公开(公告)号：US20050217998A1

公开(公告)日：2005-10-06

申请号：US11088509

申请日：2005-03-24

Applicant: Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/04 ,  H01G9/155 ,  H01M4/137 ,  H01M4/60 ,  H01M4/04

CPC classification number: H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

Abstract: Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5·10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

Abstract translation: 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不低于5.10〜5mol / l，（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是 双（水杨醛） - 乙二胺在希夫碱。

公开(公告)号：US20090026085A1

公开(公告)日：2009-01-29

申请号：US11917002

申请日：2005-06-10

Applicant: Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

Inventor： Hidenori Uchi ,  Kenji Tamamitsu ,  Shunzo Suematsu ,  Satoru Tsumeda ,  Alexander M. Timonov ,  Sergey A. Logvinov ,  Nikolay Shkolnik ,  Sam Kogan

IPC: C25B3/00

CPC classification number: H01G11/48 ,  H01G11/24 ,  H01G11/28 ,  H01G11/30 ,  H01G11/32 ,  H01G11/86 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/60 ,  H01M4/602 ,  H01M4/606 ,  H01M10/052 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: A method for producing an electrode for an electrochemical element absorbs monomers for polymerization on a surface having a specific surface area of 100 to 3000 m2g−1 and having an average pore diameter in the range of 0.4 to 100 nm, performing electrolysis polymerization by applying pulse voltage, and forming a conductive polymer layer on the surface of the conductive porous material, forming a thin and uniform electrode film. In a method for producing an electrochemical element, a conductive polymer layer is formed on the conductive porous material by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area and pore diameter as above forming a electrochemical cell by using the conductive porous material, the monomers are absorbed in the pores, putting the electrochemical cell and the electrolyte solution in an outer casing, and performing electrolysis polymerization of the monomers in the electrolyte solution.

Abstract translation: 一种电化学元件用电极的制造方法，在比表面积为100〜3000m 2 / g的表面吸收聚合用单体，平均孔径为0.4〜100nm，通过施加脉冲进行电解聚合 电压，并在导电性多孔材料的表面上形成导电聚合物层，形成薄而均匀的电极膜。 在电化学元件的制造方法中，通过在上述形成电化学电池的比表面积和孔径以上的导电性多孔质材料的表面上吸收用于聚合的单体，在导电性多孔质材料上形成导电性聚合物层， 导电多孔材料，单体被吸收在孔中，将电化学电池和电解质溶液放入外壳中，并进行电解液中单体的电解聚合。

公开(公告)号：US06996428B2

公开(公告)日：2006-02-07

申请号：US10782542

申请日：2004-02-18

Applicant: Alexander V. Kislov ,  Igor A. Novikov ,  Sergey V. Petrovykh ,  Oleg N. Khomyakov

Inventor： Alexander V. Kislov ,  Igor A. Novikov ,  Sergey V. Petrovykh ,  Oleg N. Khomyakov

IPC: A61B5/04

CPC classification number: A61B5/681 ,  A61B5/02116 ,  A61B5/0531

Abstract: The sensor has four electrodes arranged on a common base, three of which are made as closed circuits, placed one into another, whereas the fourth electrode is placed inside the smallest circuit. The external and the central electrodes form a pair of current-feeding electrodes, whereas the electrodes disposed between them form a pair of measuring electrodes. The second design option of the sensor has three electrodes, two of which are made as closed circuits placed one into another, whereas the third electrode is placed inside the electrode that is smaller. The external and the central electrodes form a pair of current-feeding electrodes, and the electrode arranged between them together with the external or the central electrode form a pair of measuring electrodes. The design of sensors makes it possible to use them in combination with biological signal sensors of non-rheographic modality, for example, pulse wave, temperature. The sensor may be incorporated in wristwatch or bracelet.

Abstract translation: 传感器具有布置在公共基座上的四个电极，其中三个电极被制成闭合电路，一个放置在另一个中，而第四电极放置在最小的电路内。 外部和中心电极形成一对馈电电极，而设置在它们之间的电极形成一对测量电极。 传感器的第二个设计选项有三个电极，其中两个电极被制成一个放置在另一个中的闭合电路，而第三个电极放置在较小的电极内部。 外部和中心电极形成一对馈电电极，并且其间与外部或中心电极一起设置在它们之间的电极形成一对测量电极。 传感器的设计使得可以将它们与非流变模态的生物信号传感器结合使用，例如脉冲波，温度。 传感器可以并入手表或手镯。

