公开(公告)号：US4797416A

公开(公告)日：1989-01-10

申请号：US607

申请日：1987-01-05

申请人： Don R. Baker ,  Keith H. Brownell ,  Charles Kezerian

发明人： Don R. Baker ,  Keith H. Brownell ,  Charles Kezerian

IPC分类号： A01N47/20 ,  C07C67/00 ,  C07C325/00 ,  C07C333/08 ,  C07C155/02 ,  A01N47/10

CPC分类号： A01N47/20

摘要： Novel fungicidal carbanilates having the general structural formula ##STR1## wherein R is methoxy or allyloxy; R.sub.1 is selected from the group consisting of hydrogen, C.sub.2 -C.sub.4 alkoxyalkyl and formyl; and R.sub.2 is C.sub.1 -C.sub.6 alkyl, preferably C.sub.2 -C.sub.3 alkyl which are highly effective fungicides are disclosed herein.

公开(公告)号：US4743403A

公开(公告)日：1988-05-10

申请号：US584972

申请日：1984-03-01

申请人： Sreeramulu Nagubandi

发明人： Sreeramulu Nagubandi

IPC分类号： C07C381/12 ,  C07C20060101 ,  C07C67/00 ,  C07C313/00 ,  C07C325/00 ,  E05B20060101 ,  C07C149/06

CPC分类号： C07C381/12

摘要： Disclosed is a process for preparing organo-sulfonium halide of the formula ##STR1## wherein X is an halide, R.sub.1, R.sub.2 and R.sub.3 are the same or different and are selected from the group consisting of: alkyl having 1 to 24 carbon atoms, inclusive; allyl having 2 to 24 carbon atoms, inclusive; alkenyl having 2 to 24 carbon atoms, inclusive; alkynyl having 2 to 24 carbon atoms, inclusive; aryl having 6 to 24 carbon atoms, inclusive; and wherein said alkyl, allyl, alkenyl, alkynyl and aryl are optionally substituted with a group that is inert to organo-sulfides comprising: reacting an alcohol, e.g. methanol, with an halide derivative which when reacted with an organo-sulfide forms an organo-sulfonium halide, e.g., thionyl halide, sulfuryl halide and carbonyl halide; and then adding an organo-sulfide, e.g., dimethyl sulfide, to the above reaction mixture with agitation while allowing the gas formed to be eliminated so that the organo-sulfonium halide, e.g., trimethyl sulfonium halide, is formed. This process can take place in the presence of an insert solvent, e.g., methylene chloride.

摘要翻译： 公开了一种制备式IMA的有机锍卤化物的方法，其中X是卤化物，R 1，R 2和R 3相同或不同，并且选自：具有1至24个碳原子的烷基，包括 ; 具有2至24个碳原子的烯丙基; 具有2至24个碳原子的烯基; 具有2至24个碳原子的炔基; 具有6至24个碳原子的芳基（包括端值）; 并且其中所述烷基，烯丙基，烯基，炔基和芳基任选被对有机硫化物惰性的基团取代，所述基团包括：使醇， 甲醇与卤化物衍生物反应，当与有机硫化物反应形成有机卤化锍时，例如亚硫酰卤，硫酰卤和羰基卤; 然后在搅拌下向上述反应混合物中加入有机硫化物，例如二甲基硫醚，同时使形成的气体被除去，从而形成卤化锍 - 卤化锍等。 该方法可以在插入溶剂例如二氯甲烷的存在下进行。

公开(公告)号：US4739057A

公开(公告)日：1988-04-19

申请号：US880469

申请日：1986-06-30

申请人： Andrea Leone-Bay ,  Elliott Bay ,  Peter E. Timony

发明人： Andrea Leone-Bay ,  Elliott Bay ,  Peter E. Timony

IPC分类号： C07B39/00 ,  C07C17/00 ,  C07C17/16 ,  C07C67/00 ,  C07D213/61 ,  C07D239/30 ,  C07F9/535 ,  C07D239/24 ,  C07C19/08 ,  C07D213/24

