公开(公告)号：US5194643A

公开(公告)日：1993-03-16

申请号：US624652

申请日：1990-12-10

申请人： Thomas E. Nappier

发明人： Thomas E. Nappier

IPC分类号： C07C51/41 ,  C07C53/126

CPC分类号： C07C51/412

摘要： Gold carboxylates and a process for preparing gold salts of organic carboxylic acids are described. The gold carboxylates are represented by the formula ##STR1## in which R represents hydrogen or an organic group of valence y and x, y and z each represent a positive integer such that x=y.z/3. The process comprises reacting an alkali or alkaline earth metal salt of an organic carboxylic acid with a gold salt in an organic liquid which at least partially dissolves the alkali and/or alkaline earth metal salt, the gold salt, and the desired gold carboxylate product, but is not a solvent for the salt formed between the alkali or alkaline earth metal and the anion of the gold salt.

摘要翻译： 描述了羧酸金属盐和制备有机羧酸的金盐的方法。 金羧酸盐由式（I）表示，其中R表示氢或价数y的有机基团，x，y和z各自表示正整数，使得x = y.z / 3。 该方法包括使有机羧酸的碱金属或碱土金属盐与有机液体中的金盐反应，该有机液体至少部分地溶解碱金属盐和/或碱土金属盐，金盐和所需的金羧酸盐产物， 但不是在碱金属或碱土金属与金盐的阴离子之间形成的盐的溶剂。

公开(公告)号：US4824611A

公开(公告)日：1989-04-25

申请号：US800458

申请日：1985-11-21

申请人： Paul L. Cells

发明人： Paul L. Cells

IPC分类号： C07C53/126 ,  C07C51/00 ,  C07C51/41 ,  C07C67/00 ,  C07F9/00 ,  C07F11/00 ,  C07F13/00 ,  C08F299/04 ,  C08K5/09 ,  C08L67/00 ,  C08L67/06 ,  C09F9/00 ,  C10L1/18 ,  C10L1/188 ,  C10L10/08 ,  C10M117/02 ,  C10M129/26 ,  C10M129/32 ,  C10M129/40 ,  C10N10/10 ,  C10N10/12 ,  C10N10/14 ,  C10N40/08 ,  C10N40/20 ,  C10N40/25 ,  C10N50/10 ,  C11C1/00

CPC分类号： C10M129/40 ,  C07C51/412 ,  C07F11/005 ,  C07F13/005 ,  C07F9/005 ,  C08F299/0464 ,  C09F9/00 ,  C10L1/1881 ,  C10M129/32 ,  C10M2207/121 ,  C10M2207/122 ,  C10M2207/125 ,  C10M2207/129 ,  C10N2210/00

摘要： A process for preparing hydrocarbon-soluble transition metal salts of organic carboxylic acids having improved properties wherein the transition metal is one capable of having a multiplicity of oxidation states is described. The process comprises the steps of (a) providing at least one transition metal compound wherein the transition metal is at one of its higher positive oxidation states, (b) treating said transition metal compound with at least one inorganic reducing agent forming an intermediate containing the transition metal in a lower positive oxidation state, and (c) reacting said intermediate with at least one organic carboxylic acid containing at least 5 carbon atoms to form the transition metal salt of said carboxylic acid. The transition metal salts prepared in accordance with the process of the invention are useful in a variety of applications including resins, inks, paints, lubricants and fuels.

摘要翻译： 描述了具有改进性质的可溶于有机羧酸的过渡金属盐的方法，其中过渡金属是能够具有多种氧化态的过渡金属。 该方法包括以下步骤：（a）提供至少一种过渡金属化合物，其中过渡金属处于其较高的正氧化态之一，（b）用至少一种无机还原剂处理所述过渡金属化合物，形成含有 过渡金属处于较低的正氧化态，和（c）使所述中间体与至少一种含有至少5个碳原子的有机羧酸反应形成所述羧酸的过渡金属盐。 根据本发明方法制备的过渡金属盐可用于各种应用，包括树脂，油墨，油漆，润滑剂和燃料。

公开(公告)号：US4779735A

公开(公告)日：1988-10-25

申请号：US60781

申请日：1987-06-10

申请人： William C. Kelso, Jr.

发明人： William C. Kelso, Jr.

IPC分类号： B27K3/14 ,  B65D75/30 ,  B65D75/58 ,  B65D73/00

CPC分类号： E04H12/2292 ,  A01N25/34 ,  B65D75/30 ,  B65D75/58 ,  B27K3/14 ,  Y10S206/813

摘要： A wood-preservative package or bandage is disclosed which comprises: a first flexible sheet; a wood-preservative material having a grease-like consistency arranged in a layer upon said first flexible sheet; a perforated flexible sheet overlying said preservative material and secured to the marginal edge of said first flexible sheet, the perforations in said perforated flexible sheet being of sufficient number and dimension to permit said wood-preservative material to pass through said perforations; and another flexible sheet overlying and secured to said perforated flexible sheet. This wood-preservative package is particularly suitable for treating poles used for supporting telephone lines, power transmission lines and the like that have been held in stock for extended periods of time and for the ground-line treatment of such poles.

