
IPC分类号： C07C5/05 , B01J23/58 , B01J21/04 , B01J23/44 , B01J35/00 , B01J35/10 , C07C5/09 , C07C15/107
CPC分类号： B01J23/58 , B01J21/04 , B01J23/44 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1066 , B01J35/108 , C07C5/05 , C07C5/09 , C07C15/107 , C07C2521/04 , C07C2523/44 , C07C2523/58 , C07C11/02
摘要： A process and catalyst are presented for the selective hydrogenation of branched diolefins and acetylenes to olefins. The process uses a catalyst having large pores, and a minimal amount of micropores. The catalyst is designed to have minimal diffusional resistance through the large pores, and to minimize the hydrogenation of olefins to paraffins.
摘要翻译： 提出了一种方法和催化剂，用于将支链二烯烃和炔烃选择性氢化成烯烃。 该方法使用具有大孔的催化剂和最少量的微孔。 该催化剂被设计为具有通过大孔的最小扩散阻力，并使烯烃氢化至链烷烃最小化。
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62.发明授权Preparing a light-olefin containing product stream from an oxygenate-containing feed steam using reactors directing a flow of a fluidized dual-function catalyst system 有权使用引导流化双功能催化剂体系流的反应器从含氧化合物的进料蒸汽制备含轻烯烃的产物流公开(公告)号：US08735639B2
公开(公告)日：2014-05-27
申请号：US12755632
申请日：2010-04-07
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present process provides a method for converting an oxygenate-containing feed stream to an olefin-containing product stream. The method includes: (1) providing a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) providing a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) providing an oxygenate containing feed to the first reactor; and (4) fluidizing the catalyst system with the oxygenate containing feed.
摘要翻译： 本发明方法提供了将含氧化合物的进料流转化为含烯烃的产物流的方法。 该方法包括：（1）提供用于将甲醇转化为丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）提供与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）向第一反应器提供含氧化合物进料; 和（4）用含氧化合物进料使催化剂体系流化。
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公开(公告)号：US08603399B2
公开(公告)日：2013-12-10
申请号：US12571841
申请日：2009-10-01
IPC分类号： B01J8/18
CPC分类号： C07C1/20 , C07C1/24 , C07C4/06 , C10G3/42 , C10G3/57 , C10G11/18 , C10G2400/20 , Y02P30/42 , Y02P30/48 , C07C11/02
摘要： An improved processing system of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. The system further comprises acid gas removal means to remove acid gases from the cracked product gas and that the olefin cracking reactor is a moving bed reactor.
摘要翻译： 含氧化合物原料的改进处理系统，用于提高轻质烯烃的生产或产率。 这种处理涉及含氧化合物转化为烯烃并随后开裂较重的烯烃，其中使用普通的压缩机将来自每个反应器的产物的至少一部分在压力下升高，然后被送至共同的产物分馏和回收段。 该系统还包括从裂化产物气体除去酸性气体的酸性气体去除装置，并且烯烃裂解反应器是移动床反应器。
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公开(公告)号：US20120322650A1
公开(公告)日：2012-12-20
申请号：US13161252
申请日：2011-06-15
申请人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , John Joseph Senetar , Erik Holmgreen , Mark G. Riley
发明人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , John Joseph Senetar , Erik Holmgreen , Mark G. Riley
IPC分类号： B01J35/02 , B01J23/42 , B01J23/44 , B01J21/04 , B01J21/08 , B01J29/06 , B01J29/00 , B01J21/06 , B01J21/16 , B01J21/10 , B01J23/04 , B01J21/12
CPC分类号： B01J35/10 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/74 , B01J35/002 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0221 , C10G45/36 , C10G45/40 , C10G2300/1088 , C10G2400/20
摘要： One exemplary embodiment can be a layered catalyst for use in a selective hydrogenation of acetylenes and diolefins to olefins. The layered catalyst may include an inner core having an inert material, an outer layer including a metal oxide bonded to the inner core, and a metal deposited on the outer layer. Generally, the metal is an IUPAC Group 8-10 metal and the layered catalyst has an accessibility index of about 3- about 500.
摘要翻译： 一个示例性实施方案可以是用于将烯烃和二烯烃选择性氢化成烯烃的层状催化剂。 层状催化剂可以包括具有惰性材料的内芯，包含结合到内芯的金属氧化物的外层和沉积在外层上的金属。 通常，金属是IUPAC Group 8-10金属，层状催化剂具有约3-约500的可达性指数。
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65.发明申请Integration of Cyclic Dehydrogenation Process with FCC for Dehydrogenation of Refinery Paraffins 有权循环脱氢工艺与FCC一起用于炼油石蜡脱氢公开(公告)号：US20120071701A1
公开(公告)日：2012-03-22
申请号：US12886966
申请日：2010-09-21
申请人： Bryan K. Glover
发明人： Bryan K. Glover
IPC分类号： C07C4/06
CPC分类号： C07C4/06 , C07C2/56 , C07C5/3335 , C07C5/3337 , C07C6/04 , C07C2521/06 , C07C2523/26 , C07C2523/42 , C10G11/18 , C10G57/00 , C10G57/005 , C10G70/00 , C10G2400/20 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： A process for increasing light olefin yields from the fluidized catalytic cracking process. The process combines small units to treat the paraffinic components in the product streams from the fluidized cracking process. The paraffins are dehydrogenated and light olefins are separated. Heavier olefins are passed to an olefin cracking unit for increasing the yields of ethylene and propylene.
