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    Radical polymerization processes for preparing halogenated polymers, and halogenated polymers
    61.
    发明申请
    Radical polymerization processes for preparing halogenated polymers, and halogenated polymers 有权
    用于制备卤化聚合物和卤代聚合物的自由基聚合方法

    公开(公告)号：US20060205906A1

    公开(公告)日：2006-09-14

    申请号：US11431836

    申请日：2006-05-11

    申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C08F214/08

    CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

    摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

    摘要翻译： 用于制备卤化聚合物的自由基聚合方法，其使用一种或多种烯键式不饱和单体，其中至少一种选自卤代单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二烷基烷烃的自由基产生剂。自由基聚合方法 用于制备，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤代聚合物嵌段。 具有大于1.0×104的数均分子量M N n N以及小于1.65的M z z / M x W比的卤化聚合物 。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量大于1.5×10 4的至少一种卤代聚合物嵌段的嵌段共聚物和多分散性指数M SUB> / M 小于1.60。

    Fluorinated elastomers with low glass transition temperatures based on vinylidene fluoride and free of tetrafluoroethylene or siloxane group
    63.
    发明申请
    Fluorinated elastomers with low glass transition temperatures based on vinylidene fluoride and free of tetrafluoroethylene or siloxane group 审中-公开
    具有低玻璃化转变温度的氟化弹性体，其基于偏二氟乙烯并且不含四氟乙烯或硅氧烷基团

    公开(公告)号：US20050215741A1

    公开(公告)日：2005-09-29

    申请号：US11106571

    申请日：2005-04-15

    申请人： Bruno Ameduri ,  Michel Armand ,  Mario Boucher ,  Bernard Boutevin

    发明人： Bruno Ameduri ,  Michel Armand ,  Mario Boucher ,  Bernard Boutevin

    IPC分类号： C08F2/12 ,  C08F214/22 ,  C08F16/24 ,  C08F216/12

    CPC分类号： C08F214/222

    摘要： The present invention describes synthesis of new fluorinated elastomers presenting very low glass transition temperatures, a good resistance to bases, petroleum and fuels and good properties for forming. These elastomers contain, by way of example, from 90 to 50 mole % of vinylidene fluoride (VDF) and from 10 to 50 molar % of perfluoromethyl vinyl ether (PMVE). In this precise case, they are prepared by radical copolymerisation of VDF and with PMVE in presence of various organic initiators such as for example the peroxides, the peresters or the diazo compounds.

    摘要翻译： 本发明描述了具有非常低的玻璃化转变温度，良好的抗碱性，石油和燃料的良好性能以及良好的形成性能的新的氟化弹性体的合成。 这些弹性体例如含有90-50摩尔％的偏二氟乙烯（VDF）和10-50摩尔％的全氟甲基乙烯基醚（PMVE）。 在这种精确的情况下，它们通过VDF和PMVE在各种有机引发剂如过氧化物，过酸酯或重氮化合物的存在下的自由基共聚来制备。

    Radical polymerization methods and halogenated polymers
    64.
    发明申请
    Radical polymerization methods and halogenated polymers 失效
    自由基聚合方法和卤代聚合物

    公开(公告)号：US20050171312A1

    公开(公告)日：2005-08-04

    申请号：US10512870

    申请日：2003-05-16

    申请人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    发明人： Patrick Lacroix-Desmazes ,  Romain Severac ,  Bernard Boutevin ,  Vincent Bodart ,  Vincent Kurowski

    IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F4/40 ,  C08F8/22 ,  C08F14/00 ,  C08F14/08 ,  C08F14/16 ,  C08F14/22 ,  C08F293/00

    CPC分类号： C08F293/005 ,  C08F8/22 ,  C08F14/00 ,  C08F214/18 ,  C08F214/186 ,  C08F293/00 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24

    摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyldiphenylalkanes. Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw, ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn, of less than 1.60.

    摘要翻译： 使用一种或多种烯属不饱和单体制备卤化聚合物的自由基聚合方法，其中至少一种选自卤化单体，分子碘和一种或多种选自重氮化合物，过氧化物和二烷基二苯基烷烃的自由基产生剂。 用于制备的自由基聚合方法，从由上述方法制备的卤化聚合物开始的嵌段共聚物，其至少一个嵌段是卤化聚合物嵌段。 具有大于1.0×10 4的数均分子量M n N以及M z z / M z的卤化聚合物， / SUB>，比值小于1.65。 嵌段共聚物，其至少一个嵌段是与上述卤化聚合物相同的卤代聚合物嵌段。 包含数均分子量大于1.5×10 4的至少一种卤代聚合物嵌段的嵌段共聚物和多分散性指数M 小于或等于1.60。

    Copolymer grafted via radical polymerization in the presence of stable radicals, its preparation and its uses
    65.
    发明授权
    Copolymer grafted via radical polymerization in the presence of stable radicals, its preparation and its uses 失效
    共聚物通过自由基聚合在稳定的自由基存在下接枝，其制备及其用途

    公开(公告)号：US06335401B1

    公开(公告)日：2002-01-01

    申请号：US09164717

    申请日：1998-10-01

    申请人： Denis Bertin ,  Bernard Boutevin ,  Jean-Jacques Robin

    发明人： Denis Bertin ,  Bernard Boutevin ,  Jean-Jacques Robin

    IPC分类号： C08L5100

    CPC分类号： C08F4/36 ,  C08F291/00 ,  C08F291/18 ,  C08L51/00

    摘要： The present invention relates to a grafted copolymer bearing grafts of formula (I): —O—PM1—(PM2)—T  (I) in which: PM1 represents a polymer block obtained by (co)polymerization of at least one monomer M1 via a radical route; and PM2, which is optionally present, represents a polymer block obtained by (co)polymerization of at least one monomer M2 via a radical route; and T represents the residue of a stable radical T•.

