Improved Process to Prepare Catalyst from In-Situ Formed Alumoxane

    公开(公告)号:US20240018278A1

    公开(公告)日:2024-01-18

    申请号:US18253835

    申请日:2021-11-17

    CPC classification number: C08F4/52 C08F2410/01 C08F2500/04 C08F2500/17

    Abstract: The present disclosure relates to processes for forming alumoxanes and catalyst systems thereof for olefin polymerization. In at least one embodiment, a process includes forming a solution by, in an aliphatic hydrocarbon having a boiling point of less than about 70 degrees Celsius, introducing at least one hydrocarbyl aluminum with at least one non-hydrolytic oxygen-containing compound and a support material. The molar ratio of aluminum to non-hydrolytic oxygen in the solution is greater than or equal to 1.5, and the combining is conducted at a temperature of less than about 70 degrees Celsius. The process includes distilling the solution at a pressure of greater than about 0.5 atm to form a supported alumoxane precursor. The process further includes heating the supported alumoxane precursor to a temperature greater than the boiling point of the aliphatic hydrocarbon fluid and less than about 160 degrees Celsius to form a supported alumoxane.

    Renewable Jet Production
    64.
    发明公开

    公开(公告)号:US20230416619A1

    公开(公告)日:2023-12-28

    申请号:US18165631

    申请日:2023-02-07

    Abstract: Systems and methods are provided for production of renewable jet fuel and/or jet fuel blending component fractions. The systems and methods provide for formation of jet boiling range fractions via hydrodeoxygenation and catalytic dewaxing of bio-derived feeds. The systems and methods for reducing or minimizing recycle and/or forming only a jet boiling range product and a lower boiling range product can be facilitated based on selection of a suitable feedstock and/or based on selection of suitable reaction conditions and catalyst for the catalytic dewaxing.

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