Polyether alcohols bearing alkoxysilyl groups by alkoxylation of epoxy-functional alkoxysilances over double metal cyanide (DMC) catalysts, and processes for preparation thereof
    83.
    发明授权
    Polyether alcohols bearing alkoxysilyl groups by alkoxylation of epoxy-functional alkoxysilances over double metal cyanide (DMC) catalysts, and processes for preparation thereof 有权
    通过双金属氰化物(DMC)催化剂上的环氧官能团烷氧基化物的烷氧基化而带有烷氧基甲硅烷基的聚醚醇及其制备方法

    公开(公告)号:US08450514B2

    公开(公告)日:2013-05-28

    申请号:US12389667

    申请日:2009-02-20

    IPC分类号: C08G65/26

    摘要: Polyether alcohols having alkoxysilyl groups, the use thereof and a process for their preparation by means of DMC catalysis, characterized in that one or more epoxy-functional alkoxysilanes are added individually or in a mixture with further epoxide compounds and optionally further comonomers, either in block form or in random distribution, onto a chain starter of the formula (VII) R1—H(VII) having at least one reactive hydroxyl group, where R1 is a saturated or unsaturated, optionally branched radical, or a polyether radical of the alkoxy-, arylalkoxy or alkylarylalkoxy group type, in which the carbon chain may be interrupted by oxygen atoms or corresponds to a polyetheralkoxy radical or to a singularly or multiply fused phenolic group.

    摘要翻译: 具有烷氧基甲硅烷基的聚醚醇,其用途及其通过DMC催化制备的方法,其特征在于一种或多种环氧官能的烷氧基硅烷单独或与另外的环氧化合物和任选的其它共聚单体混合加入, 形式或随意分布于具有至少一个反应性羟基的式(Ⅶ)R 1-H(Ⅶ)的链式起始物,其中R 1是饱和或不饱和的,任意支化的基团,或烷氧基 - ,芳基烷氧基或烷基芳基烷氧基类型,其中碳链可以被氧原子间隔或对应于聚醚烷氧基或单个或多重稠合的酚基。

    Compound having silsesquioxane skeleton and its polymer
    84.
    发明授权
    Compound having silsesquioxane skeleton and its polymer 有权
    具有倍半硅氧烷骨架的化合物及其聚合物

    公开(公告)号:US08420764B2

    公开(公告)日:2013-04-16

    申请号:US13423548

    申请日:2012-03-19

    IPC分类号: C08G77/00

    摘要: A polymer having a structural unit represented by Formula (3): wherein R1 is phenyl in which any hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms; in the alkyl having 1 to 5 carbon atoms, any —CH2—, which is not adjacent to each other, may be replaced by —O—, and any hydrogen may be replaced by halogen; Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, or phenyl in which any hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms; in the alkyl having 1 to 10 carbon atoms and alkyl having 1 to 5 carbon atoms which is a substituent of phenyl, any —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and any hydrogen may be replaced by halogen; and Q3 is a group represented by Formula (4):

    摘要翻译: 具有由式(3)表示的结构单元的聚合物:其中R 1是其中任何氢可以被卤素或具有1至5个碳原子的烷基取代的苯基; 在具有1至5个碳原子的烷基中,不相邻的任何-CH 2 - 可以被-O-代替,并且任何氢可以被卤素取代; Q1是氢,卤素,具有1-10个碳原子的烷基,环丙基,环丁基,环戊基,环己基,环己烯基或苯基,其中任何氢可以被卤素或具有1-5个碳原子的烷基取代; 在具有1至10个碳原子的烷基和具有1至5个碳原子的烷基作为苯基的取代基时,任何不相邻的-CH 2 - 可以被-O - , - CH = CH- 或-C≡C-,并且任何氢可以被卤素取代; Q3为由式(4)表示的基团:<-Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z5-(4)其中代码<表示与硅的键合点; l,m,n和p独立地为0,1,2或3; A1,A2,A3,A4,Z0,Z1,Z2,Z3和Z5如权利要求1中所定义。

    COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER
    85.
    发明申请
    COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER 有权
    具有SILESESQUIOXANE SKELETON及其聚合物的化合物

