公开(公告)号：US07449471B2

公开(公告)日：2008-11-11

申请号：US11677862

申请日：2007-02-22

申请人： Andreas Gypser ,  Thomas Grote ,  Anja Schwögler ,  Joachim Rheinheimer ,  Frank Schieweck ,  Jordi Tormo i Blasco ,  Ingo Rose ,  Peter Schäfer ,  Markus Gewehr ,  Wassilios Grammenos ,  Bernd Müller ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz ,  Reinhard Stierl

发明人： Andreas Gypser ,  Thomas Grote ,  Anja Schwögler ,  Joachim Rheinheimer ,  Frank Schieweck ,  Jordi Tormo i Blasco ,  Ingo Rose ,  Peter Schäfer ,  Markus Gewehr ,  Wassilios Grammenos ,  Bernd Müller ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Gisela Lorenz ,  Reinhard Stierl

IPC分类号： C07D239/42 ,  C07D239/30 ,  A61K31/505 ,  A61K31/506 ,  A01N43/54

CPC分类号： C07D239/42 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D403/12

摘要： 5-Phenylpyrimidines of the formula I in which the substituents and the index are as defined below: R1,R2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, and R1 and R2 together with the nitrogen atom to which they are attached may also form a saturated or unsaturated ring which may be interrupted by an ether, thio, sulfoxyl or sulfonyl group and may be substituted by one to four groups Ra and/or Rb; R3 is hydrogen, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy or alkenyloxy; R4 is hydrogen, halogen, cyano, hydroxyl, mercapto, azido, alkyl, alkenyl, alkynyl, haloalkyl, alkoxy, alkenyloxy, alkynyloxy, haloalkoxy, alkylthio, alkenylthio, alkynylthio, haloalkylthio, —ON═CRaRb, —CRc═NORa, —NRcN═CRaRb, —NRaRb, —NRcNRaRb, —NORa, —NRcC(═NRc′)NRaRb, —NRcC(═O)NRaRb, —NRaC(═O)Rc, —NRaC(═NORc)Rc′, —OC(═O)Rc, —C(═NORc)NRaRb, —CRc(═NNRaRb), —C (═O)NRaRb or —C(═O)Rc; in which Ra, Rb and Rc are as defined in the description; X is halogen, alkyl, alkoxy or haloalkyl; and m is an integer from 1 to 5 ; processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi are described.

公开(公告)号：US20080176831A1

公开(公告)日：2008-07-24

申请号：US11596891

申请日：2005-05-17

申请人： Anja Schwogler ,  Frank Schieweck ,  Joachim Rheinheimer ,  Markus Gewehr ,  Bernd Muller ,  Thomas Grote ,  Wassilios Grammenos ,  Udo Hunger ,  Carsten Blettner ,  Peter Schafer ,  Oliver Wagner ,  Reinhard Stierl ,  Ulrich Schofl ,  Siegfried Strathmann ,  Maria Scherer

发明人： Anja Schwogler ,  Frank Schieweck ,  Joachim Rheinheimer ,  Markus Gewehr ,  Bernd Muller ,  Thomas Grote ,  Wassilios Grammenos ,  Udo Hunger ,  Carsten Blettner ,  Peter Schafer ,  Oliver Wagner ,  Reinhard Stierl ,  Ulrich Schofl ,  Siegfried Strathmann ,  Maria Scherer

IPC分类号： A01N43/46 ,  C07D403/04 ,  A01N43/54 ,  A01P7/00 ,  A01P3/00 ,  A01N43/58

CPC分类号： C07D401/04 ,  C07D403/04

摘要： The invention relates to 2-substituted pyrimidines of the formula I in which the index n and the substituents L and R1 to R3 are as defined in the description and X is a group —CH—Ra, —N— or —S—; R1 may be hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, cyano or C1-C6-alkoxycarbonyl; Rb is hydrogen, C1-C6-alkyl or C3-C6-cycloalkyl; T is a group —CH—Ra—; p is an integer from 1 to 4; Y is a group —CH—Ra— or —N—Rb o is 0 or 1; Z is O, S or a group N(Rc) Rc is hydrogen, C1-C6-alkyl or C1-C6-alkoxy, and to processes for their preparation, to pesticidal compositions comprising them and to their use as pesticides.

