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公开(公告)号：US4045170A
公开(公告)日：1977-08-30
申请号：US662964
申请日：1976-03-01
摘要： A dye composition for keratinic fibers comprises an aqueous alcoholic solution of an indoaniline selected from (a) one having the formula ##STR1## wherein Z is selected from amino, acetylamino and hydroxy; R.sub.5, R.sub.6 and R.sub.7 each independently are selected from hydrogen, lower alkyl having 1-6 carbon atoms and lower alkoxy having 1-6 carbon atoms; R.sub.8 is selected from hydrogen, lower alkyl having 1-6 carbon atoms and together with R.sub.5 and the nitrogen atom to which R.sub.8 is attached form dihydro-paroxazine; and R.sub.9 is selected from hydrogen, lower alkyl having 1-6 carbon atoms and together with R.sub.6 and the nitrogen atom to which R.sub.9 is attached form dihydro-paroxazine, with the proviso that at least two of R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are other than hydrogen when Z is NH.sub.2 and that only one of R.sub.8 and R.sub.9 form dihydro-paroxazine; (b) an acid salt of said indoaniline in (a); and (c) a double chloride of zinc and said indoaniline in (a). When the indoaniline is employed in combination with an aqueous alcoholic solution, a hair dyeing lotion which also sets the hair is provided by the inclusion therein of a cosmetic film forming resin.
摘要翻译： 用于角蛋白纤维的染料组合物包含选自（a）具有式“IMAGE”的吲哚苯胺的水溶液，其中Z选自氨基，乙酰氨基和羟基; R5，R6和R7各自独立地选自氢，具有1-6个碳原子的低级烷基和具有1-6个碳原子的低级烷氧基; R8选自氢，具有1-6个碳原子的低级烷基以及与R5连接的氮原子和二氢 - 苯丙嗪; 并且R 9选自氢，具有1-6个碳原子的低级烷基以及与R6连接的氮原子和R9连接的氮原子形成二氢 - 苯并嗪，条件是R5，R6，R7，R8和R9中的至少两个 当Z是NH 2时不同于氢，R8和R9中只有一个形成二氢 - 苯并嗪; （b）（a）中所述吲哚苯胺的酸式盐; 和（c）（a）中的二氯化锌和所述吲哚苯胺。 当将吲哚苯胺与含水醇溶液组合使用时，通过在其中包含化妆品成膜树脂来提供也设置毛发的染发洗剂。
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公开(公告)号：US4035422A
公开(公告)日：1977-07-12
申请号：US633394
申请日：1975-11-19
IPC分类号： C07C103/29 , C07C91/30 , C07C91/44 , C07C103/38
摘要： Oxidation dye coupling compound, for use in dyeing live human hair, having the formula: ##STR1## wherein R is lower alkyl having 1-6 carbon atoms, hydroxyalkyl having 1-6 carbon atoms, acetyl, propionyl, amino alkyl wherein the alkyl moiety has 1-6 carbon atoms, N-dialkylated amino alkyl wherein each of the alkyl moieties has 1-6 carbon atoms and carbamyl methyl.
摘要翻译： 氧化染料偶联化合物，用于染色活人发，具有下式：其中R是具有1-6个碳原子的低级烷基，具有1-6个碳原子的羟烷基，乙酰基，丙酰基，氨基烷基，其中 烷基部分具有1-6个碳原子，N-二烷基化氨基烷基，其中每个烷基部分具有1-6个碳原子和氨甲酰甲基。
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公开(公告)号：US4007747A
公开(公告)日：1977-02-15
申请号：US530975
申请日：1974-12-09
摘要： New dyestuffs are described for keratinic fibers which produce particularly luminous shades without the need for an oxidizing agent. These dyestuffs have the formula: ##STR1## or a tautomeric form thereof wherein each of R.sub.1 and R.sub.4, which may be identical or different, represents a member selected from hydrogen, halogen, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, acylamino and ureido;Each of R.sub.2 and R.sub.3, which may be identical or different, represents a member selected from hydrogen, halogen, alkyl having 1 to 6 carbon atoms, alkoxy having 1 to 6 carbon atoms, amino, N-alkylamino, N-(hydroxyalkyl)-amino, N-(carbamyl-alkyl)-amino, acylamino and ureido, each of said alkyls containing 1 to 6 carbon atoms;Each of R.sub.5 and R.sub.6, which may be identical or different, represents a member selected from hydrogen, halogen, alkyl containing 1 to 6 carbon atoms and alkoxy containing 1 to 6 carbon atoms, with the proviso that when R.sub.5 and R.sub.6 are both other than hydrogen at least one is in a meta-position relative to the NHR.sub.7 group; and R.sub.7 represents a member selected from alkyl, hydroxyalkyl, acylaminoalkyl, mesylaminoalkyl, carbamylalkyl, aminoalkyl, piperidinoalkyl and morpholinoalkyl, each of said alkyls containing 1 to 6 carbon atoms.