    公开(公告)号:US20120178894A1

    公开(公告)日:2012-07-12

    申请号:US13423548

    申请日:2012-03-19

    IPC分类号: C08G77/26

    摘要: The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms,

    摘要翻译: 本发明涉及由式(1)表示的化合物和使用该化合物获得的聚合物:其中R1是可具有取代基的苯基,Q1是氢,卤素,具有1-10个碳原子的烷基,环丙基,环丁基,环戊基, 环己基,环己烯基或苯基,其中任选的氢可以被卤素或具有1至5个碳原子的烷基取代,-A-Z 0 A 1 -Z 1,A 2-Z 2,A 3-Z 3, - (2)和Q2是由式(2)表示的基团:其中代码<表示具有硅的键合点,l,m,n和p独立地为0,1,2或3,A1至A4独立地为 单键,1,4-亚环己基,1,4-亚环己烯基,作为二价基团的碳原子数为6〜10的稠环基或1,4-亚苯基,Z0〜Z3独立为单键,CH = CH - ,-C≡C-,-COO-,-OCO-或具有1至20个碳原子的亚烷基,Z 4是单键,-CH = CH - , - C≡C - , - COO-,-OCO - 或亚烷基 e具有1至20个碳原子。 而式(1)中的Y1是权利要求1中定义的基团。

    Organosilicone compositions and methods for preparing them
    86.
    发明授权
    Organosilicone compositions and methods for preparing them 有权
    有机硅组合物及其制备方法

    公开(公告)号:US07902314B2

    公开(公告)日:2011-03-08

    申请号:US12718552

    申请日:2010-03-05

    摘要: Disclosed herein is a composition comprising a structure (M1)a(ME)b(D1)c(D2)d(T)e(Q)f, wherein M1=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D1=R6R7SiO2/2; D2=R8R9SiO2/2; T=R10SiO3/2; and Q=SiO4/2; wherein each RE is independently a monovalent hydrocarbon radical containing an epoxy group; R9 comprises a structure -L1-Si(R11)g(OR12)3-g or L2(D3)h(M2)i-L3-Si(R13)g′(OR14)3-g′, wherein L1, L2, and L3 are independently divalent linking groups; g and g′ independently have a value from 0 to 2; M2=R15R16R17SiO1/2; D3=R18R19SiO2/2; wherein R1, R2, R3, R4, R5, R6, R7, R8, R10, R11, R12, R13, R14, R15, R16, R17, R18, and R19 are independently monovalent hydrocarbon radicals; wherein a, b, c, d, e, f, h, and i are stoichiometric subscripts that are zero or positive subject to the following limitations: b has a value of 2; d is greater than or equal to 1; when (a+c+e+f) is equal to zero, (b+d) is greater than or equal to 3; and when i=0, h is at least 1.

    摘要翻译: 本文公开了包含结构(M1)a(ME)b(D1)c(D2)d(T)e(Q)f的组合物,其中M1 = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D1 = R6R7SiO2 / 2; D2 = R8R9SiO2 / 2; T = R10SiO3 / 2; 和Q = SiO4 / 2; 其中每个RE独立地为含有环氧基的单价烃基; R9包括结构-L1-Si(R11)g(OR12)3-g或L2(D3)h(M2)i-L3-Si(R13)g'(OR14)3-g',其中L1,L2, 和L3独立地是二价连接基团; g和g'独立地具有0至2的值; M2 = R15R16R17SiO1 / 2; D3 = R18R19SiO2 / 2; 其中R1,R2,R3,R4,R5,R6,R7,R8,R10,R11,R12,R13,R14,R15,R16,R17,R18和R19独立地是一价烃基; 其中a,b,c,d,e,f,h和i是化学计量下标,其为零或正,受制于以下限制:b具有值2; d大于或等于1; 当(a + c + e + f)等于零时,(b + d)大于或等于3; 当i = 0时,h至少为1。

    Organosilicone Compositions and Methods for Preparing Them
    87.
    发明申请
    Organosilicone Compositions and Methods for Preparing Them 有权
    有机硅组合物及其制备方法

    公开(公告)号:US20100249358A1

    公开(公告)日:2010-09-30

    申请号:US12718552

    申请日:2010-03-05

    IPC分类号: C08G77/06

    摘要: Disclosed herein is a composition comprising a structure (M1)a(ME)b(D1)c(D2)d(T)e(Q)f, wherein M1=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D1=R6R7SiO2/2; D2=R8R9SiO2/2; T=R10SiO3/2; and Q=SiO4/2; wherein each RE is independently a monovalent hydrocarbon radical containing an epoxy group; R9 comprises a structure -L1-Si(R11)g(OR12)3-g or L2(D3)h(M2)i-L3-Si(R13)g′(OR14)3-g′, wherein L1, L2, and L3 are independently divalent linking groups; g and g′ independently have a value from 0 to 2; M2=R15R16R17SiO1/2; D3=R18R19SiO2/2; wherein R1, R2, R3, R4, R5, R6, R7, R8, R10, R11, R12, R13, R14, R15, R16, R17, R18, and R19 are independently monovalent hydrocarbon radicals; wherein a, b, c, d, e, f, h, and i are stoichiometric subscripts that are zero or positive subject to the following limitations: b has a value of 2; d is greater than or equal to 1; when (a+c+e+f) is equal to zero, (b+d) is greater than or equal to 3; and when i=0, h is at least 1.

