Process for the preparation of high molecular thermoplastic
polycarbonates of low flammability
    61.
    发明授权
    Process for the preparation of high molecular thermoplastic polycarbonates of low flammability 失效
    制备低易燃性的高分子量热塑性聚碳酸酯的方法

    公开(公告)号:US4098754A

    公开(公告)日:1978-07-04

    申请号:US640109

    申请日:1975-12-11

    摘要: The present invention is concerned with a process for the production of high molecular weight thermoplastic ppolycarbonates having improved flame resistance and in conjunction with glass fibres, improved mechanical properties and the polycarbonates so produced. A solution polycarbonate is reacted with an alkali metal salt soluble in the melt of the polycarbonate until the Staudinger Index has increased by about 3 to 30 cm.sup.3 /g. This usually requires about 0.0001 to 0.1 wt. % of the salt, based on the weight of polycarbonate and a temperature of about 250.degree. to 400.degree. C for between about 1 and 30 minutes. In a preferred embodiment the reaction is conducted in a self-cleaning twin screw extruder.

    摘要翻译: 本发明涉及生产具有改进的阻燃性和与玻璃纤维相结合的改进的机械性能和如此生产的聚碳酸酯的高分子量热塑性聚碳酸酯的方法。 将溶液聚碳酸酯与可溶于聚碳酸酯熔体中的碱金属盐反应直到Staudinger指数增加约3至30cm 3 / g。 这通常需要约0.0001至0.1wt。 %的盐,基于聚碳酸酯的重量和约250-400℃的温度约1至30分钟。 在优选的实施方案中,反应在自清洁双螺杆挤出机中进行。

    Short glass fibers covered with polymeric materials
    63.
    发明授权
    Short glass fibers covered with polymeric materials 失效
    用聚合材料覆盖的短玻璃纤维

    公开(公告)号:US4055611A

    公开(公告)日:1977-10-25

    申请号:US561827

    申请日:1975-03-25

    摘要: This invention provides spheres of high molecular weight thermoplastics filled with short glass fibers which may be easily metered, incorporated into thermoplastic resins or fused into glass mats or shaped articles. It also provides a method of producing such spheres by treating glass fibers with a dilute (1 to 30 wt% strength) solution of the plastic having a viscosity of less than 1,000 cP. The fibers are rotated with the polymer solution and the solvent is subsequently evaporated off. Preferably, the coating plastic is a high molecular weight thermoplastic.

    摘要翻译: 本发明提供了填充有短玻璃纤维的高分子量热塑性塑料球,其可以容易地计量,并入热塑性树脂中或熔合成玻璃垫或成型制品。 它还提供了通过用粘度小于1,000cP的塑料的稀(1至30重量%强度)溶液处理玻璃纤维来生产这种球体的方法。 纤维与聚​​合物溶液一起旋转,随后将溶剂蒸发掉。 优选地,涂料塑料是高分子量热塑性塑料。

    Thermoplastic carbonate-modified copolyesters and a process for their
preparation
    64.
    发明授权
    Thermoplastic carbonate-modified copolyesters and a process for their preparation 失效
    热塑性碳酸酯改性共聚酯及其制备方法

    公开(公告)号:US4041018A

    公开(公告)日:1977-08-09

    申请号:US597167

    申请日:1975-07-18

    CPC分类号: C08G63/64

    摘要: Carbonate-modified copolyesters which are suitable for the production of mouldings by injection moulding or for the production of pipes, films and fibers by extrusion, can be obtained by reacting aromatic dicarboxylic acids or their ester-forming derivatives and carbonic acid esters of dihydric aliphatic alcohols which have carbonic acid ester groupings in the molecule and hydroxyalkyl end groups.

    摘要翻译: 适用于通过注射成型生产模制品或通过挤出生产管材,薄膜和纤维的碳酸酯改性共聚酯可以通过使芳族二羧酸或其酯形成衍生物与二元脂肪醇的碳酸酯反应而获得 其在分子中具有碳酸酯基团和羟烷基端基。

    Moulding compositions of graft polycarbonate and graft polymer rubbers
    66.
    发明授权
    Moulding compositions of graft polycarbonate and graft polymer rubbers 失效
    接枝聚碳酸酯和接枝聚合物橡胶的成型组合物

    公开(公告)号:US3991009A

    公开(公告)日:1976-11-09

    申请号:US459604

    申请日:1974-04-10

    摘要: Thermoplastic moulding compositions of1. 70 - 20 % by weight of graft polycarbonates whose graft stock is a vinyl polymer with a molecular weight of from 10,000 to 100,000, containing from 3 to 10 side chains attached by carbon, each of which contains a hydroxyphenyl group, on which aromatic polycarbonate chains are condensed, and2. 30 - 80 % by weight of graft polymer rubbers obtained by polymerizing a mixture of2.1. 50 - 90 % by weight styrene, .alpha.-methylstyrene, methylmethacrylate or mixtures thereof, and2.2. 10 - 50 % by weight acrylonitrile, methacrylonitrile, methylmethacrylate or mixtures thereof on a diene or acrylate rubber.

    摘要翻译: 热塑性成型组合物的重量百分比为70-20%,聚碳酸酯的重量为聚碳酸酯,分子量为10,000至100,000的乙烯基聚合物,含有碳原子数为3〜10个的链,每个碳链均含有羟基苯基 ,其中芳族聚碳酸酯链是稠合的,和2.通过聚合2.1的混合物获得的聚合物橡胶重量的30-80%。 50-90%重量苯乙烯,α-甲基苯乙烯,甲基丙烯酸甲酯或其混合物,和2.2。 10 - 50%的重量丙烯腈,甲基丙烯酸甲酯,甲基丙烯酸甲酯或其混合物在二烯或丙烯酸酯橡胶上。