摘要:
The invention concerns a dyeing composition for dyeing keratinous fibers, in particular human keratinous fibers and more particularly hair, comprising a dicationic diazo dye of formula W1—N═N—W2—N═N—W3 as well as the dyeing method using same and the novel compounds of formula (I).
摘要:
An ink jet ink composition comprising water, a humectant, and a delocalized cationic azo dye derived from the quatemization of a heterocyclic azoaminothiazole dye.
摘要:
Disclosed are dyes having the formula ##STR1## in which R.sub.1 is C.sub.1 -C.sub.4 alkoxy or chlorine,R.sub.2 is C.sub.1 -C.sub.4 alkyl,R.sub.3 is C.sub.1 -C.sub.4 alkyl,R.sub.4 is C.sub.1 -C.sub.4 alkyl,R.sub.5 is hydroxyethyl or hydroxypropyl, andAn.sup..crclbar. is an anion, in which R.sub.3 and R.sub.4 are not both ethyl at the same time, compositions containing the dyes and methods of using and preparing the dyes. The dyes are especially useful for dyeing polyacrylonitrile.
摘要:
Process for the preparation of benzthiazole dyestuffs by alkylation of compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 denote hydrogen, alkyl, alkenyl, cycloalkyl, aryl or aralkyl, or, conjointly with the N-atom, form a ring, or R.sub.1 can be linked to the o-position of the ring B and the rings A and B and the radicals R.sub.1 and R.sub.2 can contain non-ionic substituents and carbocyclic or heterocyclic rings can be fused to the rings A and B, with esters of the formulaR.sub.3 --SO.sub.3 RwhereinR denotes an alkyl radical andR.sub.3 denotes an aryl radical or R--O,in organic solvents and consequently alkylation by the addition of water.
摘要:
Monoazo dyes of the formula ##STR1## is optionally substituted thiazolyl, benzothiazolyl, 1,2,4-triazolyl, indazolyl, imidazolyl or pyridyl or naphtho-[2,1-d]-thiazolyl,R.sub.1 is optionally substituted alkyl, phenylalkyl, cycloalkyl or alkenyl,each of R.sub.2 and R.sub.3 is independently optionally substituted alkyl,R.sub.4 is hydrogen or optionally substituted alkyl, phenylalkyl, cycloalkyl or phenyl,R.sub.5 is hydrogen or optionally substituted alkyl, orR.sub.4 and R.sub.5 taken together and with the nitrogen atom to which they are joined are optionally substituted saturated heterocyclyl,R.sub.6 is hydrogen or methyl, andA.sup..crclbar. is an anion,with the proviso that the molecule is free of sulfo groups,are useful for the dyeing and printing of basic dyeable substrates, e.g., materials comprising or consisting of homo- or mixed-polymers of acrylonitrile or asymmetrical dicyanoethylene or synthetic polyamides or polyesters modified to contain acid groups, leather and paper.
摘要:
Dyestuffs of the formula ##SPC1##WhereinR, r', r" and R'" denote hydrogen, methyl, ethyl or propyl, but at least two of the radicals R, R', R" and R'" denote hydrogen,R.sub.2 denotes a non-ionic substituent,R.sub.3 denotes alkyl, alkenyl, cycloalkyl or aralkyl,R.sub.4 denotes an acyclic saturated or unsaturated unsubstituted hydrocarbon radical, halogenoalkyl, alkoxyalkyl, hydroxyalkyl, hydroxy-alkoxyalkyl, halogenohydroxyalkyl, cyanoalkyl, carboxyalkyl, aminocarbonylalkyl, acyloxyalkyl, cycloalkoxyalkyl, cycloalkenyloxyalkyl, aroyloxyalkyl, aroxyalkoxyalkyl, aralkoxyalkyl, arylthioalkyl, cycloalkyl, aralkyl, aroxyalkyl or arylaminocarbonyloxyalkyl,R.sub.5 denotes a non-ionic substituent or a carboxyl group,p denotes the numbers 0, 1, 2, 3 or 4,n denotes the numbers 0, 1, 2 or 3 andX.sup.- denotes an anion.Are suitable for dyeing and printing of natural and synthetic materials, particularly of polyacrylonitrile, copolymers of acrylonitrile with other vinyl compounds, of acid modified polyesters and acid modified polyamides.Dyestuffs of the formula I are prepared by the action of quaternising agents of the formulaR.sub.3 -X (VII)on axo dyestuffs of the formula: ##SPC2##Wherein R, R', R", R"' , R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are as defined above.
