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公开(公告)号：US06657013B2
公开(公告)日：2003-12-02
申请号：US09952010
申请日：2001-09-11
IPC分类号： C08L2712
摘要： A composition that includes a fluoropolymer comprising interpolymerized units derived from a cure site monomer comprising a nitrile group; and (b) a catalyst composition comprising a compound having the formula R1C(OR2)═NH, and salts thereof, where R1 and R2, independently, are a substituted or unsubstituted alkyl, aryl, aralkyl, or alkenyl group, as well as a method for curing this composition and cured articles prepared from this composition.
摘要翻译： 一种组合物，其包含含有衍生自包含腈基的固化位点单体的共聚单元的含氟聚合物; 和（b）包含式R 1 C（OR 2）= NH的化合物及其盐的催化剂组合物，其中R 1和R 2独立地是取代或未取代的烷基 ，芳基，芳烷基或烯基，以及用于固化该组合物的方法和由该组合物制备的固化物。
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公开(公告)号：US5301254A
公开(公告)日：1994-04-05
申请号：US768778
申请日：1991-11-07
IPC分类号： C08F16/14 , C08F214/26 , C08F216/14 , C08L27/18 , G02B1/04 , G02B6/00
CPC分类号： C08F216/14 , C08F214/262 , G02B1/045
摘要： A transparent thermoplastic molding compound consisting of 40 to 90% by weight of units derived from tetrafluoroethylene, and 60 to 10% by weight of units derived from compounds of formula I or II:CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.m --(CF.sub.2).sub.n --CF.sub.3 (I)CF.sub.2 .dbd.CF--O--(CF.sub.2 --CF(CF.sub.3)--O).sub.p --(CF.sub.2).sub.q --COO--R (II)is particularly suitable for manufacturing the sheath of beam waveguides whose core has a higher transparency than polymethyl methacrylate.
摘要翻译： PCT No.PCT / EP90 / 00585第 371日期1991年11月7日 102（e）1991年11月7日PCT PCT 1990年4月13日提交PCT公布。 出版物WO90 / 12043 日本1990年10月18日。由40〜90重量％衍生自四氟乙烯的单元和60〜10重量％衍生自式I或II化合物的单元组成的透明热塑性模塑料：CF 2 = CF-O- （CF2-CF（CF3）-O）m-（CF2）n-CF3（I）CF2 = CF-O-（CF2-CF（CF3）-O）对 - （CF2）q-COO-R 特别适用于制造其核心具有比聚甲基丙烯酸甲酯更高透明度的光束波导鞘。
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公开(公告)号：US09711816B2
公开(公告)日：2017-07-18
申请号：US14234464
申请日：2012-07-27
IPC分类号： C08F214/18 , H01M8/102 , C08L41/00 , H01M8/1032 , H01M8/1039 , H01M8/1023 , H01M8/1072 , H01M8/1086 , C08J5/22 , H01M8/1051
CPC分类号： H01M8/102 , C08F214/18 , C08J5/2237 , C08L41/00 , H01M8/1023 , H01M8/1032 , H01M8/1039 , H01M8/1051 , H01M8/1072 , H01M8/109 , H01M2300/0082 , Y02P70/56
摘要： Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX1X2═CX3[(CX4X5)w—O—R1—SO2Y] where X1, X2, X3, X4, and X5 are independently selected from H, Cl, or F; w is 0 or 1; R1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and (c) a polyfunctional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers.
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74.发明授权Melt-processible fluoropolymers having long-chain branches, methods of preparing them and uses thereof 有权具有长链分支的可熔融加成的含氟聚合物，其制备方法和用途公开(公告)号：US08969500B2
公开(公告)日：2015-03-03
申请号：US12597022
申请日：2008-04-24
申请人： Klaus Hintzer , Harald Kaspar
发明人： Klaus Hintzer , Harald Kaspar
IPC分类号： C08F216/12 , C08F214/18 , C08F236/20 , C08K5/09 , C08K5/42
CPC分类号： C08F214/18 , C08F236/20 , C08K5/09 , C08K5/42
摘要： The present disclosure describes fluoropolymers having long chain branches and methods of making these fluoropolymers. These fluoropolymers may have improved melt processing properties. Shaped articles containing these fluoropolymers are also provided.