    摘要翻译： 本发明涉及具有式（I）的接枝接枝物的接枝共聚物：其中：PM1表示通过自由基途径（共）聚合至少一种单体M1而获得的聚合物嵌段; 和任选存在的PM2表示通过自由基途径（共）聚合至少一种单体M2获得的聚合物嵌段; 和T表示稳定基团T的残基

    Process for preparing an active telogen
    68.
    发明授权
    Process for preparing an active telogen 失效
    准备活跃期限的过程

    公开(公告)号：US5283380A

    公开(公告)日：1994-02-01

    申请号：US76527

    申请日：1993-06-11

    申请人： Bernard Boutevin ,  Gerald A. Gornowicz

    发明人： Bernard Boutevin ,  Gerald A. Gornowicz

    IPC分类号： C07B61/00 ,  C07C17/04 ,  C07C19/16 ,  C07C19/08

    CPC分类号： C07C17/04

    摘要： This invention relates to an improved method of preparing the active telogen CF.sub.3 CFClI. The process comprises reacting chlorotrifluoroethylene, iodine, and iodine pentafluoride in the presence of an aluminum bromide catalyst at a temperature above about 25.degree. C.

    摘要翻译： 本发明涉及一种制备活性停用前体CF3CFClI的改进方法。 该方法包括在溴化铝催化剂存在下，在高于约25℃的温度下使氯三氟乙烯，碘和五氟化碘反应。

    Batching process for treatment of carbon fibers
    69.
    发明授权
    Batching process for treatment of carbon fibers 失效
    用于处理碳纤维的分批处理

    公开(公告)号：US5189093A

    公开(公告)日：1993-02-23

    申请号：US729923

    申请日：1991-07-15

    申请人： Daniel Beziers ,  Bernard Boutevin ,  Jean-Pierre Parisi ,  Yannig Thomas ,  Evelyne Chataignier

    发明人： Daniel Beziers ,  Bernard Boutevin ,  Jean-Pierre Parisi ,  Yannig Thomas ,  Evelyne Chataignier

    IPC分类号： C08J5/06

    CPC分类号： C08J5/06

    摘要： According to the invention, the reactive lubricating product of carbon fibres for embedding in a resin which can be hardened by X or beta radiation according to a radical mechanism is constituted by a monomer having at least one functional group (F.sub.1) able to form a covalent chemical bond with the hydroxyl sites of the carbon fibres and an ethylene unsaturation (F.sub.2) able to crosslink with the resin during its hardening under irradiation.

    摘要翻译： 根据本发明，用于嵌入树脂中的碳纤维的反应性润滑产物可以通过X或β辐射根据自由基机理硬化由具有至少一个能够形成共价键的官能团（F1）的单体构成， 化学键与碳纤维的羟基位置和乙烯不饱和度（F2）能够在树脂硬化过程中与树脂交联。

    Perchlorofluorinated hydrocarbons and process for their preparation
    70.
    发明授权
    Perchlorofluorinated hydrocarbons and process for their preparation 失效
    全氟氯化烃及其制备方法

    公开(公告)号：US4740640A

    公开(公告)日：1988-04-26

    申请号：US792969

    申请日：1985-10-30

    申请人： Bernard Boutevin ,  Yves Hervaud

    发明人： Bernard Boutevin ,  Yves Hervaud

    IPC分类号： C07C21/02 ,  B01J23/72 ,  B01J27/10 ,  C07B61/00 ,  C07C17/00 ,  C07C17/26 ,  C07C17/278 ,  C07C19/10 ,  C07C67/00 ,  C07C19/02 ,  C07C ,  C07C17/24

    CPC分类号： C07C19/10 ,  C07C17/278

    摘要： Novel perchlorofluorinated hydrocarbons of the general formula:Cl-(CFX-CF.sub.2).sub.m -CCl.sub.2 -(CF.sub.2 -CFY).sub.n -Clwherein X and Y represent chlorine or fluorine atoms, and m and n are integers from 1 to 5, together with a process for preparing such perchlorofluorocarbons by reacting chlorotrifluoroethylene or tetrafluoroethylene with carbon tetrachloride or a telomer having the formula Cl.sub.3 C-(CF.sub.2 -CFX).sub.m -Cl in a polar solvent at a temperature of at least 120.degree. C. in the presence of copper or a copper salt.

    摘要翻译： 新型全氟氯化烃，具有以下通式：Cl-（CFX-CF2）m-CCl2-（CF2-CFY）n-Cl，其中X和Y表示氯或氟原子，m和n是1至5的整数，以及 通过使氯三氟乙烯或四氟乙烯与四氯化碳或具有式Cl3C-（CF2-CFX）m-Cl的调聚物在极性溶剂中在至少120℃的温度下在铜的存在下反应来制备这种全氟氯烃的方法或 铜盐。