Polymer compositions based on sulfonated ionomers and amine containing
polymers
    64.
    发明授权
    Polymer compositions based on sulfonated ionomers and amine containing polymers 失效
    基于磺化离聚物和含胺聚合物的聚合物组合物

    公开(公告)号:US4480063A

    公开(公告)日:1984-10-30

    申请号:US547911

    申请日:1983-11-02

    CPC分类号: C08L23/32 C08L51/06

    摘要: This invention relates to thermoplastic and/or elastomer blend compositions having a viscosity at 200.degree. C., at 0.73 sec.sup.-1 of about 5000 to about 5.times.10.sup.6 poises, wherein the compositions used for elastomeric articles which include a polymer complex of a neutralized sulfonated polymer and a polymer containing basic nitrogen atoms can also include about 25 to about 150 parts by weight of a nonpolar process oil per 100 parts of the polymer complex and about 50 to 300 parts by weight of a filler per 100 parts of the polymer complex. These blend compositions can be processed on conventional plastic fabrication equipment into polymeric articles having excellent physical properties.

    摘要翻译: 本发明涉及热塑性和/或弹性体共混物组合物,其在200℃,在0.73秒-1下具有约5000至约5×10 6泊的粘度,其中用于弹性体制品的组合物包括中和的磺化聚合物 含有碱性氮原子的聚合物还可包含每100份聚合物复合物约25至约150重量份的非极性加工油,每100份聚合物配合物约含有50至300重量份的填料。 这些共混组合物可以在常规塑料制造设备上加工成具有优异物理性能的聚合物制品。

    Sulfonated polymer and compositions thereof
    65.
    发明授权
    Sulfonated polymer and compositions thereof 失效
    磺化聚合物及其组合物

    公开(公告)号:US4446267A

    公开(公告)日:1984-05-01

    申请号:US426666

    申请日:1982-09-29

    摘要: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.

    摘要翻译: 本发明涉及基于化学组合磺化聚合物和叔胺封端的聚内酯组合物的独特且新颖的组合物。 所得胺中和的磺化聚合物组合物具有多种用途,包括各种用途,包括粘合剂,热塑性弹性体,添加剂用途,其中这些材料可用于使通常不相容的两种不同聚合物相容。 当磺化聚合物是弹性体时,这些组合物也可与填料和/或油混合。 材料显示热塑性。

    Conversion of polymer solutions into solids or more viscous solution
    67.
    发明授权
    Conversion of polymer solutions into solids or more viscous solution 失效
    将聚合物溶液转化为固体或更粘稠的溶液

    公开(公告)号:US4412028A

    公开(公告)日:1983-10-25

    申请号:US335450

    申请日:1981-12-29

    CPC分类号: C08L23/32 C08F8/00 C08J3/02

    摘要: The present invention relates to a process for forming a gel having improved creep resistance at elevated temperatures and having a viscosity of at least about 100,000 cps which includes the steps forming a solvent system of an organic liquid and a water miscible cosolvent, the water miscible cosolvent being less than about 15 wt. % of the solvent system, a viscosity of the solvent system being less than about 1000 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, adding a free radical generating initiator to the solution at a concentration level of about 0.01 to about 1%, a concentration of the neutralized sulfonated polymer in the solution being about 0.5 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding under shear conditions about 5 to about 500 vol. % water to the solution having a viscosity less than about 20,000 cps, the water being immiscible with the solution and the water miscible cosolvent transferring from the solution phase to the water phase thereby causing the viscosity of said solution to increase from less than 20,000 cps to greater than 100,000 cps.

