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    2,3,5-Trialkyl-4-hydroxybenzylphosphonates and phosphinates
    74.
    发明授权
    2,3,5-Trialkyl-4-hydroxybenzylphosphonates and phosphinates 失效
    2,3,5-三烷基-4-羟基苄基膦酸酯和次膦酸酯

    公开(公告)号：US3962377A

    公开(公告)日：1976-06-08

    申请号：US492089

    申请日：1974-07-26

    申请人： John D. Spivack

    发明人： John D. Spivack

    IPC分类号： C07F9/32 ,  C07F9/40 ,  C08K5/5333 ,  C10L1/26

    CPC分类号： C07F9/32 ,  C07F9/40 ,  C08K5/5333 ,  C10L1/26 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/065 ,  C10N2240/401

    摘要： The compounds are trialkylsubstituted hydroxybenzylphosphonates and phosphinates having the formula ##SPC1##Wherein R, R.sup.1 and R.sup.2 are independently lower alkyl or cycloalkyl groups, R.sup.3 is alkyl, alkyl substituted with one halogen atom, phenyl, phenyl substituted with alkyl groups, alkoxy, alkoxy substituted with one halogen group, phenoxy, phenoxy substituted with alkyl groups, alkylthioethoxy, alkylpolyoxyalkylenoxy, R.sup.4 is alkyl, alkylsubstituted with one halogen atom, cycloalkyl, phenyl, phenyl substituted with alkyl groups alkylthioethyl, thiobis-alkylene, alkyleneoxyalkylene, polyoxyalkylene, alkylpolyoxyalkylene, alkylene, polyvalent cyclic or acyclic hydrocarbon radical, R.sup. 5 and R.sup. 6 are independently hydrogen, alkyl of 1 to 12 carbon atoms, R.sup.6 may also be the group Ic ##SPC2##Or together R.sup.5 and R.sup.6 represent the group Id ##SPC3##R.sup.7 is hydrogen, alkyl or phenyl, A is lower alkylene and n is 1 to 4.These compounds are usually prepared by reacting the trialkylsubstituted hydroxybenzyl or hydroxyphenylalkyl halide with the appropriate trialkyl or triaryl phosphite or appropriate substituted phosphonite.The compounds are useful as stabilizers of organic materials subject to oxidative, thermal and photochemical degradation.

    摘要翻译： 化合物是三烷基取代的羟基苄基膦酸酯和具有下式的三烷基化合物：其中R 1，R 2和R 2独立地为低级烷基或环烷基，R 3为烷基，被一个卤素原子取代的烷基，苯基，被烷基取代的苯基，烷氧基，被一个卤素取代的烷氧基 基团，苯氧基，被烷基取代的苯氧基，烷基硫代乙氧基，烷基聚氧亚烷基氧基，R4是被一个卤原子烷基取代的烷基，环烷基，苯基，被烷基取代的苯基，烷基硫代乙基，硫代双亚烷基，亚烷基氧化烯，聚氧化烯，烷基聚氧化烯，亚烷基，多价环或 无环烃基，R 5和R 6独立地是氢，1至12个碳原子的烷基，R 6也可以是基团C 1或R 4，R 6代表基团，其中R 7是氢，烷​​基或苯基，A是低级亚烷基和 n为1〜4。

    2,4,6-Trialkyl-3-hydroxyphenylalkane phosphonates and phosphinates
    75.
    发明授权
    2,4,6-Trialkyl-3-hydroxyphenylalkane phosphonates and phosphinates 失效
    2,4,6-三烷基-3-羟基苯基烷基膦酸酯和次膦酸酯

    公开(公告)号：US3962376A

    公开(公告)日：1976-06-08

    申请号：US491074

    申请日：1974-07-22

    申请人： John D. Spivack ,  Martin Dexter

    发明人： John D. Spivack ,  Martin Dexter

    IPC分类号： C07F9/32 ,  C07F9/40 ,  C08K5/5333

    CPC分类号： C08K5/5333 ,  C07F9/3241 ,  C07F9/4056 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/065 ,  C10N2240/401

    摘要： The compounds are trialkylsubstituted hydroxyphenylalkanephosphinates and phosphonates having the formula ##SPC1##Wherein R, R.sup.1 and R.sup.2 are independently lower alkyl or cycloalkyl groups, R.sup.3 is alkyl, alkyl substituted with one halogen atom, phenyl, phenyl substituted with alkyl groups, alkoxy, alkoxy substituted with one halogen groups, phenoxy, phenoxy substituted with alkyl groups, alkylthioethoxy, alkyloxalkylenoxy, R.sup.4 is alkyl, alkyll substituted with one halogen atom, cycloalkyl, phenyl, phenyl substituted with alkyl groups, alkylthioethyl, thiobisalkylene, alkylene, polyvalent cyclic or acyclic hydrocarbon radical, A is lower alkylene and n is 1 to 4.These compounds are usually prepared by reacting the trialkylsubstituted hydroxybenzyl or hydroxyphenylalkyl halide with the appropriate trialkyl or triaryl phosphite or appropriate substituted phosphinite.The compounds are useful as stabilizers of organic materials subject to oxidative, thermal and UV light deterioration.

    摘要翻译： 化合物是三烷基取代的羟苯基烷基亚膦酸酯和具有下式的三烷基取代羟基苯基烷基亚膦酸酯和膦酸酯，其中R 1，R 2和R 2独立地为低级烷基或环烷基，R 3为烷基，被一个卤素原子取代的烷基，苯基，被烷基取代的苯基，烷氧基，被一个卤素取代的烷氧基 基团，苯氧基，被烷基取代的苯氧基，烷硫基乙氧基，烷氧基亚烷基氧基，R4是烷基，被一个卤素原子取代的烷基，环烷基，苯基，被烷基取代的苯基，烷基硫代乙基，硫代双亚烷基，亚烷基，多价环或非环状烃基，A是 低级亚烷基，n为1〜4。