摘要翻译： 公开了防腐剂包或绷带，其包括：第一柔性片; 具有布置在所述第一柔性片上的层中的油脂状稠度的防木材料; 穿过所述防腐材料并固定到所述第一柔性片的边缘的穿孔柔性片，所述穿孔柔性片中的穿孔具有足够的数量和尺寸以允许所述木材防腐材料通过所述穿孔; 以及覆盖并固定到所述穿孔柔性片的另一柔性片。 这种木防腐包装特别适用于处理长时间保存的电话线，输电线路等用的杆，以及这些杆的地线处理。

公开(公告)号：US4532161A

公开(公告)日：1985-07-30

申请号：US598774

申请日：1984-04-19

申请人： Albert V. Collins ,  Richard W. Asmus

发明人： Albert V. Collins ,  Richard W. Asmus

IPC分类号： B27K3/36 ,  B27K3/38 ,  A01N55/02 ,  B05D1/18

CPC分类号： B27K3/36 ,  B27K3/08 ,  B27K3/22 ,  B27K3/32 ,  B27K3/343 ,  B27K3/38 ,  B27K3/52 ,  B27K5/001 ,  B27K5/02 ,  B27K2240/30

摘要： A process for impregnating green wood with oil-soluble metal salts is described. The method comprises(a) contacting the green wood with an aqueous system comprising(i) water,(ii) at least one oil-soluble metal salt of an organic carboxylic acid, and(iii) at least one surfactant for a period of time sufficient to enable the metal salt to penetrate into the wood, and(b) removing the wood from contact with the aqueous system. Good penetration of the metal salt into the green wood is realized by this method when conducted under vacuum, at atmospheric pressure or at elevated pressures. Preferably, the metal salt is a preservative such as a fungicide, and the aqueous system also contains other desirable components such as fire retardants, coloring agents and insecticides.

摘要翻译： 描述了用油溶性金属盐浸渍绿色木材的方法。 该方法包括（a）使绿色木材与水系统接触，所述水性体系包含（i）水，（ii）至少一种有机羧酸的油溶性金属盐，和（iii）至少一种表面活性剂一段时间 足以使金属盐渗透到木材中，和（b）除去木材与水系统的接触。 当在真空下，在大气压或高压下进行时，通过这种方法可以实现金属盐对绿色木材的良好渗透。 优选地，金属盐是防腐剂如杀真菌剂，并且水性体系还含有其它所需组分如阻燃剂，着色剂和杀虫剂。

公开(公告)号：US4162986A

公开(公告)日：1979-07-31

申请号：US881363

申请日：1978-02-27

申请人： Anthony Alkaitis ,  Paul L. Cells

发明人： Anthony Alkaitis ,  Paul L. Cells

IPC分类号： C09K3/00 ,  B01D53/14 ,  B01J27/00 ,  B01J31/00 ,  B01J31/22 ,  C07C51/41 ,  C07C53/126 ,  C07C53/128 ,  C07F1/08 ,  C07F13/00 ,  C07F15/02 ,  C07F15/04 ,  C07F15/06 ,  C07F19/00 ,  C10L1/188 ,  C10L1/24 ,  C10M159/18 ,  C10M159/20 ,  C10N10/02 ,  C10N10/14 ,  C10N10/16 ,  C10M1/40 ,  B21B45/02 ,  C10L1/32 ,  C10M1/24

CPC分类号： B01J31/2226 ,  B01D53/1493 ,  B01J31/04 ,  C07C51/414 ,  C07C53/126 ,  C07C53/128 ,  C07F13/005 ,  C07F15/025 ,  C07F15/045 ,  C07F15/065 ,  C10L1/188 ,  C10L1/2437 ,  C10M159/20 ,  B01J2231/70 ,  B01J2531/0216 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/84

摘要： Metallo-organic compositions soluble in oils and hydrocarbon solvents, of a high transitional metal content and highly overbased character, are prepared from sources of transitional metals (or of transitional in conjunction with nontransitional metals) reacted with mixed organic acids comprising at least one monocarboxylic acid and a second acid, either a sulfonic acid or a different molecular weight monocarboxylic acid. Formation of the complexes requires the use of excesses of metal over acids, and the use of an oxygen-supplying material such as air, regardless of whether the metal source be a free metal, an oxide or a hydroxide. Alkoxyalkanols or glycols may be used in addition to the required acids.These compositions comprise (1) a polynuclear core of a normally insoluble metal oxide or hydroxide which is crystalline by X-ray and electron diffraction observation, with metal hydroxyl carboxylate groups (and when present, sulfonate or alkoxyalkanol or glycol groups) ionically and hydrogen bonded to the core element atoms, and additional acid groups having an unbound association with a core and its bonded groups; (2) ultimate particles having structure with minimum average undissociated molecular weight of about 10.sup.4 ; and (3) a ratio of total moles of metal to total moles of organic acid moieties being greater than 1 to 1.

