公开(公告)号：US5139920A

公开(公告)日：1992-08-18

申请号：US724448

申请日：1991-07-03

申请人： Katsumi Hayashi ,  Morio Yagihara ,  Shinji Ueda ,  Yoshihiro Fujita ,  Toshihiko Maekawa ,  Kiyoshi Morimoto

发明人： Katsumi Hayashi ,  Morio Yagihara ,  Shinji Ueda ,  Yoshihiro Fujita ,  Toshihiko Maekawa ,  Kiyoshi Morimoto

IPC分类号： G03C5/42

CPC分类号： G03C5/42

摘要： A reducer and a method for conducting dot etching processing using the reducer, the reducer comprising (1) an amino polycarboxylic acid ferric chelate compound having an oxidation-reduction potential of -100 mV or above, (2) a complexing agent, and (3) at least one member of the compounds represented by the following general formulae (IA) to (VIIA). ##STR1## All symbols are defined in the specification.

摘要翻译： 一种还原剂和使用该还原剂进行点蚀处理的方法，所述还原剂包含（1）氧化还原电位为-100mV以上的氨基多元羧酸铁螯合物，（2）络合剂和（3 ）由以下通式（IA）至（VIIA）表示的化合物中的至少一个成员。 （VIIA）R1ASR1A（IAA）R1ASSR6A（IIA）（IIIA）（IVA）（VA）（VIA）（VIIA）所有符号在本说明书中定义。

公开(公告)号：USRE33964E

公开(公告)日：1992-06-16

申请号：US581630

申请日：1990-09-11

申请人： Takatoshi Ishikawa ,  Hiroshi Fujimoto ,  Nobutaka Ohki ,  Morio Yagihara

发明人： Takatoshi Ishikawa ,  Hiroshi Fujimoto ,  Nobutaka Ohki ,  Morio Yagihara

IPC分类号： G03C7/413

CPC分类号： G03C7/413

摘要： A method of processing a silver halide color photographic material in which the color developer used comprises an aromatic primary amine color developing agent and a compound of formula: ##STR1## wherein X represents a trivalent group necessary to complete a condensed ring;R.sup.1 and R.sup.2 each represents an alkylene group, an arylene group, an alkenylene group, or an aralkylene group;and, if desired, does not contain a substantial amount of benzyl alcohol to achieve improved stability and color developability of the color developer and a reduction of fog generation in the running development process.

公开(公告)号：US5030542A

公开(公告)日：1991-07-09

申请号：US385509

申请日：1989-07-27

申请人： Koichi Nakamura ,  Morio Yagihara

发明人： Koichi Nakamura ,  Morio Yagihara

IPC分类号： C07D233/84 ,  C07D249/12 ,  G03C1/06 ,  G03F7/004 ,  G03F7/028 ,  G03F7/06

CPC分类号： G03C1/061 ,  G03F7/0285

摘要： A light-sensitive material which comprises a light-sensitive layer and a support is disclosed. The light-sensitive layer contains silver halid grains, at least two hydrazine derivatives and a polymerizable compounds. One hydrazine derivative has the following formula [I]: ##STR1## in which one of R.sup.1 and R.sup.2 is hydrogen, and the other is hydrogen, an alkylsulfonyl group, an arylsulfonyl group or an acyl group; R.sup.3 is an aliphatic group, an aromatic group or a heterocyclic group; R.sup.4 is hydrogen, an alkyl group, an aralkyl group, an aryl group, an alkoxy group, an aryloxy group, amino or carbamoyl; at least one hydrogen atom contained in R.sup.3 or R.sup.4 is replaced with a group capable of being adsorbed on silver halide grains; G is carbonyl, sulfonyl, sulfinyl, ##STR2## (R.sup.5 has the same meanings as for R.sup.4); and each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and G may have one or more substituent groups. The hydrazine derivative having the formula [I] is adsorbed on the silver halide grains in an amount of 5.times.10.sup.-6 to 5.times.10.sup.-2 mole based on 1 mole of the silver halide grains. The other hydrazine derivative functions as a reducing agent.

