Abstract:
A method for manufacturing an ammonia storage cartridge includes a step for supplying a material by ammonia absorption or adsorption by absorbent salts, a step for producing an intermediate element, including compacting the material to form the intermediate element, a step for stacking at least two intermediate elements in a shell of the cartridge, and a step for compressing the stack of intermediate elements in the shell.
Abstract:
A system for storing and delivering gaseous ammonia to a consumer unit (30) including: a plurality of gaseous ammonia storage cells (10) each including: a storage material (102) that is a gaseous ammonia absorber, a pressure adjuster for adjusting an internal pressure of each cell independently of the other cells of the plurality, including a heater (106), an outlet interface (40) connecting the plurality of cells (10) to the consumer unit (30) allowing gaseous ammonia to leave the cell (10) when the internal pressure is higher than a pressure downstream, a control device (50) common to the plurality of cells (10) allowing control, independently of the other cells of the plurality, of the activity of each cell (10) in delivering ammonia to the outlet interface (40) using a controller (502) which controls the heater (106) for the pressure adjuster (10).
Abstract:
Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Thermal energy transfer assemblies are provided. Methods for transferring thermal energy are also provided.
Abstract:
An assembly and method for storing a reductant, including ammonia, for use in the treatment of NOx in an exhaust stream, is disclosed. The assembly comprises a cartridge having an interior space, a disk formed from compacted reductant adsorbing/desorbing material contained within a heat transfer material, and, an expandable element positioned within the interior space of the cartridge for receiving a plurality of disks within the interior space of the cartridge. The expandable element or conduit may also be used to charge or recharge the adsorbing/desorbing material with ammonia.
Abstract:
A method and system for purifying exhaust gases of a combustion engine or an SCR method for purifying exhaust gases of an internal combustion engine of a vehicle, according to which ammonia gas is exclusively metered in the exhaust gases. The method includes: releasing ammonia gas from at least one solid absorbing matrix where it is stored by sorption; metering the released ammonia gas in the exhaust gases; regenerating the solid absorbing matrix including: generating a refilling ammonia gas by chemically decomposing an ammonia precursor in a biochemical decomposition unit mounted on board the vehicle and storing at least one protein component adapted to decompose the ammonia precursor; directing the refilling ammonia gas to the solid absorbing matrix where it is stored thereon.
Abstract:
Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Thermal energy transfer assemblies are provided. Methods for transferring thermal energy are also provided.
Abstract:
The electronic structure of nanowires, nanotubes and thin films deposited on a substrate is varied by doping with electrons or holes. The electronic structure can then be tuned by varying the support material or by applying a gate voltage. The electronic structure can be controlled to absorb a gas, store a gas, or release a gas, such as hydrogen, oxygen, ammonia, carbon dioxide, and the like.
Abstract:
A system for storage and dosing of ammonia, including a solid ammonia storage material capable of binding and releasing ammonia reversibly by adsorption/absorption. The system is able to release ammonia gradually according to a demand that can vary over time with intermediate periods of no ammonia demand. A main storage unit and a start-up storage unit are provided. The storage units hold ammonia storage material. At least one one-way valve is provided via which the one main storage unit is in communication with the start-up storage unit. The one-way valve prevents any back-flow of ammonia from the start-up storage unit to the main storage unit. Heating devices are arranged to heat the main storage unit and the start-up storage unit separately to generate gaseous ammonia by thermal desorption from the solid storage material. A controller controls the heating power of the main storage unit and the start-up storage unit, thereby enabling ammonia release from at least one of the start-up and/or the main storage unit. A dosing valve controls ammonia flow from the storage units according to a demand.
Abstract:
A system and method relate to a reductant dosing for use in the reduction of NOx in an exhaust stream is disclosed. The system and method incorporates a separate first or start-up cartridge and an insulated mantel or housing containing at least one to a plurality of main cartridges. The first and main cartridges store an ammonia adsorbing/desorbing material, which releases ammonia gas upon application of sufficient heat. The start-up cartridge permits the initial release of ammonia gas into the exhaust stream even during start-up of an engine, and because it is separate from the main cartridge, the first cartridge cools faster than the main cartridge and can be replenished with ammonia sooner than the main cartridge. The start-up cartridge is housed in or surrounded by a non-insulating debris shield.