公开(公告)号：US09932422B2

公开(公告)日：2018-04-03

申请号：US15069778

申请日：2016-03-14

申请人： Chevron Phillips Chemical Company LP

发明人： John D. Hottovy ,  Scott E. Kufeld

IPC分类号： B01J8/00 ,  B01J19/00 ,  B01J19/18 ,  B01J19/24 ,  B01D1/00 ,  B01D1/04 ,  B01D1/22 ,  B01D1/24 ,  C08F2/14 ,  C08F6/00 ,  C08F10/00 ,  C08F110/02 ,  B01J19/06 ,  C08F2/00 ,  C08F2/12 ,  C08F110/00 ,  C08L23/00

CPC分类号： C08F110/02 ,  B01D1/04 ,  B01D1/24 ,  B01J8/005 ,  B01J19/06 ,  B01J19/1837 ,  B01J2219/00006 ,  C08F6/003 ,  C08F10/00 ,  C08F2/00 ,  C08F2/14 ,  C08L23/00

摘要： The present embodiments provide a system and method for separation within a polymer production process. Specifically, a flashline heater configured according to present embodiments may provide more time than is required for complete vaporization of liquid hydrocarbons that are not entrained within a polymer fluff produced within a polymerization reactor. Such extra time may allow for liquid hydrocarbons that are entrained within the polymer fluff to be vaporized.

公开(公告)号：US09809659B2

公开(公告)日：2017-11-07

申请号：US15321152

申请日：2015-06-22

申请人： Basell Polyolefine GmbH

发明人： Giuseppe Penzo ,  Rodrigo Carvajal ,  Reinhard Kuehl ,  Elke Damm

IPC分类号： C08F10/02 ,  C08F2/01 ,  C08F2/12 ,  C08F2/14 ,  C08F2/18 ,  B01J19/18

CPC分类号： C08F10/02 ,  C08F2/01 ,  C08F2/12 ,  C08F2/18

摘要： A process for the preparation of polyethylene by polymerizing in a slurry ethylene and optionally one or more C3 to C10 alpha-olefins in a reactor system comprising a polymerization reactor and one or more first heat exchangers located outside the polymerization reactor where the slurry in the polymerization reactor is cooled by withdrawing slurry from the polymerization reactor, cooling the slurry in the one or more first heat exchangers and returning the cooled slurry to the polymerization reactor, wherein the one or more first heat exchangers are cooled by a first coolant having a temperature of 29° C. or higher.

公开(公告)号：US09650454B2

公开(公告)日：2017-05-16

申请号：US15309158

申请日：2015-05-13

申请人： Basell Polyolefine GmbH

发明人： Harald Prang ,  Suresh Babu Vatti ,  Peter Rohrbach ,  Mudit Ashtana

IPC分类号： C08F110/02 ,  C08F2/01 ,  C08F2/12 ,  B01J19/18 ,  B01J19/00 ,  C08F2/14

CPC分类号： C08F110/02 ,  B01J19/006 ,  B01J19/18 ,  B01J19/1862 ,  B01J2219/0009 ,  B01J2219/00094 ,  B01J2219/00765 ,  B01J2219/00768 ,  B01J2219/0077 ,  C08F210/16 ,  C08L23/0815 ,  C08L2205/025 ,  C08F210/08 ,  C08F2/001

摘要： A slurry polymerization process comprising polymerizing monomers in a reactor comprising baffles, a first slurry feed line for returning cooled slurry from a cooler and optionally a second slurry feed line for transferring reactor slurry from a previous reactor of a cascade of polymerization reactors, wherein the baffle top, the first slurry feed line discharge end and the second slurry feed line end are located below the reactor liquid level.