    摘要翻译: 本发明涉及形成凝胶的方法,其在高温下具有改善的抗蠕变性,并且具有至少约100,000cps的粘度,其包括形成有机液体和水混溶性共溶剂的溶剂体系的步骤,水混溶性共溶剂 小于约15wt。 %的溶剂体系,溶剂系统的粘度小于约1000cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液,以约0.01至约1%的浓度水平向溶液中加入产生自由基的引发剂,溶液中中和的磺化聚合物的浓度为约0.5至约 20重量% %,溶液的粘度小于约20,000cps; 并在剪切条件下加入约5至约500vol。 %的水溶于具有小于约20,000cps的粘度的溶液中,水与溶液不混溶,水可混溶的共溶剂从溶液相转移到水相,从而使所述溶液的粘度从小于20,000cps增加至 大于100,000 cps。

    Polycaprolactone polymers
    68.
    发明授权
    Polycaprolactone polymers 失效
    聚己内酯聚合物

    公开(公告)号:US4379914A

    公开(公告)日:1983-04-12

    申请号:US332813

    申请日:1981-12-21

    摘要: The instant invention relates to a process for the formation of polylactone polymers which are terminated on one end by a tertiary amine group and on the other end by a hydroxyl group. An .epsilon.-caprolactone is reacted with a diamine in the presence of a catalyst, wherein one of the amine groups of the diamine is a tertiary amine and the other amine group is primary or secondary.

    摘要翻译: 本发明涉及形成聚内酯聚合物的方法,所述聚内酯聚合物的一端由叔胺基封端,另一端由羟基封端。 在催化剂存在下,ε-己内酯与二胺反应,其中二胺的一个胺基是叔胺,另一个胺基是伯或仲的。

    Hot melt adhesive compositions
    69.
    发明授权
    Hot melt adhesive compositions 失效
    热熔胶组合物

    公开(公告)号:US4361672A

    公开(公告)日:1982-11-30

    申请号:US319700

    申请日:1981-11-09

    摘要: This invention relates to hot melt adhesive compositions which includes a hydrogenated block copolymer block such as Kraton G, about 25 to about 250 parts by weight of a hydrocarbon resin made from a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 to 6 carbon atoms and hydrogenated polycyclics per 100 parts by weight of the hydrogenated block copolymer, and about 25 to about 200 parts by weight of a polybutene or polyisobutylene per 100 parts of the hydrogenated block copolymer.

    摘要翻译: 本发明涉及热熔粘合剂组合物,其包括氢化嵌段共聚物嵌段例如Kraton G,约25至约250重量份由石油或煤焦油馏出物制成的烃树脂,脂族二烯和单和二烯烃,环烯烃 每100重量份氢化嵌段共聚物为5至6个碳原子和氢化聚环酯,每100份氢化嵌段共聚物为约25至约200重量份聚丁烯或聚异丁烯。

    Elastomeric systems having unusual memory characteristics
    70.
    发明授权
    Elastomeric systems having unusual memory characteristics 失效
    具有异常记忆特性的弹性系统

    公开(公告)号:US4193899A

    公开(公告)日:1980-03-18

    申请号:US855567

    申请日:1977-11-29

    IPC分类号: B29C61/00 C08L57/06 C08L91/00

    摘要: This invention involves a process for the utilization of an unusual memory characteristic which is present in neutralized sulfonated elastomeric materials, wherein the process includes the steps of distorting or compressing the neutralized sulfonated elastomeric article, then heating the article to a selected elevated temperature, holding the article at the elevated temperature for a limited time while maintaining the distorted shape, cooling the article to near room temperature, and releasing it from the device used to compress or distort it. The released cooled elastomer does not return to its original form, but rather substantially retains the distorted shape for an indefinite period of time. The elastomer in the distorted shape is heated to an appropriate elevated temperature thereby allowing the article to recover towards its original undistorted shape.

    摘要翻译: 本发明涉及利用存在于中和的磺化弹性体材料中的异常记忆特征的方法,其中该方法包括扭曲或压缩中和的磺化弹性体制品的步骤,然后将制品加热至选定的升高温度, 制品在高温下保持有限的时间,同时保持变形形状,将制品冷却至接近室温,并将其从用于压缩或扭曲的装置中释放出来。 释放的冷却弹性体不会恢复到其原始形式,而是基本上保持扭曲的形状无限期的时间。 将变形形状的弹性体加热至适当的升高温度,从而允许制品朝其原始的未失真形状恢复。