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81.发明申请Method for making a hydrophilic corrosion resistant coating on low grade stainless steel/alloys for bipolar plates 审中-公开在低档不锈钢/双极板合金上制造亲水性耐腐蚀涂层的方法公开(公告)号：US20070287057A1
公开(公告)日：2007-12-13
申请号：US11450793
申请日：2006-06-09
CPC分类号： C23C26/00 , C23C10/02 , H01M8/0204 , H01M8/0206 , H01M8/021 , H01M8/0228 , H01M8/0258 , H01M8/0267 , H01M8/2457 , Y02P70/56 , Y10T428/2457
摘要： A stainless steel flow field plate for a fuel cell that includes a layer of titanium or titanium oxide and a layer of titanium oxide/ruthenium oxide that makes the plate conductive and hydrophilic. In one embodiment, titanium is deposited on the surface of a stainless steel bipolar plate as a metal or an oxide using a suitable process, such as PVD or CVD. A solution of ruthenium chloride in ethanol is brushed on the titanium layer. The plate is then calcinated to provide a dimensionally stable titanium oxide/ruthenium oxide layer on the stainless steel that is hydrophilic and electrically conductive in the fuel cell environment.
摘要翻译： 一种用于燃料电池的不锈钢流场板，其包括钛或氧化钛层和氧化钛/氧化钌层，其使得该导电性和亲水性。 在一个实施例中，使用合适的工艺（例如PVD或CVD）将钛作为金属或氧化物沉积在不锈钢双极板的表面上。 将氯化钌在乙醇中的溶液刷在钛层上。 然后将板煅烧以在不锈钢上提供在燃料电池环境中亲水和导电的尺寸稳定的氧化钛/氧化钌层。
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82.发明授权公开(公告)号：US08323851B2
公开(公告)日：2012-12-04
申请号：US11434386
申请日：2006-05-15
CPC分类号： H01M8/0228 , H01M8/0204 , H01M8/0206 , H01M8/021 , H01M8/0213 , H01M8/0245 , H01M8/0267 , H01M8/242 , H01M8/2483 , H01M2250/20 , Y02T90/32
摘要： A fuel cell stack that includes a non-permeable shim plate positioned between a composite unipolar plate and a terminal plate at both ends of the stack, where the shim plate is made of a non-corrosive material, such as stainless steel, titanium or sealed graphite. Because the shim plate is non-permeable, it prevents cooling fluid that diffuses through the unipolar plate from contacting the terminal plate, which would otherwise corrode the terminal plate. The shim plate can be coated with a conductive material, such as gold, platinum, ruthenium oxide or mixtures thereof, to reduce its contact resistance.
摘要翻译： 一种燃料电池堆，其包括位于堆叠两端的复合单极板和端子板之间的不可渗透垫片，垫片由非腐蚀性材料制成，例如不锈钢，钛或密封 石墨。 因为垫板是不可渗透的，所以它防止通过单极板扩散的冷却液与接线板接触，否则会使端子板腐蚀。 垫板可以涂覆有导电材料，例如金，铂，氧化钌或其混合物，以降低其接触电阻。
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83.发明授权Fast recycling process for ruthenium, gold and titanium coatings from hydrophilic PEM fuel cell bipolar plates 有权从亲水PEM燃料电池双极板钌，金和钛涂层的快速回收过程公开(公告)号：US08323415B2
公开(公告)日：2012-12-04
申请号：US11463614
申请日：2006-08-10
IPC分类号： C23G1/02
CPC分类号： H01M8/008 , C22B7/007 , C22B11/046 , C22B34/124 , H01M8/0206 , Y02P10/214 , Y02P10/234 , Y02W30/86
摘要： A method for recovering ruthenium oxide or gold and titanium or titanium oxide from a bipolar plate at the end of the life of a fuel cell stack so as to use these materials in other fuel cell stacks thereafter. The bipolar plate is immersed in a solution including a suitable acid that dissolves the titanium or titanium oxide. The ruthenium oxide or gold will be released from the plate and will float on the solution from which it can be removed. The solution is then heated to evaporate the acid solution leaving a powder of the titanium oxide. The stainless steel of the bipolar plate is thus cleaned of the titanium or titanium oxide, and can be reused.
