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    Method of coloring porous material
    1.
    发明授权
    Method of coloring porous material 失效
    多孔材料着色方法

    公开(公告)号：US07232467B2

    公开(公告)日：2007-06-19

    申请号：US10525300

    申请日：2003-08-26

    申请人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

    发明人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

    IPC分类号： A61K7/13

    CPC分类号： A61K8/4966 ,  A61Q5/065 ,  C07C245/24 ,  C09B67/0079

    摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component

    摘要翻译： 描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在 至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团， 并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分， 不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应

    Method of coloring keratin-containing fibres using diazonium salts
    2.
    发明授权
    Method of coloring keratin-containing fibres using diazonium salts 失效
    使用重氮盐对含角蛋白的纤维进行着色的方法

    公开(公告)号：US07192453B2

    公开(公告)日：2007-03-20

    申请号：US10492325

    申请日：2002-10-08

    申请人： Jean-Marie Adam ,  Taher Yousaf

    发明人： Jean-Marie Adam ,  Taher Yousaf

    IPC分类号： A61K7/13

    CPC分类号： A61K8/494 ,  A61K8/415 ,  A61Q5/065

    摘要： The present invention relates to a method of coloring keratin-containing fibres, especially human hair, in which method a compound of formula (I), wherein R is hydroxy or NHR1, R1 being hydrogen or C1–C4alkyl, and B is an aromatic or heterocyclic ring, is diazotised, and the resulting diazonium salt is applied at a pH of from 2 to 5 to the material being colored and then, by means of increasing the pH to from 7 to 12, is fixed on the material in the form of an oligomeric or polymeric colorant

    摘要翻译： 本发明涉及一种着色含角蛋白的纤维，特别是人类头发的方法，其中式（I）化合物，其中R是羟基或NHR 1，R 1， / SUB>为氢或C 1 -C 4烷基，B为芳族或杂环，被重氮化，所得重氮盐的pH为 从2至5对被着色的材料，然后通过将pH升高至7至12，以低聚或聚合着色剂的形式固定在材料上

    New compounds, a process for their preparation and their use as dyes and pigments
    4.
    发明申请
    New compounds, a process for their preparation and their use as dyes and pigments 审中-公开
    新化合物，其制备方法及其作为染料和颜料的用途

    公开(公告)号：US20060124017A1

    公开(公告)日：2006-06-15

    申请号：US10548360

    申请日：2004-03-10

    申请人： Jean-Marie Adam ,  Pramod Dalvi ,  Vadiraj Ekkundi ,  Jean-Pierre Bacher ,  Dandip Tiwari

    发明人： Jean-Marie Adam ,  Pramod Dalvi ,  Vadiraj Ekkundi ,  Jean-Pierre Bacher ,  Dandip Tiwari

    IPC分类号： G03G15/32

    CPC分类号： G03G9/0906 ,  B41M1/04 ,  B41M1/06 ,  B41M1/12 ,  B41M3/14 ,  B41M2205/06 ,  C07D233/96 ,  C07D263/42 ,  C07D307/34 ,  C09B23/04 ,  C09B23/102 ,  C09B55/003 ,  C09D7/41 ,  C09D11/037 ,  C09D11/328 ,  G03G9/0916 ,  G03G9/0924 ,  G11B7/246

    摘要： Compounds of formula (1) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkoxy, aryloxy, alkylthio or arylthio, X is —O—, —S—, —NH— or —N(alkyl)-, Y is hydrogen or carboxylic ester, Z is ═C— or ═N—, T is ═C— or ═N—, R2 is hydrogen, alkyl or CN, n is 0 or 1, when Z is ═N— then n is 0, m is 0 or 1, when T is ═N— then m is 0, A is a heterocyclic or linear or polycondensed aromatic group which is unsubstituted or substituted by hydroxy alkyl, halogen, nitro, cyano, amino, acylamino, carboxylic ester, sulfonic ester, carboxylic amide, sulfonic amide, alkoxy, aryloxy, alkylthio, arylthio or phenyl, or A together with T and R2 can form an allycyclic or heterocyclic ring, their preparation and their use in the production of coloured plastics or polymeric colour particles.

