公开(公告)号：US20060093534A1

公开(公告)日：2006-05-04

申请号：US11204385

申请日：2005-08-16

申请人： Kenichi Okada ,  Shintaro Honjo ,  Susumu Okino ,  Toru Takashina ,  Masashi Yoshikawa ,  Tsuyoshi Oishi

发明人： Kenichi Okada ,  Shintaro Honjo ,  Susumu Okino ,  Toru Takashina ,  Masashi Yoshikawa ,  Tsuyoshi Oishi

IPC分类号： B01D50/00 ,  B01D53/50

CPC分类号： B01D53/185 ,  B01D53/504 ,  B01D2251/404 ,  B01D2257/302

摘要： A liquid column type exhaust gas treatment apparatus comprising a spray header (2) for injecting an absorbing solution upward in an absorption tower (1), wherein exhaust gas introduced from a lower part of the absorption tower (1) and the absorbing solution injected from the spray header (2) are brought into gas-liquid contact with each other, by which desulfurization of exhaust gas is accomplished, characterized in that drift preventing plates (5a and 5b) are provided in a liquid top portion of a liquid column (6) formed by the absorbing solution and/or at the installation position of the spray header (2).

摘要翻译： 一种液柱式废气处理装置，包括：用于在吸收塔（1）中向上注入吸收溶液的喷雾头（2），其中从吸收塔（1）的下部引入的废气和从吸收塔 喷雾集管（2）彼此气液接触，由此实现废气的脱硫，其特征在于，在液柱的液体顶部设置防漂移板（5a和5b） （6）由吸收溶液和/或在喷雾头（2）的安装位置形成。

公开(公告)号：US06740297B2

公开(公告)日：2004-05-25

申请号：US10294204

申请日：2002-11-14

申请人： Taku Shimizu ,  Kazuaki Kimura ,  Kiyoshi Okazoe ,  Atsushi Tatani ,  Naohiko Ukawa ,  Masao Hino ,  Susumu Okino ,  Takashi Haruki ,  Toru Takashina ,  Eiji Ochi

发明人： Taku Shimizu ,  Kazuaki Kimura ,  Kiyoshi Okazoe ,  Atsushi Tatani ,  Naohiko Ukawa ,  Masao Hino ,  Susumu Okino ,  Takashi Haruki ,  Toru Takashina ,  Eiji Ochi

IPC分类号： B01J808

CPC分类号： C10M173/02 ,  B01D53/46 ,  B01D53/501 ,  C10M2215/042 ,  C10M2229/045 ,  C10M2229/046 ,  C10N2220/13 ,  C10N2240/58 ,  F23J15/003 ,  F23J15/022 ,  F23J2215/20 ,  F23J2219/50

摘要： Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.

公开(公告)号：US6149713A

公开(公告)日：2000-11-21

申请号：US191958

申请日：1998-11-13

申请人： Eiji Ochi ,  Takeo Shinoda ,  Toru Takashina ,  Susumu Okino

发明人： Eiji Ochi ,  Takeo Shinoda ,  Toru Takashina ,  Susumu Okino

IPC分类号： F23J15/00 ,  B01D53/34 ,  B01D53/50 ,  B01D53/77 ,  B03C3/01 ,  B03C3/014 ,  B03C3/019 ,  B03C3/02 ,  F23J15/02 ,  B03C3/017

CPC分类号： F23J15/02 ,  B01D53/508 ,  B03C3/014 ,  B03C3/019 ,  F23J2215/20 ,  F23J2217/102 ,  F23J2219/50

摘要： The dust concentration of the flue gas leaving an electrostatic precipitator and introduced into an absorption tower of a desulfurizer is adjusted to a level of 100 to 500 mg/Nm.sup.3. At the same time, a dust slurry having a higher dust concentration is separated and withdrawn from the slurry within the aforesaid absorption tower, and then subjected to a solid-liquid separation treatment. Thus, solid matter containing dust at a high concentration is extracted and discharged out of the system of the desulfurizer.