摘要翻译： 对于不需要氧化剂而产生特别发光色调的角质纤维，描述了新的染料。 这些染料具有下式：其中R 1和R 4各自可以相同或不同，表示选自氢，卤素，具有1-6个碳原子的烷基，具有1-6个碳原子的烷氧基， 1至6个碳原子，酰氨基和脲基; R 2和R 3可以相同或不同，表示选自氢，卤素，具有1-6个碳原子的烷基，具有1-6个碳原子的烷氧基，氨基，N-烷基氨基，N-（羟烷基） - 氨基，N-（氨甲酰基 - 烷基） - 氨基，酰氨基和脲基，所述烷基各自含有1至6个碳原子; 每个R 5和R 6可以相同或不同，表示选自氢，卤素，含有1至6个碳原子的烷基和含有1至6个碳原子的烷氧基的成员，条件是当R 5和R 6均为 氢至少一个相对于NHR7基团处于间位; 并且R 7表示选自烷基，羟基烷基，酰氨基烷基，甲磺酰氨基烷基，氨基甲酰基烷基，氨基烷基，哌啶子基烷基和吗啉代烷基的成员，所述烷基各自含有1至6个碳原子。
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公开(公告)号：US3977825A
公开(公告)日：1976-08-31
申请号：US482494
申请日：1974-06-24
IPC分类号： A61K8/41 , A61Q5/10 , C07C275/26 , A61K7/13
CPC分类号： C07C275/26 , A61K8/413 , A61Q5/10 , Y10S424/01 , Y10S424/02
摘要： Indoaniline of the formula ##SPC1##wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.
摘要翻译： 下式的吲哚苯胺其中R 1表示氢，卤素，烷基或烷氧基; R2和R3表示烷基; R4，R5和R6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R5也可以表示氨基，烷基氨基，羟基烷基氨基或氨基甲酰基烷基氨基，上述烷基和烷氧基能够含有1至6个碳原子 和2〜7个碳原子的酰基，其中R5不代表氢，氯，甲基或甲氧基，当R5表示乙酰氨基时，R6不代表氢; 应当理解，上述化合物可以以由式（I）表示的互变异构体形式存在。 吲哚苯胺有效地用于角蛋白纤维，特别是活人的头发的染料组合物中。
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公开(公告)号：US3963764A
公开(公告)日：1976-06-15
申请号：US580830
申请日：1975-05-27
IPC分类号： A61K8/41 , A61Q5/10 , C09B53/02 , C07C119/14 , C07D265/36
CPC分类号： C09B53/02 , A61K8/413 , A61Q5/10 , Y10S424/01 , Y10S424/02
摘要： Indoaniline having the formula ##SPC1##Wherein Z represents amino, acylamino or hydroxy; R.sub.5, R.sub.6 and R.sub.7 each independently represent hydrogen, lower alkyl or lower alkoxy; R.sub.8 and R.sub.9 each independently represent hydrogen, lower alkyl or lower alkyl substituted with hydroxy, carbamoyl, acylamino or piperidinyl, R.sub.8 and R.sub.5 or R.sub.9 and R.sub.6 being able to form with the adjacent nitrogen and carbon atoms a dihydrooxazine or pyrroline heterocycle; and the salts formed by these indoanilines with an organic or inorganic acid, and the double zinc salts of these indoanilines, and the tautomers thereof. These indoanilines are usefully employed for dyeing keratinous fibers, and in particular, human hair.
