公开(公告)号：US07334780B2

公开(公告)日：2008-02-26

申请号：US11802496

申请日：2007-05-23

申请人： Hiroki Sakakibara ,  Ken Ooyachi ,  Hiroshi Tasaka

发明人： Hiroki Sakakibara ,  Ken Ooyachi ,  Hiroshi Tasaka

IPC分类号： B01F3/04

CPC分类号： A61H33/02 ,  A23L2/54 ,  A61H33/60 ,  A61H2033/145 ,  A61M35/00 ,  B01F3/0446 ,  B01F3/04787 ,  B01F3/04985 ,  B01F15/0022 ,  B01F15/00344 ,  B01F2003/04404 ,  B01F2003/04858 ,  B01F2003/04893 ,  B01F2215/0052 ,  Y10S261/07

摘要： Hot water (12) in a bath (11) is pumped up by a suction pump (9) and introduced into a carbon dioxide gas dissolver (7) through solution flow rate adjusting means (14) and then, poured into the bath (11). Carbon dioxide gas supplied from a carbon dioxide gas cylinder (1) is introduced into the carbon dioxide gas dissolver (7) through gas flow rate adjusting means (5). At this time, the quantity of bubbles existing in artificial carbonated spring in a take-out pipe (15) is measured with a measuring device (13), and the solution flow rate adjusting means (14), gas flow rate adjusting means (5) and the like are controlled by means of a control device (16) using a relational expression between a preliminarily set quantity of bubbles and carbon dioxide concentration to obtain a desired concentration of carbon dioxide gas in carbonated spring. Because the carbon dioxide gas flow control means (5) is provided between the carbon dioxide gas dissolver (7) and a carbon dioxide gas supply source, carbonated spring of a high concentration can be always manufactured even if the pressure of supplied carbon dioxide gas changes or the permeating performance of a membrane changes.

摘要翻译： 将浴（11）中的热水（12）通过抽吸泵（9）泵送，并通过溶液流速调节装置（14）引入二氧化碳气体溶解器（7）中，然后倒入槽 ）。 从二氧化碳气瓶（1）供给的二氧化碳气体通过气体流量调节机构（5）引入二氧化碳气体溶解器（7）。 此时，通过测量装置（13）测量出料管（15）中人造碳酸弹簧中存在的气泡量，溶液流​​量调节装置（14），气体流量调节装置（5） ）等通过使用预先设定量的气泡和二氧化碳浓度之间的关系式的控制装置（16）来控制，以在碳酸弹簧中获得所需的二氧化碳浓度。 由于二氧化碳气体流量控制装置（5）设置在二氧化碳气体溶解器（7）和二氧化碳气体供应源之间，所以即使所供给的二氧化碳气体的压力变化，也可以始终制造高浓度的碳酸泉 或膜的渗透性能发生变化。

公开(公告)号：US5073606A

公开(公告)日：1991-12-17

申请号：US684504

申请日：1991-04-15

申请人： Isao Sasaki ,  Kozi Nishida ,  Hisao Anzai

发明人： Isao Sasaki ,  Kozi Nishida ,  Hisao Anzai

IPC分类号： C08F8/32 ,  C08F8/48 ,  C08F20/52

CPC分类号： C08F8/48

摘要： A methacrylimide containing polymer which is a thermoplastic polymer comprising from 2% to 100% by weight of a structural unit represented by the general formula: ##STR1## where R represents a hydrogen atom or an aliphatic group, aromatic group or cycloaliphatic hydrocarbon group with 1 to 20 carbon atoms and from 0 to 98% by weight of a structural unit derived from as ethylenic monomer, the polymer having(a) a molecular weight (Mw) of greater than 50,000 and less than 200,000 as measured by GPC, and(b) an amount of amide segments in the polymer of less than 5% by weight. The methacrylimide containing polymer has excellent transparency and heat resistance, as well as a low yellowness and aging coloration under heating.

公开(公告)号：USH1004H

公开(公告)日：1991-12-03

申请号：US381478

申请日：1989-07-18

申请人： Isao Sasaki ,  Kozi Nishida ,  Hisao Anzai

发明人： Isao Sasaki ,  Kozi Nishida ,  Hisao Anzai

IPC分类号： C08L23/08 ,  C08L33/10 ,  C08L33/24 ,  C08L79/08 ,  C08F8/00

CPC分类号： C08L23/0869 ,  C08L33/10 ,  C08L33/24 ,  C08L79/08 ,  C08L2666/04 ,  C08L2666/02

摘要： A thermoplastic resin composition comprising:(A) 1-99 parts by weight of polymethacrylimide and(B) 99-1 parts by weight of ethylene-ethyl acrylate copolymer, polyamide-imide, polyether-ether ketone, or polyether sulfone. The thermoplastic resin composition has a high impact strength as well as good processability.