摘要翻译： 本公开描述了具有长链分支的含氟聚合物和制备这些含氟聚合物的方法。 这些含氟聚合物可具有改进的熔融加工性能。 还提供了含有这些含氟聚合物的成型制品。
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公开(公告)号：US08809580B2
公开(公告)日：2014-08-19
申请号：US13497173
申请日：2010-10-21
申请人： Klaus Hintzer , Dennis E. Vogel , Miguel A. Guerra , Jolanta Ignatowska , Gerd-Volker Röschenthaler , Oleg Shyshkov , Kim M. Vogel , Tilman C. Zipplies
发明人： Klaus Hintzer , Dennis E. Vogel , Miguel A. Guerra , Jolanta Ignatowska , Gerd-Volker Röschenthaler , Oleg Shyshkov , Kim M. Vogel , Tilman C. Zipplies
IPC分类号： C07C51/27
CPC分类号： C07C51/27 , C07C53/21 , C07C59/135
摘要： A method for preparing fluorinated carboxylic acids and theirs salts is described comprising subjecting a fluorinated to at least one first and at least one second oxidizing agent to produce a highly fluorinated carboxylic acid or their salts. The first oxidizing agent is a compound that can be converted, by action of the second oxidizing agent, into a reactive species capable of oxidizing the fluorinated alcohol.
摘要翻译： 描述了制备氟化羧酸及其盐的方法，其包括使氟化至少一种第一和至少一种第二氧化剂以产生高度氟化的羧酸或其盐。 第一氧化剂是可以通过第二氧化剂的作用转化为能够氧化氟化醇的反应性物质的化合物。
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公开(公告)号：US08710257B2
公开(公告)日：2014-04-29
申请号：US13511939
申请日：2010-11-18
申请人： Klaus Hintzer , Tilman C. Zipplies , Oleg Shyshkov
发明人： Klaus Hintzer , Tilman C. Zipplies , Oleg Shyshkov
IPC分类号： C07C69/66 , C07C59/135 , C07C235/06
CPC分类号： C07C51/353 , C07C67/347 , C07C231/12 , C07C53/21 , C07C69/708 , C07C235/06
摘要： A method for preparing highly fluorinated carboxylic acids and theirs salts and the precursors thereof.
摘要翻译： 一种制备高度氟化的羧酸及其盐及其前体的方法。
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公开(公告)号：US20130281607A1
公开(公告)日：2013-10-24
申请号：US13995615
申请日：2011-12-21
申请人： Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
发明人： Klaus Hintzer , Michael Juergens , Gunther J. Kaempf , Harald Kaspar , Kai H. Lochhaas , Andre Streiter , Oleg Shyshkov , Tilman C. Zipplies , Herbert Koenigsmann
IPC分类号： C25B3/08
CPC分类号： C08F6/003 , C02F1/26 , C02F1/461 , C02F2001/46138 , C02F2001/46147 , C08F2/10 , C08F2/20 , C08F14/08 , C08F14/18 , C08F2800/10 , Y02P20/582 , C08F2/24
摘要： Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.
摘要翻译： 本文描述的是包含氟化单体的水性聚合反应产物的组合物，其中聚合反应开始于（i）在不存在氟化乳化剂的情况下，并且由此在聚合过程中不加入氟化乳化剂，或（ii）在氟化乳化剂存在下 选自：[Rf-OL-COO-] i Xi +（I）其中L表示直链或支链，非氟化，部分氟化或完全氟化的亚烷基，Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团，X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺，并且基本上不含低分子量氟代有机化合物及其方法。
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78.发明申请PEROXIDE CURABLE FLUOROELASTOMERS CONTAINING MODIFIERS AND IODINE OR BROMINE ENDGROUPS 有权含有改性剂和碘或溴的过氧化物可固化荧光体公开(公告)号：US20130129954A1
公开(公告)日：2013-05-23
申请号：US13813691
申请日：2011-07-26
IPC分类号： C08F14/18
CPC分类号： C08F14/18 , C08F214/18 , C08F214/184 , C08F214/222 , C08F214/262 , C08F214/28 , Y10T428/139
摘要： Provided are curable fluoroelastomers. Further provided are methods of making the curable elastomers, curable fluoroelastomer compositions and methods of making them and shaped articles made from the curable fluoroelastomer compositions.
