摘要:
Compounds of the formula ##STR1## wherein K.sup..sym. is a cationic group, preferably heterocyclic,R is hydrogen or an organic radical, preferably alkyl, phenyl or acyl,R.sub.1 is hydrogen, hydrocarbyl, substituted hydrocarbyl, heterocyclyl, substituted heterocyclyl, amino or substituted amino, andA.sup..crclbar. is an anion,Are useful as intermediates in the synthesis of azo dyes of the formula ##STR2## wherein D is an aromatic carbocyclic or heterocyclic diazo component radical, andK.sup..sym., r, r.sub.1 and A.sup..crclbar. are as defined above.
摘要:
Azo dyestuffs devoid of carboxylic acid and sulphonic acid groups and of the formula I: ##STR1## wherein A.sym. is a positively-charged aromatic or heterocyclic group, X.crclbar. is an anion; R is hydrogen or an optionally-substituted alkyl, aryl, aralkyl or cycloalkyl group, R.sup.1 is hydrogen, or an optionally-substituted alkyl or aralkyl group and the quinoline ring may be further substituted, and processes for the manufacture of such dyestuffs which are useful for the coloration of synthetic polymeric materials such as acrylonitrile polymers and copolymers.
摘要:
A basic azo dyestuff, which is free form acid groups conferring solubility in water, of the formula ##STR1## wherein two radicals Z represent groups of the formula --NR'R" and one radical Z represents a group of the formula --NR'R", --OR'" or --SR'", wherein R', R", and R'" each represents hydrogen, aryl, cycloalkyl or an aliphatic radical and R' and R" are able to form a ring containing the amino nitrogen and the radicals --NR'R" may be the same or different, R is alkyl, substituted alkyl or cycloalkyl, n is 1 or 2, Y represents a radical of the formula --CN or --CONH.sub.2, and D represents the radical of an aromatic or heterocyclic diazo component, and wherein at least one radical Z and/or D contains a basic, optionally cationic group. These dyestuffs are useful for dyeing and printing synthetic fibers to produce intensive and level dyeings with good fastness to light and general fastness properties.
摘要:
Dyes of the formula ##STR1## wherein R.sub.1 is hydrogen or cyano,R.sub.2 is alkyl, aryl or heterocyclyl, or a substituted derivative there f,R.sub.20 is hydrocarbyl, heterocyclyl or amino, or a substituted derivative thereof preferably containing a protonizable nitrogen atom, andD is aromatic carbocyclyl or heterocyclyl, or a substituted derivative thereof, with the proviso that it is free of cationic groups,With the proviso that the molecule contains at least one protonizable nitrogen atom. These dyes are eminently suitable for the dyeing and printing of textiles which consist of or contain fibers of polyacrylonitrile or copolymers of acrylonitrile. They are suitable for dyeing polyesters and polyamides modified to contain acid groups as well as leather and paper. The dyes have high tinctorial strengths and give level dyeings exhibiting good fastness to light and wet treatments. The dyes are produced by diazotizing an amine of the formula D-NH.sub.2 and coupling the resulting compound with a pyridone of the formula ##STR2##
WHEREIN Y DENOTES AN ALKYLENE CHAIN OF UP TO 6 CARBON ATOMS WHICH MAY BE INTERRUPTED BY A HETERO-ATOM SELECTED FROM THE GROUP CONSISTING OF NITROGEN, OXYGEN OR SULFUR, A DENOTES AMINO OR LOWER ALKYLAMINO, B DENOTES HYDROGEN, LOWER ALKYL, LOWER ALKOXY OR PHENYL, Z DENOTES AN AMINO, HYDRAZINO OR ETHERIFIED HYDROZYLAMINO GROUP WHICH MAY BE QUATERNIZED, AND D1 IS THE RESIDUE OF A DIAZO COMPONENT; THE NEW DYESTUFFS ARE ESPECIALLY VALUABLE FOR DYEING SYNTHETIC FIBERS SUCH AS POLYVINYLCHLORIDE, POLYAMIDE OR POLYURETHANE WITH GOOD GENERAL FASTNESS PROPERTIES, SUCH AS FASTNESS TO LIGHT, WASHING AND SUBLIMATION.
摘要:
BASIC AZO DYESTUFFS CONTAINING A HETEROCYCLIC DIAZO COMPONENT AND AS RADICAL OF THE COUPLING COMPONENT A PARAALKYLAMINOBENZENE CONTAINING A HETEROCYCLIC TERTIARY OR QUATERNARY AMINE BOUND TO THE ALKYL RADICAL VIA ITS NITROGEN ATOM.
摘要:
The invention relates to cationic direct dyes of the formula I (1), wherein m and n are independently from each other 0 or 1, D is an aromatic or a cationic heteroaromatic group, which are further specified, K is an aromatic or heteroaromatic group, E1 and E2 are independently from each other ═CH— or ═N—, An is an anion and a is a number from 1 to 6 and R1 and R2 are independently from each other and further specified. The compounds show washfastness at hair-dying.
摘要:
The present invention is directed towards polymerizable dichroic azo dyes comprising azo-chromophores having at least one standard mesogenic ring system attached to said chromophores and at least one polymerizable group leading to dyes having sufficient solubilty and a very high order parameter.
摘要:
A process for printing an image on a substrate, the process comprising applying to the substrate an ink composition which comprises a liquid medium and a compound selected from the group consisting of compounds of Formula (1I), compounds of Formula (1II), compounds of Formula (1III) and compounds of Formula (1IV): wherein: A and D each independently represent optionally substituted aryl or optionally substituted heteroaryl; E represents optionally substituted pyrazolyl; Z represents H, halogen, nitro, cyano, hydroxy, amino, carboxy, optionally substituted alkyl, optionally substituted alkoxy or optionally substituted aryloxy; and p is an integer from 0 to 5. Preferably, the printing process is ink jet printing. Also provided are compounds of Formula (1I), (1II), (1III) and (1IV) and ink compositions comprising the same.