摘要翻译： 本发明涉及式I的2-取代嘧啶，其中指数n和取代基L和R 1至R 3如在说明书中所定义，X是 基团-CH-R a，N - 或-S-; R 1可以是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 3 > 6个 - 烷氧基，氰基或C 1 -C 6 - 烷氧基羰基; R b是氢，C 1 -C 6 - 烷基或C 3 -C 6 - 环烷基; T是基团-CH-R a， p是1至4的整数; Y是基团-CH-R a - 或-N-R b是0或1; Z是O，S或基团N（R c）R c是氢，C 1 -C 6 烷基或C 1 -C 6 - 烷氧基，并且其制备方法，包含它们的杀虫组合物及其作为农药的用途。

公开(公告)号：US20080108686A1

公开(公告)日：2008-05-08

申请号：US11628325

申请日：2005-06-16

申请人： Markus Gewehr ,  Bernd Muller ,  Thomas Grote ,  Wassilios Grammenos ,  Anja Schwogler ,  Joachim Rheinheimer ,  Carten Blettner ,  Peter Schafer ,  Frank Schieweck ,  Oliver Wagner ,  Frank Werner ,  Jan Rether ,  Siegfried Strathmann ,  Reinhard Stierl ,  Maria Scherer

发明人： Markus Gewehr ,  Bernd Muller ,  Thomas Grote ,  Wassilios Grammenos ,  Anja Schwogler ,  Joachim Rheinheimer ,  Carten Blettner ,  Peter Schafer ,  Frank Schieweck ,  Oliver Wagner ,  Frank Werner ,  Jan Rether ,  Siegfried Strathmann ,  Reinhard Stierl ,  Maria Scherer

IPC分类号： A01N43/56 ,  A01P3/00 ,  C07D231/12

CPC分类号： A01N43/56 ,  C07D231/14

摘要： The present invention relates to N-(ortho-phenyl)-1-methyl-3-difluoromethylpyrazole-4-carboxanilides of the formula I in which the substituents are as defined below:R1 and R2 independently of one another are halogen, C1-C6-alkyl, C1-C6-haloalkyl, cyano, nitro, methoxy, trifluoromethoxy or difluoromethoxy.

摘要翻译： 本发明涉及式I的N-（邻苯基）-1-甲基-3-二氟甲基吡唑-4-甲酰苯胺，其中取代基如下：R 1和R 2 > 2个彼此独立地是卤素，C 1 -C 6 - 烷基，C 1 -C 6 氰基，硝基，甲氧基，三氟甲氧基或二氟甲氧基。

公开(公告)号：US20080058208A1

公开(公告)日：2008-03-06

申请号：US11547185

申请日：2005-03-26

申请人： Jordi Tormo i Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Tormo i Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： C07D487/04 ,  A01N25/34 ,  A01N43/90

CPC分类号： C07D487/04

摘要： The invention relates to 5,6-cycloalkyl-7-aminotriazolopyrimidines of formula (I), where X=alkylene or alkenylene, whereby the carbon chain can be interrupted by one or two heteroatoms selected from S, O or NR1, R1═H, alkyl or C(═O)alkyl, L=halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, alkinyl or NR2R3; R2,R3=each one of the groups given for R1 and m=a whole number from 0 to 5, whereby the aliphatic groups can be substituted by one to three of the following groups: halogen, cyano, nitro, hydroxy, alkoxy, alkylthio, or NRaRb, where Ra, Rb═H or alkyl in which the carbon chains can be halogenated. The invention further relates to methods for production of said compounds, agents comprising the same and use thereof for the prevention of fungal pests harmful to plants.

