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    Battery
    62.
    发明申请
    Battery 审中-公开
    电池

    公开(公告)号：US20040259000A1

    公开(公告)日：2004-12-23

    申请号：US10865198

    申请日：2004-06-09

    发明人： Momoe Adachi ,  Shigeru Fujita ,  Masahiro Aoki ,  Hiroyuki Akashi ,  Yoshiaki Naruse

    IPC分类号： H01M006/18 ,  H01M006/16 ,  H01M004/00 ,  H01M004/50

    CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M10/054 ,  H01M10/0565 ,  H01M10/0568 ,  H01M10/0587 ,  H01M2300/0025 ,  H01M2300/004

    摘要： A battery capable of improving battery characteristics such as cycle characteristics is provided. The battery includes a spirally wound electrode body including a cathode and an anode spirally wound with a separator in between. The capacity of the anode includes a capacity component by insertion and extraction of light metal and a capacity component by precipitation and dissolution of the light metal, and is represented by the sum of them. The separator is impregnated with an electrolyte solution formed through dissolving a lithium salt in a solvent. As the electrolyte salt, difluoronulloxalato-O,Onullnulllithium borate, tetrafluoronulloxalato-O,Onullnulllithium phosphate or difluorobisnulloxalato-O,Onullnulllithium phosphate is used. By the formation of a stable coating, decomposition of the solvent and a reaction between precipitated lithium metal and the solvent can be prevented.

    摘要翻译： 提供了能够提高电池特性例如循环特性的电池。 电池包括螺旋缠绕的电极体，其包括阴极和在其间螺旋地缠绕有隔膜的阳极。 阳极的容量包括通过轻金属的插入和抽出以及通过沉淀和溶解轻金属的容量分量的容量分量，并且由它们的总和来表示。 用通过将锂盐溶解在溶剂中形成的电解质溶液浸渍隔板。 作为电解质盐，使用二氟[草酸-O，O']硼酸锂，四氟[草酸-O，O']磷酸锂或二氟双[草酸-O，O']磷酸锂。 通过形成稳定的涂层，可以防止溶剂的分解和析出的锂金属与溶剂之间的反应。

    Positive electrode material, its manufacturing method and lithium secondary battery
    63.
    发明申请
    Positive electrode material, its manufacturing method and lithium secondary battery 有权
    正极材料，其制造方法和锂二次电池

    公开(公告)号：US20040253516A1

    公开(公告)日：2004-12-16

    申请号：US10787222

    申请日：2004-02-27

    发明人： Toyotaka Yuasa ,  Masahiro Kasai ,  Genei Nakajima

    IPC分类号： H01M004/50 ,  H01M004/52 ,  C01G045/12 ,  C01G051/04 ,  C01G053/04

    CPC分类号： H01M4/0435 ,  H01M4/043 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M2004/021

    摘要： The object of the invention is to provide positive electrode material in which a discharge rate characteristic and battery capacity are hardly deteriorated in the environment of low temperature of null30null C., its manufacturing method and a lithium secondary battery using the positive electrode material. The invention is characterized by the positive electrode material in which plural primary particles are flocculated and a secondary particle is formed, and the touch length of the primary particles is equivalent to 10 to 70% of the length of the whole periphery on the section of the touched primary particles.

    摘要翻译： 本发明的目的是提供在-30℃的低温环境下的放电特性和电池容量几乎不劣化的正极材料，其制造方法和使用该正极材料的锂二次电池。 本发明的特征在于其中多个一次粒子絮凝并形成二次粒子的正极材料，一次粒子的接触长度相当于全部周边的长度的10〜70％ 触摸初级粒子。

    Active material for positive electrode in non-aqueous electrolyte secondary battery
    66.
    发明申请
    Active material for positive electrode in non-aqueous electrolyte secondary battery 有权
    非水电解质二次电池中正极活性物质

    公开(公告)号：US20040197658A1

    公开(公告)日：2004-10-07

    申请号：US10781624

    申请日：2004-02-20

    发明人： Katsuya Kase ,  Hirofumi Iisaka ,  Satoru Suzuki ,  Manabu Yamada

    IPC分类号： H01M004/52 ,  H01M004/50 ,  C01G051/04 ,  C01G053/04

    CPC分类号： H01M4/525 ,  C01G53/42 ,  C01P2002/52 ,  C01P2006/40 ,  C01P2006/82 ,  H01M4/485 ,  H01M4/505 ,  H01M4/58 ,  H01M10/052

