N-substituted chloroacetanilides processes for production thereof, and
herbicidal composition comprising the same
    62.
    发明授权
    N-substituted chloroacetanilides processes for production thereof, and herbicidal composition comprising the same 失效
    N-取代的氯乙酰苯胺的制备方法以及含有它们的除草组合物

    公开(公告)号:US4802907A

    公开(公告)日:1989-02-07

    申请号:US94092

    申请日:1987-09-04

    摘要: An N-substituted chloroacetanilide represented by the following formula (I) ##STR1## wherein A represents a member selected from the class consisting of halogen atoms, alkoxy groups having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group, alkylthio groups having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group, and alkoxyalkyl groups having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group and having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkylene group, R.sub.1, R.sub.2 and R.sub.3 are identical or different, and each represents a hydrogen atom, a halogen atom, a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group, an alkoxy group having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group R is a hydrogen atom or a linear or branched, saturated or unsaturated C.sub.1 -C.sub.4 alkyl group, or an alkylthio group having a linear or branched, saturated or unsaturated C.sub.1 -C.sub.6 alkyl group, and n represents 1 or 2, and when n is 2, the two A's may be identical or different; a process for producing the above compound by reacting an N-substituted aniline with a chloroacetyl halogenide or by reacting a 2-substituted thiophene with a chloroacetanilide; and a herbicidal composition containing a herbicidally effective amount of the compound of formula (I).

    摘要翻译: 由下式(I)表示的N-取代的氯代乙酰苯胺其中A表示选自卤素原子,具有直链或支链,饱和或不饱和的C1-C6烷基的烷氧基的成员, 具有直链或支链,饱和或不饱和的C1-C6烷基的烷硫基和具有直链或支链,饱和或不饱和的C1-C6烷基并具有直链或支链,饱和或不饱和的C1-C6亚烷基的烷氧基烷基, R1,R2和R3相同或不同,各自表示氢原子,卤原子,直链或支链饱和或不饱和的C1-C6烷基,具有直链或支链,饱和或不饱和的C1-C6烷氧基 烷基R是氢原子或直链或支链,饱和或不饱和的C1-C4烷基或具有直链或支链,饱和或不饱和的C1-C6烷基的烷硫基,n表示1或2,当 n为2,t 他的两个A可能是相同或不同的; 通过使N-取代苯胺与氯乙酰卤反应或2-取代噻吩与氯乙酰苯胺反应来制备上述化合物的方法; 和含有除草有效量的式(I)化合物的除草组合物。

    Novel benzenesulfonamide derivatives
    70.
    发明授权
    Novel benzenesulfonamide derivatives 失效
    新型苯磺酰胺衍生物

    公开(公告)号:US4233061A

    公开(公告)日:1980-11-11

    申请号:US974517

    申请日:1978-12-29

    IPC分类号: A01N41/06 C07C311/15 A01N9/14

    CPC分类号: C07C255/00 A01N41/06

    摘要: A compound of the general formula ##STR1## wherein R.sub.0 represents an alkyl group optionally having a substituent selected from the class consisting of a cyano group, lower alkoxy groups and di-(lower alkyl)amino groups, a lower alkenyl group, or a lower alkynyl group; R.sub.1, R.sub.2 and R.sub.3, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8, independently from each other, represent a hydrogen atom, a halogen atom, a lower alkyl group, or a lower alkoxy group; Y represents a group of the formula ##STR2## or a group of the formula ##STR3## in which one of R.sub.9 and R.sub.10 is a lower alkyl group and the other is a hydrogen atom or a lower alkyl group; with the proviso that when Y is the group ##STR4## and R.sub.0 represents an unsubstituted alkyl group, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 do not represent hydrogen atoms at the same time. The compounds of formula (I) are produced by the reaction of the corresponding benzenesulfonamide derivatives with the corresponding benzyl or benzoyl halides; the reaction of the corresponding benzenesulfonyl halides with the corresponding benzylamines or benzoyl amides; or by the alkylation, alkenylation or alkynylation of the corresponding compounds of formula (I) in which R.sub.0 is hydrogen. The compounds of formula (I) have superior selective herbicidal effects, and are useful as active ingredients of herbicides, especially those for application to aquatic rice paddies.

    摘要翻译: 通式(I)的化合物,其中R 0表示任选具有选自氰基,低级烷氧基和二 - (低级烷基)氨基的取代基的烷基,低级烯基, 或低级炔基; R 1,R 2和R 3彼此独立地表示氢原子,卤素原子,低级烷基或低级烷氧基; R4,R5,R6,R7和R8彼此独立地表示氢原子,卤素原子,低级烷基或低级烷氧基; Y表示式为“IMAGE”的基团或其中R9和R10中的一个为低级烷基且另一个为氢原子或低级烷基的式“IMAGE”的基团; 条件是当Y为基团时,R 0表示未取代的烷基,R 4,R 5,R 6,R 7和R 8不同时表示氢原子。 式(I)化合物通过相应的苯磺酰胺衍生物与相应的苄基或苯甲酰基卤化物的反应产生; 相应的苯磺酰卤与相应的苄胺或苯甲酰胺的反应; 或通过其中R 0是氢的相应的式(I)化合物的烷基化,烯基化或炔基化。 式(I)的化合物具有优异的选择性除草效果,并且可用作除草剂的活性成分,特别是用于水稻的施用。