公开(公告)号：US09315620B2

公开(公告)日：2016-04-19

申请号：US14236282

申请日：2012-07-17

申请人： Vincenzo Arcella ,  Claudio Adolfo Pietro Tonelli ,  Solange Barbieri

发明人： Vincenzo Arcella ,  Claudio Adolfo Pietro Tonelli ,  Solange Barbieri

IPC分类号： C08G65/00 ,  C08L71/00 ,  C08L27/12 ,  C08G65/333

CPC分类号： C08G65/00 ,  C08G65/007 ,  C08G65/33303

摘要： The present invention relates to (per)fluoropolymer compositions, in particular to (per)fluoropolyether compositions comprising:—a (per)fluoropolymer having more than two carboxy groups and—a polyamine. The invention further relates to processes for preparing said compositions and to molded articles obtained from said compositions.

摘要翻译： 本发明涉及（全）氟聚合物组合物，特别是涉及（全）含氟聚醚组合物，其包含：-a（全）氟聚合物，其具有多于两个羧基和多胺。 本发明还涉及制备所述组合物的方法和由所述组合物获得的模塑制品。

公开(公告)号：US09190687B2

公开(公告)日：2015-11-17

申请号：US12306883

申请日：2007-06-25

申请人： Vincenzo Arcella ,  Luca Merlo ,  Alessandro Ghielmi

发明人： Vincenzo Arcella ,  Luca Merlo ,  Alessandro Ghielmi

IPC分类号： H01M4/86 ,  H01M8/10 ,  H01M4/90 ,  H01M4/92 ,  H01M8/02

CPC分类号： H01M8/1004 ,  H01M4/8605 ,  H01M4/90 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0271 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01M8/1093 ,  Y02E60/521 ,  Y02P70/56

摘要： MEA 7-layer assemblies with gasket, comprising: a film of ionomeric membrane (3), containing functional acid groups —SO3H and/or —COOH, having in at least one direction, called direction x, a size variation lower than 0.08%; two GDL sheets (1) and (2) in porous material having on one surface an electrocatalytic layer, not shown in the Figures, of which: the first sheet DGL (1) is coextensive with the membrane (3) surface, positioned so as to overlap thereto; the second sheet GDL (2), having a lower width but the same length of the film of membrane (3), measured in the x direction; the two sheets (1) and (2) placed so that the electrocatalytic layer comes into contact, respectively, with each of the two membrane faces; a gasket positioned according to a frame shape along the assembly perimeter.

摘要翻译： 具有垫片的MEA7层组件包括：包含官能酸基-SO 3 H和/或-COOH的离聚物膜（3）的膜，在至少一个方向上称为方向x，尺寸变化小于0.08％; 两个GDL片（1）和（2）在多孔材料中，在一个表面上具有电催化层，图中未示出，其中：第一片DGL（1）与膜（3）表面共同延伸， 与其重叠; 第二片材GDL（2）在x方向上测量的膜的宽度较低但长度相同; 将两片（1）和（2）放置成使得电催化层分别与两个膜面中的每一个接触; 沿着组件周边根据框架形状定位的垫圈。

公开(公告)号：US09090794B2

公开(公告)日：2015-07-28

申请号：US13697744

申请日：2011-05-19

申请人： Vincenzo Arcella ,  Eliana Ieva ,  Shiow-Ching Lin ,  Marco Avataneo ,  Giuseppe Marchionni

发明人： Vincenzo Arcella ,  Eliana Ieva ,  Shiow-Ching Lin ,  Marco Avataneo ,  Giuseppe Marchionni

IPC分类号： C08K9/10 ,  C08K9/06 ,  C08K3/04 ,  C09D127/16 ,  C09C1/30 ,  C09C1/36 ,  C09C3/08 ,  C09C3/10 ,  C09C3/12 ,  B82Y30/00 ,  C08K9/08 ,  C08L33/00 ,  C08K3/32

CPC分类号： C09D127/16 ,  B82Y30/00 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C08K3/32 ,  C08K9/08 ,  C08L33/00 ,  C09C1/3063 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/3669 ,  C09C1/3676 ,  C09C1/3684 ,  C09C3/08 ,  C09C3/10 ,  C09C3/12 ,  C08L2666/04

摘要： A composition comprising at least one vinylidene fluoride (VDF) polymer [polymer (F)]; and inorganic particles at least partially coated with at least one perfluoropolyether block copolymer [polymer (E)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain Rf), comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain Ra) comprising recurring units of formula: —(CR1R2—CR3R4)—, wherein R1, R2, R3, R4, equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C1-C6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, referably perfluoroalkyl or (per)fluorooxyalkyl. The invention also discloses a method of coating various substrates using said composition.