    摘要翻译： 式（1）的化合物，其中R 1是氢，羟基，卤素，硝基，氰基，氨基，羧基，羧酸酯，磺基，磺酸酯，羧酸酰胺，磺酰胺，烷氧基，芳氧基，烷硫基 或芳硫基，X是-O - ， - S-，-NH-或-N（烷基） - ，Y是氢或羧酸酯，Z是-C-或-N-，T是-C-或-N- R 2为氢，烷基或CN，n为0或1，当Z为-N-时，则n为0，m为0或1，当T为-N-时，m为0 A是未被取代或被羟基烷基，卤素，硝基，氰基，氨基，酰基氨基，羧酸酯，磺酸酯，羧酸酰胺，磺酰胺，烷氧基，芳氧基，烷硫基，芳硫基或芳氧基取代的杂环或直链或缩缩芳族基团 苯基或A与T和R 2一起可以形成烯丙基或杂环，它们的制备及其在生产有色塑料或聚合物着色颗粒中的用途。

    Dye mixtures and the use thereof
    5.
    发明授权
    Dye mixtures and the use thereof 失效
    染料混合物及其用途

    公开(公告)号：US6030420A

    公开(公告)日：2000-02-29

    申请号：US207540

    申请日：1998-12-08

    申请人： Jean-Marie Adam

    发明人： Jean-Marie Adam

    IPC分类号： C09B1/34 ,  C09B29/00 ,  C09B67/22 ,  D06P1/40 ,  D06P1/96 ,  D06P3/14 ,  D06P3/24 ,  D06P3/87 ,  D06P5/00

    CPC分类号： C09B67/0038 ,  D06P1/40 ,  D06P1/96 ,  Y10S8/924

    摘要： The invention relates to dye mixtures comprising at least one dye of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, together with at least one dye of formula (2) ##STR2## wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.5 is C.sub.2 -C.sub.6 alkyl uninterrupted or interrupted by oxygen, with the proviso that R.sub.1 is not methyl when R.sub.2, R.sub.3 and R.sub.4 are hydrogen and R.sub.5 is ethyl.The dye mixtures are suitable for dyeing or printing natural or synthetic polyamide fibre materials, especially in combination with other dyes and especially from short liquors. The dye mixture is distinguished by generally good properties, especially good uptake and good solubility.

    摘要翻译： 本发明涉及包含至少一种式（1）的染料的染料混合物，其中R1是氢，C1-C4烷基或C1-C4烷氧基，R2是氢或C1-C4烷基，以及至少一种式（2）的染料，其中R3 是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 4是氢或C 1 -C 4烷基，R 5是不间断或被中断的C 2 -C 6烷基，条件是当R 2，R 3和R 4是氢时，R 1不是甲基，R 5是乙基 。 染料混合物适用于染色或印刷天然或合成聚酰胺纤维材料，特别是与其他染料，尤其是短酒混合。 染料混合物通常具有良好的性能，特别是良好的吸收性和良好的溶解性。

    Process for trichromatic dyeing or printing
    6.
    发明授权
    Process for trichromatic dyeing or printing 失效
    三色染色或印刷方法

    公开(公告)号：US5630851A

    公开(公告)日：1997-05-20

    申请号：US609217

    申请日：1996-03-01

    申请人： Guido Jordine ,  Jean-Marie Adam

    发明人： Guido Jordine ,  Jean-Marie Adam

    IPC分类号： C09B29/01 ,  C09B29/30 ,  C09B67/22 ,  D06P3/16 ,  D06P3/24

    CPC分类号： C09B67/0051 ,  C09B29/0007 ,  C09B29/30 ,  D06P3/16 ,  D06P3/241 ,  Y10S8/917 ,  Y10S8/924

    摘要： A process for dyeing or printing polyamide material by the trichromatic technique using a dye mixture which contains least two yellow- or orange-dyeing dyes of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, and X is hydrogen or C.sub.1 -C.sub.4 alkyl; together with at least one red-dyeing dye of formulae (2) and (3) ##STR2## wherein R.sub.2 is C.sub.1 -C.sub.6 alkyl, phenyl or cyclohexyl and R.sub.3 is C.sub.1 -C.sub.6 alkyl, or wherein R.sub.2 and R.sub.3, together with the linking nitrogen atom, form an azepinyl ring, and R.sub.4 is hydrogen, C.sub.2 -C.sub.4 alkanoylamino or halogen; and together with at least one of the blue-dyeing dyes of formulae (4) and (5) ##STR3## wherein R.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.6 is C.sub.1 -C.sub.4 alkyl or amino, R.sub.7 is hydrogen or methyl, and R.sub.8 is a C.sub.2-4 hydroxyalkylsulfamoyl radical, is disclosed.