公开(公告)号：US5024914A

公开(公告)日：1991-06-18

申请号：US422772

申请日：1989-10-17

申请人： Ryo Funato ,  Syuji Takahiro ,  Keiji Yoshida ,  Shinji Kubo ,  Motoshi Inagaki

发明人： Ryo Funato ,  Syuji Takahiro ,  Keiji Yoshida ,  Shinji Kubo ,  Motoshi Inagaki

IPC分类号： G03G9/08 ,  G03G9/087

CPC分类号： G03G9/08702 ,  G03G9/0819 ,  G03G9/08797

摘要： A resin for toner containing fine particles with a particle size passing through a 200 mesh sieve of not greater than 10% by weight.

公开(公告)号：US4977197A

公开(公告)日：1990-12-11

申请号：US192931

申请日：1988-05-12

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/08 ,  A61K6/083 ,  A61K6/09

CPC分类号： A61K6/083 ,  A61K6/09

摘要： A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing at least one carboxylic acid monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOY group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOZ group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.3 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and each of X, Y and Z is a hydrogen atom, NH.sub.4 or an alkali metal atom; or the formula: ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is a diaminobenzophenone compound of the formula: ##STR4## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group.

摘要翻译： 一种可光聚合的牙科用组合物，其包含：（A）通过聚合至少一种下式的羧酸单体获得的有机复合填料：其中R 1是氢原子，C 1 -C 15烷基，-COOY基， 卤素原子或苯基或其衍生物; R2是氢原子，C1-C15烷基，-COOZ基，卤原子或苯基或其衍生物; R3是氢原子，C1-C15烷基，卤原子或苯基或其衍生物; X，Y和Z各自为氢原子，NH 4或碱金属原子; 或下式：其中R 4和R 5各自为氢原子，C 1 -C 15烷基，卤原子或苯基或其衍生物; 和在其中分散无机化合物的聚合体系中的至少一种可自由基聚合的乙烯基单体; （B）包含2,2-双[4-（甲基丙烯酰氧基乙氧基）苯基]丙烷，至少一种下式的六官能氨基甲酸酯（甲基）丙烯酸酯的单体混合物：其中n为1至10的整数 R 1和R 2可以相同或不同，为氢原子或甲基，稀释乙烯基乙烯基单体; 和（C）包含α-二酮化合物和还原剂的光聚合引发剂，其中还原剂是下式的二氨基二苯甲酮化合物：其中可以相同或不同的R 1至R 4各自为氢原子 或C 1 -C 5烷基，条件是它们中的至少一个是烷基。 n

公开(公告)号：US4933376A

公开(公告)日：1990-06-12

申请号：US184803

申请日：1988-04-22

申请人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

发明人： Isao Sasaki ,  Nobuhiro Mukai ,  Hitoshi Ige

IPC分类号： A61K6/083 ,  A61K6/09

CPC分类号： A61K6/083 ,  A61K6/087 ,  A61K6/09

摘要： A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing a sulfonic acid or sulfonate monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.20 alkyl group, a phenyl group or a derivative thereof, or a halogen atom; ##STR2## wherein each of R.sub.2 and R.sub.3 is a hydrogen atom or a C.sub.1 -C.sub.15 alkyl group, R.sub.4 is a C.sub.1 -C.sub.15 alkylene group, m is an integer of from 1 to 20 and n is an integer of from 0 to 20; and Y is a hydrogen atom, NH.sub.4 or an alkali metal atom, and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein X is ##STR4## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is at least one member selected from the group consisting of diaminobenzophenone compounds of the formula: ##STR5## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group, and C.sub.5 -C.sub.10 alkyl esters of 4-(N,N-dimethylamino)benzoic acid.

公开(公告)号：US4877844A

公开(公告)日：1989-10-31

申请号：US135470

申请日：1987-12-21

申请人： Kazuo Kishida ,  Yutaka Toyooka ,  Yoshiyuki Mikami

发明人： Kazuo Kishida ,  Yutaka Toyooka ,  Yoshiyuki Mikami

IPC分类号： C08F236/12 ,  C08F279/02

CPC分类号： C08F236/12 ,  C08F279/02

摘要： A process for producing a low gloss thermoplastic resin which comprises polymerizing in two steps from 20 to 70 parts by weight of a butadiene polymer, at least 70% by weight of which is constituted by butadiene, with from 30 to 80 parts by weight of a total of from 15 to 40% by weight of a vinyl cyanide monomer and from 60 to 85% by weight of an aromatic vinyl monomer, characterized in that for the polymerization of the first step, the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged in amounts corresponding to from 20 to 80% by weight of the entire butadiene polymer, from 20 to 80% by weight of the entire vinyl cyanide monomer and from 20 to 80% by weight of the entire aromatic vinyl monomer, respectively, and after the completion of the polymerization of the first step, the rest of the butadiene polymer, the vinyl cyanide monomer and the aromatic vinyl monomer were charged for the polymerization of the second step.