公开(公告)号：US09580370B2

公开(公告)日：2017-02-28

申请号：US15189453

申请日：2016-06-22

申请人： Chevron Phillips Chemical Company LP

发明人： John D. Hottovy ,  Ai-fu Chang

IPC分类号： C07C7/11 ,  C07C7/156 ,  C07C5/327 ,  B01J19/24 ,  B01D53/18 ,  C08F6/00 ,  C08F110/02 ,  C08L23/04 ,  B01D53/14 ,  C08F2/12 ,  C08F10/02

CPC分类号： C07C7/11 ,  B01D53/1487 ,  B01D53/1493 ,  B01D53/18 ,  B01D2252/10 ,  B01D2252/20405 ,  B01D2252/20421 ,  B01D2252/20431 ,  B01D2252/20436 ,  B01D2252/20468 ,  B01D2252/504 ,  B01D2257/7022 ,  B01J19/24 ,  B01J19/2455 ,  B01J2219/24 ,  C07C5/327 ,  C08F6/001 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04

摘要： A process for recovery of ethylene from a polymerization product stream of a polyethylene production system, comprising separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein the contacting the light gas stream with the absorption solvent system occurs at a temperature in a range of from about 40° F. to about 110° F., wherein at least a portion of the unreacted ethylene from the light gas stream is absorbed by the absorption solvent system, and recovering unreacted ethylene from the absorption solvent system to yield recovered ethylene.

摘要翻译： 一种从聚乙烯生产系统的聚合产物流中回收乙烯的方法，包括从聚合产物流中分离轻质气体流，其中轻质气体流包含乙烷和未反应的乙烯，使轻质气体物流与吸收溶剂体系接触 其中轻质气体流与吸收溶剂体系的接触在约40°F至约110°F的温度范围内发生，其中来自轻质气体流的至少一部分未反应的乙烯被吸收 通过吸收溶剂体系，从吸收溶剂体系中回收未反应的乙烯，得到回收的乙烯。

公开(公告)号：US09556288B2

公开(公告)日：2017-01-31

申请号：US14597475

申请日：2015-01-15

申请人： Chevron Phillips Chemical Company, LP

发明人： Maruti Bhandarkar ,  Elizabeth A Benham ,  Rebecca A. Gonzales ,  Scott E. Kufeld ,  Joel A Mutchler ,  Catherine M. Gill ,  Thanh T. Nguyen ,  Timothy O. Odi

IPC分类号： C08F10/02 ,  C08F2/12 ,  C08F2/38 ,  B01J19/18 ,  B01J19/24 ,  C08F2/00 ,  C08F2/01 ,  C08L23/02 ,  C08F110/02

CPC分类号： C08F10/02 ,  B01J19/242 ,  B01J19/2435 ,  B01J19/245 ,  B01J19/246 ,  B01J2219/24 ,  C08F2/001 ,  C08F2/01 ,  C08F110/02 ,  Y10S526/905 ,  C08F10/00 ,  C08F2/38 ,  C08F2/14

摘要： A system and method for polymerizing olefin in the presence of a chain transfer agent in a first reactor to form a first polyolefin, discharging from the first reactor a transfer slurry having the first polyolefin and the chain transfer agent, and processing the transfer slurry in a separator to remove chain transfer agent and to provide a fluff slurry having the first polyolefin and a lower content of chain transfer agent than in the transfer slurry. The system and method provide for feeding the fluff slurry to a second reactor, polymerizing olefin in the second reactor to form a second polyolefin, and discharging from the second reactor a slurry having the second polyolefin.

摘要翻译： 一种用于在第一反应器中在链转移剂存在下使烯烃聚合以形成第一聚烯烃的系统和方法，从第一反应器排出具有第一聚烯烃和链转移剂的转移浆料，并将转移浆料加工成 分离器以除去链转移剂，并提供具有第一聚烯烃和较低含量的链转移剂的绒毛浆料，而不是转移浆料。 该系统和方法提供将绒毛浆料供给到第二反应器，在第二反应器中聚合烯烃以形成第二聚烯烃，并从第二反应器排出具有第二聚烯烃的浆料。

公开(公告)号：US09403921B2

公开(公告)日：2016-08-02

申请号：US14829190

申请日：2015-08-18

申请人： Chevron Phillips Chemical Company LP

发明人： Maruti Bhandarkar ,  Elizabeth A. Benham ,  Rebecca A. Gonzales ,  Scott E. Kufeld ,  Joel A. Mutchler ,  Catherine M. Gill ,  Thanh T. Nguyen ,  Timothy O. Odi