公开(公告)号：US20050225928A1

公开(公告)日：2005-10-13

申请号：US11098698

申请日：2005-04-04

Applicant: Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/00 ,  H01G9/022 ,  H01G9/04 ,  H01G9/042 ,  H01G9/22 ,  H01M4/04 ,  H01M4/60

CPC classification number: H01M4/602 ,  H01G9/042 ,  H01G9/22 ,  H01G11/02 ,  H01G11/26 ,  H01G11/32 ,  H01G11/48 ,  Y02E60/13 ,  Y10T29/417

Abstract: The invention is an electrochemical capacitor with its electrodes made on a conducting substrate with a layer of a redox polymer of the poly[Me(R-Salen)] type deposited onto the substrate. Me is a transition metal (for example, Ni, Pd, Co, Cu, Fe), R is an electron-donating substituent (for example, CH3O—, C2H5O—, HO—, —CH3), Salen is a residue of bis(salicylaldehyde)-ethylendiamine in Schiff's base. The electrolyte comprises of an organic solvent, compounds capable of dissolving in such solvents with the resulting concentration of no less than 0.01 mol/l and dissociating with the formation of ions, which are electrochemically inactive within the range of potentials from −3.0 V to +1.5 V (for example, salts of tetramethyl ammonium, tetrapropyl ammonium, tetrabutyl ammonium), and a dissolved metal complex [Me(R-Salen)]. The method of using the capacitor contemplates periodically alternating the connection polarity of the electrodes, causing the electrochemical characteristics of the electrodes to regenerate.

Abstract translation: 本发明是一种电化学电容器，其电极在导电衬底上制成，其上沉积有一层聚[Me（R-Salen）]型氧化还原聚合物。 Me是过渡金属（例如Ni，Pd，Co，Cu，Fe），R是给电子取代基（例如CH 3 O，C 2， H 2 O-，HO-，-CH 3 3），Salen是席夫碱中双（水杨醛） - 乙二胺的残基。 电解质包括有机溶剂，能够溶解在这样的溶剂中的化合物，所得到的浓度不低于0.01mol / l，并​​且在电位从-3.0V到+ 1.5V（例如四甲基铵，四丙基铵，四丁基铵的盐）和溶解的金属络合物[Me（R-Salen）]。 使用电容器的方法考虑周期性地交替电极的连接极性，导致电极的电化学特性再生。

公开(公告)号：US07563354B2

公开(公告)日：2009-07-21

申请号：US11088509

申请日：2005-03-24

Applicant: Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Mikhailovich Timonov ,  Sergey Anatolijevich Logvinov ,  Dmitriy Ivanovich Pivunov ,  Svetlana Viktorovna Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: C25D9/00

CPC classification number: H01M4/0438 ,  C08G12/06 ,  H01G9/0036 ,  H01G9/155 ,  H01M4/0452 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  Y02E60/13

Abstract: Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from −3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5-10−5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

Abstract translation: 聚 - [Me（R-Salen）]型氧化还原聚合物在导电基材上的应用是通过电化学聚合的方法实现的。 所述聚合是通过在衬底（用作阳极）和对电极（用作阴极）之间提供电压来实现的，两者都被浸没在含有机溶剂的电解质中，并且能够溶解在 所述溶剂。 该过程伴随着在-3.0V至+1.5V的电位范围内产生电化学惰性的（浓度不小于0.01mol / l）的离子，并且溶解在金属络合物[Me（R-Salen） 浓度不小于5-10-5mol / l（其中：Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是双 - （水杨醛）的残基， 乙二胺在希夫的基地。

公开(公告)号：US20050258042A1

公开(公告)日：2005-11-24

申请号：US11100036

申请日：2005-04-06

Applicant: Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

Inventor： Alexander Lyubomirskiy ,  Valeriy Pavlov ,  Alexander Timonov ,  Sergey Logvinov ,  Dmitriy Pivunov ,  Svetlana Vasiljeva ,  Nik Shkolnik ,  Sam Kogan

IPC: H01G9/00 ,  H01G9/04 ,  H01G9/058 ,  H01M4/137 ,  H01M4/60 ,  H01M4/66 ,  H01M4/04

CPC classification number: H01M4/137 ,  H01G9/0032 ,  H01G9/0036 ,  H01G9/04 ,  H01G11/48 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/60 ,  H01M4/66 ,  H01M4/663 ,  H01M4/667 ,  H01M4/668 ,  Y02E60/13

Abstract: Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.

Abstract translation: 公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。 所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。 在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。