    摘要： An active material for positive electrode for a non-aqueous electrolyte secondary battery comprises a lithium-metal composite oxide that is expressed by the general formula of Lix(Ni1-yCoy)1-zMzO2 (where 0.98nullxnull1.10, 0.05nullynull0.4, 001nullznull0.2, and where M is at least one metal element selected from the group of Al, Mg, Mn, Ti, Fe, Cu. Zn and Ga), and where the SO4 ion content is in the range from 0.4 weight % to 2.5 weight %, and the occupancy rate of lithium found from the X-ray diffraction chart and using Rietveld analysis is 98% or greater, and the carbon amount measured by way of the high frequency heating-infrared adsorption method is 0.12 weight % or less, and that the Karl Fischer water content due to heating at 180null C. be 0.2 weight % or less.

    摘要翻译： 用于非水电解质二次电池的正极活性材料包括由通式Lix（Ni1-yCoy）1-zMzO2表示的锂金属复合氧化物（其中0.98 <= x <= 1.10,0.05 < = y <= 0.4，001 <= z <= 0.2，其中M是选自Al，Mg，Mn，Ti，Fe，Cu，Zn和Ga中的至少一种金属元素，并且其中SO 4离子 含量在0.4重量％至2.5重量％的范围内，并且从X射线衍射图和使用Rietveld分析发现的锂的占有率为98％以上，通过高频加热测量的碳量 - 红外吸收法为0.12重量％以下，由于180℃下加热引起的卡尔费休含水量为0.2重量％以下。

    Zinc/air cell
    67.
    发明申请
    Zinc/air cell 有权
    锌/空气池

    公开(公告)号：US20040197644A1

    公开(公告)日：2004-10-07

    申请号：US10405430

    申请日：2003-04-02

    发明人： Keith Buckle

    IPC分类号： H01M002/08 ,  H01M002/02 ,  H01M004/50

    CPC分类号： H01M2/0222 ,  H01M2/08 ,  H01M4/02 ,  H01M4/0478 ,  H01M4/24 ,  H01M4/364 ,  H01M4/366 ,  H01M4/42 ,  H01M12/06 ,  H01M2004/027 ,  H01M2004/028

    摘要： A zinc/air cell having thin walled cup shaped anode casing and cathode casing. The cell may be a button cell having an anode comprising zinc and a cathode, which may be catalytic, comprising manganese dioxide. The anode and cathode casings have small wall thicknesses, preferably between 2 and 5 mil (0.0508 and 0.127 mm), desirably between about 2 and 3 mil (0.0508 and 0.0762 mm). There is an insulating seal ring covering at least a portion of the anode casing side walls. During cell assembly the cathode casing side wall is pushed over at least a portion of the anode casing side wall with insulating sealing disk therebetween. A tight interference fit is achieved with the outside diameter of the anode casing plus insulating seal thereon being preferably between about 2 and 4.5 mil (0.0508 and 0.114 mm) greater than the inside diameter of the cathode casing. This reduces the tendency of the casing side walls to spring back after crimping.

    摘要翻译： 具有薄壁杯形阳极壳体和阴极壳体的锌/空气电池。 电池可以是具有包括锌和阴极的阳极的钮扣电池，其可以是催化的，包括二氧化锰。 阳极和阴极壳体具有较小的壁厚度，优选在2密耳（5〜50密耳）（0.0508和0.127mm）之间，理想地在约2〜3密耳（0.0508〜0.0762mm）之间。 存在覆盖阳极壳体侧壁的至少一部分的绝缘密封环。 在电池组装过程中，阴极壳侧壁被绝缘密封盘压在阳极壳侧壁的至少一部分上。 通过阳极套管的外径加上其上的绝缘密封件，绝缘密封比较阴极套管的内径大约在2到4.5密耳（0.0508和0.114毫米）之间才能实现。 这降低了压接后壳体侧壁弹回的趋势。

    Non-aqueous electrolyte secondary battery, positive electrode active material and method of manufacturing the same
    68.
    发明申请
    Non-aqueous electrolyte secondary battery, positive electrode active material and method of manufacturing the same 审中-公开
    非水电解质二次电池，正极活性物质及其制造方法

    公开(公告)号：US20040191628A1

    公开(公告)日：2004-09-30

    申请号：US10801655

    申请日：2004-03-17

    申请人： SANYO ELECTRIC CO., LTD.