IPC分类号： C08F2/12 ,  C08F2/38 ,  B01J19/18 ,  B01J19/24 ,  C08F10/02 ,  C08F2/00 ,  C08F2/01 ,  C08L23/02 ,  C08F110/02

CPC分类号： C08F10/02 ,  B01J19/242 ,  B01J19/2435 ,  B01J19/245 ,  B01J19/246 ,  B01J2219/24 ,  C08F2/001 ,  C08F2/01 ,  C08F110/02 ,  Y10S526/905 ,  C08F10/00 ,  C08F2/38 ,  C08F2/14

摘要： A system and method for polymerizing olefin in the presence of a chain transfer agent in a first reactor to form a first polyolefin, discharging from the first reactor a transfer slurry having the first polyolefin and the chain transfer agent, and processing the transfer slurry in a separator to remove chain transfer agent and to provide a fluff slurry having the first polyolefin and a lower content of chain transfer agent than in the transfer slurry. The system and method provide for feeding the fluff slurry to a second reactor, polymerizing olefin in the second reactor to form a second polyolefin, and discharging from the second reactor a slurry having the second polyolefin.

公开(公告)号：US08846831B2

公开(公告)日：2014-09-30

申请号：US13812713

申请日：2011-07-29

申请人： Daan Dewachter ,  Alain Brusselle

发明人： Daan Dewachter ,  Alain Brusselle

IPC分类号： C08F2/12 ,  C08F2/00 ,  C08F10/00 ,  B01J8/00 ,  C08F210/16 ,  F03B17/00 ,  F04B53/10 ,  C08F4/659

CPC分类号： F03B17/00 ,  B01J8/002 ,  B01J2208/00752 ,  C08F4/65916 ,  C08F10/00 ,  C08F210/16 ,  Y10S417/90 ,  Y10S526/919 ,  Y10T137/0318 ,  C08F2/14 ,  C08F2/01 ,  C08F210/14

摘要： The present invention relates to a method for feeding metallocene catalyst slurry to an olefin polymerization loop reactor (1) using a positive displacement device (5) positive displacement device comprising a first chamber and a second chamber, each chamber having an inlet and an outlet and each chamber comprising an ball arranged between the walls of said chamber, wherein said chambers are connected to each other by a pump chamber operably connected to a pump, wherein, the difference between the diameter of said ball and the diameter of said chamber is comprised between 5 to 200 times the average particle size (d50) of said catalyst.

摘要翻译： 本发明涉及使用包括第一室和第二室的正位移装置（5）的正位移装置将茂金属催化剂浆料供给到烯烃聚合反应器（1）的方法，每个室具有入口和出口， 每个室包括布置在所述室的壁之间的球，其中所述室通过可操作地连接到泵的泵室彼此连接，其中，所述球的直径和所述室的直径之间的差包括在 所述催化剂的平均粒度（d50）为5〜200倍。

公开(公告)号：US08802795B2

公开(公告)日：2014-08-12

申请号：US13818845

申请日：2011-08-30

申请人： Gerhardus Meier ,  Reinhard Kuehl ,  Harald Prang ,  Michael Aulbach

发明人： Gerhardus Meier ,  Reinhard Kuehl ,  Harald Prang ,  Michael Aulbach

IPC分类号： C08F2/12 ,  C08F6/24 ,  C08F210/08

CPC分类号： C08F2/04 ,  C08F210/16 ,  C08F2/001 ,  C08F2/14 ,  C08F210/14

摘要： Process for the preparation of a polyolefin polymer by continuously polymerizing one or more olefin monomers in suspension at temperatures of from 40° C. to 120° C. and pressures of from 0.1 to 10 MPa in the presence of a polymerization catalyst in at least one polymerization reactor, comprising a) withdrawing a suspension of solid polyolefin particles in a suspension medium from the polymerization reactor, wherein the suspension has a temperature of from 65° C. to 120° C.; b) feeding the suspension withdrawn from the polymerization reactor to a moderating vessel; c) keeping the suspension in the moderating vessel at a temperature of from 60° C. to 85° C. for a time sufficiently long that the mean residence time of the suspension in the moderating vessel is at least 5 min; d) withdrawing suspension from the moderating vessel; e) cooling the suspension withdrawn from the moderating vessel to a temperature of from 20° C. to 55° C.; and f) mechanically separating the solid polyolefin particles from the liquid suspension medium, and method for controlling the content of hydrocarbons with from 14 to 300 carbon atoms in a polyolefin polymer prepared by polymerizing one or more olefin monomers in suspension.

