公开(公告)号：US20100247990A1

公开(公告)日：2010-09-30

申请号：US12677663

申请日：2009-06-02

申请人： Masaya Ugaji ,  Hideharu Takezawa ,  Taisuke Yamamoto ,  Yasushi Hirakawa

发明人： Masaya Ugaji ,  Hideharu Takezawa ,  Taisuke Yamamoto ,  Yasushi Hirakawa

IPC分类号： H01M6/10 ,  H01M6/42

CPC分类号： H01M2/0202 ,  H01M2/0257 ,  H01M2/1022 ,  H01M2/1094 ,  H01M4/134 ,  H01M4/139

摘要： A battery pack 1 of the present invention includes: a plurality of lithium ion secondary batteries 10 electrically connected together in series, in parallel, or in series-parallel combination; a tray 11; and a housing 12. The lithium ion secondary batteries 10 each include an electrode assembly containing an alloy-based negative electrode active material serving as a negative electrode active material, and each have a sealed surface 10a. The lithium ion secondary battery 10 is mounted on the tray. The housing 12 accommodates the tray 11 with the lithium ion secondary battery 10 mounted thereon. Even if high-temperature contents are produced in the interior of the lithium ion secondary battery 10 in the event of internal short circuiting or overcharging, this configuration prevents the high-temperature contents from leaking out of the batter pack 1, and thus improves the safety of the battery pack 1.

摘要翻译： 本发明的电池组1包括：串联，并联或并联组合电连接在一起的多个锂离子二次电池10; 托盘11; 以及壳体12.锂离子二次电池10各自包括含有作为负极活性物质的合金系负极活性物质的电极体，各具有密封面10a。 锂离子二次电池10安装在托盘上。 壳体12容纳托架11，其上安装有锂离子二次电池10。 即使在内部短路或过充电的情况下在锂离子二次电池10的内部产生高温成分，也能够防止高温成分从电池组1泄漏出来，从而提高安全性 的电池组1。

公开(公告)号：US07754390B2

公开(公告)日：2010-07-13

申请号：US11708341

申请日：2007-02-21

申请人： Hideharu Takezawa ,  Toshitada Sato

发明人： Hideharu Takezawa ,  Toshitada Sato

IPC分类号： H01M4/24

CPC分类号： H01M4/40 ,  H01M4/0421 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/382 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/025

摘要： A negative electrode for a nonaqueous electrolytic rechargeable battery capable of storing and discharging lithium ions is manufactured in the steps of forming a lithium metal layer on a carrier substrate by a gas phase method, superimposing the surface of the lithium metal layer formed on the carrier substrate on a negative electrode active material layer formed on a collecting body, storing the lithium metal layer into the negative electrode active material layer in nonaqueous electrolyte, and removing the carrier substrate from the negative electrode active material layer.

摘要翻译： 在通过气相法在载体基板上形成锂金属层的步骤中制造能够储存和排出锂离子的非水电解可再充电电池用负极，将形成在载体基板上的锂金属层的表面 在形成在集电体上的负极活性物质层上，将锂金属层储存在非水电解质中的负极活性物质层中，从负极活性物质层除去载体基板。

公开(公告)号：US20080248388A1

公开(公告)日：2008-10-09

申请号：US12098126

申请日：2008-04-04

申请人： Takashi Ohtsuka ,  Kaoru Nagata ,  Hideharu Takezawa ,  Shoichi Imashiku

发明人： Takashi Ohtsuka ,  Kaoru Nagata ,  Hideharu Takezawa ,  Shoichi Imashiku

IPC分类号： H01M4/24 ,  H01M4/38

CPC分类号： H01M4/70 ,  H01M4/0404 ,  H01M4/134 ,  H01M10/0525 ,  H01M2004/027

摘要： The invention presents an electrode for an electrochemical element for inserting and extracting a lithium ion reversibly, comprising a current collector forming a concave portion and a convex portion at least on one side, and a columnar body including an active material formed on the convex portion of the current collector, in which the columnar body covers at least a part of respective sides of the convex portion. By this configuration, an electrode for an electrochemical element of long life and excellent reliability is realized.

摘要翻译： 本发明提出了一种用于电化学元件的用于可逆地插入和提取锂离子的电极，包括至少在一侧形成凹部和凸部的集电体，以及包括形成在凸部上的活性材料的柱状体 柱状体覆盖凸部的各侧的至少一部分的集电体。 通过这种构造，实现了长寿命和高可靠性的电化学元件用电极。

公开(公告)号：US20080248189A1

公开(公告)日：2008-10-09

申请号：US12061479

申请日：2008-04-02

申请人： Takashi Ohtsuka ,  Kaoru Nagata ,  Hideharu Takezawa ,  Shoichi Imashiku

发明人： Takashi Ohtsuka ,  Kaoru Nagata ,  Hideharu Takezawa ,  Shoichi Imashiku

IPC分类号： H01M4/04

CPC分类号： H01M4/70 ,  H01M4/0423 ,  H01M4/131 ,  H01M4/134 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/364 ,  H01M10/0525

摘要： The invention presents a manufacturing method of an electrode for an electrochemical element for inserting and extracting a lithium ion reversibly, comprising; forming a concave portion and a convex portion at least on one side of a current collector, preparing a raw material containing a element for composing an active material, introducing a specified supply amount of the raw material and a carrier gas into a film forming device to form a plasma, and injecting the plasma of the raw material on the current collector, in which the active material is grown on the convex portion of the current collector, and a columnar body is formed by covering at least a part of respective sides of the convex portion.

