公开(公告)号：US07345128B2

公开(公告)日：2008-03-18

申请号：US10834438

申请日：2004-04-29

Applicant: Rui Resendes ,  Adam Gronowski

Inventor： Rui Resendes ,  Adam Gronowski

IPC: C08F210/10 ,  C08F110/10

CPC classification number: C08K5/14 ,  C08L23/22

Abstract: The present invention relates to a peroxide curable rubber compound comprising at least one elastomeric polymer comprising repeating units derived from at least one C4 to C7 isomonoolefin monomer, at least one C4 to C14 multiolefin monomer and at least one m- or p-alkylstyrene monomer.

Abstract translation: 本发明涉及一种过氧化物可固化橡胶化合物，其包含至少一种弹性体聚合物，所述弹性体聚合物包含衍生自至少一种C 4至C 7异单烯烃单体的重复单元，至少一个C 与C 14-14多烯烃单体和至少一种间 - 或对 - 烷基苯乙烯单体反应。

公开(公告)号：US20070276084A1

公开(公告)日：2007-11-29

申请号：US10577888

申请日：2003-10-02

Applicant: Adam Gronowski ,  Stephan Glander

Inventor： Adam Gronowski ,  Stephan Glander

IPC: C08K3/00 ,  C09J7/00

CPC classification number: C08L23/22 ,  C09J7/10 ,  C09J2423/00 ,  C08L2666/02

Abstract: The present invention relates to a substantially gel-free sealant or adhesive compound comprising butyl-type polymer without any conjugated aliphatic diene in its composition having an average molecular weight Mn of more than 20,000 g/mol and containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. In another of its aspects, the present invention relates to a self-supporting shaped article comprising said compound optionally layered on or interposed between one or more supporting means. In still another of its aspects, the present invention relates to a tape comprising said substantially gel-free compound optionally layered on or interposed between one or more supporting means. In still another of its aspects, the present invention relates to an adhesive composition comprising said substantially gel-free compound. In still another of its aspects, the present invention relates to a sealant composition comprising said substantially gel-free compound.

Abstract translation: 本发明涉及一种基本上不含凝胶的密封剂或粘合剂，其包含其组成中没有任何共轭脂族二烯的丁基型聚合物，其平均分子量M n大于20,000g / mol，并且含有 小于15重量％ ％的固体物质不溶于沸腾的环己烷中回流60分钟。 在其另一方面，本发明涉及一种自支撑成形制品，其包括任选地层叠在一个或多个支撑装置上或插入在一个或多个支撑装置之间的所述化合物。 在其另一方面，本发明涉及一种包含所述基本上不含凝胶的化合物的带，任选地层压在一个或多个支撑装置上或插入在一个或多个支撑装置之间。 在另一方面，本发明涉及包含所述基本上不含凝胶的化合物的粘合剂组合物。 在其另一方面，本发明涉及包含所述基本上不含凝胶的化合物的密封剂组合物。

公开(公告)号：US07214741B2

公开(公告)日：2007-05-08

申请号：US10915619

申请日：2004-08-10

Applicant: Rui Resendes ,  Adam Gronowski

Inventor： Rui Resendes ,  Adam Gronowski

IPC: C08C19/04 ,  C08F8/06

CPC classification number: C08L23/22 ,  C08L2666/02

Abstract: The present invention relates to a peroxide curable rubber compound containing at least one elastomeric polymer comprising repeating units derived from at least one C4 to C7 isomonoolefin monomer, at least one C4 to C14 multiolefin monomer, at least one p- or m-alkylstyrene monomer and at least one co-agent.