摘要翻译： 公开了一种包含光敏层和载体的感光材料。 感光层含有卤化银颗粒，至少两种肼衍生物和可聚合化合物。 一种肼衍生物具有下式[Ⅰ]：其中R 1和R 2中的一个为氢，另一个为氢，烷基磺酰基，芳基磺酰基或酰基; R3是脂族基，芳基或杂环基; R4是氢，烷基，芳烷基，芳基，烷氧基，芳氧基，氨基或氨基甲酰基; R3或R4中所含的至少一个氢原子被能够吸附在卤化银颗粒上的基团所取代; G是羰基，磺酰基，亚磺酰基，（R 5具有与R 4相同的含义）。 R 1，R 2，R 3，R 4，R 5和G中的每一个可以具有一个或多个取代基。 基于1摩尔卤化银颗粒，具有式[I]的肼衍生物以5×10-6至5×10-2摩尔的量吸附在卤化银颗粒上。 另一肼衍生物用作还原剂。

公开(公告)号：US4985348A

公开(公告)日：1991-01-15

申请号：US306139

申请日：1989-02-06

申请人： Mitsunori Hirano ,  Masato Hirano ,  Morio Yagihara ,  Hisashi Okada

发明人： Mitsunori Hirano ,  Masato Hirano ,  Morio Yagihara ,  Hisashi Okada

IPC分类号： G03C5/26 ,  C07D285/12 ,  C07D285/135 ,  G03C5/305

CPC分类号： C07D285/135 ,  G03C5/305

摘要： A process for development-processing a black-and-white silver halide light-sensitive material is disclosed, which comprises using a developer containing at least one compound represented by formulae (I) and (II): ##STR1## wherein R.sub.1 and R.sub.2 each represents hydrogen atom, an alkyl group or an aryl group;M represents hydrogen atom, an alkali metal atom, an alkaline earth metal atom, a quaternary ammonium salt, a quaternary phosphonium salt, an amidino group or a group capable of being converted to hydrogen or an alkali metal atom under alkaline conditions;n represents an integer of 1 or more; andZ.sup..crclbar. represents an anion.

公开(公告)号：US4950578A

公开(公告)日：1990-08-21

申请号：US381209

申请日：1989-07-18

申请人： Morio Yagihara ,  Kazunobu Katoh

发明人： Morio Yagihara ,  Kazunobu Katoh

IPC分类号： G03C1/06 ,  G03C1/485 ,  G03C8/00

CPC分类号： G03C1/48561 ,  G03C1/061

摘要： A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloid layers, wherein at least one of said silver halide photographic emulsion layers and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represent a hydrogen atom and the other represents a hydrogen atom, a sulfonyl group or an acyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group, a ##STR3## group, or an iminomethylene group; L.sub.1 represents a bivalent group; X.sub.1 represents --O-- or an ##STR4## group wherein R.sub.4 is hydrogen, an alkyl group or an aryl group; Y.sub.1 represents ##STR5## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, a heterocyclic group, --OR.sub.5 or --NR.sub.5 R.sub.6 wherein R.sub.5 is an aliphatic group, an aromatic group or a heterocyclic group, and R.sub.6 is a hydrogen atom, an liphatic group, an aromatic group or a heterocyclic group; and R.sub.3 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aralkyl group, an aryloxy group, a hydrazino group or an amino group.

摘要翻译： 公开了一种卤化银照相材料，其包括其上具有卤化银照相乳剂层和其它亲水胶体层中的至少一种的载体，其中所述卤化银照相乳剂层和其它亲水胶体层中的至少一种含有式 （I）：其中A 1和A 2中的至少一个表示氢原子，另一个表示氢原子，磺酰基或酰基; G 1表示羰基，磺酰基，磺氧基，基团，基团或亚氨基亚甲基基团; L1表示二价基团; X1表示-O-或其中R4为氢，烷基或芳基的基团; Y1表示R1和R2各自表示脂族基，芳基，杂环基，-OR5或-NR5R6，其中R5是脂族基，芳族基或杂环基，R6是氢原子， 脂族基，芳基或杂环基; R 3表示氢原子，烷基，芳基，烷氧基，芳烷基，芳氧基，肼基或氨基。

公开(公告)号：US4801516A

公开(公告)日：1989-01-31

申请号：US66022

申请日：1987-06-24

申请人： Takatoshi Ishikawa ,  Morio Yagihara

发明人： Takatoshi Ishikawa ,  Morio Yagihara

IPC分类号： G03C7/30 ,  G03C1/035 ,  G03C7/392 ,  G03C7/407 ,  G03C7/413

CPC分类号： G03C7/413

摘要： There is provided a method of processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific hydroxylamine compound. According to this method the stability of a color developer is improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened.

