Process for the preparation of cephem compounds
    71.
    发明授权
    Process for the preparation of cephem compounds 有权
    头孢烯化合物的制备方法

    公开(公告)号:US06576761B1

    公开(公告)日:2003-06-10

    申请号:US10049048

    申请日:2002-02-07

    IPC分类号: C07D50122

    CPC分类号: C07D501/00 Y02P20/55

    摘要: 1. A process for preparing a 3-alkenylcephem compound or 3-norcephem compound of the formula (3) characterized in that an alkenyl halide of the formula (2), a nickel catalyst, a metal up to −0.3 (V/SCE) in standard oxidation reduction potential and a compound of a metal having a higher standard oxidation reduction potential than the metal are caused to act on a 3-cephem compound of the formula (1) in a solvent wherein R1 is a hydrogen atom or the like, R2 is a hydrogen atom or the like, R3 is a hydrogen atom or carboxylic acid protective group, and X is a halogen atom or the like, R4—Y  (2) wherein R4 is 1-alkenyl having or not having a substituent, and Y is a halogen atom wherein R1, R2 and R3 are as defined above, and R5 is a hydrogen atom or 1-alkenyl having or not having a substituent.

    摘要翻译: 1.一种制备式(3)的3-链烯基头孢烯化合物或3-诺卡波姆化合物的方法,其特征在于式(2)的烯基卤,镍催化剂,高达-0.3(V / SCE) 在标准氧化还原电位和具有比金属更高的标准氧化还原电位的金属的化合物在R1是氢原子等的溶剂中作用于式(1)的3-头孢烯化合物时,R2 是氢原子等,R 3为氢原子或羧酸保护基,X为卤素原子等,其中,R 4为具有或不具有取代基的1-烯基,Y为卤素原子,R1, R2和R3如上定义,R5是氢原子或具有或不具有取代基的1-烯基。

    Penam derivatives
    72.
    发明授权
    Penam derivatives 失效
    Penam衍生物

    公开(公告)号:US5599925A

    公开(公告)日:1997-02-04

    申请号:US314307

    申请日:1994-09-30

    CPC分类号: C07D499/00 Y02P20/55

    摘要: A penam derivative of the general formula ##STR1## wherein R.sup.1 means hydrogen, halogen, amino or protected amino; R.sup.2 means hydrogen, halogen, lower alkoxy, lower acyl, lower alkyl, hydroxy- or protected hydroxy-substituted lower alkyl, hydroxy or protected hydroxy, or R.sup.1 and R.sup.2 may jointly represent oxo; R.sup.3 means hydrogen or a carboxy-protecting group; R.sup.4 means hydrogen; R.sup.5 means a group of the formula --CH.sub.2 Y where Y means halogen, --N.sub.3, --ONO.sub.2, --OR.sup.6, --OCOR.sup.6, --SCSOR.sup.6, --SCSN(R.sup.6).sub.2, --SR.sup.6, --SO.sub.2 R.sup.6, --NHR.sup.6, --N(R.sup.6).sub.2 or a substituted or unsubstituted nitrogen-containing heterocyclic group having a free valence on nitrogen; R.sup.6 means a lower alkyl, aryl or heterocyclic group which is substituted or unsubstituted; or R.sup.4 and R.sup.5 may jointly represent .dbd.CH.sub.2 ; n means 0, 1 or 2; provided, however, that where R.sup.4 and R.sup.5 jointly represent .dbd.CH.sub.2, n is not equal to 0.

    摘要翻译: 其中R 1表示氢,卤素,氨基或被保护的氨基; R 2表示氢,卤素,低级烷氧基,低级酰基,低级烷基,羟基或保护的羟基取代的低级烷基,羟基或保护的羟基,或者R 1和R 2可以共同表示氧代; R3表示氢或羧基保护基; R4表示氢; R5表示式-CH2Y的基团,其中Y表示卤素,-N3,-ONO2,-OR6,-OCOR6,-SCSOR6,-SCSN(R6)2,-SR6,-SO2R6,-NHR6,-N(R6) 2或在氮上具有游离价的取代或未取代的含氮杂环基; R6表示取代或未取代的低级烷基,芳基或杂环基; 或者R4和R5可以共同表示= CH2; n表示0,1或2; 但是,如果R4和R5共同表示= CH2,则n不等于0。

    Process for producing oxide with higher oxidation than alcohol
    73.
    发明授权
    Process for producing oxide with higher oxidation than alcohol 失效
    生产氧化物高于酒精的氧化物的方法

    公开(公告)号:US06797830B2

    公开(公告)日:2004-09-28

    申请号:US09959844

    申请日:2001-11-28

    IPC分类号: C07C4529

    摘要: The present invention provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound thereon and an oxidative catalyst thereon, and oxidizing the alcohol compound in the presence of an oxidizing agent, giving an oxide higher in oxidizing degree than the alcohol compound, and also provides a process for producing an oxide from an alcohol compound, the process comprising the steps of causing silica gel to carry the alcohol compound, and subjecting the alcohol compound to an electrolytic oxidation, giving an oxide higher in oxidizing degree than the alcohol compound.