摘要翻译： 本发明提出了用于电化学元件的电极的制造方法，用于可逆地插入和提取锂离子，包括： 在集电体的至少一侧形成凹部和凸部，准备含有构成活性物质的元素的原料，将规定的原料和载气的供给量引入成膜装置， 形成等离子体，并且将原料的等离子体注入到集电体上，其中活性材料在集电体的凸部上生长，并且通过覆盖所述集电体的两侧的至少一部分来形成柱状体 凸部。

公开(公告)号：US20070204457A1

公开(公告)日：2007-09-06

申请号：US11600103

申请日：2006-11-16

申请人： Toshitada Sato ,  Hideharu Takezawa ,  Syoichi Imashiku ,  Kazuyoshi Honda

发明人： Toshitada Sato ,  Hideharu Takezawa ,  Syoichi Imashiku ,  Kazuyoshi Honda

IPC分类号： H01M10/04

CPC分类号： H01M10/058 ,  H01M4/13 ,  H01M4/485 ,  H01M10/0525 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49112 ,  Y10T29/49115

摘要： A non-aqueous electrolyte secondary battery having both high capacity and long-life is provided by solving the problem of the large irreversible capacity of a negative electrode active material. The non-aqueous electrolyte secondary battery is produced by a method including the steps of: reacting lithium with a negative electrode active material by bringing a metal film that is composed mainly of lithium into contact with a surface of a negative electrode active material layer; and thereafter combining the negative electrode with a positive electrode to form an electrode assembly. The metal film composed mainly of lithium is preferably formed on a carrier that does not chemically react with lithium, and the metal film on the carrier is preferably brought into contact with the negative electrode active material layer while heating and applying a pressure thereto.

摘要翻译： 通过解决负极活性物质的不可逆容量大的问题，提供了高容量，长寿命的非水电解质二次电池。 非水电解质二次电池是通过以下方法制造的：通过使主要由锂组成的金属膜与负极活性物质层的表面接触而使锂与负极活性物质反应; 然后将负极与正极组合以形成电极组件。 主要由锂组成的金属膜优选形成在不与锂发生化学反应的载体上，并且载体上的金属膜优选在加热并施加压力的同时与负极活性物质层接触。

公开(公告)号：US20070190419A1

公开(公告)日：2007-08-16

申请号：US10592959

申请日：2005-03-14

申请人： Hideharu Takezawa

发明人： Hideharu Takezawa

IPC分类号： H01M4/52 ,  H01M4/00 ,  H01M4/58 ,  H01M4/50

CPC分类号： H01M4/60 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/50 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/54 ,  C01P2002/74 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/134 ,  H01M4/1395 ,  H01M4/38 ,  H01M4/386 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0567 ,  Y02T10/7011

摘要： A lithium secondary battery includes: a positive electrode including a positive electrode active material; a negative electrode including a negative electrode active material; and a non-aqueous electrolyte. The positive electrode active material comprises at least one lithium-containing composite oxide represented by the following general formula: LixM1l−yM2yO2 where M1 and M2 are different elements, M1 is Ni or Co, M2 is at least one selected from Ni, Co, Mn, Mg, and Al, 1≦x≦1.05, and 0≦y≦0.7. The negative electrode active material comprises at least one selected from the group consisting of silicon, tin, a silicon-containing alloy, and a tin-containing alloy. At least one of the positive electrode, the negative electrode, and the non-aqueous electrolyte includes an organic peroxide. The above-mentioned combination of the positive electrode and the negative electrode makes it possible to improve battery capacity. Also, the inclusion of the organic peroxide in at least one of the positive electrode, the negative electrode and the non-aqueous electrolyte makes it possible to improve cycle characteristics.

摘要翻译： 锂二次电池包括：正极，包括正极活性物质; 负极，包括负极活性物质; 和非水电解质。 所述正极活性物质包含至少一种由以下通式表示的含锂复合氧化物：Li＆lt; x＆gt; M＆lt; 其中M 1和M 2 2是不同的元素，M ^{2 > 1是Ni或Co，M 2是选自Ni，Co，Mn，Mg和Al中的至少一种，1≤x≤1.05，0≤y <= 0.7。 负极活性物质包含选自硅，锡，含硅合金和含锡合金中的至少一种。 正极，负极和非水电解质中的至少一个包括有机过氧化物。 正极和负极的上述组合使得可以提高电池容量。 此外，将有机过氧化物包含在正电极，负极和非水电解质中的至少一种中使得可以改善循环特性。}