摘要翻译： 提供了一种处理卤化银彩色照相材料的方法，其包括用含有芳族伯胺显色剂和特定羟胺化合物的显色剂处理卤化银彩色照相材料。 根据该方法，改善了彩色显影剂的稳定性，从而减少了连续处理中增加的雾化问题，缩短了处理时间。

公开(公告)号：US4294918A

公开(公告)日：1981-10-13

申请号：US168917

申请日：1980-07-14

申请人： Morio Yagihara ,  Yukio Yokota

发明人： Morio Yagihara ,  Yukio Yokota

IPC分类号： G03C7/34 ,  C09B53/00 ,  C09B55/00 ,  G03C7/305 ,  G03C1/40

CPC分类号： G03C7/30523

摘要： A color photographic silver halide light-sensitive material is described containing a colorless photographic cyan color-forming coupler having, in a position for coupling with the oxidation product of an aromatic primary amine developing agent, as a coupling-off group, at least one alkoxy group substituted with a sulfinyl group represented by the formula (I)-O-R-SO-R.sub.1 (I)wherein R represents a saturated or unsaturated, divalent aliphatic group which may be straight or branched chain and may be substituted; and R.sub.1 represents a substituted or unsubstituted straight or branched chain alkyl group, an alkenyl group, an aralkyl group, an aralkenyl group, a cycloalkyl group, an aryl group or a heterocyclic group; and said heterocyclic group being connected with a sulfinyl group on the position of a carbon atom of the heterocyclic group.

摘要翻译： 描述了一种彩色照相卤化银感光材料，其含有无色摄影青色成色剂，其在与芳族伯胺显影剂的氧化产物偶联的位置作为偶联离去基团，至少一个烷氧基 用式（I）-OR-SO-R 1（I）表示的亚磺酰基取代的基团，其中R表示饱和或不饱和的二价脂族基团，其可以是直链或支链并且可以被取代; R 1表示取代或未取代的直链或支链烷基，烯基，芳烷基，芳烯基，环烷基，芳基或杂环基; 并且所述杂环基与杂环基的碳原子的位置上的亚磺酰基连接。

公开(公告)号：US4187110A

公开(公告)日：1980-02-05

申请号：US858225

申请日：1977-12-07

申请人： Morio Yagihara ,  Mitsugu Tanaka ,  Takeshi Hirose ,  Toshiaki Aono

发明人： Morio Yagihara ,  Mitsugu Tanaka ,  Takeshi Hirose ,  Toshiaki Aono

IPC分类号： G03C7/26 ,  C07C67/00 ,  C07C301/00 ,  C07C309/72 ,  C07C313/00 ,  C07C317/14 ,  C07C317/24 ,  C07C317/28 ,  C07C317/44 ,  C07C323/22 ,  C07C323/52 ,  C07C323/56 ,  C07C323/66 ,  C07C323/67 ,  C07D249/12 ,  C07D249/18 ,  C07D257/04 ,  C07D417/12 ,  C07D417/14 ,  C07D487/04 ,  G03C1/04 ,  G03C7/305 ,  G03C7/32 ,  G03C1/06

CPC分类号： C07D257/04 ,  C07C205/45 ,  G03C7/305 ,  G03C7/30535 ,  Y10S430/158

摘要： A silver halide photographic light-sensitive material containing a development inhibitor releasing compound, which is capable of forming a substantially colorless product, and which is represented by the following general formula (I): ##STR1## wherein X represents ##STR2## --SO.sub.2 R.sub.1, --SO.sub.2 OR.sub.1, --SO.sub.2 NH.sub.2, --SO.sub.2 NHR.sub.1, --SO.sub.2 N(R.sub.1).sub.2, --CN, --N.sup.+ (R.sub.1).sub.3 or ##STR3## R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.1 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; R represents an aromatic group substituted with at least one of a nitro group, an acyl group, an alkoxycarbonyl group, a cyano group, a sulfamoyl group, a carbamoyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkoxysulfonyl group and an aryloxysulfonyl group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a developing agent to provide an arylmercapto compound, a heterocyclic mercapto compound, a triazole compound, a benzotriazole compound or a naphthotriazole compound which has a development inhibiting effect.

