摘要:
The present invention is concerned with a process for the production of high molecular weight thermoplastic ppolycarbonates having improved flame resistance and in conjunction with glass fibres, improved mechanical properties and the polycarbonates so produced. A solution polycarbonate is reacted with an alkali metal salt soluble in the melt of the polycarbonate until the Staudinger Index has increased by about 3 to 30 cm.sup.3 /g. This usually requires about 0.0001 to 0.1 wt. % of the salt, based on the weight of polycarbonate and a temperature of about 250.degree. to 400.degree. C for between about 1 and 30 minutes. In a preferred embodiment the reaction is conducted in a self-cleaning twin screw extruder.
摘要:
The present invention is concerned with polycarbonate molding resins with improved flow and strength properties which contain about 10 to 40 wt.% glass fibers and about 0.5 to 5 wt. % of polyalkylene glycol terephthalate or about 0.5 to 10 wt.% of polyalkylene glycol isophthalate.
摘要:
This invention provides spheres of high molecular weight thermoplastics filled with short glass fibers which may be easily metered, incorporated into thermoplastic resins or fused into glass mats or shaped articles. It also provides a method of producing such spheres by treating glass fibers with a dilute (1 to 30 wt% strength) solution of the plastic having a viscosity of less than 1,000 cP. The fibers are rotated with the polymer solution and the solvent is subsequently evaporated off. Preferably, the coating plastic is a high molecular weight thermoplastic.
摘要:
Carbonate-modified copolyesters which are suitable for the production of mouldings by injection moulding or for the production of pipes, films and fibers by extrusion, can be obtained by reacting aromatic dicarboxylic acids or their ester-forming derivatives and carbonic acid esters of dihydric aliphatic alcohols which have carbonic acid ester groupings in the molecule and hydroxyalkyl end groups.
摘要:
A process for the preparation of a symmetric diarylcarbonate by reacting phosgene with a phenol wherein said reactions is carried out by the phase interface process in a diphastic mixture of an aqueous alkali metal hydroxide solution and a liquid diaryl carbonate in the presence of from 0.001 to 0.1 mol of a tertiary amine or a quaternary ammonium compound per mol of phenol.
摘要:
Thermoplastic moulding compositions of1. 70 - 20 % by weight of graft polycarbonates whose graft stock is a vinyl polymer with a molecular weight of from 10,000 to 100,000, containing from 3 to 10 side chains attached by carbon, each of which contains a hydroxyphenyl group, on which aromatic polycarbonate chains are condensed, and2. 30 - 80 % by weight of graft polymer rubbers obtained by polymerizing a mixture of2.1. 50 - 90 % by weight styrene, .alpha.-methylstyrene, methylmethacrylate or mixtures thereof, and2.2. 10 - 50 % by weight acrylonitrile, methacrylonitrile, methylmethacrylate or mixtures thereof on a diene or acrylate rubber.
摘要:
Thermoplastic moulding compositions ofA. 15 to 80 % by weight of an aromatic polycondensate containing s-triazine rings, andB. 20 to 85 % by weight of a graft polymer obtained by polymerizing a mixture ofB.1. 50 to 90 % by weight of styrene, .alpha.-methyl styrene, methyl methacrylate or mixtures thereof andB.2. 10 to 50 % by weight of acrylonitrile, methacrylonitrile, methyl methacrylate or mixtures thereof,Onto a diene or acrylate rubber, the mixture as a whole containing from 5 to 25 % by weight of s-triazine rings, based on (A) and (B), and 5 to 40% by weight of rubber, based on (A) and (B).
摘要:
The contaminating inorganic compounds such as alkali metal salts or alkali metal hydroxides which remain in a polycarbonate solution prepared by reacting phosgene with a dihydroxy-aryl compound are removed by contacting the solution with a molecular sieve.