摘要翻译： 提供可固化的含氟弹性体。 进一步提供制备可固化弹性体，可固化含氟弹性体组合物及其制备方法和由可固化含氟弹性体组合物制成的成型制品的方法。
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79.发明申请POLYMERIZABLE COMPOSITIONS FREE OF ORGANIC EMULSIFIER AND POLYMERS AND METHODS OF MAKING THEREOF 审中-公开无机有机聚合物和聚合物的可聚合组合物及其制备方法公开(公告)号：US20130090441A1
公开(公告)日：2013-04-11
申请号：US13704064
申请日：2011-06-09
申请人： Jimmie R. Baran, JR. , Duane D. Fansler , Klaus Hintzer , William J. Hunt , Harald Kaspar , Tilman C. Zipplies
发明人： Jimmie R. Baran, JR. , Duane D. Fansler , Klaus Hintzer , William J. Hunt , Harald Kaspar , Tilman C. Zipplies
IPC分类号： C08F2/10
CPC分类号： C08F2/10 , C08F2/20 , C08F2/22 , C08K3/36 , C08K2201/011
摘要： Described herein is a polymerizable composition substantially free of an organic emulsifier, methods of making, and articles thereof. The polymerizable composition comprises: a continuous phase; a polymerizable monomer; an initiator; and inorganic nanoparticles, wherein the inorganic nanoparticles are substantially free of groups that will copolymerize with the polymerizable monomer.
摘要翻译： 本文描述的是基本上不含有机乳化剂，制备方法及其制品的可聚合组合物。 可聚合组合物包括：连续相; 可聚合单体; 发起者 和无机纳米颗粒，其中无机纳米颗粒基本上不含可与可聚合单体共聚的基团。
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80.发明申请公开(公告)号：US20110245520A1
公开(公告)日：2011-10-06
申请号：US13133734
申请日：2009-11-24
申请人： Tilman Zipplies , Klaus Hintzer , Oleg Shyshkov
发明人： Tilman Zipplies , Klaus Hintzer , Oleg Shyshkov
IPC分类号： C07C247/04 , C07C51/08
CPC分类号： C07C255/13 , C07C51/08 , C07C59/135 , C07C67/08 , C07C69/708 , C07C247/04 , C07C253/14
摘要： A method for preparing saturated partially fluorinated alkoxy carboxylic acids or salts thereof by treating a compound: (II), where Rf represents a fluorinated, linear or branched alkyl residue interruptible by one or more oxygen atoms, n is 0 or 1, with a Z-anion in a reaction medium comprising water and an organic solvent, where the Z-anion is selected from CN—, SCN— and OCN— or combinations thereof. A method of making partially fluorinated ethers of the general formula (I) wherein Rf is defined as above, n is 0 or 1, and Z is nitrile (—CN), azide (—N3), thiocyanate (—SCN) or cyanate (—OCN) group, said method comprising treating a fluorinated olefin of the general formula (II) wherein the Z-anion is CN—, OCN—, SCN— or N3−. A compound of the general formula (I) as previously described where Z is selected from SCN, OCN and N3.
摘要翻译： 通过处理化合物（II）制备饱和部分氟化的烷氧基羧酸或其盐的方法，其中Rf表示可被一个或多个氧原子中断的氟化的直链或支链烷基，n为0或1，Z为 阴离子在包含水和有机溶剂的反应介质中，其中Z-阴离子选自CN-，SCN-和OCN-或其组合。 制备通式（I）的部分氟化醚的方法，其中Rf定义如上，n为0或1，Z为腈（-CN），叠氮化物（-N 3），硫氰酸酯（-SCN）或氰酸酯 -OCN）基团，所述方法包括处理通式（II）的氟化烯烃，其中Z-阴离子是CN-，OCN-，SCN-或N 3 - 。 其中Z选自SCN，OCN和N 3，如前所述的通式（I）的化合物。
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