摘要翻译： 将离开静电除尘器并引入脱硫器的吸收塔的烟道气的灰尘浓度调节至100至500mg / Nm 3的水平。 同时，将粉尘浓度较高的粉尘浆料从上述吸收塔内的浆料中分离并取出，然后进行固液分离处理。 因此，含有高浓度的灰尘的固体物质被提取出并排出脱硫装置。

公开(公告)号：US6096279A

公开(公告)日：2000-08-01

申请号：US033894

申请日：1998-03-03

申请人： Koichiro Iwashita ,  Kazuaki Kimura ,  Toyoshi Nakagawa ,  Naohiko Ukawa ,  Susumu Okino ,  Kiyoshi Okazoe

发明人： Koichiro Iwashita ,  Kazuaki Kimura ,  Toyoshi Nakagawa ,  Naohiko Ukawa ,  Susumu Okino ,  Kiyoshi Okazoe

IPC分类号： B01D53/14 ,  B01D53/50

CPC分类号： B01D53/508 ,  B01D53/1481

摘要： Flue gas is treated for the presence of SO.sub.3, without resorting to ammonia injection, by adding a powder into the flue gas and subsequently bringing the flue gas into gas-liquid contact with an absorbing fluid, whereby the SO.sub.2 present in the flue gas is removed by absorption into the absorbing fluid. The treatment process may also include introducing the flue gas into a dust collector, whereby dust, including the powder present in the flue gas, is collected, and/or recovering heat from the flue gas by means of a heat exchanger, whereby the flue gas is cooled. A system for treating flue gas is also provided.

摘要翻译： 对烟气进行处理，不用借助氨注入，通过向烟道气中加入粉末，随后使烟道气与吸收液体气液接触，由此除去烟道气中存在的SO2 通过吸收到吸收液中。 处理过程还可以包括将烟道气引入集尘器，由此收集包括烟道气中存在的粉末的粉尘，和/或通过热交换器从烟道气中回收热量，从而烟道气 被冷却。 还提供了一种处理烟气的系统。

公开(公告)号：US6001154A

公开(公告)日：1999-12-14

申请号：US73349

申请日：1998-05-06

申请人： Shinichiro Kotake ,  Kazuaki Kimura ,  Eiji Ochi ,  Toru Takashina ,  Susumu Okino

发明人： Shinichiro Kotake ,  Kazuaki Kimura ,  Eiji Ochi ,  Toru Takashina ,  Susumu Okino

IPC分类号： B01D53/18 ,  B01D53/50 ,  B01D53/77 ,  B01D53/79 ,  B01D47/06

CPC分类号： B01D53/504 ,  B01D53/185

摘要： The present invention provides a gas-liquid contact apparatus which can make the equipment more compact and reduce the cost while achieving high gas-liquid contact efficiency. In the apparatus of the present invention, an oxidation tank (2) is installed in proximity to an absorption tower (1), and an absorbing fluid (3) is stored in this oxidation tank (2). The level H of the absorbing fluid (3) is determined so as to be above the position of nozzles (7), whereby the absorbing fluid is spouted upward from the nozzles (7). Flue gas is introduced into the absorption tower (1) from a flue gas inlet section (8) and made to flow upward at a high velocity, so that the peaks of the spouted streams are raised above level H. The absorbing fluid (3) is caught by catcher device (11) installed at a position above level H, and returned to the oxidation tank (2) through a circulation pipe (12). An air pipe (20) is connected to the circulation pipe (12) so as to suck in air.

摘要翻译： 本发明提供一种气液接触装置，其能够使设备更紧凑，并降低成本，同时实现高气液接触效率。 在本发明的装置中，氧化槽（2）安装在吸收塔（1）的附近，吸收流体（3）被储存在该氧化罐（2）中。 吸收流体（3）的高度H被确定为高于喷嘴（7）的位置，从而吸收流体从喷嘴（7）向上喷出。 烟气从烟道气体入口部分（8）引入吸收塔（1）中并使其高速流动，使得喷射流的峰值升高到高于水平面H.吸收流体（3） 被捕获装置（11）捕获，并且通过循环管（12）返回到氧化罐（2）。 空气管（20）与循环管（12）连接以吸入空气。

公开(公告)号：US5766563A

公开(公告)日：1998-06-16

申请号：US767639

申请日：1996-12-17

申请人： Hiroshi Tanaka ,  Susumu Okino ,  Koosoo Tao

发明人： Hiroshi Tanaka ,  Susumu Okino ,  Koosoo Tao

IPC分类号： B01D53/00 ,  B01D53/32 ,  B01D53/34 ,  B01D53/50 ,  B01D53/77 ,  B01D53/81 ,  B01J19/08 ,  G01N27/18 ,  G01N27/416 ,  G05D7/00