Abstract translation: 本发明涉及含有至少一种弹性体聚合物的过氧化物可固化橡胶化合物，所述弹性聚合物包含衍生自至少一种C 4〜C 7异单烯烃单体的重复单元，至少一个C 4-14碳烯单体，至少一种对或间烷基苯乙烯单体和至少一种助剂。

公开(公告)号：US07081502B2

公开(公告)日：2006-07-25

申请号：US10676916

申请日：2003-10-01

Applicant: Adam Gronowski ,  Akhtar Osman ,  Stephan Glander

Inventor： Adam Gronowski ,  Akhtar Osman ,  Stephan Glander

IPC: C08F10/10 ,  C08L9/00

CPC classification number: C08F210/10 ,  C08F210/12 ,  C08L23/22 ,  C08F4/14 ,  C08F212/36 ,  C08F2500/17 ,  C08F236/08

Abstract: The present invention relates to a shaped article containing at least one peroxide curable compound containing a butyl-like polymer(s) without any conjugated aliphatic diene in its composition, said polymer containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. The present invention also relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a butyl-like polymer containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. Further, the present invention relates to a process for producing a butyl-like polymer having no conjugated aliphatic diene in its composition and containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. In addition, the present invention relates to a process the manufacturing of the inventive compound wherein the elastomeric polymer is mixed with at least one filler and at least one peroxide curing system in a mixing means.

Abstract translation: 本发明涉及含有至少一种含有在其组成中不含任何共轭脂族二烯的丁基样聚合物的过氧化物可固化化合物的成型制品，所述聚合物含有小于15wt。 ％的固体物质不溶于沸腾的环己烷中回流60分钟。 本发明还涉及一种密封材料和医疗装置，其包含至少一种含有小于15wt。的叔丁基聚合物的过氧化物可固化化合物。 ％的固体物质不溶于沸腾的环己烷中回流60分钟。 此外，本发明涉及其组成中不含共轭脂族二烯的丁基样聚合物的制备方法，其含量小于15wt。 ％的固体物质不溶于沸腾的环己烷中回流60分钟。 此外，本发明涉及制造本发明化合物的方法，其中弹性体聚合物与混合装置中的至少一种填料和至少一种过氧化物固化体系混合。

公开(公告)号：US09309333B2

公开(公告)日：2016-04-12

申请号：US12999669

申请日：2009-07-09

Applicant: Hanns-Ingolf Paul ,  Rolf Feller ,  John Lovegrove ,  Adam Gronowski ,  Andreas Jupke ,  Martin Hecker ,  Jörg Kirchhoff ,  Rainer Bellinghausen

Inventor： Hanns-Ingolf Paul ,  Rolf Feller ,  John Lovegrove ,  Adam Gronowski ,  Andreas Jupke ,  Martin Hecker ,  Jörg Kirchhoff ,  Rainer Bellinghausen

IPC: C08F36/00 ,  C08F110/10 ,  C08F8/20 ,  C08F8/22

CPC classification number: C08F8/20 ,  C08F8/22 ,  Y02P20/124 ,  Y02P20/125 ,  C08F210/12

Abstract: An integrated process for the solution polymerization and subsequent halogenation of butyl rubber in a common medium is disclosed. The process comprises providing a solution polymerization reactor containing a C6 medium mixed with a monomer mixture comprising at least an isoolefin monomer and a multiolefin monomer in a mass ratio of monomer mixture to medium of from 61:39 to 80:20. Once polymerized, residual unreacted monomer mixture is separated from the rubber solution using a distillation process. The residual monomers may then be purified and recycled back into the reactor. The separated rubber solution is then halogenated. The process obviates the need for separating the rubber from the medium following polymerization, then re-dissolving it in another solvent for halogenation, thereby saving energy cost. The process optionally employs heat exchangers for the reactor feed streams to further reduce energy consumption.

Abstract translation: 公开了一种用于普通介质中的丁基橡胶的溶液聚合和随后卤化的整合方法。 该方法包括提供一种溶液聚合反应器，其包含与包含至少异构烯烃单体和多烯烃单体的单体混合物的C6介质，其中单体混合物的质量比为61:39至80:20。 一旦聚合，残留的未反应单体混合物就使用蒸馏方法从橡胶溶液中分离出来。 然后可以将残留的单体纯化并循环回到反应器中。 然后将分离的橡胶溶液卤化。 该方法消除了在聚合之后将橡胶与介质分离的需要，然后将其再溶解在另一溶剂中用于卤化，由此节省了能量成本。 该方法任选地使用反应器进料流的热交换器来进一步降低能量消耗。