摘要翻译： 本发明涉及式（I）的5,6-环烷基-7-氨基三唑并嘧啶，其中X =亚烷基或亚烯基，其中碳链可被一个或两个选自S，O或NR 1的杂原子中断， 卤素，氰基，硝基，烷基，卤代烷基，烷氧基，卤代烷氧基，烯基，炔基或NR 2（O） 3 3 R 2，R 3 =每个给定R 1的基团，m = 0至5的整数，由此脂族基 基团可以被一至三个以下基团取代：卤素，氰基，硝基，羟基，烷氧基，烷硫基或NR a R b，其中R 0， 或其中碳链可以被卤化的烷基。 本发明还涉及生产所述化合物的方法，包含该化合物的试剂及其用于预防对植物有害的真菌害虫的用途。

公开(公告)号：US07317015B2

公开(公告)日：2008-01-08

申请号：US10565656

申请日：2004-07-03

申请人： Frank Schieweck ,  Jordi Tormo i Blasco ,  Carsten Blettner ,  Bernd Müller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schäfer ,  Anja Schwögler ,  Oliver Wagner ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Maria Scherer ,  Reinhard Stierl

发明人： Frank Schieweck ,  Jordi Tormo i Blasco ,  Carsten Blettner ,  Bernd Müller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schäfer ,  Anja Schwögler ,  Oliver Wagner ,  Siegfried Strathmann ,  Ulrich Schöfl ,  Maria Scherer ,  Reinhard Stierl

IPC分类号： A01N43/54 ,  C07D239/42 ,  C07D401/04 ,  C07D239/02

CPC分类号： C07D239/42

摘要： The invention relates to 2-substituted pyrimidines of the formula I in which the index n and these substituents R1, R2 and R3 are as defined in the description and R4 is as defined below: R4 corresponds to one of the formulae where Ra is hydrogen, C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C3-C6-cycloalkyl or C1-C4-alkoxy and R5 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkyloxy-C1-C2-alkyl, phenyl-C1-C2-alkyl or phenyloxy-C1-C2-alkyl, to processes for preparing these compounds, to compositions comprising these compounds and to their use as pesticides.

摘要翻译： 本发明涉及式I的2-取代嘧啶，其中指数n和这些取代基R 1，R 2和R 3是 如在说明书中所定义的，R 4是如下定义的：R 4对应于下式之一其中R a a是氢，C 1〜 C 1 -C 6烷基，C 2 -C 8 - 烯基，C 2 - 亚烷基，C 2 -C 6 - C 1 -C 8 - 炔基，C 3 -C 6 - 环烷基或C 1 -C 6 - 4 - 烷氧基和R 5是氢，C 1 -C 6 - 烷基，C 2〜 C 1 -C 6 - 烯基，C 2 -C 6 - 炔基，C 1 -C 6 - 4 - 烷氧基-C 1 -C 2 - 烷基，苯基-C 1 -C 2 - 亚烷基 烷基或苯氧基-C 1 -C 2 - 烷基，用于制备这些化合物的方法，包含这些化合物的组合物及其作为农药的用途。

公开(公告)号：US20070238744A1

公开(公告)日：2007-10-11

申请号：US11629126

申请日：2005-06-14

申请人： Carsten Blettner ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Udo Hunger ,  Bernd Muller ,  Matthias Niedenbruck ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Barbara Nave ,  Maria Scherer ,  Sigfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Carsten Blettner ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Udo Hunger ,  Bernd Muller ,  Matthias Niedenbruck ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Barbara Nave ,  Maria Scherer ,  Sigfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A61K31/519 ,  C07D487/02

CPC分类号： A01N43/90 ,  C07D487/04

摘要： The use of substituted triazolopyrimidines of the formula I in which R1 is alkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or naphthyl, or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle comprising one to four heteroatoms from the group consisting of O, N and S, R2 is hydrogen or a group R1, where R1 and/or R2 may be substituted according to the description, and X is halogen; as fungicides, novel 6-(2-tolyl)triazolopyrimidines, processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.

摘要翻译： 使用式I的取代三唑并嘧啶，其中R 1是烷基，环烷基，卤代环烷基，烯基，卤代烯基，环烯基，卤代环烯基，炔基，卤代炔基或萘基，或五或六元饱和 ，包含一至四个由O，N和S组成的组的杂原子的部分不饱和或芳族杂环，R 2是氢或基团R 1，其中R 0 > 1和/或R 2可以根据描述被取代，X是卤素; 作为杀真菌剂，新颖的6-（2-甲苯基）三唑并嘧啶，制备这些化合物的方法，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途。

公开(公告)号：US20070179061A1

公开(公告)日：2007-08-02

申请号：US10590368

申请日：2005-03-08

申请人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Matthias Niedenbruck ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A01N43/54 ,  C07D487/08

CPC分类号： C07D487/04

摘要： The invention relates to 5,6-dialkyl-7-amino-triazolopyrimidines of formula (I), in which the substituents are defined as follows: R1 represents alkyl or alkoxyalkyl; R2 represents alkyl, R1 and/or R2 being substituted according to the description. The invention also relates to a method for producing said compounds, to agents containing the latter and to their use for controlling plant-pathogenic fungi.