公开(公告)号：US20070015058A1

公开(公告)日：2007-01-18

申请号：US11485999

申请日：2006-07-14

申请人： Hideharu Takezawa ,  Hajime Nishino

发明人： Hideharu Takezawa ,  Hajime Nishino

IPC分类号： H01M4/58 ,  H01M4/50 ,  H01M4/52

CPC分类号： H01M10/0525 ,  H01M4/13 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/136 ,  H01M4/364 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M10/0587 ,  H01M2300/004 ,  Y02E60/122 ,  Y02T10/7011

摘要： A positive electrode for use in a lithium secondary battery comprises a positive electrode current collector, and a positive electrode film which is carried on the positive electrode current collector and includes a plurality of mixture layers. The positive electrode film contains, as a positive electrode active material, two or more kinds of lithium-containing compounds having exothermic initiation temperatures different from each other. At least one kind of the two or more kinds of lithium-containing compounds has the exothermic initiation temperature of 300° C. or higher. A first mixture layer of the plural mixture layers closest to the positive electrode current collector contains at least one kind of the lithium-containing compound having the exothermic initiation temperature of 300° C. or higher.

摘要翻译： 用于锂二次电池的正极包括正极集电体和承载在正极集电器上并包括多个混合层的正电极膜。 作为正极活性物质，正极膜含有两种以上具有彼此不同的放热起始温度的含锂化合物。 这两种以上的含锂化合物中的至少一种的放热开始温度为300℃以上。 最靠近正极集电体的多个混合物层的第一混合层包含至少一种具有300℃或更高的放热起始温度的含锂化合物。

公开(公告)号：US07132199B2

公开(公告)日：2006-11-07

申请号：US10311811

申请日：2001-06-11

申请人： Shigeyuki Unoki ,  Hajime Konishi ,  Katsumi Yamashita ,  Shoichiro Watanabe ,  Takashi Takeuchi ,  Hideharu Takezawa ,  Toshikazu Hamamoto ,  Akira Ueki ,  Koji Abe

发明人： Shigeyuki Unoki ,  Hajime Konishi ,  Katsumi Yamashita ,  Shoichiro Watanabe ,  Takashi Takeuchi ,  Hideharu Takezawa ,  Toshikazu Hamamoto ,  Akira Ueki ,  Koji Abe

IPC分类号： H01M6/16 ,  H01M6/14 ,  H01M6/18

CPC分类号： H01M10/0567 ,  H01M6/168 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0017

摘要： A non-aqueous electrolyte containing propylene carbonate and 1,3-propanesultone as additives can reduce the amount of a gas evolved during storage at a high temperature of a non-aqueous electrolyte secondary cell comprising the electrolyte, a non-aqueous electrolyte containing at least one compound selected from the group consisting of vinylene carbonate, diphenyl disulfide, di-p-tolydisulfide and bis(4-methoxyphenyl)disulfide as comprising the electrolyte, and a non-aqueous electrolyte containing a combination of the above-two types of additives can provide a non-aqueous electrolyte secondary cell exhibiting excellent retention of capacity and storage stability.

摘要翻译： 含有碳酸丙烯酯和1,3-丙磺酸内酯作为添加剂的非水电解质可以减少在包含电解质的非水电解质二次电池的高温储存期间放出的气体的量，至少包含至少 选自碳酸亚乙烯酯，二苯基二硫醚，二对二甲苯二硫化物和包含电解质的双（4-甲氧基苯基）二硫化物的一种化合物和包含上述两种添加剂的组合的非水电解质可以 提供具有优异的容量保持性和储存稳定性的非水电解质二次电池。

公开(公告)号：US06682857B2

公开(公告)日：2004-01-27

申请号：US09984159

申请日：2001-10-29

申请人： Hideharu Takezawa ,  Shoichiro Watanabe ,  Shusaku Goto ,  Kunio Tsuruta

发明人： Hideharu Takezawa ,  Shoichiro Watanabe ,  Shusaku Goto ,  Kunio Tsuruta

IPC分类号： H01M614

CPC分类号： H01M10/0567 ,  H01M6/164 ,  H01M10/052

摘要： The non-aqueous electrolyte-containing secondary battery of the present invention uses a non-aqueous electrolyte including at least one phosphoric ester derivative expressed by Formula (1): (R1aO)(R2aO)P(O)X and by Formula (2): R(1bO)P(O)X2, wherein R1a, R2a, and R1b independently denote aliphatic hydrocarbon groups having 1 to 12 carbon atoms and X denotes a halogen atom. This arrangement improves the high-temperature storage characteristics after charging and the charge-discharge cycle characteristics of the secondary battery.

摘要翻译： 本发明的非水电解质二次电池使用包含由式（1）表示的至少一种磷酸酯衍生物的非水电解质：（R 1a）O（R 2a）O（R 2a）O ）X和式（2）：R（1b）O）P（O）X 2，其中R 1a，R 2a和R 1b独立地表示具有1至12个碳原子的脂族烃基， X表示卤素原子。 这种布置改善了充电后的高温存储特性和二次电池的充放电循环特性。