摘要翻译： 一种低光泽性热塑性树脂的制造方法，其特征在于，将20〜70重量份的丁二烯聚合物，其中至少70重量％由丁二烯构成，其中20〜70重量份， 总计为15至40重量％的乙烯基氰单体和60至85重量％的芳族乙烯基单体，其特征在于，对于第一步骤的聚合，丁二烯聚合物，乙烯基氰单体和芳族化合物 乙烯基单体的量相当于整个丁二烯聚合物的20至80重量％，全部乙烯基氰单体的20至80重量％和芳族乙烯基单体总量的20至80重量％ ，在第一步聚合完成后，加入其余的丁二烯聚合物，乙烯基氰单体和芳族乙烯基单体进行第二步的聚合反应。

公开(公告)号：US4816524A

公开(公告)日：1989-03-28

申请号：US857163

申请日：1986-04-29

申请人： Hisao Anzai ,  Hideaki Makino ,  Isao Sasaki ,  Kozi Nishida ,  Masaru Morimoto

发明人： Hisao Anzai ,  Hideaki Makino ,  Isao Sasaki ,  Kozi Nishida ,  Masaru Morimoto

IPC分类号： C08F8/32

CPC分类号： C08F8/32

摘要： Methacrylimide-containing polymers are continuously produced by introducing 10 to 60 wt. % of an inert solvent, 90 to 40 wt. % of methacrylic acid, a methacrylic acid ester or a monomer mixture comprising at least 50 wt. % of methacrylic acid or a methacrylic acid ester, and a radical polymerization initiator and a molecular weight modifier into a polymerization reaction zone, converting at least 80 wt. % of the charged monomer to a polymer at 60.degree.-170.degree. C., adding a compound represented by the formula:R--NH.sub.2wherein R represents a hydrogen atom, an alkyl group having 1-12 carbon atoms, a cycloalkyl group having 7-11 carbon atoms or an aryl group having 6-10 carbon atoms,to the polymerization reaction liquid, carrying out reaction of the resulting mixture at 150.degree. to 300.degree. C. in an imidization reaction zone, and finally separating volatile substances from the reaction fluid.

摘要翻译： 含有甲基丙烯酰胺的聚合物通过引入10至60wt。 ％的惰性溶剂，90〜40wt。 ％的甲基丙烯酸，甲基丙烯酸酯或包含至少50wt。 ％的甲基丙烯酸或甲基丙烯酸酯，以及自由基聚合引发剂和分子量调节剂进入聚合反应区，将至少80wt。 加入到60℃-170℃的聚合物的％，加入由式R-NH 2表示的化合物，其中R表示氢原子，具有1-12个碳原子的烷基，具有7个 -11个碳原子或具有6-10个碳原子的芳基，在聚合反应液中，在酰亚胺化反应区中将所得混合物在150-300℃下进行反应，最后从反应中分离出挥发性物质 流体。

公开(公告)号：US4741932A

公开(公告)日：1988-05-03

申请号：US68808

申请日：1987-06-30

申请人： Kiyoshi Ichimura ,  Koichiro Kido ,  Kazuhiko Hotta ,  Shogo Yamamoto

发明人： Kiyoshi Ichimura ,  Koichiro Kido ,  Kazuhiko Hotta ,  Shogo Yamamoto

IPC分类号： C08L61/20 ,  C09D133/06 ,  B05D3/02

CPC分类号： C09D133/066 ,  C08L61/20

摘要： A coating composition comprising (A) 100 parts by weight of an acrylic copolymer and (B) from 0 to 40 parts by weight of a curing agent, wherein said acrylic copolymer is a copolymer of a monomer mixture composed essentially of:(1) from 1 to 50% by weight of 1,4-butanediol mono(meth)acrylate,(2) from 0.2 to 10% by weight of an .alpha.,.beta.-monoethylenic unsaturated carboxylic acid, and(3) from 40 to 98.8% by weight of other copolymerizable monomers,provided that the total of the 1,4-butanediol mono(meth)acrylate and hydroxyl group-containing monomers in the copolymerizable monomers, is not more than 50% by weight of the monomer mixture.