    摘要翻译： 一种通过三色技术使用含有至少两种式（1）的黄色或橙色染色染料（1）的染料混合物染色或印刷聚酰胺材料的方法，其中R1是氢，C1-C4烷基，C1-C4烷氧基 或卤素，X为氢或C 1 -C 4烷基; 连同至少一种式（2）和（3）的染色染料，烷基，苯基或环己基，R 3是C 1 -C 6烷基，或其中R 2和R 3与连接氮原子一起形成吖庚因环，R 4 是氢，C 2 -C 4烷酰基氨基或卤素; 并且与至少一种式（4）和（5）的染色染料中的至少一种（5）其中R 5是氢或C 1 -C 4烷基，R 6是C 1 -C 4烷基或氨基， R7是氢或甲基，R8是C2-4羟烷基氨磺酰基。

    Cationic phthalocyanine compounds
    8.
    发明授权
    Cationic phthalocyanine compounds 失效
    阳离子酞菁化合物

    公开(公告)号：US4845209A

    公开(公告)日：1989-07-04

    申请号：US229789

    申请日：1988-08-04

    申请人： Jean-Marie Adam

    发明人： Jean-Marie Adam

    IPC分类号： C07D487/22 ,  C09B47/08 ,  C09B47/26 ,  C09B47/32 ,  D06P1/14 ,  D06P1/42 ,  D21H19/10 ,  D21H21/28

    CPC分类号： D21H21/28 ,  C09B47/32 ,  D06P1/14

    摘要： The invention relates to phthalocyanine compounds of the formula ##STR1## wherein MePc is a copper, cobalt or nickel phthalocyanine radical,R.sub.1 is hydrogen or alkyl,X is alkylene, andR.sub.2, R.sub.3 and R.sub.4, are each independently alkyl which is unsubstituted or substituted by hydroxy, alkoxy, phenyl or amino, or R.sub.1 and R.sub.2, when taken together, are methylene, ethylene or propylene if X is methylene or ethylene, or two or three of R.sub.2, R.sub.3 and R.sub.3, together with the nitrogen atom, form a 5- to 7-membered unsubstituted or substituted heterocyclic ring which may contain one or two additional hetero atoms selected from the group consisting of O, N and S as ring members,An.sup..crclbar. is a cation and M is a cation, and x is greater than y and y is greater than 0, and the sum of x+y is 4 or less than 4.These compounds can be used as dyes, in particular for dyeing and printing cellulosic materials and polyacrylonitrile materials, especially paper.

    摘要翻译： 本发明涉及式（I）的酞菁化合物，其中MePc是铜，钴或镍酞菁基，R 1是氢或烷基，X是亚烷基，R 2，R 3和R 4各自独立地是烷基， 如果X是亚甲基或亚乙基，或者R 2，R 3和R 3的两个或三个与氮原子一起，则它们被羟基，烷氧基，苯基或氨基取代，或者R 1和R 2一起是亚甲基，亚乙基或丙烯 形成5至7元未取代或取代的杂环，其可以含有一个或两个另外的选自O，N和S的杂原子作为环成员，An（ - ）是阳离子，M是阳离子 ，x大于y且y大于0，x + y之和为4或小于4.这些化合物可用作染料，特别用于染色和印花纤维素材料和聚丙烯腈材料，特别是纸张 。

    3(5-tetrazolyl)1,4-diaminoanthraquinones
    9.
    发明授权
    3(5-tetrazolyl)1,4-diaminoanthraquinones 失效
    3（5-四唑基）1,4-二氨基蒽醌