CPC分类号： B01D53/346 ,  B01D53/007 ,  B01D53/32 ,  B01D53/501 ,  B01D53/504 ,  B01J19/085 ,  B01D2259/812 ,  Y10S423/05

摘要： A method of controlling the oxidation of sulfites in a flue gas desulfurization process involves treating the exhaust gas with an absorbing fluid containing a calcium compound and controlling the oxidation of sulfites by regulating oxygen flow into the absorbing fluid. Oxygen flow is controlled by continuously monitoring the oxidation-reduction potential (ORP) of the absorbing fluid relative to the same fluid in a completely oxidized state using a detector with a plurality of fluid tanks, one of which functions as a reference tank at any particular time. The fully oxidized reference tank is periodically switched, reducing adherence of oxidizing substances to the ORP electrodes, resulting in more accurate measurements and reduced chemical oxygen demand of the waste water.

摘要翻译： 在烟道气脱硫工艺中控制亚硫酸盐氧化的方法包括用含有钙化合物的吸收液处理废气，并通过调节进入吸收流体的氧气来控制亚硫酸盐的氧化。 通过使用具有多个流体罐的检测器连续监测吸收流体相对于相同流体在完全氧化状态下的氧化还原电位（ORP）来控制氧气流，其中一个流体罐在任何特定的位置上用作参考罐 时间。 周期性地切换完全氧化的参比罐，减少氧化物质对ORP电极的粘附，从而进行更精确的测量并减少废水的化学需氧量。

公开(公告)号：US5295400A

公开(公告)日：1994-03-22

申请号：US779189

申请日：1991-10-22

申请人： Atsushi Tatani ,  Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Tsumoru Nakamura ,  Tokuma Arai ,  Yoshihiro Shiraishi

发明人： Atsushi Tatani ,  Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Tsumoru Nakamura ,  Tokuma Arai ,  Yoshihiro Shiraishi

IPC分类号： G01N1/00 ,  G01N1/10 ,  G01N1/20

CPC分类号： G01N35/1097 ,  G01N1/2035

摘要： A slurry sampling device (3) for sampling a slurry in which solid particles are dispersed has upper and lower blocks (105, 109), and a rotator (102) for collection which is rotatably held between the blocks and has a plurality of through holes (111) each having a volume corresponding to the amount of sample to be collected. The upper and lower blocks are provided with slurry conduits (101, 108) and carrier fluid conduits (107, 110) which can be communicated with the through holes so that slurry and carrier fluid can flow therethrough. Arc-shaped long grooves (113, 114) are provided on portions of the upper and lower blocks where ends of the slurry conduits (101, 108) come into contact with, or are adjacent to, the rotator, so that at least one of the through holes is thereby constantly in contact with the long grooves. In the method for sampling slurry a part of the slurry is pumped (2) from a slurry tank (1) and returned (4) to the slurry tank, and that part of the slurry is sampled intermittently by the sampling device (3) and sent to an analyzer (6) for analysis of the composition of the slurry.

摘要翻译： 用于对其中分散有固体颗粒的浆料进行取样的浆料取样装置（3）具有上下块（105,109）和用于收集的旋转体（102），其被可旋转地保持在块之间并具有多个通孔 （111），每个具有对应于要收集的样品量的体积。 上部和下部块设置有可与通孔连通的浆液管道（101,108）和载体流体管道（107,110），使得浆料和载体流体可以流过其中。 在上部和下部块的部分上设置有弧形的长槽（113,114），其中浆料管道（101,108）的端部与旋转体接触或相邻，使得至少一个 因此通孔与长槽不断地接触。 在采样浆料的方法中，将一部分浆料从浆料罐（1）泵送（2）并返回（4）到浆料罐中，并且该部分浆料被取样装置（3）间歇地取样， 送到分析仪（6），分析浆料的组成。

公开(公告)号：US5266286A

公开(公告)日：1993-11-30

申请号：US895546

申请日：1992-06-08

申请人： Naohiko Ukawa ,  Susumu Okino ,  Kenji Inoue ,  Toshiaki Kinomoto ,  Taku Shimizu