摘要翻译： 从含有至少一种单羧酸的混合有机酸反应的过渡金属（或与非过渡金属结合的过渡金属）的来源制备可溶于油和烃溶剂的金属有机组合物，其具有高过渡金属含量和高度过碱性特征。 和第二酸，磺酸或不同分子量的一元羧酸。 络合物的形成需要使用过量的金属超过酸，以及使用供氧材料如空气，而不管金属源是游离金属，氧化物还是氢氧化物。 除了所需的酸之外，还可以使用烷氧基醇或二醇。

公开(公告)号：US5210245A

公开(公告)日：1993-05-11

申请号：US852673

申请日：1992-03-17

申请人： Thomas E. Nappier

发明人： Thomas E. Nappier

IPC分类号： C07C51/41

CPC分类号： C07C51/412

摘要： Gold carboxylates and a process for preparing gold salts of organic carboxylic acids are described. The gold carboxylates are represented by the formula ##STR1## in which R represents hydrogen or an organic group of valence y and x, y and z each represent a positive integer such that x=y.multidot.z/3. The process comprises reacting an alkali or alkaline earth metal salt of an organic carboxylic acid with a gold salt in an organic liquid which at least partially dissolves the alkali and/or alkaline earth metal salt, the gold salt, and the desired gold carboxylate product, but is not a solvent for the salt formed between the alkali or alkaline earth metal and the anion of the gold salt.

摘要翻译： 描述了羧酸金属盐和制备有机羧酸的金盐的方法。 金羧酸盐由式（I）表示，其中R表示氢或价数y的有机基团，x，y和z各自表示正整数，使得x = yxz / 3。 该方法包括使有机羧酸的碱金属或碱土金属盐与有机液体中的金盐反应，该有机液体至少部分地溶解碱金属盐和/或碱土金属盐，金盐和所需的金羧酸盐产物， 但不是在碱金属或碱土金属与金盐的阴离子之间形成的盐的溶剂。

公开(公告)号：US5141562A

公开(公告)日：1992-08-25

申请号：US719317

申请日：1991-06-21

申请人： Paul L. Cells

发明人： Paul L. Cells

IPC分类号： C09D7/12 ,  C09D11/02 ,  C09F9/00

CPC分类号： C09D11/03 ,  C09F9/00

摘要： The present invention relates to a composition which comprises a zirconium salt of at least one organic carboxylic acid and an alkali metal or alkaline earth metal perborate. The compositions are useful in promoting the drying of ink compositions and particularly in printing inks used in the lithographic printing process.

公开(公告)号：US4633001A

公开(公告)日：1986-12-30

申请号：US682783

申请日：1984-12-18

申请人： Paul L. Cells

发明人： Paul L. Cells

IPC分类号： C08L67/00 ,  C07C51/41 ,  C07F9/00 ,  C07F11/00 ,  C07F13/00 ,  C08F299/04 ,  C08K5/09 ,  C08L67/06 ,  C09F9/00 ,  C10L1/188 ,  C10M129/32 ,  C10M129/40

CPC分类号： C10M129/40 ,  C07C51/412 ,  C08F299/0464 ,  C09F9/00 ,  C10L1/1881 ,  C10M129/32 ,  C10M2207/121 ,  C10M2207/122 ,  C10M2207/125 ,  C10M2207/129 ,  C10N2210/00

摘要： A process for preparing transition metal salt compositions of organic carboxylic acids having improved properties wherein the transition metal is one capable of having a multiplicity of oxidation states is described. The process comprises the steps of (a) providing at least one transition metal compound wherein the transition metal is at one of its higher positive oxidation states, (b) treating said transition metal compound with at least one reducing agent forming an intermediate containing the transition metal in a lower positive oxidation state, (c) reacting said intermediate with at least one organic carboxylic acid to form the transition metal salt of said carboxylic acid, and (d) mixing said transition metal salt formed in step (c) with (i) at least one antioxidant, or (ii) at least one additional metal salt wherein the additional metal is more electronegative than the transition metal, or (iii) mixtures of (i) and (ii). The transition metal salt compositions prepared in accordance with the process of the invention are useful in a variety of applications including resins, inks, paints, lubricants and fuels.