摘要翻译： 包含至少一种偏二氟乙烯（VDF）聚合物[聚合物（F）]的组合物; 至少部分涂覆有至少一种全氟聚醚嵌段共聚物[聚合物（E）]的无机颗粒，其包含：A）一种或多种（全）氟聚氧亚烷基链段（链Rf），其包含具有至少一个链烯键的重复单元，并且至少 一个碳氟部分，和B）一个或多个包含式： - （CR 1 R 2 -CR 3 R 4） - 的重复单元的聚亚烷基链段（链Ra），其中彼此等于或不同的R 1，R 2，R 3，R 4， 由H组成的组，卤素（优选F，Cl）; 任选地含有氟或其它杂原子的C 1 -C 6（氢）碳基团是指全氟烷基或（全）氟氧基烷基。 本发明还公开了使用所述组合物涂覆各种底物的方法。

公开(公告)号：US20130244138A1

公开(公告)日：2013-09-19

申请号：US13988746

申请日：2011-11-17

申请人： Luca Merlo ,  Claudio Oldani ,  Vincenzo Arcella

发明人： Luca Merlo ,  Claudio Oldani ,  Vincenzo Arcella

IPC分类号： C08F14/04 ,  H01M8/02

CPC分类号： C08F14/04 ,  C08F8/12 ,  C08F214/18 ,  C08F214/242 ,  C08F216/1408 ,  C08J3/09 ,  C08J3/091 ,  C08J3/11 ,  C08J5/2237 ,  C08J2327/02 ,  C08J2327/18 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1039

摘要： A liquid composition comprising at least one aprotic organic solvent and at least one fluorinated ion exchange polymer which consists of recurring units derived from a chlorofluoroolefin of formula CF2═CCIY, wherein Y is F or CI, and from at least one fluorinated functional monomer selected among those of formula CF2═CF—O—(CF2CF(CF3)O)m—(CF2)nSO2X, wherein m is an integer equal to 0 or 1, n is an integer from 0 to 10 and X is chosen among halogens (CI, F, Br, I), —O−M+, wherein M+ is a cation selected among H+, NH4+, K+, Li+, Na+, or mixtures thereof is disclosed. The liquid composition is suitable for the preparation of ion exchange membranes, in particular composite membranes, for use in fuel cell applications.

摘要翻译： 一种液体组合物，其包含至少一种非质子有机溶剂和至少一种氟化离子交换聚合物，所述氟化离子交换聚合物由衍生自式CF2 = CCIY的氯氟烯烃的重复单元组成，其中Y为F或Cl，以及至少一种氟化官能单体，其选自 式CF 2 = CF-O-（CF 2 CF（CF 3）O）m - （CF 2）n SO 2 X的那些，其中m是等于0或1的整数，n是0至10的整数，X选自卤素 ，F，Br，I），-O-M +，其中M +是选自H +，NH 4 +，K +，Li +，Na +或其混合物的阳离子。 液体组合物适用于制备用于燃料电池应用的离子交换膜，特别是复合膜。

公开(公告)号：US08536237B2

公开(公告)日：2013-09-17

申请号：US11374467

申请日：2006-03-14

申请人： Alessandro Ghielmi ,  Paola Vaccarono ,  Vincenzo Arcella

发明人： Alessandro Ghielmi ,  Paola Vaccarono ,  Vincenzo Arcella

IPC分类号： C08J5/20

CPC分类号： C08J5/2237 ,  B01D71/32 ,  B01D71/82 ,  C08J2327/12 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1081 ,  Y02P70/56

摘要： An ionomeric membrane formed of a sulphonic (per)fluorinated ionomer wherein the sulphonic groups are at the end of short side chains (SSC), said ionomer having: equivalent weight between 700 and 1600 g/eq; side chains of formula: —O—CF2—CF2—SO3−M+, wherein M is hydrogen or an alkaline metal; said membrane having the following combination of properties: size variations, for both the orthogonal directions xy of the plane, lower than 15%, measured after dipping of the ionomeric membrane, dried at 105° C. under vacuum for one hour, in demineralized water at 100° C. for 30 minutes; the membrane, dipped at the temperature of 50° C. for 22 hours in a water/ethanol mixture containing 40% by weight of alcohol, remains integral.

