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公开(公告)号：US5356440A
公开(公告)日：1994-10-18
申请号：US96143
申请日：1993-07-22
申请人： Pierre Galafassi , Jean-Marie Adam
发明人： Pierre Galafassi , Jean-Marie Adam
IPC分类号： C09B62/503 , D06P3/24 , D06P1/384 , C09B62/527 , C09B62/53
CPC分类号： C09B62/503 , D06P3/248
摘要： The invention relates to a process for the dyeing of synthetic polyamide fibre materials, which comprises dyeing these fibre materials with a reactive dye of the formulaHO.sub.3 S--Fa--X--SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H).sub.m(1),in which Fa is a dye radical, X is a direct bond or a radical of the formula --CONHCH.sub.2 CH.sub.2 -- and m is the number 1 or 2, the dye of the formula (1) containing only one sulfo group, from an aqueous liquor at a pH of 5 to 9 and, to set the dyeing temperature, raising the temperature from 80.degree. C. to at least 95.degree. C. over a period of at least 20 minutes. The process according to the invention produces level dyeings on synthetic polyamide fibre materials.
摘要翻译： 本发明涉及一种染色合成聚酰胺纤维材料的方法，其中包括使用式HO3S-Fa-X-SO2CH2CH2OSO3H）m（1）的活性染料染色这些纤维材料，其中Fa是染料基团，X 是式-CONHCH 2 CH 2 - 的直接键或基团，m为1或2，式（1）的染料仅含有一个磺基，pH为5至9的含水液体，以及 设定染色温度，在至少20分钟的时间内将温度从80℃提高至至少95℃。 根据本发明的方法在合成聚酰胺纤维材料上产生高级染色。
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公开(公告)号：US5196520A
公开(公告)日：1993-03-23
申请号：US645374
申请日：1991-01-18
申请人： Jurgen Schaetzer , Jean-Marie Adam
发明人： Jurgen Schaetzer , Jean-Marie Adam
IPC分类号： C09B31/143 , C09B31/10 , C09B43/00 , D06P3/24 , D06P5/00
摘要： The invention relates to azo dyes of formula ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is C.sub.2 -C.sub.4 alkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted or substituted C.sub.5 -C.sub.7 cycloalkyl or phenyl, and the benzene rings I and II are unsubstituted or substituted.The azo dyes are suitable for dyeing or printing synthetic polyamide materials, especially in conjunction with other dyes and, preferably, from short liquors. The azo dyes have good allround properties, in particular good affinity.
摘要翻译： 本发明涉及式（1）的偶氮染料，其中R 1是氢或C 1 -C 4烷基，R 2是C 2 -C 4烷基，R 3是氢，C 1 -C 4烷基或未取代或取代的C 5 -C 7环烷基或苯基，苯环 I和II是未取代或取代的。 偶氮染料适用于染色或印刷合成聚酰胺材料，特别是与其它染料结合使用，优选来自短酒。 偶氮染料具有良好的全面性能，特别是良好的亲和力。
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公开(公告)号：US5049161A
公开(公告)日：1991-09-17
申请号：US360577
申请日：1989-06-01
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B67/22
CPC分类号： C09B67/0034 , Y10S8/922
摘要： Dye mixtures particularly suitable for dyeing polyester material by the exhaust process containing at least two dicyanobenzanthrone compounds of the formula ##STR1## wherein R is hydrogen or a substituted or unsubstituted alkyl or aryl group and X is hydrogen or halogen located in the 6- or 7-position.
摘要翻译： 特别适用于通过含有至少两种式（1）的二氰基苯酮酮化合物（1）的排气方法染色聚酯材料的染料混合物，其中R是氢或取代或未取代的烷基或芳基，X是位于6 - 或7位。
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公开(公告)号：US5028709A
公开(公告)日：1991-07-02
申请号：US5991
申请日：1987-01-21
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
摘要： The invention relates to vat dyes of the formula ##STR1## wherein [A] and [A'] and X are as defined in claim 1. The vat dyes of formula I are suitable for dyeing or printing a wide range of materials. Dyeings with good fastness properties are obtained in particular on cellulose material.