摘要翻译： 本发明涉及式（I）的5,6-二烷基-7-氨基 - 三唑并嘧啶，其中取代基定义如下：R 1表示烷基或烷氧基烷基; R 2表示根据描述被取代的烷基，R 1和/或R 2 O 2。 本发明还涉及一种生产所述化合物的方法，含有后者的药剂及其用于控制​​植物致病真菌的用途。

公开(公告)号：US20070111889A1

公开(公告)日：2007-05-17

申请号：US10580990

申请日：2004-12-17

申请人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagne ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

发明人： Jordi Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagne ,  Maria Scherer ,  Siegfried Strathmann ,  Ulrich Schofl ,  Reinhard Stierl

IPC分类号： A01N43/90 ,  C07D487/04

CPC分类号： C07D487/04 ,  A01N43/90

摘要： Triazolopyrimidines of the formula I in which the substituents are as defined below: R1, R2 are hydrogen, alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkenyl, haloalkenyl, cycloalkenyl, halocycloalkenyl, alkynyl, haloalkynyl or phenyl, naphthyl or a five- or six-membered saturated, partially unsaturated or aromatic heterocycle which contains one to four heteroatoms from the group consisting of O, N and S, R1 and R2 together with the nitrogen atom to which they are attached may also form a five- or six-membered heterocyclyl or heteroaryl which is attached via N and may contain a further heteroatom from the group consisting of O, N and S as ring member and may be substituted as defined in the description; L is halogen, cyano, alkyl, haloalkyl, alkoxy, alkenyloxy or alkoxycarbonyl; m is 1, 2, 3 or 4, where the groups L may be different if m is greater than 1; X is halogen, cyano, alkyl, haloalkyl, alkoxy or haloalkoxy; Processes and intermediates for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi

摘要翻译： 其中取代基如下定义的式I的三唑并嘧啶：R 1，R 2是氢，烷基，卤代烷基，环烷基，卤代环烷基，烯基，卤代烯基，环烯基， 卤代环烯基，炔基，卤代炔基或苯基，萘基或五或六元饱和的部分不饱和或芳族杂环，其含有一至四个由O，N和S组成的组的杂原子，R 1， 和R 2与它们所连接的氮原子一起也可以形成五元或六元杂环基或杂芳基，其通过N连接并且可以含有另外的杂原子，由O ，N和S作为环成员，并且可以如说明书中所定义的取代; L是卤素，氰基，烷基，卤代烷基，烷氧基，烯氧基或烷氧基羰基; m为1,2,3或4，其中如果m大于1，则基团L可以不同; X是卤素，氰基，烷基，卤代烷基，烷氧基或卤代烷氧基; 制备这些化合物的方法和中间体，包含它们的组合物及其用于控制​​植物病原性有害真菌的用途

公开(公告)号：US07186861B2

公开(公告)日：2007-03-06

申请号：US10507605

申请日：2003-03-12

申请人： Wassilios Grammenos ,  Thomas Grote ,  Carsten Blettner ,  Markus Gewehr ,  Andreas Gypser ,  Bernd Müller ,  Joachim Rheinheimer ,  Peter Schäfer ,  Anja Schwögler ,  Jordi Tormo i Blasco ,  Norbert Götz ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Reinhard Stierl

发明人： Wassilios Grammenos ,  Thomas Grote ,  Carsten Blettner ,  Markus Gewehr ,  Andreas Gypser ,  Bernd Müller ,  Joachim Rheinheimer ,  Peter Schäfer ,  Anja Schwögler ,  Jordi Tormo i Blasco ,  Norbert Götz ,  Gisela Lorenz ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Reinhard Stierl

IPC分类号： C07C233/09 ,  A01N37/18

CPC分类号： C07C235/34 ,  A01N37/18 ,  A01N37/36 ,  A01N37/38 ,  C07C233/22 ,  C07C2601/02 ,  C07C2601/08 ,  C07C2601/14

摘要： Z-substituted acrylamides of formula (I), where the substituents have the following meanings: X═H, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, with X in the 3- or 4-position, n=1 or 2, where X can be different if n=2, R1=alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, aziridine and oxirane and R2═H, alkyl, haloalkyl, allyl, propargyl or CH2C≡C-alkyl. Methods for production thereof, agents comprising the above and the use thereof for the treatment of plant-pathogenic fungal pests.