摘要翻译： 由磺酸（全）氟化离聚物形成的离聚物膜，其中磺基在短侧链（SSC）的末端，所述离聚物具有700至1600g / eq当量的当量; 式-O-CF2-CF2-SO3-M +的侧链，其中M为氢或碱金属; 所述膜具有以下特性组合：在垂直方向xy的平面上的尺寸变化小于15％，在离聚物膜浸渍后，在105℃真空干燥1小时，在软化水中 在100℃下30分钟; 膜在50℃的温度下浸渍在含有40重量％醇的水/乙醇混合物中22小时保持一体。

公开(公告)号：US07943267B2

公开(公告)日：2011-05-17

申请号：US11645539

申请日：2006-12-27

申请人： Luca Merlo ,  Alessandro Ghielmi ,  Vincenzo Arcella

发明人： Luca Merlo ,  Alessandro Ghielmi ,  Vincenzo Arcella

IPC分类号： H01M8/02 ,  H01M8/10 ,  H01M4/94

CPC分类号： H01M8/0271 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0273 ,  H01M8/0276 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1067 ,  H01M2008/1095 ,  Y02P70/56

摘要： Assemblies or MEA devices (Membrane Electrode Assembly) comprising a membrane and two electrocatalytic layers on each side thereof, wherein: the area of each of the two electrocatalytic layers is lower than that of the membrane; on each of the two sides of the ionomeric membrane there is at least one subgasket, applied on the MEA non catalyzed area; the edges of the ionomeric membranes being enclosed among said subgaskets.

摘要翻译： 组件或MEA装置（膜电极组件），其每侧包括膜和两个电催化层，其中：两个电催化层中的每一个的面积低于膜的面积; 在离聚物膜的两侧各有至少一个垫片，施加在MEA非催化区域上; 离聚物膜的边缘被封闭在所述子垫中。

公开(公告)号：US20100040912A1

公开(公告)日：2010-02-18

申请号：US12520017

申请日：2007-12-20

申请人： Vincenzo Arcella ,  Alessandro Ghielmi ,  Luca Merlo

发明人： Vincenzo Arcella ,  Alessandro Ghielmi ,  Luca Merlo

IPC分类号： H01M8/10

CPC分类号： C08J5/2237 ,  C08J2327/18 ,  H01M8/04007 ,  H01M8/04089 ,  H01M8/04126 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067

摘要： The invention pertains to a process for operating a polymer electrolyte membrane fuel cell (PEMFC), said PEMFC comprising: (a) a membrane comprising at least one fluorinated ionomer [polymer (I)] comprising recurring units derived from tetrafluoroethylene (TFE) and from at least one monomer of formula (M): wherein m is an integer between 1 and 6 and X′ is chosen among halogens (Cl, F, Br, I), —O−M+, wherein M+ is a cation selected among H+, NH4+, K+, Li+, Na+, or mixtures thereof, said polymer (I) having an equivalent weight (EW) of from 700 to 850 g/eq.; (b) a cathode; (c) an anode; said process comprising: (i) feeding gaseous reactants at the electrodes at a relative humidity of at most 66%; (ii) maintaining an average current density between 0.05 and 1.5 A/cm2; and (iii) maintaining an average temperature of more than 65° C.

摘要翻译： 本发明涉及一种操作聚合物电解质膜燃料电池（PEMFC）的方法，所述PEMFC包括：（a）包含至少一种氟化离聚物[聚合物（I）]的膜，其包含衍生自四氟乙烯（TFE）的重复单元和 至少一种式（M）的单体：其中m是1和6之间的整数，X'选自卤素（Cl，F，Br，I），-O-M +，其中M +是选自H +， NH 4 +，K +，Li +，Na +或其混合物，所述聚合物（I）的当量重量（EW）为700至850g / eq; （b）阴极; （c）阳极; 所述方法包括：（i）在至多66％的相对湿度下在电极处输入气态反应物; （ii）保持0.05至1.5A / cm2之间的平均电流密度; 和（iii）保持超过65℃的平均温度。

公开(公告)号：US20090108501A1

公开(公告)日：2009-04-30

申请号：US12296216

申请日：2007-04-06

申请人： Vincenzo Arcella ,  Valeri Kapeliouchko ,  Stefano Ferrero ,  Aniello Gargiulo

发明人： Vincenzo Arcella ,  Valeri Kapeliouchko ,  Stefano Ferrero ,  Aniello Gargiulo

IPC分类号： C08J5/00 ,  C08F2/00

CPC分类号： C08F2/01 ,  B01F7/00975 ,  B01F7/166 ,  B01F7/1665 ,  C08F14/18 ,  C08F14/26 ,  Y10S526/918 ,  C08F2/02

摘要： A fluoropolymer [polymer (F)], a polymerisation process for its manufacture, and a moulding process using such fluoropolymer [polymer (F)].The polymerisation process comprises polymerising at least one fluorinated monomer in a polymerization medium, in which the polymerization medium is mixed by means of a stirring system comprising at least two counter-rotating impellers. Surprisingly and advantageously, the polymerization occurs without fouling or deposit formation on the reactor walls, and moreover, occurs with improved homogeneity, without composition, pressure or temperature gradients, thus enabling obtaining homogeneous polymer composition with no risk of local overheating.A polymer (F) obtained from such process has improved morphology (percentage of organized structures, i.e. of particles of regular shape) and, hence, has good free flowing properties which make it suitable for being processed by compression moulding with no need of intermediate milling or grinding process or other size reduction process.