摘要翻译： 具有式WHEREIN Z的氨基苯甲酰胺代表氨基，酰氨基或羟基; R5，R6和R7各自独立地表示氢，低级烷基或低级烷氧基; R8和R9各自独立地表示氢，被羟基，氨基甲酰基，酰基氨基或哌啶基取代的低级烷基或低级烷基，R8和R5或R9和R6能够与相邻的氮和碳原子一起形成二氢恶嗪或吡咯啉杂环; 由这些吲哚苯胺与有机或无机酸形成的盐，以及这些吲哚苯胺的双锌盐及其互变异构体。 这些吲哚尼尔可有效地用于染色角质纤维，特别是人发。
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公开(公告)号：US3961879A
公开(公告)日：1976-06-08
申请号：US482559
申请日：1974-06-24
申请人： Andree Bugaut , Monique Laudon
发明人： Andree Bugaut , Monique Laudon
摘要： A dye composition for keratinic fibers comprising in combinationA. at least one oxidation base comprising a paraphenylenediamine, present in the form of a free base, or in the form of an acid addition salt thereof andB. at least one coupler of the formula: ##SPC1## wherein Y represents a member selected from the group consisting of --NHCOCH.sub.3 and --NHCONH.sub.2 ; and X represents a member selected from the group consisting of fluorine, chlorine, and bromine, or the acid addition salt of the compound of formula (I).
摘要翻译： 用于角蛋白纤维的染料组合物，其组合为A.在至少一个含有苯甲烯胺的氧化基质，以无机碱形式存在的情况下，或以酸加成盐形式存在。B.本公式的至少一个偶联物：
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77.发明授权Indoaniline and indophenol compounds, a process for their preparation, dyeing compositions containing them and a hair-dyeing process 失效吲哚苯胺和靛酚化合物，其制备方法，含有它们的染色组合物和染发方法
公开(公告)号：US4702863A
公开(公告)日：1987-10-27
申请号：US884904
申请日：1986-07-14
申请人： Andree Bugaut , Alex M. Junino
发明人： Andree Bugaut , Alex M. Junino
IPC分类号： A61K8/00 , A61K8/34 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/49 , A61Q5/10 , C07C67/00 , C07C241/00 , C07C251/20 , C09B53/02 , C07C50/04 , C07C50/06
摘要： New indolaniline and indophenol compounds of formula (I): ##STR1## wherein Z represents a monohydroxylated or polyhydroxylated hydrocarbon radical, of 1 to 6 carbon atoms, or an aminoalkyl radical of formula ##STR2## wherein n is an integer from 1 to 6 and R.sub.1 and R.sub.2, which are identical or different, represent a hydrogen atom or an alkyl, hydroxyalkyl or acyl radical of 1 to 4 carbon atoms; R represents a hydrogen atom or an alkyl, hydroxyalkyl, polyhydroxyalkyl, monocarbamylalkyl, dicarbamylalkyl, aminoalkyl, acyl, alkoxycarbonyl, carbamyl or monoalkylcarbamyl radical of 1 to 6 carbon atoms; R'.sub.1, R'.sub.2, R'.sub.3 and R'.sub.4, which are identical or different, represent a hydrogen atom, a halogen atom or an alkyl, hydroxyalkyl, alkoxy or hydroxyalkoxy radical, of 1 to 6 carbon atoms; and Y represents OH or NR'.sub.5 R'.sub.6, wherein R'.sub.5 and R'.sub.6, which are identical or different, represent a hydrogen atom or an alkyl, monohydroxyalkyl, polyhydroxyalkyl, carbamylalkyl, mesylaminoalkyl or methoxy alkyl radical of 1 to 6 carbon atoms are disclosed, together with a process for their preparation, hair-dyeing compositions containing them and a hair dyeing process.