发明人： Naohiko Ukawa ,  Susumu Okino ,  Kenji Inoue ,  Toshiaki Kinomoto ,  Taku Shimizu

IPC分类号： B01D53/50 ,  B01D53/60 ,  B01D53/68 ,  B01D53/70 ,  B01D53/73 ,  B01D53/77 ,  C01B17/00 ,  C01B17/22

CPC分类号： B01D53/501 ,  B01D53/73

摘要： A flue gas desulfurization process for treating flue gases containing SO.sub.2, NO.sub.x, and halogen gases by the wet lime method, in which part of the absorbent liquid is extracted, freed from iodine, and recycled as makeup water to the absorption column.

公开(公告)号：US5192518A

公开(公告)日：1993-03-09

申请号：US701652

申请日：1991-05-16

申请人： Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Masakazu Onizuka ,  Kenji Inoue

发明人： Naohiko Ukawa ,  Susumu Okino ,  Toru Takashina ,  Masakazu Onizuka ,  Kenji Inoue

IPC分类号： B01D47/00 ,  B01D53/50 ,  B01D53/77 ,  B03C1/00 ,  C01F11/46

CPC分类号： C01F11/464 ,  B01D53/501

摘要： For the purposes of solving a problem due to a fly ash and HF in an exhaust gas, maintaining the activity of calcium carbonate as an absorbent, and recovering a high-purity gypsum, there is here provided a method for desulfurizing an exhaust smoke which comprises the steps of leading the exhaust gas containing the fly ash to a gas absorbing step, removing SO.sub.2 and the fly ash from the exhaust gas by the use of an absorbing solution slurry containing calcium carbonate as an absorbent in the gas absorbing step, and blowing air into the absorbing solution slurry circulating through the gas absorbing step to oxidize it and to thereby produce the gypsum, the aforesaid method being characterized by drawing a portion of the absorbing solution slurry therefrom, leading it to a magnetic field to separate and recover the fly ash from the absorbing solution slurry, and then returning, to the gas absorbing step, a portion or all of the absorbing solution slurry from which the fly ash has been separated.

公开(公告)号：US4677077A

公开(公告)日：1987-06-30

申请号：US638574

申请日：1984-08-07

申请人： Masakazu Onizuka ,  Susumu Kono ,  Susumu Okino

发明人： Masakazu Onizuka ,  Susumu Kono ,  Susumu Okino

IPC分类号： B01D53/50 ,  G01N31/00 ,  G01N1/00 ,  G01N33/00 ,  G01N35/00

CPC分类号： B01D53/501 ,  G01N31/00 ,  Y10T436/115831 ,  Y10T436/117497 ,  Y10T436/12 ,  Y10T436/204998 ,  Y10T436/235 ,  Y10T436/25125 ,  Y10T436/25625 ,  Y10T436/25875

摘要： A method for continuously measuring the concentration of CaCO.sub.3 in slurries comprising CaCO.sub.3 is described. The method comprises continuously sampling a given amount of the slurry, feeding the sampled slurry into an agitated continuous reactor container which is isolated from the outside air, keeping the slurry in the reactor container at a temperature of at least 50.degree. C., adding sulfuric acid or hydrochloric acid to adjust the pH to below 4, blowing air into the slurry in the reactor container, withdrawing from the reactor container CO.sub.2, produced by the reaction between CaCO.sub.3 and the acid, by entrainment with the air, and calculating the concentration of CaCO.sub.3 in the slurry from the concentration of CO.sub.2 in the withdrawn gas, the amount of the sampled slurry and the flow rate of the blown air.

摘要翻译： 描述了用于连续测量包含CaCO 3的浆料中CaCO 3浓度的方法。 该方法包括连续取样给定量的浆料，将采样的浆料送入搅拌的连续反应器容器中，该容器与外部空气隔离，将反应器容器中的浆料保持在至少50℃的温度，加入硫酸 酸或盐酸以将pH调节至4以下，将空气吹入反应器容器中的浆料中，通过夹带空气从CaCO 3和酸之间的反应产生的反应容器CO 2中排出，并计算浓度 从抽出的气体中的CO 2浓度的浆料中的CaCO 3，取样浆料的量和吹入空气的流量。