摘要翻译： 一种从流化催化裂化过程中提高轻质烯烃产率的方法。 该方法结合了小单位来处理来自流化裂解过程的产物流中的链烷烃组分。 链烷烃脱氢，轻质烯烃分离。 较重的烯烃被传递到烯烃裂解装置以提高乙烯和丙烯的产率。
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公开(公告)号：US20100331590A1
公开(公告)日：2010-12-30
申请号：US12491344
申请日：2009-06-25
申请人： Debarshi Majumder , Bryan K. Glover
发明人： Debarshi Majumder , Bryan K. Glover
IPC分类号： C07C4/06
CPC分类号： C10G11/00 , C10G2300/1044 , C10G2400/20 , C10G2400/30
摘要： Processes for the conversion of both straight- or branched-chain (e.g., paraffinic) as well as cyclic (e.g., naphthenic) hydrocarbons of a hydrocarbon feedstock into value added product streams are disclosed. The processes involve the use of both dehydrogenation and olefin cracking to produce both light olefins and aromatics in varying proportions depending on the feedstock composition and particular processing scheme. The processes are especially applicable to naphtha feedstocks comprising paraffins and naphthenes in the C5-C11 carbon number range.
摘要翻译： 公开了将烃原料的直链或支链（例如链烷烃）以及环状（例如环烷烃）烃转化成增值产物流的方法。 这些方法包括使用脱氢和烯烃裂解以根据原料组成和特定加工方案以不同比例生产轻质烯烃和芳族化合物。 该方法特别适用于包含C 5 -C 11碳数范围内的链烷烃和环烷烃的石脑油原料。
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67.发明申请Preparing A Light-Olefin Containing Product Stream from an Oxygenate-Containing Feed Steam Using Reactors Directing a Flow of a Fluidized Dual-Function Catalyst System 有权使用引导流化双功能催化剂体系流动的反应器，从含氧化合物的进料蒸汽制备含有轻烯烃的轻质烯烃公开(公告)号：US20100204530A1
公开(公告)日：2010-08-12
申请号：US12755632
申请日：2010-04-07
IPC分类号： C07C1/20
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present invention provides a reactor system for converting an oxygenate-containing feed stream to an olefin-containing product stream. The system includes: (1) a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) wherein the first catalyst is a non-zeolite molecular sieve catalyst; and (4) wherein the second catalyst is a zeolite molecular sieve catalyst.
摘要翻译： 本发明提供了一种用于将含氧化合物的进料流转化为含烯烃的产物流的反应器系统。 该系统包括：（1）用于将甲醇转化成丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）其中第一催化剂是非沸石分子筛催化剂; 和（4）其中第二催化剂是沸石分子筛催化剂。
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公开(公告)号：US07687671B2
公开(公告)日：2010-03-30
申请号：US11293934
申请日：2005-12-05
IPC分类号： C07C1/00
CPC分类号： C07C1/20 , C07C1/24 , C07C4/06 , C10G3/42 , C10G3/57 , C10G11/18 , C10G2400/20 , Y02P30/42 , Y02P30/48 , C07C11/02
摘要： Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.
摘要翻译： 改进含氧化合物原料的加工，以提高轻质烯烃的生产或产率。 这种处理涉及含氧化合物转化为烯烃并随后开裂较重的烯烃，其中使用普通的压缩机将来自每个反应器的产物的至少一部分在压力下升高，然后被送至共同的产物分馏和回收段。 在一个具体实施方案中，可以处理裂化产物气体以从其中除去酸性气体。 在另一个实施方案中，烯烃裂解反应器是移动床反应器。
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69.发明授权公开(公告)号：US07683226B1
公开(公告)日：2010-03-23
申请号：US11608137
申请日：2006-12-07
申请人： Bryan K. Glover , Stephen W. Sohn , Mark G. Riley , Dean E. Rende
发明人： Bryan K. Glover , Stephen W. Sohn , Mark G. Riley , Dean E. Rende
CPC分类号： C07C15/107 , C07C2/66 , C07C5/333 , C07C2521/12 , Y02P20/125
摘要： Integrated processes for making detergent range alkylbenzenes from C5-C6-containing feeds involve feed pretreatment and/or selective hydrogenation to enable acceptable quality alkylbenzene production at attractive capital and operating costs.
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公开(公告)号：US20100055008A1
公开(公告)日：2010-03-04
申请号：US12617944
申请日：2009-11-13
IPC分类号： B01J8/02
摘要： An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by louvers that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.
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