摘要翻译： 新的吲哚苯胺和式（I）的靛酚化合物：其中Z代表具有1至6个碳原子的单羟基化或多羟基化烃基，或式IMA图形的氨基烷基，其中n是1的整数 至6和相同或不同的R 1和R 2表示氢原子或具有1至4个碳原子的烷基，羟烷基或酰基; R代表1到6个碳原子的氢原子或烷基，羟基烷基，多羟基烷基，单链烷基烷基，二氨基烷基，氨基烷基，酰基，烷氧基羰基，氨基甲酰基或单烷基氨基甲酰基; R'1，R'2，R'3和R'4相同或不同，表示1至6个碳原子的氢原子，卤素原子或烷基，羟基烷基，烷氧基或羟基烷氧基; Y表示OH或NR'5R'6，其中R'5和R'6相同或不同，表示氢原子或1至6个碳原子的烷基，单羟基烷基，多羟基烷基，氨基甲酰基烷基，甲磺酰氨基烷基或甲氧基烷基 公开了原料及其制备方法，含有它们的染发组合物和染发方法。
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公开(公告)号：US4494953A
公开(公告)日：1985-01-22
申请号：US225355
申请日：1981-01-15
申请人： Andree Bugaut , Francoise Estradier
发明人： Andree Bugaut , Francoise Estradier
IPC分类号： A61K8/00 , A61K8/22 , A61K8/23 , A61K8/25 , A61K8/33 , A61K8/34 , A61K8/35 , A61K8/39 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61K8/73 , A61Q5/10 , C07D295/135 , C07D307/14 , C07D307/52 , C09B53/00 , D06P3/08 , A61K7/13 , C09B57/00
CPC分类号： C07D295/135 , A61K8/413 , A61Q5/10 , C07D307/14 , C07D307/52
摘要： This invention pertains to compounds suitable for dyeing keratin fibers, especially human hair. The compounds have the formula: ##STR1## or an acid addition salt thereof, in which formula R.sub.1 and R.sub.2 form, together with the nitrogen atom to which they are bonded, a morpholino or piperidino ring and R represents a hydrogen atom.This invention also pertains to compositions for dyeing keratin fibers, especially human hair, such composition containing the compounds set forth above and/or compounds of formula (I) wherein R.sub.1 represents a hydrogen atom, R.sub.2 represents a tetrahydrofurfuryl or methoxyethyl radical and R represents a hydrogen atom or a methyl radical, or an acid addition salt thereof.The invention also pertains to the method of using these compositions.
摘要翻译： 本发明涉及适用于染色角蛋白纤维，特别是人发的化合物。 化合物具有下式：其中式R1和R2与它们所键合的氮原子一起形成吗啉代或哌啶子基环，R代表氢原子。 本发明还涉及用于染色角蛋白纤维，特别是人发的组合物，该组合物含有上述化合物和/或式（I）化合物，其中R 1表示氢原子，R 2表示四氢糠基或甲氧基乙基，R表示 氢原子或甲基，或其酸加成盐。 本发明还涉及使用这些组合物的方法。
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79.发明授权Nitrated coupler compounds useful in direct dyeing and simultaneous oxidation and direct dyeing of keratinic fibers 失效用于直接染色和同时氧化和直接染色角蛋白纤维的硝化成色剂化合物
公开(公告)号：US4473374A
公开(公告)日：1984-09-25
申请号：US351300
申请日：1982-02-22
申请人： Andree Bugaut , Ginette Jeanminet
发明人： Andree Bugaut , Ginette Jeanminet
IPC分类号： C07D295/10 , A61K8/00 , A61K8/22 , A61K8/34 , A61K8/40 , A61K8/41 , A61K8/46 , A61K8/49 , A61Q5/06 , A61Q5/10 , C07C67/00 , C07C213/00 , C07C215/74 , C07C215/76 , C07C233/15 , C07C233/25 , C07C233/36 , C07C237/06 , C07C239/00 , C07C271/28 , C07D263/22 , C07D295/12 , C07D295/13 , C09B51/00 , C09B53/02 , C09B57/00 , D06P1/00 , D06P1/32 , D06P3/24 , A61K7/13
CPC分类号： C07D295/13 , A61K8/418 , A61Q5/065 , A61Q5/10 , C07D263/22
摘要： A cosmetic composition for application to the hair contains either (a) at least one compound having the formula ##STR1## wherein R is hydrogen, alkyl or halogen; andR' is hydrogen, alkyl, hydroxyalkyl, carbamylalkyl, mesylaminoalkyl, aminoalkyl, acylaminoalkyl, monoalkylaminoalkyl, dialkylaminoalkyl, piperidinoalkyl, morpholinoalkyl, carbamoyl, acyl or carbalkoxy; or (b) at least one of said compounds having formula I above and at least one benzene or heterocyclic oxidation base. The invention also relates to new couplers of formula I as well as to new indo compounds which result from the coupling of said compounds with an oxidation base. These cosmetic compositions for application to the hair are useful in direct dyeing, oxidation dyeing or simultaneous oxidation and direct dyeing or said hair.