摘要翻译： 式（I）的Z-取代的丙烯酰胺，其中取代基具有以下含义：XH，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，其中X为3-或4-位，n = 1或2，其中X可以 如果n = 2，R 1 =烷基，卤代烷基，环烷基，烷氧基，卤代烷氧基，氮丙啶和环氧乙烷和R 2 -H，烷基，卤代烷基，烯丙基，炔丙基 或CH 2C≡C-烷基。 其制备方法，包含上述物质及其用于治疗植物致病性真菌害虫的用途。

公开(公告)号：US20060199801A1

公开(公告)日：2006-09-07

申请号：US10551810

申请日：2004-04-16

申请人： Jordi i Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Maria Scherer ,  Reinhard Stierl

发明人： Jordi i Blasco ,  Carsten Blettner ,  Bernd Muller ,  Markus Gewehr ,  Wassilios Grammenos ,  Thomas Grote ,  Andreas Gypser ,  Joachim Rheinheimer ,  Peter Schafer ,  Frank Schieweck ,  Anja Schwogler ,  Oliver Wagner ,  Eberhard Ammermann ,  Siegfried Strathmann ,  Ulrich Schofl ,  Maria Scherer ,  Reinhard Stierl

IPC分类号： A61K31/551 ,  A61K31/541 ,  A61K31/53 ,  A61K31/519

CPC分类号： C07D487/04 ,  A01N43/90

摘要： Bicyclic compounds of the formula I in which A1 or A5 is C and the other of the two variables A1, A5 is N, C or C—R3; A2, A3, A4 independently of one another are N or C—R3a, where one of the variables A2, A3 or A4 may also be S or a group N—R4 if A1 and A5 are both C, and where A4 is not N or C—R3a if A1 is N, A3 is C—R3a and A5 is C, and where A1 is attached to A2 and A3 to A4 or A2 is attached to A3 and A4 to A5 or A1 is attached to A5 and A2 to A3 or A1 is attached to A5 and A3 to A4 or A1 is attached to A2 and A4 to A5 by double bonds; n is 0, 1, 2, 3, 4 or 5; Ra is halogen, cyano, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-haloalkoxy, C2-C6-alkenyl, C2-C6-alkenyloxy or C(O)R5; R1 is halogen, cyano, C1-C10-alkyl, where a carbon atom of the C1-C10-alkyl radical may be replaced by a silicium atom, C1-C6-haloalkyl, C2-C10-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, where the cycloalkyl moiety of the two last-mentioned groups may be unsubstituted or contain 1, 2, 3, 4, 5, or 6 radicals selected from the group consisting of C1-C4-alkylidene, C1-C4-alkyl, halogen, C1-C4-haloalkyl and hydroxy and the alkyl moiety of C3-C8-cycloalkyl-C1-C4-alkyl may be unsubstituted or contain 1, 2, 3, or 4 radicals selected from the group consisting of halogen, C1-C4-haloalkyl and hydroxy, C5-C8-cycloalkenyl which may be unsubstituted or contain 1, 2, 3 or 4 radicals selected from the group consisting of C1-C4-alkyl, halogen, C1-C4-haloalkyl and hydroxy, OR6, SR6, NR7R8, a radical of the formula —C(R11)(R12)C(═NOR13)(R14) or a radical of the formula —C(═NOR15)C(═NOR16)(R17); R2 is halogen, cyano, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C8-cycloalkyl, C5-C8-cycloalkenyl, OR6, SR6 or NR7R8; and the agriculturally acceptable salts of the compounds I, crop protection compositions comprising at least one compound of the formula I and/or an agriculturally acceptable salt of I and at least one solid or liquid carrier and a method for controlling phytopathogenic harmful fungi are described.