    摘要翻译: 本发明提供一种由醇化合物制备氧化物的方法,该方法包括以下步骤:使硅胶在其上载有醇化合物及其上的氧化催化剂,并在氧化剂存在下氧化醇化合物,得到 氧化度高于醇化合物的氧化物,还提供了由醇化合物制造氧化物的方法,该方法包括使硅胶携带醇化合物,并对醇化合物进行电解氧化, 产生氧化度高于醇化合物的氧化物。

    Process for preparing examethylenecephem compounds
    74.
    发明授权
    Process for preparing examethylenecephem compounds 失效
    制备二亚甲基化合物的方法

    公开(公告)号:US5470972A

    公开(公告)日:1995-11-28

    申请号:US129130

    申请日:1993-10-14

    摘要: The object of the invention is to provide a .beta.-lactam compound and a 2-substituted methyl-3-cephem compound, both of which are of value as intermediates for the synthesis of cephem antibiotics.The .beta.-lactam compound of the invention may be represented by the general formula ##STR1## wherein R.sup.1 represents a protected amino group, for instance; R.sup.2 represents hydrogen for instance; R.sup.3 represents hydrogen or a carboxy-protecting group; R.sup.4 represents an aryl group which may be substituted; R.sup.5 represents an alkenyl group which may be substituted, for instance. The 2-substituted methyl-3-cephem compound of the invention may be represented by the general formula ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above; R.sup.6 represents an aryl group which may be substituted.

    摘要翻译: 本发明的目的是提供β-内酰胺化合物和2-取代的甲基-3-头孢烯化合物,它们都作为合成头孢类抗生素的中间体。 本发明的β-内酰胺化合物可以由通式为“IMAGE”表示,其中R 1表示被保护的氨基; R2代表氢; R3表示氢或羧基保护基; R4代表可被取代的芳基; R5表示例如可被取代的烯基。 本发明的2-取代的甲基-3-头孢烯化合物可以由通式(IMAGE)表示,其中R 1,R 2和R 3如上定义; R6表示可以被取代的芳基。

    Process for production of phosphine derivative from phosphine oxide derivative
    76.
    发明授权
    Process for production of phosphine derivative from phosphine oxide derivative 失效
    由氧化膦衍生物制备膦衍生物的方法

    公开(公告)号:US08426629B2

    公开(公告)日:2013-04-23

    申请号:US12991931

    申请日:2009-05-14

    IPC分类号: C07F9/28

    摘要: Disclosed is a process for producing a phosphine derivative from a phosphine oxide derivative, which comprises the following steps: (I) mixing a phosphine oxide derivative represented by formula (1) with a chlorinating agent in a polar organic solvent to cause the reaction between these components; and (II-1) adding a salt of a metal having an ionization tendency equal to or lower than that of aluminum to the reaction mixture and carrying out the reductive reaction in the presence of aluminum or (II-2) subjecting the reaction mixture to electrolytic reduction, thereby producing a phosphine derivative represented by formula (2). ArnR3-nP═O (1) ArnR3-nP (2) In formulae (1) and (2), Ar represents an aryl group such as a phenyl group, a phenyl group having a substituent, a heteroaromatic ring group, and a heteroaromatic ring group having a substituent; R represents an aliphatic hydrocarbon group or an aliphatic hydrocarbon group having a substituent; and n represents an integer of 0 to 3.