CPC分类号： C07F9/535 ,  C07B39/00 ,  C07C17/16 ,  C07D213/61

摘要： A process for converting organic hydroxyl-containing compounds to halides which comprises reacting the hydroxyl-containing compound with a phosphorushalide reagent of formula: R.sub.n PX.sub.5-n wherein n is selected from 1, 2 and 3; R is selected from the group consisting of C-6 to C-10 aryl and substituted aryl wherein the substituents are selected from the group consisting of straight and branched chain alkyl, alkoxy, and haloalkyl, halogen, sulfonate and mixtures thereof; and X is a halogen. It is preferred to carry out the reaction in the presence of an arylphosphorusoxydihalide solvent. The use of an arylphosphorustetrahalide and particularly phenylphosphorustetrachloride is preferred. The arylphoshorustetrahalide can be prepared in situ by contacting a solution of the corresponding arylphosphorusdihalide in an arylphosphorusoxydihalide solvent with a halogen. The process can further comprise the step of heating the reaction mixture. Maintaining a reaction temperature of from about 0.degree. C. to about 150.degree. C. for from about 1 hour to about 24 hours is preferred.

公开(公告)号：US4727178A

公开(公告)日：1988-02-23

申请号：US885492

申请日：1986-07-14

申请人： Danielle A. Bright

发明人： Danielle A. Bright

IPC分类号： C07F9/42 ,  C07F9/20

CPC分类号： C07F9/20

摘要： S-substituted phosphorodichloridothiolates such as S-alkyl, cycloalkyl, aralkyl, and arylphosphorodichloridothiolates are prepared by reacting a sulfuryl chloride and a mercaptan or disulfide with phosphorus trichloride and a carboxylic acid anhydride.

摘要翻译： 通过使硫酰氯和硫醇或二硫化物与三氯化磷和羧酸酐反应来制备S-取代的二氯化硫代磷酸酯如S-烷基，环烷基，芳烷基和芳基二氯硫代硫酸酯。

公开(公告)号：US4652300A

公开(公告)日：1987-03-24

申请号：US649105

申请日：1984-09-10

申请人： Reed A. Gray ,  Daniel L. Hyzak

发明人： Reed A. Gray ,  Daniel L. Hyzak

IPC分类号： A01N25/22 ,  A01N57/30

CPC分类号： A01N25/22 ,  A01N57/30

摘要： Herbicidally active thiolcarbamates are employed in combination with certain organophosphorus compounds having the formula ##STR1## in which R.sup.4 is selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.4 alkoxy, and C.sub.1 -C.sub.4 alkylthio, R.sup.5 is selected from the group consisting of hydrogen and C.sub.1 -C.sub.4 alkyl, R.sup.6 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, and C.sub.2 -C.sub.4 alkoxyalkyl, R.sup.7 is selected from the group consisting of hydrogen and methyl and R.sup.8 is selected from the group consisting of hydrogen and methylthio. As a result, the herbicidal effectiveness of the thiocarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.

摘要翻译： 除草活性硫代氨基​​甲酸酯与某些具有式“IMAGE”的有机磷化合物组合使用，其中R 4选自C 1 -C 3烷基，C 1 -C 4烷氧基和C 1 -C 4烷硫基，R 5选自 的氢和C 1 -C 4烷基，R 6选自氢，C 1 -C 4烷基和C 2 -C 4烷氧基烷基，R 7选自氢和甲基，R 8选自氢 和甲硫基。 结果，硫代氨基甲酸酯的除草效力得到提高和延长，使除草剂的单次施用在更长的时间内有效。