摘要翻译： 在燃料电池堆的寿命结束时从双极板回收氧化钌或金和钛或氧化钛的方法，以便此后在其它燃料电池堆中使用这些材料。 将双极板浸入包括溶解钛或氧化钛的合适的酸的溶液中。 氧化钌或金将从板上释放并漂浮在可从中除去的溶液上。 然后将溶液加热以蒸发酸溶液，留下氧化钛粉末。 因此，双极板的不锈钢被清除钛或氧化钛，并且可以重复使用。
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84.发明授权Adhesion of polymeric coatings to bipolar plate surfaces using silane coupling agents 有权使用硅烷偶联剂将聚合物涂层粘合到双极板表面公开(公告)号：US08133591B2
公开(公告)日：2012-03-13
申请号：US11475499
申请日：2006-06-27
申请人： Feng Zhong , Tao Xie , Richard H. Blunk , Mahmoud H. Abd Elhamid , Brian K. Brady , Timothy J. Fuller
发明人： Feng Zhong , Tao Xie , Richard H. Blunk , Mahmoud H. Abd Elhamid , Brian K. Brady , Timothy J. Fuller
CPC分类号： H01M8/0228 , C09D183/04 , C09D183/14 , H01M8/0204 , H01M8/0206 , H01M8/021 , H01M8/0221 , H01M2008/1095 , Y02P70/56 , Y10T428/31663
摘要： The present invention provides an electrically conductive element for an electrochemical cell element having enhanced protection for an underlying metal substrate with a surface susceptible to forming metal oxides. One or more regions of the surface are coated with a metal coating overlaid with an adhesion promoting coating comprising a silicon containing material derived from organosilanes. The adhesion promoting coating is overlaid with a conductive, protective polymeric coating. The present invention further provides methods of making such an electrochemical cell element to have improved adhesion of conductive, protective polymer coatings.
摘要翻译： 本发明提供了一种用于电化学电池元件的导电元件，其具有对具有易于形成金属氧化物的表面的下面的金属基底的增强的保护。 表面的一个或多个区域涂覆有覆盖有包含源自有机硅烷的含硅材料的粘附促进涂层的金属涂层。 粘合促进涂层覆盖有导电的保护性聚合物涂层。 本发明还提供了使这种电化学电池元件具有改进的导电保护性聚合物涂层的粘附性的方法。
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公开(公告)号：US20100124675A1
公开(公告)日：2010-05-20
申请号：US12271972
申请日：2008-11-17
CPC分类号： H01M8/0206 , H01M8/0208 , H01M8/0221 , H01M8/0228 , Y02E60/50 , Y10T29/49108 , Y10T29/49114 , Y10T29/49115
摘要： One exemplary embodiment discloses a bipolar plate assembly including a cathode plate and an anode plate. Each of the cathode plate and the anode plate includes a core material, a first surface material coupled to a first side of the core material, and a second surface material coupled to a second side of the core material, wherein the first surface material and the second surface material have a different composition from the core material.
摘要翻译： 一个示例性实施例公开了一种包括阴极板和阳极板的双极板组件。 阴极板和阳极板中的每一个包括芯材料，耦合到芯材的第一侧的第一表面材料和耦合到芯材料的第二侧的第二表面材料，其中第一表面材料和 第二表面材料与芯材料具有不同的组成。
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86.发明申请REMOVAL OF NON-CONDUCTIVE HYDROPHILIC COATINGS FROM LANDS OF FUEL CELL BIPOLAR PLATES 有权从燃料电池双极板的地面去除非导电水解涂料公开(公告)号：US20080248370A1
公开(公告)日：2008-10-09
申请号：US11696361
申请日：2007-04-04
CPC分类号： H01M8/0228 , H01M8/0213 , H01M8/0221 , H01M8/0258 , H01M2008/1095 , Y02E60/50 , Y02P70/56
摘要： A bipolar plate for a fuel cell is provided including a plate having an active surface with a plurality of flow channels formed therein. The plurality of flow channels have a hydrophilic coating deposited thereon and define a plurality of lands disposed therebetween. The plurality of lands is substantially free of the hydrophilic coating. Furthermore, a thickness of the hydrophilic coating is substantially constant along a length of the active surface and an edge of the hydrophilic coating adjacent the plurality of lands is substantially continuous. A method for preparing the bipolar plate is also provided.
摘要翻译： 提供了一种用于燃料电池的双极板，包括具有形成在其中的多个流动通道的活性表面的板。 多个流动通道具有沉积在其上的亲水涂层并且限定了设置在其间的多个焊盘。 多个平台基本上没有亲水涂层。 此外，亲水涂层的厚度沿着活性表面的长度基本恒定，并且邻近多个焊盘的亲水涂层的边缘基本上是连续的。 还提供了制备双极板的方法。
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87.发明授权公开(公告)号：US06887610B2
公开(公告)日：2005-05-03
申请号：US10347890
申请日：2003-01-21
CPC分类号： H01M8/0228 , H01M8/0206 , H01M8/0247 , H01M8/0263 , H01M8/0267 , H01M8/0271 , H01M8/0273 , H01M8/2404 , H01M8/241 , H01M8/2483
摘要： A bipolar plate assembly for a proton exchange membrane fuel cell stack advantageously connects electrically conductive plate surfaces, without the requirement to weld or braze the plate pairs. Each plate has alternating coolant channels and lands formed on an inside facing surface. An electrically conductive layer is deposited over at least the coolant channels and lands. Pairs of plates are aligned having facing electrically conductive layers. A fluid seal is disposed between the inside facing surfaces about a perimeter of the coolant channels. Each plate pair is compressed to form a plurality of electrical bond lines between adjacent lands within the perimeter seal. The perimeter seal prevents stack reactant gas oxygen from contacting and oxidizing the electrically conductive layer. A dielectric coolant is also used to reduce oxidation of the electrically conductive layer.