摘要翻译： 含有显影抑制剂释放化合物的卤化银照相感光材料，其能够形成基本上无色的产物，并且由以下通式（I）表示：其中X表示 -SO2R1，-SO2OR1，-SO2NH2，-SO2NHR1，-SO2N（R1）2，-CN，-N +（R1）3或R1表示脂族基团，芳香族基团或杂环基团， 可以组合并表示与其连接的氮原子一起形成含氮杂环基所需的原子团; R表示被硝基，酰基，烷氧基羰基，氰基，氨磺酰基，氨基甲酰基，芳氧基羰基，烷基磺酰基，芳基磺酰基，烷氧基磺酰基中的至少一种取代的芳基 和芳氧基磺酰基; Y表示与显影剂的氧化物反应后能够从通式（I）表示的化合物中释放的基团，提供芳基巯基化合物，杂环巯基化合物，三唑化合物，苯并三唑化合物或 萘并三唑化合物，其具有显影抑制作用。

公开(公告)号：US4157916A

公开(公告)日：1979-06-12

申请号：US815407

申请日：1977-07-13

申请人： Morio Yagihara ,  Mitsugu Tanaka ,  Toshiaki Aono ,  Takeshi Hirose

发明人： Morio Yagihara ,  Mitsugu Tanaka ,  Toshiaki Aono ,  Takeshi Hirose

IPC分类号： G03C7/26 ,  C07D249/18 ,  C07D249/22 ,  C07D487/04 ,  G03C7/305 ,  G03C7/00 ,  G03C1/76 ,  G03C5/30

CPC分类号： C07D487/04 ,  C07D249/18 ,  C07D249/22 ,  G03C7/305 ,  Y10S430/158

摘要： A silver halide photographic light-sensitive material containing a novel development inhibitor releasing coupler compound, capable of forming a substantially colorless product, represented by the following general formula (I): ##STR1## wherein R represents ##STR2## X represents ##STR3## --SO.sub.2 R.sub.2, --SO.sub.2 OR.sub.2, --SO.sub.2 N(R.sub.2).sub.2, --SO.sub.2 NHR.sub.2, --CN, --N.sup.+ (R.sub.2).sub.3 or ##STR4## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.2 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a color developing agent to provide a compound which has a development inhibiting effect and having a triazole ring bonded to the carbon atom through the nitrogen atom at the 1-position thereof.

摘要翻译： 含有下述通式（I）表示的能够形成基本无色的产物的新型显影抑制剂释放成色剂化合物的卤化银照相感光材料：其中R表示X表示< 图像> -SO 2 R 2，-SO 2 OR 2，-SO 2 N（R 2）2，-SO 2 NHR 2，-CN，-N +（R 2）3或R 1和R 2各自表示脂族基，芳基或杂环基， R2基团可以组合并且表示与它们所连接的氮原子一起形成含氮杂环基所需的原子团; Y表示与彩色显影剂的氧化物反应后能够从由通式（I）表示的化合物释放的基团，提供具有显影抑制作用的化合物，并且具有与碳键合的三唑环 原子通过其1位上的氮原子。

公开(公告)号：US06824948B1

公开(公告)日：2004-11-30

申请号：US09759362

申请日：2001-01-16

申请人： Toshiaki Aoai ,  Yutaka Adegawa ,  Morio Yagihara

发明人： Toshiaki Aoai ,  Yutaka Adegawa ,  Morio Yagihara

IPC分类号： G03F7004

CPC分类号： G03F7/0045 ,  G03F7/038

摘要： A negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B) a resin which is insoluble in water and soluble in an alkali aqueous solution, (C) a crosslinking agent causing crosslinking with the resin of component (B) by the action of an acid, and (D) a compound having at least one unsaturated bond capable of being polymerized by an acid and/or a radical, and a negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B′) a resin having at least one unsaturated bond polymerizable by an acid and/or an alkali, which is insoluble in water but soluble in an alkali aqueous solution, and (C) a crosslinking agent causing crosslinking with the resin (B′) by the action of an acid are disclosed.

摘要翻译： 一种用于电子束或X射线的负性抗蚀剂组合物，包括（A）通过电子束或X射线的照射产生酸和/或自由基的化合物，（B）不溶于水和可溶的树脂 在碱性水溶液中，（C）通过酸的作用与成分（B）的树脂交联的交联剂，（D）具有至少一个能够被酸和/ 或用于电子束或X射线的负性抗蚀剂组合物，其包含（A）通过照射电子束或X射线产生酸和/或自由基的化合物，（B'）具有 至少一个不溶于水但可溶于碱性水溶液的酸和/或碱可聚合的不饱和键，和（C）通过酸的作用与树脂（B'）交联的交联剂 被披露。