摘要翻译： 用于头发的化妆品组合物含有（a）至少一种具有式（I）的化合物，其中R是氢，烷基或卤素; 氨基烷基，酰基氨基烷基，单烷基氨基烷基，二烷基氨基烷基，哌啶子基烷基，吗啉代烷基，氨基甲酰基，酰基或烷氧羰基; 或（b）至少一种上述具有式I的化合物和至少一种苯或杂环氧化碱。 本发明还涉及式I的新的成色剂以及由所述化合物与氧化碱的偶联产生的新的吲哚化合物。 用于毛发的这些化妆品组合物可用于直接染色，氧化染色或同时氧化和直接染色或所述毛发。
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公开(公告)号：US4305717A
公开(公告)日：1981-12-15
申请号：US722485
申请日：1976-09-13
IPC分类号： A61K8/00 , A61K20060101 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/46 , A61K8/49 , A61Q5/10 , C07C20060101 , C07C233/12 , C07C237/00 , C07C237/06 , C09B53/00 , C09B53/02 , D06P3/14 , A61K7/13
摘要： Dye compositions comprising a coupler having to the formula ##STR1## in which formula R.sub.1 and R.sub.2 are identical or different and represent a hydrogen atom or an alkyl radical having 1 to 2 carbon atoms and n represents a number equal to 1 or 2 and a paraphenylenediamine.This coupler is particularly suitable for use in a dyeing composition comprising paraphenylenediamines responding to the formula ##STR2## or the corresponding acid salts; formula in which R.sub.1, R.sub.2 and R.sub.3 are identical or different and represent a hydrogen atom, an alkyl or alkoxy radical having 1 to 2 carbon atoms, R.sub.4 and R.sub.5 are identical or different and represent a hydrogen atom, a alkyl radical, hydroxyalkyl, alkoxyalkyl in which the alkoxy group comprises 1 to 2 carbon atoms, carbamylalkyl, mesylaminoalkyl, acetylaminoalkyl, ureidoaminoalkyl, carbethoxyaminoalkyl, the alkyl groups in R.sub.4 and R.sub.5 having 1 to 3 carbon atoms, with the reservation that R.sub.1 or R.sub.3 represents hydrogen when R.sub.4 and R.sub.5 do not represent a hydrogen atom.
摘要翻译： 包含具有式（I）的成色剂的染料组合物，其中式R 1和R 2相同或不同，表示氢原子或具有1至2个碳原子的烷基，n表示等于1或2的数 和对苯二胺。 该成色剂特别适用于染色组合物，其包含响应式（II）的对苯二胺或相应的酸式盐; 其中R1，R2和R3相同或不同并且表示氢原子，具有1至2个碳原子的烷基或烷氧基，R4和R5相同或不同，表示氢原子，烷基，羟基烷基，烷氧基烷基 其中烷氧基包含1至2个碳原子，氨基甲酰基烷基，甲磺酰基氨基烷基，乙酰氨基烷基，脲基氨基烷基，乙氧基氨基烷基，R4和R5中的烷基具有1至3个碳原子，保留当R 1和R 3表示氢时，R 4和R 5 不代表氢原子。
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