    发明人： Takao Inoue ,  Masahisa Fujimoto ,  Masaharu Itaya

    IPC分类号： H01M004/48 ,  H01M004/52 ,  H01M004/50 ,  C01G045/12 ,  C01G049/04 ,  C01G051/04 ,  C01G053/04

    CPC分类号： H01M4/525 ,  C01G45/1228 ,  C01G49/009 ,  C01G51/42 ,  C01G51/66 ,  C01G53/42 ,  C01G53/66 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/40 ,  H01M4/0438 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M10/0525

    摘要： As a positive electrode active material, a lithium transition metal complex oxide having a layered rock-salt structure containing lithium (Li) and containing magnesium atoms (Mg) substituted for part of lithium atoms (Li) is used. The lithium transition metal complex oxide is formed by chemical or electrochemical substitution of Mg atoms for part of Li atoms in LiCoO2, LiMnO2, LiFeO2, LiNiO2, or the like. A cell is prepared in which a negative electrode 2 and a positive electrode 1 including the lithium transition metal complex oxide (positive electrode active material) are disposed in a non-aqueous electrolyte 5 including a lithium salt, and part of Li in the lithium transition metal complex oxide is extracted by discharging the cell. Then, the electrolyte including Li is replaced with an electrolyte including Mg; and the cell is discharged, so that Mg atoms are substituted for the part of Li atoms in the lithium transition metal complex oxide.

    摘要翻译： 作为正极活性物质，使用具有锂（Li）层状岩盐结构并含有镁原子（Mg）取代部分锂原子（Li）的锂过渡金属络合物氧化物。 锂过渡金属复合氧化物通过Mg原子在LiCoO 2，LiMnO 2，LiFeO 2，LiNiO 2等中的部分Li原子的化学或电化学取代而形成。 制备电池，其中将包含锂过渡金属络合物（正极活性物质）的负极2和正极1设置在包含锂盐的非水电解质5中，并且在锂转变中的一部分Li 通过排出电池提取金属复合氧化物。 然后，将包含Li的电解质替换为包含Mg的电解质; 并且电池被放电，使得Mg原子代替锂过渡金属复合氧化物中的部分Li原子。

    Lithium secondary battery comprising overdischarge-preventing agent
    70.
    发明申请
    Lithium secondary battery comprising overdischarge-preventing agent 有权
    锂二次电池，其包含过放电防止剂

    公开(公告)号：US20040157124A1

    公开(公告)日：2004-08-12

    申请号：US10478802

    申请日：2003-11-25

    发明人： Eun-Young Goh ,  Seung-Tae Hong ,  Hyoung-Jin Kim ,  Hyung-Keun Lee

    IPC分类号： H01M004/52 ,  H01M004/48 ,  H01M004/50 ,  H01M010/40

    CPC分类号： H01M4/525 ,  H01M4/131 ,  H01M4/364 ,  H01M4/505 ,  H01M4/62 ,  H01M10/0525 ,  H01M10/4235 ,  H01M2004/028 ,  H01M2300/0037 ,  Y02E60/122

    摘要： The present invention relates to a lithium secondary battery comprising an overdischarge-preventing agent. Particularly, the present invention provides a lithium secondary battery comprising an overdischarge-preventing agent having superior effects for an overdischarge test and showing 90% or more capacity recovery after the test, by introducing lithium nickel oxide into a cathode for a lithium secondary battery comprising a lithium transition metal oxide capable of occluding and releasing lithium ions as an overdischarge-preventing agent to supply lithium ions such that irreversible capacity of an anode can be compensated or better, thereby lowering voltage of a cathode first to prevent voltage increase of an anode during the overdischarge test.

    摘要翻译： 本发明涉及包含防止过放电剂的锂二次电池。 特别地，本发明提供一种锂二次电池，其具有对过放电试验具有优异效果的过放电防止剂，并且在试验后显示出90％以上的容量恢复率，将锂二氧化镍引入锂二次电池用阴极中， 能够吸收和释放锂离子的锂过渡金属氧化物作为过放电防止剂以提供锂离子，从而可以补偿或更好地补偿阳极的不可逆容量，从而首先降低阴极的电压以防止阳极的电压升高 过放电试验。