摘要翻译： 用于质子交换膜燃料电池堆的双极板组件有利地连接导电板表面，而不需要焊接或钎焊板对。 每个板具有形成在面向内侧的表面上的交替的冷却剂通道和平台。 在至少冷却剂通道和焊盘上沉积导电层。 一对板对准具有面向导电层。 流体密封件围绕冷却剂通道的周边布置在面向内的表面之间。 每个板对被压缩以在周边密封件内的相邻平台之间形成多个电接合线。 周边密封件防止堆叠反应物气体氧气接触并氧化导电层。 电介质冷却剂也用于减少导电层的氧化。
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公开(公告)号：US06811918B2
公开(公告)日：2004-11-02
申请号：US09997190
申请日：2001-11-20
IPC分类号： H01M496
CPC分类号： H01M8/0228 , H01M8/0206 , H01M8/021 , H01M8/0213 , H01M8/0221 , H01M8/0223
摘要： A PEM fuel cell having a current collector comprising a polymer composite and a diffusion media engaging said polymer composite. The polymer composite has a hyperconductive surface layer engaging the diffusion media to reduce the contact resistance therebetween. The hyperconductive surface layer is formed by depositing or smearing an electrically-conductive material on the surface of the polymer composite.
摘要翻译： 一种具有集电器的PEM燃料电池，其包括聚合物复合材料和与所述聚合物复合材料接合的扩散介质。 聚合物复合材料具有与扩散介质接合的超导表面层，以减小它们之间的接触电阻。 超导表面层通过在聚合物复合材料的表面上沉积或涂抹导电材料而形成。
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89.发明授权Removal of non-conductive hydrophilic coatings from lands of fuel cell bipolar plates 有权从燃料电池双极板的焊盘上去除非导电亲水涂层公开(公告)号：US08563075B2
公开(公告)日：2013-10-22
申请号：US11696361
申请日：2007-04-04
IPC分类号： B05D5/12
CPC分类号： H01M8/0228 , H01M8/0213 , H01M8/0221 , H01M8/0258 , H01M2008/1095 , Y02E60/50 , Y02P70/56
摘要： A bipolar plate for a fuel cell is provided including a plate having an active surface with a plurality of flow channels formed therein. The plurality of flow channels have a hydrophilic coating deposited thereon and define a plurality of lands disposed therebetween. The plurality of lands is substantially free of the hydrophilic coating. Furthermore, a thickness of the hydrophilic coating is substantially constant along a length of the active surface and an edge of the hydrophilic coating adjacent the plurality of lands is substantially continuous. A method for preparing the bipolar plate is also provided.
摘要翻译： 提供了一种用于燃料电池的双极板，包括具有形成在其中的多个流动通道的活性表面的板。 多个流动通道具有沉积在其上的亲水涂层并且限定了设置在其间的多个焊盘。 多个平台基本上没有亲水涂层。 此外，亲水涂层的厚度沿着活性表面的长度基本恒定，并且邻近多个焊盘的亲水涂层的边缘基本上是连续的。 还提供了制备双极板的方法。
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公开(公告)号：US20110311720A1
公开(公告)日：2011-12-22
申请号：US13222162
申请日：2011-08-31
IPC分类号： B05D5/12
CPC分类号： H01M8/0206 , H01M8/021 , H01M8/0221 , H01M8/0226 , H01M8/0228 , Y02P70/56 , Y10T428/31678
摘要： In at least one embodiment, the present invention provides an electrically conductive fluid distribution plate and a method of making, and system for using, the electrically conductive fluid distribution plate. In at least one embodiment, the plate comprises an electrically conductive fluid distribution plate comprising a metallic plate body defining a set of fluid flow channels configured to distribute flow of a fluid across at least one side of the plate, a metal-containing adhesion promoting layer having a thickness less than 100 nm disposed on the plate body, and a composite polymeric conductive layer disposed on the metal-containing adhesion promoting layer.
摘要翻译： 在至少一个实施例中，本发明提供了一种导电流体分配板以及用于制造导电流体分布板和使用该系统的方法。 在至少一个实施例中，板包括导电流体分配板，该导电流体分配板包括金属板体，其限定一组流体流动通道，所述一组流体流动通道被配置成分配流体流过板的至少一侧，含金属的粘附促进层 具有设置在板体上的厚度小于100nm的复合聚合物导电层和设置在含金属的粘附促进层上的复合聚合物导电层。
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