摘要翻译： 一种涂料组合物，其包含（A）100重量份的丙烯酸共聚物和（B）0-40重量份的固化剂，其中所述丙烯酸共聚物是基本上由以下组成的单体混合物的共聚物：（1） 1〜50重量％的1,4-丁二醇单（甲基）丙烯酸酯，（2）0.2〜10重量％的α，β-单亚乙烯基不饱和羧酸，（3）40〜98.8重量％ 的其它可共聚单体，只要共聚单体中的1,4-丁二醇单（甲基）丙烯酸酯和含羟基的单体的总量不超过单体混合物的50重量％。

公开(公告)号：US4526929A

公开(公告)日：1985-07-02

申请号：US284668

申请日：1981-07-20

申请人： Kazuo Kishida ,  Akira Hasegawa ,  Yasunori Kawachi ,  Hiroshi Kawasaki ,  Hiroshi Mizukoshi

发明人： Kazuo Kishida ,  Akira Hasegawa ,  Yasunori Kawachi ,  Hiroshi Kawasaki ,  Hiroshi Mizukoshi

IPC分类号： C08F285/00 ,  C08L7/00 ,  C08L21/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/06 ,  C08L51/00 ,  C08L51/02 ,  C08L51/06 ,  C08L31/02 ,  C08L33/08 ,  C08L33/10 ,  C08L51/08

CPC分类号： C08L33/06 ,  C08F285/00 ,  C08L51/003 ,  C08L51/00 ,  Y10S525/902

摘要： Disclosed is a resin composition which is usable for an exterior article without being coated on its surface when molded into the article and is excellent in the color tone and has good impact resistance and weatherability, said composition comprising (I) 10 to 70% by weight of a high-rubber-content graft polymer obtained by polymerizing 50 to 10% by weight of a monomer mixture (C) comprising 10 to 90% by weight of at least one aromatic vinyl monomer and 90 to 10% by weight of at least one ethylenically unsaturated monomer represented by the following general formula:CH.sub.2 .dbd.CRXwherein R stands for a hydrogen atom or methyl group, and X stands for a group --CN or --COOR.sub.1 in which R.sub.1 stands for an alkyl group having 1 to 8 carbon atoms, in the presence of a latex of a multi-layer crosslinked acrylic rubber particles containing 5 to 30% by weight of a rigid crosslinked resin (A) having a core particle size of 0.15 to 0.40.mu. in the interior of the rubber particles and 45 to 85% by weight of a crosslinked acrylic acid ester polymer (B) comprising an acrylic acid ester as the main component in the outer layer of the rubber particles, so that the total amount of the components (A), (B) and (C) is 100% by weight, (II) 90 to 30% by weight of a thermoplastic resin obtained by polymerizing at least one alkyl acrylate or methacrylate represented by the following general formula:CH.sub.2 .dbd.CRCOOR.sub.1wherein R stands for a hydrogen atom or methyl group, and R.sub.1 stands for an alkyl group having 1 to 8 carbon atoms, in an amount of at least 90% by weight, and (III) 0 to 50% by weight of a diene type rubber-containing thermoplastic resin, the sum of the amounts of the components (I), (II) and (III) being 100% by weight.

摘要翻译： 公开了一种树脂组合物，其可以用于外部制品而不被模制在制品中的表面上，并且色调优异并且具有良好的耐冲击性和耐候性，所述组合物包含（I）10至70重量％ 通过聚合50至10重量％的包含10至90重量％的至少一种芳族乙烯基单体和90至10重量％的至少一种的单体混合物（C）而获得的高橡胶含量的接枝聚合物 由以下通式表示的烯键式不饱和单体：CH 2 = CRX其中R代表氢原子或甲基，X代表基团-CN或-COOR1，其中R1代表具有1至8个碳原子的烷基， 在含有5〜30重量％的在橡胶粒子内部具有0.15〜0.40μm核心粒径的刚性交联树脂（A）的多层交联丙烯酸橡胶粒子的乳胶的存在下，在45〜 85重量％ （A），（B）和（C）成分的总量为100质量％的由丙烯酸酯作为主要成分的交联丙烯酸酯系聚合物（B） 重量，（II）90〜30重量％的通过聚合至少一种由以下通式表示的丙烯酸烷基酯或甲基丙烯酸烷基酯得到的热塑性树脂：CH2 = CRCOOR1其中R代表氢原子或甲基，R1代表 碳原子数为1〜8的烷基，至少90重量％，（III）0〜50重量％的含二烯系橡胶的热塑性树脂，成分的总量（ I），（II）和（III）为100重量％。