    摘要翻译: 本文公开了包含结构(M1)a(ME)b(D1)c(D2)d(T)e(Q)f的组合物,其中M1 = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D1 = R6R7SiO2 / 2; D2 = R8R9SiO2 / 2; T = R10SiO3 / 2; 和Q = SiO4 / 2; 其中每个RE独立地为含有环氧基的单价烃基; R9包括结构-L1-Si(R11)g(OR12)3-g或L2(D3)h(M2)i-L3-Si(R13)g'(OR14)3-g',其中L1,L2, 和L3独立地是二价连接基团; g和g'独立地具有0至2的值; M2 = R15R16R17SiO1 / 2; D3 = R18R19SiO2 / 2; 其中R1,R2,R3,R4,R5,R6,R7,R8,R10,R11,R12,R13,R14,R15,R16,R17,R18和R19独立地是一价烃基; 其中a,b,c,d,e,f,h和i是化学计量下标,其为零或正,受制于以下限制:b具有值2; d大于或等于1; 当(a + c + e + f)等于零时,(b + d)大于或等于3; 当i = 0时,h至少为1。

    Pitch pocket and sealant
    88.
    再颁专利
    Pitch pocket and sealant 有权
    口袋和密封剂

    公开(公告)号:USRE41586E1

    公开(公告)日:2010-08-24

    申请号:US11152840

    申请日:2005-06-14

    IPC分类号: C08K5/06 C08K5/053

    摘要: A one-part pourable sealant that is thermosetting, non-shrinking, and capable of quickly curing in a closed cavity to a depth of at least two inches includes a silyl-terminated polymer, a hygroscopic plasticizer present in an amount that is effective to promote rapid and deep curing, and a catalyst for promoting curing of the silyl-terminated polymer. The sealer composition is useful in a method of forming a seal around a roof penetration. The method includes dispensing the sealer composition into a pitch pocket formed around a roof penetration and allowing the sealer composition dispensed into the pitch pocket to cure by exposure to moisture in the air.

    摘要翻译: 热固性,非收缩性和能够在封闭空腔中快速固化至至少两英寸深度的单组分可倾注密封剂包括甲硅烷基封端的聚合物,以有效促进的量的吸湿增塑剂 快速和深度固化,以及用于促进甲硅烷基封端的聚合物固化的催化剂。 密封剂组合物可用于围绕屋顶穿透形成密封的方法。 该方法包括将密封剂组合物分配成围绕屋顶穿透形成的沥青袋,并且通过暴露于空气中的湿气使分配到沥青袋中的密封剂组合物固化。

    SILANE-TERMINATED PREPOLYMERS AND RELATIVE ADHESIVE SEALANT FORMULATIONS
    89.
    发明申请
    SILANE-TERMINATED PREPOLYMERS AND RELATIVE ADHESIVE SEALANT FORMULATIONS 审中-公开
    硅烷封端的预处理剂和相关的胶粘剂配方

    公开(公告)号:US20100010166A1

    公开(公告)日:2010-01-14

    申请号:US12441345

    申请日:2007-09-14

    摘要: Silane-terminated prepolymers which contain, on at least one silicon atom, at least one hydrolyzable aryloxy type functional group. The use of these prepolymers, containing silyl-aryloxy terminated groups, in adhesive sealant formulations increases their reactivity so enabling the use of metal-based catalysts, which are in most cases toxic and act as oxidation catalysts, to be avoided or their quantity to be reduced compared with the standard quantity used in conventional formulations, yet ensuring considerably shorter cross-linking times than those of formulations based on known silane-terminated prepolymers.

    摘要翻译: 在至少一个硅原子上含有至少一个可水解的芳氧基型官能团的硅烷封端的预聚物。 在粘合剂密封剂配方中使用这些含有甲硅烷基 - 芳氧基封端基团的预聚物增加了它们的反应性,从而能够使用金属基催化剂,这在大多数情况下是有毒的并且作为氧化催化剂被避免或者其数量 与常规制剂中使用的标准量相比降低,但确保了与基于已知的硅烷封端的预聚物的制剂相比短得多的交联时间。