公开(公告)号：US4650516A

公开(公告)日：1987-03-17

申请号：US144703

申请日：1980-04-28

申请人： Francis H. Walker

发明人： Francis H. Walker

IPC分类号： A01N25/32 ,  A01N37/18 ,  A01N37/46 ,  A01N37/00 ,  A01N43/36 ,  A01N43/38 ,  A01N43/40

CPC分类号： C07C255/00 ,  A01N25/32

摘要： .alpha.-Halo-.OMEGA.-haloalkylamide compounds have the following formula ##STR1## in which R is selected from the group consisting of chlorine and bromine;R.sub.1 is selected from the group consisting of chlorine and bromine, provided that it is different from R;R.sub.2 is selected from the group consisting of hydrogen and methyl; andR.sub.3 is selected from the group consisting of alkyl having 1 to 10 carbon atoms, alkynyl having 2 to 10 carbon atoms, cyanoalkyl having 2 to 10 carbon atoms, methoxy substituted cyanoalkyl having 2 to 10 carbon atoms, cyanocycloalkyl having 5 to 14 carbon atoms. The compounds are useful as antidotes for the protection of crops from herbicidal injury.

摘要翻译： α-羟基 - 欧米茄 - 卤代烷基酰胺化合物具有下式：其中R选自氯和溴; R1选自氯和溴，条件是它不同于R; R2选自氢和甲基; R3选自碳原子数为1〜10的烷基，碳原子数2〜10的炔基，碳原子数2〜10的氰基烷基，碳原子数2〜10的甲氧基取代的氰基烷基，碳原子数为5〜14的氰基环烷基 。 这些化合物可用作保护作物免受除草伤害的解毒剂。

公开(公告)号：US4636244A

公开(公告)日：1987-01-13

申请号：US630171

申请日：1984-07-12

申请人： Eugene G. Teach

发明人： Eugene G. Teach

IPC分类号： C07D263/04 ,  C07D277/04 ,  A01N43/78 ,  A01N43/76

CPC分类号： C07D263/04 ,  C07D277/04

摘要： Haloacyl and thiohaloacyl aryl-substituted oxazolidines and thiazolidines useful as active antidotes against crop injury when used with various herbicides; herbicidal compositions and utility of various herbicides and aryl substituted oxazolidines and thiazolidines having the formula ##STR1## wherein X and Y are independently oxygen or sulfur; R is haloalkyl or chloroalkenyl; R.sub.1 is hydrogen, lower alkyl, phenyl, naphthyl, substituted phenyl wherein said substituents are monofluoro, mono- or di- chloro, nitro, methyl, methoxy, or hydroxyl; R.sub.2 is hydrogen or lower alkyl; R.sub.3 is hydrogen, lower alkyl, hydroxymethyl, N-methyl carbamoyloxymethyl or dichloroacetoxymethyl; R.sub.4 is hydrogen or lower alkyl; R.sub.5 is hydrogen, lower alkyl or phenyl; and R.sub.6 is hydrogen; provided that at least one of R.sub.1 or R.sub.5 is phenyl, substituted phenyl or naphthyl.

摘要翻译： 当与各种除草剂一起使用时，可用作抗作物活性解毒剂的卤酰基和硫代卤代芳基取代的恶唑烷和噻唑啉; 各种除草剂和芳基取代的恶唑烷和噻唑烷的除草组合物和用途，其中X和Y独立地是氧或硫; R是卤代烷基或氯代烯基; R 1是氢，低级烷基，苯基，萘基，取代的苯基，其中所述取代基是单氟，单或二氯，硝基，甲基，甲氧基或羟基; R2是氢或低级烷基; R3是氢，低级烷基，羟甲基，N-甲基氨基甲酰氧基甲基或二氯乙酰氧基甲基; R4是氢或低级烷基; R5是氢，低级烷基或苯基; R6是氢; 条件是R 1或R 5中的至少一个为苯基，取代的苯基或萘基。

公开(公告)号：US4628120A

公开(公告)日：1986-12-09

申请号：US661440

申请日：1984-10-16

申请人： Genichi Tsuchihashi ,  Keisuke Suzuki

发明人： Genichi Tsuchihashi ,  Keisuke Suzuki

IPC分类号： C07D307/46 ,  B01J31/00 ,  B01J31/14 ,  C07B31/00 ,  C07B53/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/51 ,  C07C45/52 ,  C07C45/54 ,  C07C49/215 ,  C07C49/217 ,  C07C49/225 ,  C07C49/255 ,  C07C49/782 ,  C07C49/784 ,  C07C67/00 ,  C07C301/00 ,  C07C303/28 ,  C07C309/64