公开(公告)号：US09273161B2

公开(公告)日：2016-03-01

申请号：US13522762

申请日：2011-01-17

Applicant: Carsten Kreuder ,  Adam Gronowski ,  John Lovegrove ,  Hanns-Ingolf Paul ,  Rolf Feller ,  Udo Wiesner

Inventor： Carsten Kreuder ,  Adam Gronowski ,  John Lovegrove ,  Hanns-Ingolf Paul ,  Rolf Feller ,  Udo Wiesner

IPC: C08F8/22 ,  B60C1/00

CPC classification number: C08F8/22 ,  B60C1/00 ,  C08F210/12

Abstract: The invention relates to an energy efficient, environmentally favorable process for the preparation of halogenated rubbers, in particular chloro- and bromobutyl rubber, that uses a common aliphatic medium of specific composition for both solution polymerization and subsequent halogenation of the rubber. More particularly, the invention relates to a process that employs a common aliphatic medium for both solution polymerization and halogenation of rubber with intermediate removal of un-reacted monomers.

Abstract translation: 本发明涉及用于制备卤化橡胶，特别是氯代和溴化丁基橡胶的能量有效，环境友好的方法，其使用具有特定组成的普通脂族介质用于溶液聚合和随后的橡胶卤化。 更具体地说，本发明涉及一种使用普通脂肪族介质进行溶液聚合和橡胶卤化的方法，同时中间除去未反应的单体。

公开(公告)号：US09273160B2

公开(公告)日：2016-03-01

申请号：US13522756

申请日：2011-01-17

Applicant: Adam Gronowski ,  Carsten Kreuder ,  John Lovegrove ,  Paul Nguyen ,  David Thompson ,  Hanns-Ingolf Paul ,  Rolf Feller ,  Udo Weisner

Inventor： Adam Gronowski ,  Carsten Kreuder ,  John Lovegrove ,  Paul Nguyen ,  David Thompson ,  Hanns-Ingolf Paul ,  Rolf Feller ,  Udo Weisner

IPC: C08F8/22 ,  C08C19/14 ,  C08F2/06 ,  C08F6/00 ,  C08F210/12

CPC classification number: C08F8/22 ,  C08C19/14 ,  C08F2/06 ,  C08F6/003 ,  C08F210/12 ,  C08L23/283 ,  C08F236/08

Abstract: The invention relates to an energy efficient, environmentally favorable process for the preparation of brominated rubbers, in particular bromobutyl rubber, that uses a common medium for both solution polymerization and subsequent bromination of the rubber and which further exhibits an enhanced bromine usage due to the use of a oxidizing agent. More particularly, the invention relates to a process that employs a common aliphatic medium for both solution polymerization and bromination of rubber in the presence of a brominating agent and an oxidizing agent with intermediate removal of un-reacted monomers.

Abstract translation: 本发明涉及一种用于制备溴化橡胶，特别是溴化丁基橡胶的能量效率高，环境友好的方法，其使用普通介质进行溶液聚合和随后的溴化溴化，并且由于使用而进一步显示出增强的溴用量 的氧化剂。 更具体地说，本发明涉及一种在溴化剂和氧化剂存在下使用普通脂族介质进行溶液聚合和溴化溴化的方法，同时中间除去未反应的单体。

公开(公告)号：US20060264575A1

公开(公告)日：2006-11-23

申请号：US11135148

申请日：2005-05-23

Applicant: Adam Gronowski ,  Akhtar Osman ,  Andrew Carr

Inventor： Adam Gronowski ,  Akhtar Osman ,  Andrew Carr

IPC: C08F8/00

CPC classification number: C08L51/04 ,  C08F210/18 ,  C08F255/00 ,  C08F255/02 ,  C08F255/10 ,  C08K5/0025 ,  C08L23/16 ,  C08L23/22 ,  C08L51/06 ,  C08L2312/00 ,  C08L2312/02 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/06 ,  C08F236/00