摘要翻译： 在聚合催化剂存在下，在至少一种聚合催化剂的存在下，通过在40℃至120℃的温度和0.1至10MPa的温度下将悬浮液中的一种或多种烯烃单体连续聚合来制备聚烯烃聚合物的方法 聚合反应器，包括a）从聚合反应器中取出固体聚烯烃颗粒在悬浮介质中的悬浮液，其中悬浮液的温度为65℃至120℃; b）将从聚合反应器中取出的悬浮液送入调节容器; c）将悬浮液在调节容器中保持在60℃至85℃的温度下足够长的时间，使得悬浮液在调节容器中的平均停留时间为至少5分钟; d）从缓和容器中取出悬浮液; e）将从调节容器中取出的悬浮液冷却至20℃至55℃的温度; 和f）从液体悬浮介质中机械分离固体聚烯烃颗粒，以及通过在悬浮液中聚合一种或多种烯烃单体制备的聚烯烃聚合物中控制含有14至300个碳原子的烃的含量的方法。

公开(公告)号：US08729199B2

公开(公告)日：2014-05-20

申请号：US13514355

申请日：2010-12-17

申请人： Daan Dewachter

发明人： Daan Dewachter

IPC分类号： C08F2/12 ,  C08F2/00 ,  B08B9/032 ,  C08F110/02

CPC分类号： C08F6/02 ,  B01J8/003 ,  B01J8/0035 ,  B01J2208/00752 ,  C08F6/003 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08L23/06 ,  C08F2/14

摘要： The present invention relates to a process for cleaning a catalyst slurry preparation system and/or a catalyst preparation system. More particularly, the invention relates to a cleaning process for a catalyst preparation system and/or for a catalyst slurry preparation system, wherein an aqueous catalyst inactivation agent is used to rinse the systems, or any parts thereof. The catalysts used in the present invention may be chromium, Ziegler-Natta or metallocene catalysts.

摘要翻译： 本发明涉及清洁催化剂浆料制备系统和/或催化剂制备系统的方法。 更具体地，本发明涉及用于催化剂制备系统和/或催化剂浆料制备系统的清洁方法，其中使用含水催化剂灭活剂来漂洗系统或其任何部分。 用于本发明的催化剂可以是铬，齐格勒 - 纳塔或茂金属催化剂。

公开(公告)号：US08703883B2

公开(公告)日：2014-04-22

申请号：US13400154

申请日：2012-02-20

申请人： Max P. McDaniel ,  Joel A. Mutchler

发明人： Max P. McDaniel ,  Joel A. Mutchler

IPC分类号： C08F2/00 ,  C08F2/12 ,  C08F2/34 ,  B01J19/18 ,  B02C4/00 ,  B02C15/00 ,  B02C19/06 ,  B02C23/08

CPC分类号： C08F210/14 ,  B01J8/0035 ,  B01J8/082 ,  B01J8/10 ,  B01J8/1809 ,  B01J8/224 ,  B01J8/36 ,  B01J2208/00672 ,  B01J2208/00752 ,  B01J2219/002 ,  B01J2219/00202 ,  B01J2219/00211 ,  B01J2219/0024 ,  Y10S526/906 ,  Y10S526/92 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/18 ,  C08F210/06

摘要： Polymerization reactor systems providing real-time control of the average particle size of catalyst system components are disclosed. Methods for operating such polymerization reactor systems also are described.

摘要翻译： 公开了提供实时控制催化剂体系组分的平均粒度的聚合反应器系统。 还描述了操作这种聚合反应器体系的方法。