摘要翻译： 描述了具有改进性质的过渡金属盐组合物的制备方法，其中过渡金属是能够具有多种氧化态的化合物。 该方法包括以下步骤：（a）提供至少一种过渡金属化合物，其中过渡金属处于其较高的正氧化态之一，（b）用形成含过渡金属的中间体的至少一种还原剂处理所述过渡金属化合物 （c）使所述中间体与至少一种有机羧酸反应以形成所述羧酸的过渡金属盐，和（d）将步骤（c）中形成的所述过渡金属盐与（i ）至少一种抗氧化剂，或（ii）至少一种另外的金属盐，其中所述另外的金属比过渡金属更具有电负性，或（iii）（i）和（ii）的混合物。 根据本发明方法制备的过渡金属盐组合物可用于各种应用，包括树脂，油墨，油漆，润滑剂和燃料。

公开(公告)号：US4539235A

公开(公告)日：1985-09-03

申请号：US673188

申请日：1984-11-19

申请人： Albert V. Collins ,  Richard W. Asmus

发明人： Albert V. Collins ,  Richard W. Asmus

IPC分类号： A01N57/16 ,  A01N57/32 ,  B27K3/50 ,  B05D1/18 ,  C09D5/16

CPC分类号： A01N57/16 ,  A01N57/32 ,  B27K3/08 ,  B27K3/166 ,  B27K3/22 ,  B27K3/343 ,  B27K3/50 ,  B27K3/52 ,  B27K5/001 ,  Y10T428/662

摘要： A method for treating wood with an aqueous composition having fungicidal and insecticidal properties. The aqueous composition comprises(a) at least one oil-soluble metal salt of an organic carboxylic acid having fungicidal properties wherein the metal is zinc, chromium, iron, antimony, lead, mercury or a mixture thereof,(b) at least one halopyridyl phosphate of the formula ##STR1## wherein R represents a halopyridyl group, Z represents oxygen or sulfur, and each R' is independently a lower alkoxy, amino or lower alkylamino group,(c) at least one surfactant, and(d) from about 60 to 99% of water.Such compositions penetrate into both dry and green wood rather readily, and the result is wood which is resistant to fungi and insects.

摘要翻译： 用具有杀真菌性和杀虫性的含水组合物处理木材的方法。 含水组合物包含（a）至少一种具有杀真菌性的有机羧酸的油溶性金属盐，其中金属是锌，铬，铁，锑，铅，汞或其混合物，（b）至少一种卤代吡啶 磷酸酯，其中R代表卤代吡啶基，Z代表氧或硫，每个R'独立地是低级烷氧基，氨基或低级烷基氨基，（c）至少一种表面活性剂，和（d）约 60至99％的水。 这样的组合物相当容易地渗入干木和绿木，结果是耐真菌和昆虫的木材。

公开(公告)号：US4507152A

公开(公告)日：1985-03-26

申请号：US557770

申请日：1983-12-02

申请人： Albert V. Collins ,  Richard W. Asmus

发明人： Albert V. Collins ,  Richard W. Asmus

IPC分类号： A01N57/16 ,  A01N57/32 ,  B27K3/50 ,  C09D5/16

CPC分类号： A01N57/32 ,  A01N57/16 ,  B27K3/166 ,  B27K3/22 ,  B27K3/343 ,  B27K3/50 ,  B27K3/52

摘要： An aqueous composition having fungicidal and insecticidal properties is described which is useful particularly for treating wood. The aqueous composition comprises(a) at least one oil-soluble metal salt of an organic carboxylic acid having fungicidal properties wherein the metal is zinc, chromium, iron, antimony, lead, mercury or a mixture thereof,(b) at least one halopyridyl phosphate of the formula ##STR1## wherein R represents a halopyridyl group, Z represents oxygen or sulfur, and each R' is independently a lower alkoxy, amino or lower alkylamino group,(c) at least one surfactant, and(d) from about 60 to 99% of water.Such compositions penetrate into both dry and green wood rather readily, and the result is wood which is resistant to fungi and insects.

摘要翻译： 描述了具有杀真菌和杀虫性质的水性组合物，其特别用于处理木材。 含水组合物包含（a）至少一种具有杀真菌性的有机羧酸的油溶性金属盐，其中金属是锌，铬，铁，锑，铅，汞或其混合物，（b）至少一种卤代吡啶 磷酸酯，其中R代表卤代吡啶基，Z代表氧或硫，每个R'独立地是低级烷氧基，氨基或低级烷基氨基，（c）至少一种表面活性剂，和（d）约 60至99％的水。 这样的组合物相当容易地渗入干木和绿木，结果是耐真菌和昆虫的木材。