CPC分类号： C07C45/512 ,  C07C45/54 ,  C07C49/782

摘要： A preparing method of optically active ketones given by a general formula ##STR1## (wherein R represents a hydrocarbon group having 2 to 20 carbon atoms and R' represents a hydrocarbon group having 1 to 20 carbon atoms. The hydrocarbon groups of R and R' may contain functional groups having no influence on the reaction. But, * represents an asymmetric carbon atom, and R represents a more electron donating group than R' (except when R=R') through the rearrangement reaction by using organoaluminum compound.

摘要翻译： 由通式（IMAGE）（其中R表示碳原子数2〜20的烃基，R'表示碳原子数1〜20的烃基）的光学活性酮的制造方法，R和R' 可以含有对反应没有影响的官能团，但是*表示不对称碳原子，R表示通过使用有机铝化合物通过重排反应而比R'（除了R = R'）以外的给电子基团。

公开(公告)号：US4623384A

公开(公告)日：1986-11-18

申请号：US822344

申请日：1986-01-24

申请人： William J. Michaely ,  Christopher Knudsen

发明人： William J. Michaely ,  Christopher Knudsen

IPC分类号： A01N37/44 ,  A01N37/34 ,  C07C121/78

CPC分类号： A01N37/44

摘要： A compound having the structural formula ##STR1## wherein R is halogen, including fluorine, chlorine, bromine and iodine, preferably chlorine; methyl, ethyl, ethenyl, methoxy, nitro, trifluoromethyl or cyano; R.sub.1 is hydrogen, methyl, ethyl, or allyl; and X is in either the 2- or 3-position and is hydrogen, 2-methyl, 3-methyl, 2-chlorine, 3-chlorine, 2-fluorine, 3-fluorine or 2-methoxy and their use as postemergent herbicides.

摘要翻译： 具有结构式的化合物，其中R是卤素，包括氟，氯，溴和碘，优选氯; 甲基，乙基，乙烯基，甲氧基，硝基，三氟甲基或氰基; R1是氢，甲基，乙基或烯丙基; X为2-或3-位，为氢，2-甲基，3-甲基，2-氯，3-氯，2-氟，3-氟或2-甲氧基，它们用作出芽后除草剂。

公开(公告)号：US4439541A

公开(公告)日：1984-03-27

申请号：US386584

申请日：1982-06-09

申请人： Masaru Takitani ,  Shizuo Tomiyasu ,  Keikichi Baba

发明人： Masaru Takitani ,  Shizuo Tomiyasu ,  Keikichi Baba

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A catalytic component for polymerization of an .alpha.-olefin is prepared by allowing an organo-magnesium compound expressed by the generic formula of RMgX (wherein R represents a hydrocarbon group having 1 to 20 carbon atoms and X a halogen atom or a hydrocarbon group having 1 to 20 carbon atoms) to react with carbon tetrahalide in the presence of an electron donor compound to obtain a solid product; by treating the solid product with phenols at 90.degree. to 180.degree. C.; and by further treating the phenol treated solid with a halogenated titanium compound. Homo- or co-polymerization of an .alpha.-olefin is carried out in the presence of a catalyst composition consisting of the catalytic component thus prepared and an organo-aluminum compound.

摘要翻译： 通过使由通式RMgX表示的有机镁化合物（其中R表示具有1至20个碳原子的烃基，X表示卤素原子或具有1个碳原子的烃基）制备用于聚合α-烯烃的催化组分 至20个碳原子）与电子给体化合物存在下与四卤化碳反应得到固体产物; 通过在90℃至180℃下用酚类处理固体产物。 并通过用卤化钛化合物进一步处理酚处理的固体。 在由如此制备的催化组分和有机铝化合物组成的催化剂组合物的存在下进行α-烯烃的均聚或共聚。