MAYENITE-TYPE COMPOUND CONTAINING IMIDE ANION, AND METHOD FOR PRODUCING SAME
    69.
    发明申请
    MAYENITE-TYPE COMPOUND CONTAINING IMIDE ANION, AND METHOD FOR PRODUCING SAME 有权
    含有阴离子的聚亚胺系化合物及其制造方法

    公开(公告)号:US20170072382A1

    公开(公告)日:2017-03-16

    申请号:US15123602

    申请日:2015-02-12

    IPC分类号: B01J20/04 C01F7/16 C01C1/00

    摘要: The invention related to a material that can stably hold an imide anion (NH2−) therein even in the atmosphere or in a solvent, and a method for synthesizing the material and a use of the material. A mayenite-type compound into which imide anions are incorporated at a concentration of 1×1018 cm−3 or more are provided. The mayenite-type compound can be produced by heating a mayenite-type compound including electrons or free oxygen ions in a cage thereof, in liquefied ammonia at 450 to 700° C. and at a pressure of 30 to 100 MPa. The compound has properties such that active imide anions can be easily incorporated into the compound and the active imide anions can be easily released in the form of ammonia from the compound, and the compound has chemical stability.

    摘要翻译: 本发明涉及即使在大气中或在溶剂中也可以稳定地保持其酰亚胺阴离子(NH 2 - )的材料,以及合成材料的方法和材料的使用。 提供以1×1018cm-3以上的浓度掺入有酰亚胺阴离子的钙铝石型化合物。 钙铝石型化合物可以通过在其笼中在液化氨中在450〜700℃,压力为30〜100MPa下加热包含电子或游离氧离子的钙铝石型化合物来制造。 该化合物具有使得活性酰亚胺阴离子可以容易地掺入化合物中的性质,并且活性酰亚胺阴离子可以容易地从化合物中以氨的形式释放,并且该化合物具有化学稳定性。