摘要翻译： 本发明涉及式（I）的还原染料，其中[A]和[A']和X如权利要求1中所定义。式I的还原染料适用于染色或印刷各种材料 。 特别是在纤维素材料上获得具有良好牢度特性的染色剂。
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公开(公告)号：US4736021A
公开(公告)日：1988-04-05
申请号：US417153
申请日：1982-09-13
申请人： Jean-Marie Adam , Pierre Galafassi
发明人： Jean-Marie Adam , Pierre Galafassi
摘要： There are described azo compounds of the formula ##STR1## wherein K is an optionally quaternized basic group,X is the radical COOR, in which R is an alkyl group or a substituted or unsubstituted phenyl group, or X is the radical CONHR', in which R' is an alkyl group or a substituted or unsubstituted phenyl group; and wherein the benzene rings B and/or D can be further substituted;and the use thereof as dyes for the dyeing of textile materials, and particularly for the dyeing of paper of all types, especially bleached, lignin-free, unsized paper.
摘要翻译： 描述了式IMA的偶氮化合物，其中K是任选季铵化的碱基，X是基团COOR，其中R是烷基或取代或未取代的苯基，或X是基团CONHR'，其中 其中R'为烷基或取代或未取代的苯基; 并且其中苯环B和/或D可以进一步被取代; 以及其作为纺织材料染色的染料的用途，特别是用于所有类型的纸张的染色，特别是漂白的无木质素的未定型纸。
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公开(公告)号：US4588811A
公开(公告)日：1986-05-13
申请号：US672869
申请日：1984-11-19
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B25/00 , D21H21/28 , C07D401/10 , C07D413/10 , C07D417/10
摘要： There are described novel cationic quinophthalone compounds of the formula I ##STR1## wherein the symbols have the meanings defined in claim 1, and also processes for producing them. These novel quinophthalone compounds can be used in particular as dyes for dyeing and printing paper, greenish-yellow dyeings having good fastness to water and to light being obtained.
摘要翻译： 描述了式I（I）的新型阳离子喹酞酮化合物，其中符号具有权利要求1中定义的含义，并且还涉及制备它们的方法。 这些新颖的喹酞酮化合物特别可用作染色和印刷纸的染料，具有良好的耐水牢度和获得光的绿黄色染色剂。
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77.发明授权
公开(公告)号：US4525583A
公开(公告)日：1985-06-25
申请号：US457822
申请日：1983-01-13
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B29/52 , C09B44/08 , C09D11/00 , C09D11/02 , D06P1/41 , D21H21/28 , C09B29/036 , C09B29/36
CPC分类号： C09B44/08
摘要： Benzthiazole compounds of the formula ##STR1## or a tautomeric form thereof, in which KK is the radical of a pyrimidine coupling compound as defined, W is a radical of the formula --CH.sub.2 --NH--CO--C.sub.1 --C.sub.4 -alkyl-Q.sup..sym. An.sup..crclbar. in which An is an anion and Q is a quaternary radical of the formula ##STR2## in which R.sub.1 to R.sub.6 independently of one another are a substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl radical, or the radicals R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4, or R.sub.3 and R.sub.4 and R.sub.5, together with the N atom, form a heterocyclic ring, m is the number 1, 2 or 3 and n is the number 0 or 1, and in which the benzene radicals A, B and/or C may be further substituted are particularly suitable as dyes for paper, brilliant yellow to orange dyeings which have, in particular, good wet-fastness and light-fastness, being obtained.
摘要翻译： 其中KK是如所定义的嘧啶偶联化合物的基团，其中W是式-CH 2 -NH-CO-C 1 -C 4 - 烷基-Q（其中R 1，R 2， +）An（ - ）其中An是阴离子，Q是式“IMAGE”的季基，其中R 1至R 6彼此独立地是取代或未取代的C 1 -C 4 - 烷基，或基团R 1和 R2或R3和R4，或R3和R4和R5与N原子一起形成杂环，m是数字1,2或3，n是数字0或1，其中苯基A ，B和/或C可以进一步被取代，特别适合作为纸的染料，具有特别好的耐湿牢度和耐光性的亮黄色至橙色染色。
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公开(公告)号：US4501592A
公开(公告)日：1985-02-26
申请号：US521904
申请日：1983-08-10
申请人： Jean-Marie Adam , Peter Bloch
发明人： Jean-Marie Adam , Peter Bloch
摘要： The invention relates to dyes of the formula ##STR1## wherein X is oxygen or sulfur, R is hydrogen or C.sub.1 -C.sub.4 alkyl, Y is an unsubstituted or substituted aryl radical, n is 1, 2 or 3, the benzene ring A may be substituted by halogen and the benzene rings B and D may each independently be substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or a radical of the formula --O--CH.sub.2 CH.sub.2 --O--R.sub.1, wherein R.sub.1 is hydrogen, methyl or ethyl. These dyes are suitable for dyeing or printing natural or synthetic polyamide fibres.