    公开(公告)号：US4598155A

    公开(公告)日：1986-07-01

    申请号：US441829

    申请日：1982-11-15

    申请人： Jean-Marie Adam

    发明人： Jean-Marie Adam

    IPC分类号： C09B1/28 ,  C07C67/00 ,  C07C253/00 ,  C07C255/58 ,  C09B1/20 ,  C09B1/22 ,  C09B1/26 ,  C09B1/32 ,  D06P1/20 ,  C07D257/04

    CPC分类号： C09B1/20

    摘要： There are described novel compounds of the formula I ##STR1## wherein the symbols R.sub.1, R.sub.2, R.sub.3, R.sub.7 and A have the meanings defined in claim 1, also processes for producing them and their use as dyes for dyeing and printing textile materials, on which are obtained brilliant, deeply colored, blue dyes, particularly on polyester materials.

    摘要翻译： 描述了式I（I）的新化合物，其中符号R1，R2，R3，R7和A具有权利要求1中定义的含义，也是制备它们的方法及其作为染色和印染纺织品的染料的用途 材料，在其上获得辉煌，深色，蓝色染料，特别是在聚酯材料上。

    Basic dioxazine compounds
    10.
    发明授权
    Basic dioxazine compounds 失效
    基本二恶嗪化合物

    公开(公告)号：US4336377A

    公开(公告)日：1982-06-22

    申请号：US116196

    申请日：1980-01-28

    申请人： Jean-Marie Adam ,  Pierre Galafassi

    发明人： Jean-Marie Adam ,  Pierre Galafassi

    IPC分类号： C09B19/00 ,  C09B19/02 ,  C09B62/44 ,  C09B69/00

    CPC分类号： C09B19/02 ,  C09B69/001

    摘要： Novel dioxazine compounds of the formula ##STR1## in which Z is a basic group, which can be quaternized, Y is an anionic group and X and X.sub.1 independently of one another are identical or different substituents from the category comprising: hydrogen, halogen, CN, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4); substituted or unsubstituted phenyl; NHCOR.sub.1 in which R.sub.1 is alkyl (C.sub.1 -C.sub.4), cycloalkyl, substituted or unsubstituted aryl or a heterocyclic radical; and OCOR.sub.2 in which R.sub.2 is substituted or unsubstituted alkyl (C.sub.1 -C.sub.4) or cycloalkyl; or X and X.sub.1 are the group ##STR2## in which R.sub.4 and R.sub.5 independently of one another are: hydrogen, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4), cycloalkyl or aryl, or R.sub.4 together with R.sub.5 and with the inclusion of the N atom forms a heterocyclic ring, or X and X.sub.1 are the group COOR.sub.6, in which R.sub.6 is hydrogen, substituted or unsubstituted alkyl or cycloalkyl; n is a number from 1 to 4 and m is a number from 0 to 2, with the proviso that the number m is smaller than n, and in which the benzo radicals A and A.sub.1 can be identical or different and can have one or more further substituents, their preparation and their use as dyes, in particular for dyeing and printing natural and regenerated cellulose materials without the addition of salt, are described.

    摘要翻译： 式（Ⅰ）的新型二嗪类化合物，其中Z为碱性基团，其可季铵化，Y为阴离子基团，X和X1彼此独立地为相同或不同的取代基，其类别包括：氢， 卤素，CN，取代或未取代的烷基（C1-C4）; 取代或未取代的苯基; NHCOR1，其中R1是烷基（C1-C4），环烷基，取代或未取代的芳基或杂环基; 和OCOR2，其中R2是取代或未取代的烷基（C1-C4）或环烷基; 或者X和X 1是其中R 4和R 5彼此独立的基团是：氢，取代或未取代的烷基（C 1 -C 4），环烷基或芳基，或R 4与R 5一起并包括N原子 形成杂环，或X和X 1为COOR 6基团，其中R 6为氢，取代或未取代的烷基或环烷基; n是1至4的数，m是0至2的数，条件是数m小于n，其中苯并基A和A1可以相同或不同，并且可以具有一个或多个 描述了进一步的取代基，它们的制备及其作为染料的用途，特别是用于染色和印刷天然和再生纤维素材料而不添加盐的用途。