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    Method for fullerene derivative and the fullerene derivative proton conductor and electrochemical device
    72.
    发明授权
    Method for fullerene derivative and the fullerene derivative proton conductor and electrochemical device 失效
    富勒烯衍生物和富勒烯衍生物质子导体和电化学装置的方法

    公开(公告)号：US07371479B2

    公开(公告)日：2008-05-13

    申请号：US10451320

    申请日：2001-12-25

    申请人： Berthold Nuber

    发明人： Berthold Nuber

    IPC分类号： H01M8/10

    CPC分类号： C07C305/20 ,  C07C35/44 ,  C07C309/25 ,  C07C2604/00 ,  H01M8/1016 ,  H01M8/1023 ,  Y02E60/324 ,  Y02P70/56 ,  Y10S977/734 ,  Y10S977/735 ,  Y10S977/74

    摘要： Provided are a method of efficiently procuding fullerene into which a OH group or a SO3H group is introduced, such as fullerenol, or a derivative thereof, the fullerene and its derivative being preferable as a proton conductor, and a novel and usable proton conductor obtained by the method. Further, provided is an electrochemical device using the proton conductor such as a fuel cell or the like. In the producing method of the fullerene derivative, halogated fullerene, which is obtained through halogating a fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one carbon atom of a fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a proton conductor, and an electrochemical device using the proton conductor such as a fuel cell can be downsized and simplified without atmosphere constraints.

    摘要翻译： 本发明提供一种有效地制备引入了OH基或SO 3 H基的富勒烯的方法，例如富勒烯醇或其衍生物，富勒烯及其衍生物优选作为质子导体， 以及通过该方法获得的新型可用的质子导体。 此外，提供了使用诸如燃料电池等的质子导体的电化学装置。 在富勒烯衍生物的制造方法中，通过使富勒烯分子卤化获得的卤代富勒烯用作前体，富勒烯衍生物是通过将一个或多个质子离解基团引入富勒烯分子的至少一个碳原子而制备的。 此外，在聚合的富勒烯衍生物的制造方法中，通过使多种富勒烯衍生物与芳香族化合物反应，多个富勒烯衍生物通过芳香族化合物的芳香族基团彼此键合。 通过这些方法中的任何一种获得的富勒烯衍生物用作质子导体，并且使用诸如燃料电池的质子导体的电化学装置可以在没有气氛限制的情况下被小型化和简化。

    Method for fullerene derivative and the fullerene derivative proton conductor and electrochemical device
    76.
    发明申请
    Method for fullerene derivative and the fullerene derivative proton conductor and electrochemical device 失效
    富勒烯衍生物和富勒烯衍生物质子导体和电化学装置的方法

    公开(公告)号：US20040062971A1

    公开(公告)日：2004-04-01

    申请号：US10451320

    申请日：2003-11-07

    发明人： Berthold Nuber

    IPC分类号： H01M008/10

    CPC分类号： C07C305/20 ,  C07C35/44 ,  C07C309/25 ,  C07C2604/00 ,  H01M8/1016 ,  H01M8/1023 ,  Y02E60/324 ,  Y02P70/56 ,  Y10S977/734 ,  Y10S977/735 ,  Y10S977/74

    摘要： Provided are a method of efficiently procuding fullerene into which a OH group or a SO3H group is introduced, such as fullerenol, or a derivative thereof, the fullerene and its derivative being preferable as a proton conductor, and a novel and usable proton conductor obtained by the method. Further, provided is an electrochemical device using the proton conductor such as a fuel cell or the like. In the producing method of the fullerene derivative, halogated fullerene, which is obtained through halogating a fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one carbon atom of a fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a proton conductor, and an electrochemical device using the proton conductor such as a fuel cell can be downsized and simplified without atmosphere constraints.

    摘要翻译： 本发明提供一种有效地制备引入了OH基团或SO 3 H基团的富勒烯如富勒烯醇或其衍生物，富勒烯及其衍生物优选作为质子导体的方法，以及由式 方法。 此外，提供了使用诸如燃料电池等的质子导体的电化学装置。 在富勒烯衍生物的制造方法中，通过使富勒烯分子卤化获得的卤代富勒烯用作前体，富勒烯衍生物是通过将一个或多个质子离解基团引入富勒烯分子的至少一个碳原子而制备的。 此外，在聚合的富勒烯衍生物的制造方法中，通过使多种富勒烯衍生物与芳香族化合物反应，多个富勒烯衍生物通过芳香族化合物的芳香族基团彼此键合。 通过这些方法中的任何一种获得的富勒烯衍生物用作质子导体，并且使用诸如燃料电池的质子导体的电化学装置可以在没有气氛限制的情况下被小型化和简化。