Abstract: The present invention is directed to a peroxide curable rubber compound containing a butyl rubber polymer, an olefin polymer of ethylene, at least one alpha-olefin and optionally at least one diene, and a non-polymeric multi-unsaturated peroxide curable compound. The present invention is also directed to a peroxide curable rubber compound containing a butyl polymer, an EPDM rubber polymer and divinylbenzene or di- or tri-(meth)acrylate. Also the present invention is directed to a process for preparing a peroxide curable rubber compound by mixing a butyl rubber polymer, a polymer of ethylene, at least one α-olefin and optionally, at least one diene and non-polymeric multi-unsaturated peroxide curable cure modifier in the presence of a peroxide curing agent.

Abstract translation: 本发明涉及含有丁基橡胶聚合物，乙烯的烯烃聚合物，至少一种α-烯烃和任选的至少一种二烯的非过氧化物可固化的橡胶化合物和非聚合的多不饱和过氧化物可固化化合物。 本发明还涉及含有丁基聚合物，EPDM橡胶聚合物和二乙烯基苯或二 - 或三（甲基）丙烯酸酯的过氧化物可固化橡胶化合物。 本发明还涉及通过将丁基橡胶聚合物，乙烯聚合物，至少一种α-烯烃和任选的至少一种二烯和非聚合多不饱和过氧化物可固化的可聚合物 在过氧化物固化剂存在下的固化改性剂。

公开(公告)号：US20060106148A1

公开(公告)日：2006-05-18

申请号：US10994135

申请日：2004-11-19

Applicant: Adam Gronowski ,  Yong Seow ,  Shunji Baba ,  Rui Resendes

Inventor： Adam Gronowski ,  Yong Seow ,  Shunji Baba ,  Rui Resendes

IPC: C08K3/34

CPC classification number: C08J3/243 ,  C08J2323/22 ,  C08K5/0025 ,  C08K5/14 ,  C08L23/22

Abstract: The present invention is directed to a peroxide cured rubber composition containing a non-crosslinked or significantly non-crosslinked (

Abstract translation: 本发明涉及含有非交联或显着非交联（<10重量％凝胶）丁基橡胶聚合物，多烯烃交联剂，过氧化物固化剂和至少一种填料的过氧化物硫化橡胶组合物。 本发明还涉及一种制备过氧化物硫化橡胶组合物的方法，其包括将非交联或显着非交联的丁基橡胶与多烯烃交联剂，至少一种填料和过氧化物固化剂混合，其中该方法 不包括添加非过氧化物固化剂如硫，醌类，树脂和硫供体。

公开(公告)号：US06974851B2

公开(公告)日：2005-12-13

申请号：US10436616

申请日：2003-05-13

Applicant: Adam Gronowski ,  Susmita Bhattacharjee ,  Gabor Kaszas

Inventor： Adam Gronowski ,  Susmita Bhattacharjee ,  Gabor Kaszas

IPC: C08L23/20 ,  C08F210/12 ,  C08J3/24 ,  C08K3/00 ,  C08K5/01 ,  C08K5/14 ,  C08L23/22 ,  H01M8/00 ,  C08K3/34 ,  C08C19/00 ,  C08F112/36 ,  C08F236/00 ,  C08L9/00

CPC classification number: C08K5/14 ,  C08L23/22 ,  C08L21/00

Abstract: The present invention relates to a shaped article for high purity applications containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In another of its aspects, the present invention relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to a fuel cell containing at least one peroxide curable compound containing a substantially gel-free butyl polymer. In still another of its aspects, the present invention relates to halogen-free and sulfur-free shaped articles.

Abstract translation: 本发明涉及含有至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物的用于高纯度应用的成型制品。 在另一个方面，本发明涉及一种密封材料和医疗装置，其包含至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物。 在其另一方面，本发明涉及一种含有至少一种含有基本上不含凝胶的丁基聚合物的过氧化物可固化化合物的燃料电池。 在其另一方面，本发明涉及无卤素和无硫成型制品。