摘要翻译： 本发明涉及下式的染料，其中X是氧或硫，R是氢或C 1 -C 4烷基，Y是未取代或取代的芳基，n是1,2或3，苯环A可被取代 苯环B和D可各自独立地被卤素，C 1 -C 4烷基，C 1 -C 4烷氧基或式-O-CH 2 CH 2 -O-R 1的基团取代，其中R 1是氢，甲基或乙基。 这些染料适用于染色或印刷天然或合成聚酰胺纤维。
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公开(公告)号：US4395545A
公开(公告)日：1983-07-26
申请号：US292970
申请日：1981-08-14
申请人： Jean-Marie Adam , Pierre Galafassi
发明人： Jean-Marie Adam , Pierre Galafassi
IPC分类号： C09B19/00 , C09B19/02 , C09B62/44 , C09B62/465 , C09B62/523 , C09B69/00 , D21H19/10 , C07D498/22
CPC分类号： C09B19/02 , C09B69/001
摘要： The invention discloses novel basic dioxazine compounds of the formula ##STR1## wherein each of X.sub.1 and X.sub.2 independently is an unbranched or branched alkyl group of 1 to 4 carbon atoms, an unsubstituted or substituted phenyl group, halogen, hydrogen, cyano, a phenylamino group which is unsubstituted or substituted in the phenyl nucleus, the CONH.sub.2 group, the CONH-phenyl group which can be substituted in the phenyl moiety, or a COO--C.sub.1 -C.sub.4 alkyl group; Z is a non-quaternized or quaternized basic group, Y is an anionic group, each B independently is a fused ring system containing 2 to 4 carbocyclic and/or heterocyclic rings and which, in addition to containing the substituents Z and Y, can be further substituted; n is 1 to 4 and m is 0 to 2, with the proviso that m is not greater than n. Processes for obtaining these compounds and their use as dyes for coloring and printing in particular cellulosic fabrics, without the addition of salt, are also disclosed.
摘要翻译： 本发明公开了式（I）的新型基本二恶嗪化合物，其中X1和X2各自独立地是1至4个碳原子的未支化或支链烷基，未取代或取代的苯基，卤素，氢，氰基， 在苯基中未取代或取代的苯基氨基，CONH 2基，可在苯基部分取代的CONH-苯基或COO-C 1 -C 4烷基; Z是非季铵化或季铵化的碱性基团，Y是阴离子基团，每个B独立地是含有2至4个碳环和/或杂环的稠环体系，并且除了含有取代基Z和Y之外，它们可以是 进一步取代; n为1〜4，m为0〜2，条件是m不大于n。 还公开了获得这些化合物的方法及其作为染料用于特别是纤维素织物着色和印刷的用途，而不添加盐。
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公开(公告)号：US4309180A
公开(公告)日：1982-01-05
申请号：US166277
申请日：1980-07-01
申请人： Roger Lacroix , Jean-Marie Adam , Janos Vincze
发明人： Roger Lacroix , Jean-Marie Adam , Janos Vincze
摘要： There are described new anthraquinone compounds which, in the form of the free acid, correspond to the formula I ##STR1## wherein the X's independently of one another are each a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms, Y is hydrogen or is the same as X, and wherein the phenyl rings a can also be substituted by one or more halogen atoms, the production and use thereof, and also dye solutions containing a solvent mixture consisting of one or more aprotic solvents, at least one glycol and/or glycol ether, and optionally water and further additives, which solutions contain in each case a mixture of two anthraquinone dyes which, in the form of the free acid, correspond to the formulae I and IV ##STR2## wherein the X's independently of one another are each a straight-chain or branched-chain alkyl group having 1 to 4 carbon atoms, Y is hydrogen or is the same as X, and wherein the phenyl rings a can also be substituted by one or more halogen atoms.
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