摘要翻译： 含氟聚合物[聚合物（F）]，其制造的聚合方法和使用这种含氟聚合物[聚合物（F）]的成型方法。 聚合方法包括在聚合介质中聚合至少一种氟化单体，其中聚合介质通过包括至少两个反向旋转叶轮的搅拌系统混合。 令人惊奇和有利地，聚合反应发生在反应器壁上没有结垢或沉积物形成，此外，在没有组成，压力或温度梯度的情况下，具有改进的均匀性发生，从而能够获得均匀的聚合物组合物，而没有局部过热的风险。 从这种方法获得的聚合物（F）具有改善的形态（有组织的结构的百分比，即规则形状的颗粒的百分比），因此具有良好的自由流动性，使其适于通过压缩加工而不需要中间研磨 或研磨过程或其他尺寸缩小过程。

公开(公告)号：US07122608B1

公开(公告)日：2006-10-17

申请号：US08885770

申请日：1997-06-30

申请人： Giulio Brinati ,  Paolo Lazzari ,  Vincenzo Arcella

发明人： Giulio Brinati ,  Paolo Lazzari ,  Vincenzo Arcella

IPC分类号： C08F2/00

CPC分类号： C08F14/22 ,  C08F2/16

摘要： VDF polymerization process, optionally modified with small amounts of one or more fluoro-containing comonomers, carried out in the presence of a microemulsion comprising a (per) fluoropolyether having neutral end groups, having number average molecular weight between 400 and 3000, and a surfactant based on perfluoropolyethers with salified acid end groups, said surfactant having a number molecular weight Mn comprised between 400–600 and having a distribution of molecular weights such that fractions having a number average molecular weight higher than 700 are not present, or are in amount less than 5% by weight.

摘要翻译： VDF聚合方法，任选地用少量一种或多种含氟共聚单体进行改性，所述共聚单体在包含数均分子量在400和3000之间的具有中性端基的（全）氟聚醚的微乳液和表面活性剂 基于具有成盐酸端基的全氟聚醚，所述表面活性剂的数均分子量Mn为400-600，分子量分布为数均分子量高于700的部分不存在，或少量 超过5重量％。

公开(公告)号：US20060216564A1

公开(公告)日：2006-09-28

申请号：US11375605

申请日：2006-03-15

申请人： Vincenzo Arcella ,  Alessandro Ghielmi ,  Paola Vaccarono ,  Luca Merlo

发明人： Vincenzo Arcella ,  Alessandro Ghielmi ,  Paola Vaccarono ,  Luca Merlo

IPC分类号： H01M8/10

CPC分类号： B01D71/82 ,  B01D67/0006 ,  B01D71/32 ,  B01D2323/24 ,  B01D2325/10 ,  H01M4/921 ,  H01M8/1004 ,  H01M8/1011 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1081 ,  H01M8/109 ,  Y02E60/523 ,  Y02P70/56 ,  Y10T428/24372

摘要： CCM formed of a membrane having on one of the two surfaces a first electrocatalytic layer containing a catalyst and on the other one a second electrocatalytic layer containing a catalyst, said electrocatalytic layers and said membrane containing (per)fluorinated ionomers, said CCM having the following characteristics: size variations, for both the orthogonal directions of the plane xy, lower than 15%, by dipping the CCM, after drying at 105° C. under vacuum for one hour in demineralized water at 100° C. for 30 minutes; the CCM remains substantially unchanged after having been subjected to treatments of 60 cycles by dipping in water at 80° C. for 8 hours and then in water at the temperature of 25° C. for 16 hours.

摘要翻译： CCM由具有在两个表面中的一个表面上的含有催化剂的第一电催化剂层和另一个包含催化剂的第二电催化剂层，所述电催化层和所述膜含有（全）氟化离聚物，所述CCM具有以下 特性：在105℃下在100℃下在软化水中真空干燥1小时30分钟后，通过浸渍CCM，平面xy的正交方向，低于15％的尺寸变化，小于15％ 在经过80℃的水中浸渍8小时，然后在25℃的水中浸渍16小时后，经过60个循环的处理后，CCM基本上保持不变。