IN WHICH A REPRESENTS AN ARYL RESIDUE, R REPRESENTS A HYDROGEN ATOM OR AN ORGANIC RESIDUE, N=1 OR 2, R'' REPRESENTS AN ALKYL OR RALKYL GROUP, Y-REPRESENTS AN ANION AND B REPRESENTS THE RESIDUE OF A COUPLING COMPONENT.
摘要:
A DRY OR WET DIAZO PROCESS GIVING DEEP COLORED TONES USING AS THE COUPLING AGENT A BENZOTHIAZOLIUM COMPOUND CORRESPONDING TO THE FOLLOWING GENERAL FORMULA:
2-CH3,3-R,5-R1,6-R2,7-R3-BENZOTHIAZOLIUM X(-)
WHEREIN: X- STANTS FOR AN ANION, AND MAY BE MISSING WHEN THE ANION IS PRESENT IN THE R GROUP, R STANDS FOR AN ORGANIC GROUP INTRODUCED BY QUATERNIZATION, R1 STANDS FOR HYDROGEN, AND ALKYL GROUP, A PHENYL GROUP, AN ALKOXY GROUP, A HALOGN ATOM, AND AMINO GROUP, CYANO, AN ALKOXYCARBONYL GROUP, AN ACYL GROUP, OR AN ALKYLSULPHONYL GROUP, R2 STANDS FOR HYDROGEN, A C2-C5 ALKYL GROUP, AN ALKOXY GROUP, CYANO, CYANOVINYL OR A HALOGEN ATOM, R3 STANDS FO HYDROGEN, HALOGEN, A SULPHO GROUP OR A SULPHAMYL GROUP, THE BENZENE RING OF THE BENZOTHIAZOLIUM NUCLIUS CARRYING AT LEAST ONE SUBSTITUENT OTHER THAN HYDROGEN AND BEING FREE OF A METHOXY GROUP IN THE 6-POSITION; AND RECORDING MATERIALS USEFUL THEREIN. A PREFERRED BENZOTHIAZOLIUM COMPOUND IS 2,3,5,6-TETRAMETHYL-BENCOTHIAZOLIUM METHYLSULPHATE AND A PREFERRED DIAZONIUM COMPOUND P-DIETHYLANINOBENZENE-DIAZONIUM TETRABOROFLUORIDE.
摘要:
DIAZO RECORDING PROCESS GIVING A NEUTRAL BLACK TONE USING AS THE COUPLING AGENT IN AN ALKALINE MEDIUM A QUATERNARY SALT OF 2-METHYL-5,6-DIMETHOXYBENZOTHIAZOLE OR A QUATERNARY SALT OF 2-METHYLBENZOTHIAZOLE WHEREIN THE CARBON ATOMS OF THE 5- AND 6-POSITION ARE PART OF A FUSED RING CLOSED BY A -O-CH2-O- OR A
-O-CH2-CH2-0-
GROUP. PREFERABLY THE QUATERNARY SALT IS SUBSTITUTED ON THE NITROGEN ATOM OF THE BENZTHIAZOLIUM NUCLEUS WITH A
-CH2-Y
GROUP IN WHICH Y IS AN ELECTRON-WITHDRAWING GROUP SUCH AS IN A -CH2-CO-NH-SO2-CH3 GROUP; AND RECORDING MATERIALS USEFUL THEREIN.