    摘要翻译: 公开了一种由氧化膦衍生物制备膦衍生物的方法,其包括以下步骤:(I)将式(1)表示的氧化膦衍生物与氯化剂在极性有机溶剂中混合,引起它们之间的反应 组件; 和(II-1)将具有等于或低于铝的电离倾向的金属的盐加入到反应混合物中并在铝的存在下进行还原反应或(II-2)使反应混合物 电解还原,从而制得由式(2)表示的膦衍生物。 ArnR3-nP = O(1)ArnR3-nP(2)在式(1)和(2)中,Ar表示芳基,例如苯基,具有取代基的苯基,杂芳族环基和杂芳族 具有取代基的环基; R表示脂肪族烃基或具有取代基的脂族烃基; n表示0〜3的整数。

    Substrate holding technique
    77.
    发明授权
    Substrate holding technique 失效
    基材保持技术

    公开(公告)号:US07999919B2

    公开(公告)日:2011-08-16

    申请号:US11675868

    申请日:2007-02-16

    IPC分类号: G03B27/62 G03B27/58 H01F7/20

    摘要: Disclosed is technology for holding a substrate and, specifically, an object holding apparatus including a chuck for holding an object, a holding unit for holding the chuck, a generating unit provided in the holding unit, for generating a field related to an attraction force, a member provided in the chuck and attracted by the generating unit in accordance with the field, and a supporting unit for supporting one of the generating unit and the member, for movement at least in a direction nearing the other and in a direction away from the other.

    摘要翻译: 公开了用于保持基板的技术,具体地,包括用于保持物体的夹头的物体保持装置,用于保持卡盘的保持单元,设置在保持单元中的用于产生与吸引力有关的场的发生单元, 设置在卡盘中并被根据现场被发电单元吸引的构件,以及用于支撑发电单元和构件中的一个的支撑单元,用于至少沿着接近另一方的方向并且沿远离 其他。

    Facsimile apparatus allowing easy management through email
    79.
    发明授权
    Facsimile apparatus allowing easy management through email 失效
    传真设备允许通过电子邮件轻松管理

    公开(公告)号:US07764391B2

    公开(公告)日:2010-07-27

    申请号:US10657097

    申请日:2003-09-09

    申请人: Hideo Tanaka

    发明人: Hideo Tanaka

    IPC分类号: G06F15/00 H04N1/00

    摘要: A facsimile apparatus configured to exchange email data via a network includes a system control unit which controls an operation of the facsimile apparatus, a communication management unit which stores communication management information in response to occurrence of a facsimile communication, an address registration unit which registers an email address to which email is transmitted, and a data-format conversion unit which converts the communication management information stored in the communication management unit into data in a text format, wherein the system control unit sends the communication management information in the text format to the email address registered in the address registration unit by email.

    摘要翻译: 配置为经由网络交换电子邮件数据的传真装置包括控制传真装置的操作的系统控制单元,响应于传真通信的发生而存储通信管理信息的通信管理单元, 电子邮件发送到的电子邮件地址,以及数据格式转换单元,其将存储在通信管理单元中的通信管理信息转换成文本格式的数据,其中系统控制单元将文本格式的通信管理信息发送到 通过电子邮件在地址注册单位注册的电子邮件地址。

    LIQUID CRYSTAL DISPLAY DEVICE EQUIPPED WITH A PHOTOVOLTAIC CONVERSION FUNCTION
    80.
    发明申请
    LIQUID CRYSTAL DISPLAY DEVICE EQUIPPED WITH A PHOTOVOLTAIC CONVERSION FUNCTION 审中-公开
    装有光伏转换功能的液晶显示装置

    公开(公告)号:US20100079711A1

    公开(公告)日:2010-04-01

    申请号:US11993765

    申请日:2006-06-16

    申请人: Hideo Tanaka

    发明人: Hideo Tanaka

    IPC分类号: G02F1/133

    摘要: A solar cell construction in a display device is provided. The photovoltaic conversion can be performed with high efficiency by the solar cell construction. The display device includes a front substrate and an opposing rear substrate, which are light-transmissive. The display device further includes an optical control layer, a solar cell layer and an insulating flattened layer. The optical control layer is disposed between the substrates, wherein images formed by the optical control layer are displayed on the outer side of the front substrate. The solar cell layer is disposed in a specific area of the major surface on the rear substrate, between the rear substrate serving as a base for supporting it and the optical control layer, and receives incident light coming from the external surroundings through the rear substrate. The insulating flattened layer is formed on the solar cell layer, wherein the optical control layer is formed on and supported by the insulating flattened layer.

    摘要翻译: 提供了一种显示装置中的太阳能电池结构。 可以通过太阳能电池结构以高效率进行光电转换。 显示装置包括透光性的前基板和相对的后基板。 显示装置还包括光学控制层,太阳能电池层和绝缘扁平层。 光学控制层设置在基板之间,其中由光学控制层形成的图像显示在前基板的外侧。 太阳能电池层设置在后基板的主表面的特定区域之间,用作支撑基板的后基板和光控制层之间,并且通过后基板接收来自外部周围的入射光。 绝缘扁平层形成在太阳能电池层上,其中光学控制层形成在绝缘扁平层上并由绝缘扁平层支撑。