Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates
    71.
    发明授权
    Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates 有权
    烷基化氟化物低聚物及其在处理纤维基材中的用途

    公开(公告)号:US06525127B1

    公开(公告)日:2003-02-25

    申请号:US09708372

    申请日:2000-11-08

    IPC分类号: C08K502

    摘要: This invention provides a method of treating fibrous substrates, such as leather, by contacting the substrate with a fluorochemical compound comprising: a fluorochemical oligomeric portion comprising an aliphatic backbone with a plurality of pendant fluoroaliphatic groups, each fluoroaliphatic group having a fully fluorinated terminal group and each independently linked to a carbon atom of the aliphatic backbone through an organic linking group; an aliphatic moiety; and a linking group which links the fluorochemical oligomeric portion to the aliphatic moiety. The fluorochemical compounds provide desirable oil, water and stain repellency to fibrous substrates.

    摘要翻译: 本发明提供了一种处理纤维基材如皮革的方法,该方法是使基材与含氟化合物接触,该含氟化合物包含:含氟脂肪族主链与多个侧链氟代脂族基团的氟化合物低聚部分,每个氟脂族基团具有完全氟化的端基, 各自独立地通过有机连接基团连接到脂族主链的碳原子上; 脂肪族部分; 以及将氟化物低聚部分连接到脂肪族部分的连接基团。 含氟化合物对纤维基质提供了所需的油,水和防污性。

    Process for preparation of fluorinated sulfinates
    72.
    发明授权
    Process for preparation of fluorinated sulfinates 失效
    氟化亚硫酸盐的制备方法

    公开(公告)号:US06462228B1

    公开(公告)日:2002-10-08

    申请号:US09582121

    申请日:2000-09-25

    申请人: Rudolf J. Dams

    发明人: Rudolf J. Dams

    IPC分类号: C07C20500

    CPC分类号: C07C313/04 C08F14/18 C08F2/16

    摘要: A process for preparation of a fluorinated sulfinate product by reacting a mixture comprising: (1) water; (2) dehalogenating and sulfinating reagent: and (3) fluoroaliphatic sulfonyl fluoride represented by the formula: Rf—[SO2F]n; and (4) at least one of the material selected from the group consisting of: (i) fluorinated surfactant, or (ii) organic cosolvent comprising, as the major component by weight of the organic solvent, alcohol having a boiling point of less than 110° C. at 760 torr; by heating the reaction mixture to a temperature between about 50° C. and 100° C. until the desired product yield is achieved. Also provided is a process of using the fluorinated sulfinate product as an initiation system for a free radical polymerization process, such as that used to prepare fluoropolymers.

    摘要翻译: 一种制备氟化亚磺酸盐产物的方法,该方法是使包含以下物质的混合物:(1)水; (2)脱卤和硫化试剂:和(3)由式Rf- [SO2F] n表示的氟代脂族磺酰氟; 和(4)选自以下的材料中的至少一种:(i)氟化表面活性剂或(ii)有机共溶剂,其包含作为主要组分的有机溶剂的重量,沸点小于 110℃,760托; 通过将反应混合物加热至约50℃至100℃的温度,直到达到所需的产物收率。 还提供了使用氟化亚磺酸盐产物作为自由基聚合方法的引发体系的方法,例如用于制备含氟聚合物的方法。

    Foamable composition containing unsaturated perfluorochemical blowing
agent
    74.
    发明授权
    Foamable composition containing unsaturated perfluorochemical blowing agent 失效
    含不饱和全氟化合物发泡剂的可发泡组合物

    公开(公告)号:US5631306A

    公开(公告)日:1997-05-20

    申请号:US511415

    申请日:1995-08-04

    IPC分类号: C08J9/14

    CPC分类号: C08J9/148 C08J9/143 C08J9/149

    摘要: Foamable compositions comprise (a) at least one normally liquid, unsaturated perfluorochemical blowing agent compound selected from the group consisting of perfluoroolefin compounds, e.g., perfluoro(4-methylpent-2-ene), perfluoroaromatic compounds, e.g., hexafluorobenzene, and perfluorocycloolefin compounds, e.g., perfluorocyclohexene, the perfluoroolefin compounds optionally containing one or more catenary heteroatoms; and (b) at least one foamable polymer or the precursors of at least one foamable polymer. The compositions are useful in preparing polymeric, e.g., polyurethane, foams.

    摘要翻译: 可发泡组合物包含(a)至少一种通常为液体的不饱和全氟化合物发泡剂化合物,其选自全氟烯烃化合物,例如全氟(4-甲基戊-2-烯),全氟芳族化合物如六氟苯和全氟环烃化合物, 例如全氟环己烯,任选地含有一个或多个链状杂原子的全氟烯烃化合物; 和(b)至少一种可发泡聚合物或至少一种可发泡聚合物的前体。 该组合物可用于制备聚合物,例如聚氨酯泡沫。

    FLUOROPOLYETHER ELASTOMER COMPOSITIONS HAVING LOW GLASS TRANSITION TEMPERATURES
    77.
    发明申请
    FLUOROPOLYETHER ELASTOMER COMPOSITIONS HAVING LOW GLASS TRANSITION TEMPERATURES 有权
    具有低玻璃化转变温度的氟聚乙烯弹性体组合物

    公开(公告)号:US20140066572A1

    公开(公告)日:2014-03-06

    申请号:US14009929

    申请日:2012-03-13

    IPC分类号: C08K5/14

    摘要: A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than −40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than −40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than −40° C.

    摘要翻译: 提供可固化组合物。 可固化组合物具有至少一种官能化氟聚醚和至少一种自由基固化体系。 还提供了玻璃化转变温度低于-40℃的含氟弹性体组合物和通过固化可固化组合物获得的包含玻璃化转变温度低于-40℃的含氟弹性体的成型制品。 还描述了制备玻璃化转变温度低于-40℃的含氟弹性体组合物的方法。

    METHOD OF CONTACTING HYDROCARBON-BEARING FORMATIONS WITH FLUORINATED ETHER COMPOSITIONS
    78.
    发明申请
    METHOD OF CONTACTING HYDROCARBON-BEARING FORMATIONS WITH FLUORINATED ETHER COMPOSITIONS 失效
    用氟化物醚组合物接触油气轴承的方法

    公开(公告)号:US20110247822A1

    公开(公告)日:2011-10-13

    申请号:US13140242

    申请日:2009-12-17

    申请人: Rudolf J. Dams

    发明人: Rudolf J. Dams

    IPC分类号: E21B43/16 E21B43/00 C09K8/584

    摘要: Method comprising contacting a hydrocarbon-bearing formation with a composition comprising solvent and a fluoropolyether compound, wherein the fluoropolyether compound comprises at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHL′-(CF2)n—; [Rfa—(O)t—C(L)H—CF2)—O]m—W—; Rfb—O—(CF2)p-; F(CkF2k)—(O—CkF2K(p—O—CF2—; and CF3—O—(CF2)3—OCF(CF3)—CF2)z—O-L1-. Treated hydrocarbon-bearing formations are also disclosed.

    摘要翻译: 方法包括使含烃地层与包含溶剂和含氟聚醚化合物的组合物接触,其中所述含氟聚醚化合物包含至少一个由式表示的第一二价单元:每个Rf独立地选自Rfa-(O)t- CHL' - (CF2)n-; [Rfa-(O)t -C(L)H-CF 2)-O] m -W-; Rfb-O-(CF2)p-; F(CkF2k) - (O-CkF2K(p-O-CF2-;和CF3-O-(CF2)3-OCF(CF3)-CF2)z-O-L1-也讨论了处理的含烃地层。